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1.
《Marine pollution bulletin》2008,56(10-12):505-511
Specimens of Nassarius nitidus were collected in seven stations of the Venice Lagoon to assess the levels of tributyltin (TBT) and its metabolites monobutyltin and dibutyltin in the tissues and monitor their effect on organisms, in particular the phenomenon of imposex (superimposition of male sexual characteristics on females). The following values of population indices were found: vas deferens sequence: 1.2 ± 0.7–4.0 ± 0.5; relative penis length: 6–47%. The least impacted station was situated in the northern part of the Lagoon, where females without imposex were found and Butyltin (BuTs) concentrations in the organisms (average sum of BuTs = 43 ± 14 ng Sn g−1 w.) were significantly lower than in the other stations (range of average sum of BuTs: 101 ± 22–217 ± 27 ng Sn g−1 d.w.). Population indices were found to be related to the TBT content in the tissues. In particular VDSI had a significant logarithmic correlation: r = 0.95, n = 8, p < 0.05.  相似文献   

2.
《Marine pollution bulletin》2012,65(12):2877-2884
We investigated heavy metal concentrations of zinc (Zn), copper (Cu), chromium (Cr), and lead (Pb), their spatial distribution and enrichment factor index in surface sediments of the Gorgan Bay. Sediment Quality Guidelines were also applied to assess adverse biological effects of these metals. Heavy metals were determined by inductively coupled plasma-mass spectroscopy (ICP-MS). The results indicated mean concentrations (ppm) of heavy metals were (mean ± S.D.) Pb: 11.5 ± 4.88, Cu: 18 ± 8.83, Zn: 42 ± 22.15 and Cr: 32 ± 15.19. Based on Enrichment index, the Gorgan Bay is a low-enriched to non-enriched bay. Heavy metal contents were lower than the standard limits of PEL, ERL, and ERM that reveal no threatening influence of the metals in the Bay.  相似文献   

3.
《Journal of Geodynamics》2010,49(3-5):253-259
We observe the Earth tidal fields at diurnal and semi-diurnal periods using Kinematic Precise Point Positioning (KPPP) GPS analysis. Our KPPP GPS solutions compare well with super-conducting gravimeter (SG) observations and a theoretical Earth tidal model, that includes both ocean tide loading model and body tides. We make a high resolution map of the observed Earth tidal response fields using the Japanese GEONET GPS network which consists of 1200 sites. We find that: (1) the average phase of GPS data lags 0.11 ± 0.04° from our theoretical Earth tidal model, (2) the average amplitude ratio between GPS and the theoretical Earth tidal model is 1.007 ± 0.003, (3) the amplitude in the Kyushu district is about 1.0–1.5 ± 0.3% larger than in the Hokkaido district, and (4) the amplitude at the Japan Sea side is about 0.5 ± 0.2% larger than that at the Pacific Ocean side. These results suggest that we may be able to place constraints on Earth structure using GPS-derived tidal information.  相似文献   

4.
《Marine pollution bulletin》2014,78(1-2):165-172
The concentrations of PCB congeners in the blubber and liver of mother Steller sea lions (Eumetopias jubatus; SSLs) and their fetuses from the coast of Hokkaido, Japan in 2008, 2010 and 2012 were analyzed by HRGC–HRMS, in order to elucidate PCB congener profiles and maternal-to-fetal transfer of PCBs in SSLs. ΣPCBs in the fetuses were 1400 ± 660 (the mean ± SD) ng/g-fat in the blubber and 570 ± 320 ng/g-fat in the liver, respectively. There was a concern that SSLs had been contaminated by PCBs during the fetal period. The concentrations of the major congeners in the blubber and liver were a correlation between the fetus and mother (blubber: r = 0.9934, liver: r = 0.9160; P ≦ 0.05). The results indicated that PCBs in the fetuses came from the mothers. #177 and #199 showed no correlations between the fetus and the mother in the blubber and liver. This indicated a selective capture by some natural protector such as the placenta.  相似文献   

5.
40Ar / 39Ar incremental heating ages for twenty one grains of cryptomelane, collected at 0, 42, 45, and 60 m depths in the Cachoeira Mine weathering profile, Minas Gerais, permit calculating long-term (10 Ma time scale) weathering rate (saprolitization rate) in SE Brazil. Pure well-crystallized cryptomelane grains with high K contents (3–5 wt.%) yield reliable geochronological results. The 40Ar / 39Ar plateau ages obtained decrease from the top to the bottom of the profile (12.7 ± 0.1 to 7.6 ± 0.1 Ma at surface; 7.6  ± 0.2 to 6.1 ± 0.2 Ma at 42 m; and 7.1 ± 0.2 to 5.9 ± 0.1 Ma at 45 m; 6.6 ± 0.1 to 5.2 ± 0.1 Ma at 60 m), yielding a weathering front propagation rate of 8.9 ± 1.1 m/m.y. From the geochronological results and the mineral transformations implicit by the current mineralogy in the weathering profiles, it is possible to calculate the saprolitization rate for the Cachoeira Mine lithologies and for adjacent weathering profiles developed on granodiorites and schists. The measured weathering front propagation rate yields a saprolitization rate of 24.9 ± 3.1 t/km2/yr. This average long-term (> 10 Ma) saprolitization rate is consistent with mass balance calculations results for present saprolitization rates in weathering watersheds. These results are also consistent with long-term saprolitization rates estimated by combining cosmogenic isotope denudation rates with mass balance calculations.  相似文献   

6.
We report a large cyst bed of the potentially toxic and bloom-forming dinoflagellate Alexandrium tamarense species complex in bottom sediments from the port of Halifax, Nova Scotia, Canada. The average cyst concentrations of that species ranged from 4033 ± 2647 to 220 872 ± 148 086 cysts g?1 of dry sediments and the highest concentrations were found near ship terminals in Bedford Basin. Although this species is endemic to this region, our work strongly suggests that some of the cysts of A. tamarense species complex found in the port of Halifax were introduced through discharged ballast water and sediments.  相似文献   

7.
《Marine pollution bulletin》2014,78(1-2):224-229
The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in the sediment from the Hormuz strait, Persian Gulf. The sum of 16 PAHs (ΣPAH) concentrations varied from 72.17 to 277.77 ng g−1 dry weight, with an average value of 131.20 ± 59.29 ng g−1 dry weight. An ecological risk assessment of PAHs, indicated that adverse biological effects caused by acenaphthene and acenaphthylene occasionally may take place in the sediment of Hormuz strait. PAH source identification showed that the PAHs in the sediments come from pyrogenic and mixed origin. Based on classification of pollution levels, sediments from Hormuz strait could be considered as low to moderately polluted with PAHs.  相似文献   

8.
The Chinese Continental Scientific Drilling (CCSD) project is located at the Sulu ultrahigh-pressure metamorphic (UHPM) belt. It offers a unique opportunity for studying the radiogenic heat production of both shallower and deeper rocks. Based on the concentrations of radiogenic elements U, Th and K on 349 samples from main hole of CCSD (CCSD MH), pilot holes and exposures, we determined radiogenic heat productions of all major rock types in the Sulu UHPM belt. Results show the mean values of orthogneiss and paragneiss are respectively 1.65 ± 0.81 and 1.24 ± 0.61 µW m? 3. Due to different composition and grade of retrogressive metamorphism, the eclogites display significant scatter in radiogenic heat production, ranging from 0.01 to 2.85 µW m? 3, with a mean of 0.44 ± 0.55 µW m? 3. The radiogenic heat production in ultramafic rocks also varies within a large range of 0.02 to 1.76 µW m? 3, and the average turns out to be 0.18 ± 0.31 µW m? 3. Based on the measurements and crustal petrologic model, the vertical distribution model of heat production in Sulu crust is established. The resulting mean heat production (0.76 µW m? 3) contributes 24 mW m? 2 to the surface heat flow. 1-D thermal model indicates that the temperature at the Moho reaches above 750 °C, and the thermal thickness of the lithosphere is ~ 75 km, in good agreement with the geophysical results. The high teat flow (~ 75 mW m? 2) together with thin lithosphere presents strong support for the extension events during the late Cretaceous and Cenozoic.  相似文献   

9.
The aim of this paper concerns Miocene igneous activity in the Alboran Sea and Peri-Alboran area (northern Morocco, western Algeria and Betic Cordilleras in Spain), considering its age and its location with regard to major tectonics structures.We have compiled previous K-Ar isotopic ages of lavas and plutonic boulders and intrusives with an error of ±1σ and completed this set by a new K-Ar isotopic age for andesitic tuffites from Alboran Island. Geochemistry of most of these samples has been considered after previous analyses completed with new data for Spain magmatism. These two sets of data allow us to place the magmatic activity within the regional stratigraphy and tectonics and their chronological framework of the three major tectonic phases of the Maghrebian orogen, at 17 Ma (Burdigalian), 15 Ma (Langhian) and 9 Ma (Tortonian). Petro-geochemical characteristics are compared through time and geographical locations. A major goal of this coupled approach is to help the elaboration of possible geodynamical processes.As an application, we present the case study of the Dellys, Djinet and Thenia region (east of Algiers) where the successive magmatic events between 19.4 ± 1 and 11.6 ± 0.5 Ma are closely related to the local tectonics and sedimentation.The Peri-Alboran igneous activity is placed in a multidisciplinary framework. Timing of activity is defined according to the ages of the neighbouring sedimentary units and the K-Ar ages of igneous rocks.In Spain, the Cabo de Gata-Carboneras magmatic province displays late Oligocene and early Miocene leucogranitic dikes, dated from 24.8 ± 1.3 to 18.1 ± 1.2 Ma; three following andesitic to rhyolitic events took place around 15.1 ± 0.8 to 14.0 ± 0.7 Ma, 11.8 ± 0.6 to 9.4 ± 0.4 Ma, 8.8 ± 0.4 to 7.9 ± 0.4 Ma; this last event displays also granitic rocks. Lamproitic magmas dated between 8.4 ± 0.4 and 6.76 ± 0.04 Ma were emplaced after the Tortonian phase.In Morocco, after the complex building of the Ras Tarf volcanic edifice, major calc-alkaline to shoshonitic volcanoes were built between 9.0 ± 0.5 and 4.8 ± 0.5 Ma, in particular the large Gourougou volcanic complex. Near Oujda, volcanic activity of alkaline affinity leads to multiple emissions of basalts throughout Pliocene times until the beginning of Pleistocene, between 6.2 ± 0.3 and 1.5 ± 0.1 Ma.In the Alboran domain, an age of 19.7 ± 0.8 Ma is reported (this study) for the andesitic tuffites that form the emergent part of the Alboran Island. This age is comparable to that of the Algerian tuffites and cherts “silexites” and the Malaga ones in Spain. Younger activity, completely separated from the previous one, forms the low-K basaltic andesitic dikes from Alboran Island, dated between 9.1 ± 0.5 and 7.5 ± 0.3 Ma. Along the Alboran Ridge both low-K and high-K andesites to dacites were emitted in the estimated range of 10.7–8.7 Ma. Low-K and high-K andesites to dacites sampled at ODP sites 977 and 978 into the East Alboran Basin, are dated between 12.1 ± 0.2 and 9.3 ± 0.1 Ma.We propose to relate with the Trans-Alboran lineament only the post-Tortonian igneous activity younger than 9 Ma.  相似文献   

10.
A feasibility study was carried out to evaluate the application of perennial/annual plant species in a phytoextraction process of a previously washed industrial urban soil contaminated by nickel, arsenic and cupper. The plant species selected for this study were Ipomea (Ipomea variada); grass (Poa pratensis); grass mixture (Festuca rubra, Cynodon dactylon, Lolium multiforum, Pennisetum sp.); Monks Cress (Tropaeolum majus); ficus (Ficus benajamina) and fern (Pteris cretica). Soil was characterized and it presented the following heavy metals concentrations (dry weight): 80 mg of Ni/kg, 456–656 mg of As/kg and 1684–3166 mg of Cu/kg. Germination and survival in contaminated soil tests were conducted, from these, P. pratensis was discarded and the rest of plant species tested were used for the phytoextraction selection test. After 4 months of growth, biomass production was determined, and content of Ni, As and Cu was analyzed in plant’s tissue. Metal biological absorption coefficient (BAC), bio-concentration factor (BCF) and translocation factor (TF), were calculated.Regarding to biomass generation it was observed, in every case, an inhibition of the plant growth compared with blanks sown in a non contaminated soil; inhibition ranged from 22.5% for the Monk cress to 98% for Ipomea. Even though the later presented high BAC, BCF and TF, its growth was severely inhibited, and therefore, due its low biomass generation, it is not recommended for phytoextraction under conditions for this study.Heavy metals concentrations in plant’s tissue (dry weight) were as high as 866 mg Cu/kg and 602 mg As/kg for grass mixture; and 825 mg As/kg was observed for Monks cress.Grass mixture and monks cress had high BAC, BCF and TF, also they had high metal concentrations in its plants tissues and the lowest growth inhibition rates; hence the application in phytoextraction processes of these plants is advisable.  相似文献   

11.
In the frame of the R&D activities performed on the Boom Clay for assessing the suitability of deep clayey formations for radioactive waste disposal, the transferability of the scientific results obtained on the Boom Clay in Mol to the whole Campine Basin is investigated. Boreholes were drilled at different locations (e.g. Mol, Doel, Essen) and cores were sampled over the entire thickness of the Boom Clay formation on which the migration parameters for iodide and tritiated water (HTO) are determined.At Essen, the transport parameters in the Boom Clay can be considered as homogeneous in the range from 159 m to 241 m Below Drilling Table. The average hydraulic conductivity is (5.4 ± 1.7) × 10−12 m/s. The average ηR value for iodide is 0.25 ± 0.03 and 0.42 ± 0.05 for HTO. For HTO, this high value is mainly due to a higher value in the Putte Member (0.46 ± 0.03) compared to the other members (0.39 ± 0.02). The apparent diffusion coefficient is (1.3 ± 0.1) × 10−10 m2/s for HTO and (1.1 ± 0.2) × 10−10 m2/s for iodide. The expected effect of ionic strength (increasing with depth) on the ηR value of iodide is of the same size as the measurement error, what might explain why it was not observed.On a lateral (horizontal) level, the hydraulic conductivity at the Essen-1 borehole (5.4 × 10−12 m/s) lies between that of Boom Clay in Mol-1 (2.5 × 10−12 m/s) and that of Boom Clay in Doel-2b (1.4 × 10−11 m/s). For iodide, the higher ηR value in Essen-1 and Doel-2b (ηR ≈ 0.25) than in Mol-1 (ηR ≈ 0.16) can partly be explained by a higher ionic strength of the pore water. Apart from the Putte Member at Essen-1, the HTO porosities of the Terhagen Member and the Transition zone in Essen are in the range of the average porosities observed in Mol and Doel (ηR ≈ 0.37–0.39). For both iodide and HTO, the value of the apparent diffusion coefficient Dapp is similar in Mol-1 and in Doel-2b, with a clearly higher value for HTO than for iodide. In Essen-1, the apparent diffusion coefficients for iodide and HTO are nearly equal, and slightly smaller than the iodide value in Mol-1/Doel-2b. Accordingly, the HTO apparent diffusion coefficient is considerably smaller in Essen-1 than in Mol-1/Doel-2b.  相似文献   

12.
To investigate the behavior of Li during low-grade metamorphism and fluid flux in an accretionary prism we measured the Li concentrations ([Li]) and isotopic compositions (δ7Li) of sub-greenschist and greenschist-facies Otago Schist composites, as well as cross-cutting quartz veins, which are interpreted to have precipitated from slab-derived fluids. The average [Li] of sub-greenschist facies composites (41 ± 13 μg/g, 2σ) is statistically distinct (97% confidence level, student t test) to that of greenschist facies composites (34 ± 9 μg/g, 2σ), which have experienced mass addition of silica in the form of quartz veins having [Li] between 0.4–2.3 μg/g. A linear regression of the correlation between [Li] and calculated mass additions suggests that the depletion of [Li] in greenschist facies composites is due to both dilution from the addition of the quartz veins, as well as metamorphic dehydration. The [Li] of both groups of composites correlates with their CIA (Chemical Index of Alteration) values (50–58), which are low, consistent with the inferred graywacke protolith of the Otago Schist. The δ7Li of sub-greenschist and greenschist facies composites are remarkably constant, with an average δ7Li of 0.2 ± 1.7 (2σ) and ?0.5 ± 1.9 (2σ), respectively, and comparable to that of the average upper continental crust. Thus, metamorphism has had no discernable effect on δ7Li in these samples. The Li isotopic signature of the schists is similar to that seen in pelitic sedimentary rocks and likely reflects the δ7Li of the protoliths. The surprisingly light δ7Li of the quartz veins (?2.8 to ?1.4) likely records kinetic fractionation associated with Li ingress into the veins from surrounding wallrock.An isotopic equilibrium fluid flow model indicates that: 1) if the [Li] of slab-derived fluids is less than a few μg/g, the δ7Li of the overlying lithologies (i.e., the schists) is not significantly influenced by the fluid flux, regardless of the δ7Li of the fluids, 2) the slab-derived fluids will have heavy δ7Li of > + 10 after reacting with the prism sediments during their ascent, and 3) the [Li] of the slab-derived fluids is likely in the range of 0 < [Li] ≤ 41(μg/g). Thus, isotopically heavy slab-derived fluids that traverse sediments in accretionary prisms may leave little trace in the rocks and their surface compositional characteristics will reflect the net result of their interaction with the sediments of the prism.  相似文献   

13.
Coupled 187Os/188Os and highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, and Re) abundance data are reported for pristine lunar crustal rocks 60025, 62255, 65315 (ferroan anorthosites, FAN) and 76535, 78235, 77215 and a norite clast in 15455 (magnesian-suite rocks, MGS). Osmium isotopes permit more refined discrimination than previously possible of samples that have been contaminated by meteoritic additions and the new results show that some rocks, previously identified as pristine, contain meteorite-derived HSE. Low HSE abundances in FAN and MGS rocks are consistent with derivation from a strongly HSE-depleted lunar mantle. At the time of formation, the lunar floatation crust, represented by FAN, had 1.4 ± 0.3 pg g? 1 Os, 1.5 ± 0.6 pg g? 1 Ir, 6.8 ± 2.7 pg g? 1 Ru, 16 ± 15 pg g? 1 Pt, 33 ± 30 pg g? 1 Pd and 0.29 ± 0.10 pg g? 1 Re (～ 0.00002 × CI) and Re/Os ratios that were modestly elevated (187Re/188Os = 0.6 to 1.7) relative to CI chondrites. MGS samples are, on average, characterised by more elevated HSE abundances (～ 0.00007 × CI) compared with FAN. This either reflects contrasting mantle-source HSE characteristics of FAN and MGS rocks, or different mantle–crust HSE fractionation behaviour during production of these lithologies. Previous studies of lunar impact-melt rocks have identified possible elevated Ru and Pd in lunar crustal target rocks. The new results provide no supporting evidence for such enrichments.If maximum estimates for HSE in the lunar mantle are compared with FAN and MGS averages, crust–mantle concentration ratios (D-values) must be ≤ 0.3. Such D-values are broadly similar to those estimated for partitioning between the terrestrial crust and upper mantle, with the notable exception of Re. Given the presumably completely different mode of origin for the primary lunar floatation crust and tertiary terrestrial continental crust, the potential similarities in crust–mantle HSE partitioning for the Earth and Moon are somewhat surprising. Low HSE abundances in the lunar crust, coupled with estimates of HSE concentrations in the lunar mantle implies there may be a ‘missing component’ of late-accreted materials (as much as 95%) to the Moon if the Earth/Moon mass-flux estimates are correct and terrestrial mantle HSE abundances were established by late accretion.  相似文献   

14.
Speleothems are found in association with hominin fossil-bearing cave deposits in South Africa and can be used to provide valuable chronological constraints. Such material is generally too old for U–Th dating and, although U–Pb geochronology presents a suitable alternative, bulk U concentrations are typically too low (<0.05 μg/g) to provide useful ages. For this reason, we used a simple non-invasive beta-scanner imaging screening step to identify U-rich (≥1 μg/g) domains that could be analyzed with MC-ICP-MS techniques to provide U–Pb ages. We demonstrate the technique using samples from Sterkfontein cave that exhibit infrequent <1 cm-thick layers with U concentrations ≥1 μg/g. Relict aragonite needles are found exclusively in these U-rich layers. We analyzed material from the same flowstone suite as Walker et al. (2006) and obtained a U–Pb age of ～2.3 Ma that agrees well with their estimate of 2.24 ± 0.09 Ma. We also obtained similar U–Pb (0.164 ± 0.026 to 0.200 ± 0.052 Ma) and U–Th (0.148 ± 0.003 Ma) ages for another sample exhibiting U-rich layers. We recognize that open-system behaviour during the partial transformation of aragonite to calcite is a potential problem and argue, on the basis of geochemistry and age consistencies, that recrystallization took place rapidly after speleothem formation and did not significantly affect the U–Pb ages.  相似文献   

15.
The brittle/ductile transition is a major rheologic boundary in the crust yet little is known about how or if rates of tectonic processes are influenced by this boundary. In this study we examine the slip history of the large-scale Naxos/Paros extensional fault system (NPEFS), Cyclades, Greece, by comparing published slip rates for the ductile crust with new thermochronological constraints on slip rates in the brittle regime. Based on apatite and zircon fission-track (AFT and ZFT) and (U–Th)/He dating we observe variable slip rates across the brittle/ductile transition on Naxos. ZFT and AFT ages range from 11.8 ± 0.8 to 9.7 ± 0.8 Ma and 11.2 ± 1.6 to 8.2 ± 1.2 Ma and (U–Th)/He zircon and apatite ages are between 10.4 ± 0.4 to 9.2 ± 0.3 Ma and 10.7 ± 1.0 to 8.9 ± 0.6 Ma, respectively. On Paros, ZFT and AFT ages range from 13.1 ± 1.4 Ma to 11.1 ± 1.0 Ma and 12.7 ± 2.8 Ma to 10.5 ± 2.0 Ma while the (U–Th)/He zircon ages are slightly younger between 8.3 ± 0.4 Ma and 9.8 ± 0.3 Ma. All ages consistently decrease northwards in the direction of hanging wall transport. Most of our new thermochronological results and associated thermal modeling more strongly support the scenario of an identical fault dip and a constant or slightly accelerating slip rate of ∼ 6–8 km Myr− 1 on the NPEFS across the brittle/ductile transition. Even the intrusion of a large granodiorite body into the narrowing fault zone at ∼ 12 Ma on Naxos does not seem to have affected the thermal structure of the area in a way that would significantly disturb the slip rate. The data also show that the NPEFS accomplished a minimum total offset of ∼ 50 km between ∼ 16 and 8 Ma.  相似文献   

16.
We present a 10Be production-rate calibration derived from an early Holocene debris-flow deposit at about 1000 m above sea level in the central Southern Alps, New Zealand, in the mid-latitude Southern Hemisphere. Ten radiocarbon ages on macrofossils from a soil horizon buried by the deposit date the deposit to 9690 ± 50 calendar years before AD2008. Surface 10Be concentrations of seven large boulders partially embedded in the stable surface of the deposit are tightly distributed, yielding a standard deviation of ～2%. Conversion of the 10Be measurements to sea level/high-latitude values using each of five standard scaling methods indicates 10Be production rates of 3.84 ± 0.08, 3.87 ± 0.08, 3.83 ± 0.08, 4.15 ± 0.09, and 3.74 ± 0.08 atoms g?1 a?1, relative to the ‘07KNSTD’ 10Be AMS standard, and including only the local time-integrated production-rate uncertainties. When including a sea level high-latitude scaling uncertainty the overall error is ～2.5% (1σ) for each rate. To test the regional applicability of this production-rate calibration, we measured 10Be concentrations in a set of nearby moraines deposited before 18 060 ± 200 years before AD2008. The 10Be ages are only consistent with minimum-limiting 14C age data when calculated using the new production rates. This also suggests that terrestrial in situ cosmogenic-nuclide production did not change significantly from Last Glacial Maximum to Holocene time in New Zealand. Our production rates agree well with those of a recent calibration study from northeastern North America, but are 12–14% lower than other commonly adopted values. The production-rate values presented here can be used elsewhere in New Zealand for rock surfaces exposed during or since the last glacial period.  相似文献   

17.
In an attempt to quantify the extent of geochemical heterogeneity within a restricted and well dated portion of the upper mantle, 27 chromite separates from the 90 My old chromite deposits in the Mayarí–Baracoa ophiolite belt in eastern Cuba have been investigated for platinum group element (PGE) concentrations and Re–Os isotopic systematics. The samples are characterized by systematically subchondritic initial 187Os/188Os ratios and substantial heterogeneity. The initial 187Os/188Os ratios vary with chromite chemistry and with geographical distribution, reflecting differences in the Os isotopic evolution for the different upper mantle sections represented by the ophiolite. Accordingly, the Os isotope data might be divided into three groups. In the Moa–Baracoa district, where the chromite bodies are located in the mantle–crust transition zone, the calculated initial γOs values average − 0.97 ± 0.69 (n = 13). In the Sagua de Tanamo district, where chromite chemistry is highly variable and their location in relation the mantle sequence is less clear, the initial γOs values are intermediate, with an average of − 1.77 ± 0.80 (n = 7). In the Mayarí district, where the chromite bodies are located in the lower part of the mantle sequence, initial γOs values average − 2.66 ± 0.29 (n = 7). These subchondritic (i.e. negative) initial γOs values are most simply explained by Re depletion during ancient partial melting and/or melt percolation events.The Os isotope heterogeneity documented here indicates a high degree of geochemical complexity on small to intermediate length scales in the upper mantle. Our results, in combination with data on chromites from the literature, show that an “average present-day Os isotopic composition” for the hypothetical depleted MORB mantle (DMM) reservoir cannot be precisely established beyond the statement that it is “broadly chondritic”. Indeed, the upper mantle cannot be considered a sufficiently homogeneous geochemical “reservoir” to serve meaningfully as a baseline against which geochemical “anomalies” are evaluated. On the other hand, our findings are consistent with the “Statistical Upper Mantle Assemblage” or “SUMA”-concept, according to which a high level of geochemical heterogeneity is maintained in the upper mantle at all relevant length scales, as a result of the plate-tectonic cycle and intra-mantle processes such as melt-migration and metasomatism.  相似文献   

18.
In this paper we tested the applicability of the Optically Stimulated Luminescence (OSL) technique through Single-Aliquot Regenerative-dose (SAR) protocol, on single grain quartz extracted from alluvial–coastal sediments. Five samples were collected from deposits belonging to a flight of seven orders of coastal–alluvial terraces outcropping in the area between Mt. Etna volcano and the Catania Plain (Sicily, southern Italy), at the front of the Sicilian fold and thrust system. After various performance tests, we obtained OSL ages ranging between 240 ± 12 and 80 ± 4 ka, consistent with the normal evolutionary model of a terraced sequence, moving from the highest to the lowest elevation. Obtained data allowed us to determine a mean uplift rate of 1.2 mm/year during the last 240 ka, mostly related to regional uplift processes coupled with sea-level changes. Moreover, terraces belonging to the two highest orders are folded, forming a large anticline. According to our results, the frontal thrust of the Sicilian chain was active between 236 and 197 ka ago, even though seismological and geodetic data suggest current activity to the back.  相似文献   

19.
《Marine pollution bulletin》2012,65(12):2857-2859
Baseline Hg concentration in bycatch fish from the SE Gulf of California were determined in muscle and liver of 19 species. Levels of Hg in muscle were compared with legal limits of this element in national and international legislation. Considering all fish species, mean concentrations in liver (2.458 ± 1.997 μg g−1) were significantly higher (p < 0.05) than in muscle (0.993 ± 0.670 μg g−1). The sequence of averaged Hg concentrations in most ichthyofauna was liver > muscle. Highest level of Hg in muscle (2.556 μg g−1) and liver (7.515 μg g−1) corresponded to Diapterus peruvianus and Ophioscion strabo, respectively. Considering muscle samples, none of the species had levels of Hg above the limit (1.0 μg g−1 wet weight) in the Mexican legislation; with respect to the Japanese (0.4 μg g−1 wet weight) and British (0.3 μg g−1 wet weight) legislations, 26.3% and 31.6% of the species respectively, were above the corresponding limits.  相似文献   

20.
《Marine pollution bulletin》2012,65(12):2829-2833
This study reports the first evidence of the quantification of two dominant perfluorinated compounds (PFCs), namely perfluorooctanesulfate (PFOS) and perfluorooctannoate (PFOA), in surface sediment samples (0–5 cm; n = 13) from the Ganges (Hugli) River including Sundarban wetland, India using HPLC–MS/MS. The concentrations of PFOA exhibited a wide range of concentrations from <0.5 to 14.09 ng/g dry wt, whereas the concentration of PFOS was always below the detection limit of <0.5 ng/g dry wt. A consistent enrichment of PFOA was recorded in all the five sites of Sundarban (mean value 11.61 ± 1.86) whereas it was of moderate concentration or below the detection level in the seven sites along with the lower stretch of the Ganges (Hugli) River estuary (mean value 5.96 ng/g dry wt ± 5.36). Wastewater and untreated effluents are likely the major causes of accumulation of PFCs in sediments. The present paper could be used as baseline study to assess future monitoring programs of the ecosystem.  相似文献   

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