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1.
地球化学测井   总被引:9,自引:0,他引:9  
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2.
气溶胶表面上SO_2的非均相氧化过程   总被引:3,自引:0,他引:3  
建立了一个可溶性气溶胶表面上SO_2氧化的非均相化学模式,分析了影响SO_2在气溶胶表面上氧化的各因子的作用.结果表明,气溶胶浓度及其成分,SO_2的初始浓度,H_2O_2的初始浓度和相对湿度是影响SO_2在气溶胶表面上氧化的主要因子.最后把该模式引入欧拉型硫沉降模式,讨论了非均相化学过程在区域硫沉降过程中的作用.气溶胶表面非均相化学过程的引入可使SO_2的近地面浓度降低5%~33%,SO_4~(2-)的近地面浓度增加8%~50%.  相似文献   

3.
首次利用6步连续化学提取法,探讨和研究了察尔汗盐湖91—Ⅳ_4孔沉积物中16种元素在不同地球化学相中的结合形态和赋存状态。结果表明:碱金属K存在于可交换部分中;碱土金属Mg、Ba存在于碳酸盐相中,Mn在碳酸盐相中的含量也较高;B、P存在于有机质部分中;痕量金属大多存在于易还原相、中等还原相和硅酸盐矿物晶格的残渣部分中。  相似文献   

4.
对江西南部黑云母花岗岩和花岗斑岩风化剖面中Sr同位素体系的研究结果显示,花岗岩化学风化过程中,Rb,Sr之间发生明显分异,风化早期释放出的Sr/Si,Sr/Ca比值大于母岩值,Sr的淋失速率大于Si,Ca,K,Rb等营养离子.主要含Sr(和Rb)矿物相对风化速率的动态变化,导致花岗岩风化壳及其释放出Sr的87Sr/86Sr比值随时间波动变化黑云母、斜长石和钾长石的先后风化,导致风化残余物的87Sr/86Sr比值历经下降-升高-下降的波动变化,最终趋于稳定.这进一步说明,当用锶同位素示踪流域和全球范围的生物地球化学过程时,必须慎重考虑Sr从溶解固相中的优先释放以及含Sr矿物相对风化速率的变化导致的87Sr/86Sr比值的波动.  相似文献   

5.
本文讨论了新疆温泉县泥火山喷出水的化学特征。于2012年10月~2014年6月测量了温泉县泥火山喷发水、明目泉泉水及附近河水的化学组分(K+、Na+、Ca2+、Mg2+、F-、Cl-、SO2-4、HCO-3♂和CO2-3)和温泉县泥火山喷发水的氢氧同位素组成(δD和δ18O)。结果表明,该泥火山喷发水的化学类型为Na-HCO3SO4,δ18O-δD值小幅度偏离大气降水线,主要形成于大气降水顺断裂或裂隙深循环过程中与围岩的水岩作用;泥火山离子浓度较高,变化幅度低于5%,背景值稳定,可作为区域地震地球化学监测的对象。  相似文献   

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黄国铭 《华南地震》1995,15(4):78-79
潮州台地下水化学异常与地震的关系黄国铭(潮州市地震局,潮州521011)潮州水化观测井位于北东向的三饶—潮州—普宁断裂与北西向的韩江断裂的交汇处,围岩为燕山期花岗岩,井深51.3m,为花岗岩微承压水,水温常年平均在24℃左右,水质为HCO3-—Ca+...  相似文献   

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10.
新疆萨尔布拉克金矿矿床地球化学及矿床成因   总被引:4,自引:0,他引:4  
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11.
Sediments samples of the Dobczyce Reservoir(South Poland) were taken in three successive years(2004-06) at 17 points,analyzed for 12 elements by atomic absorption spectrometry.Substantial variations in elemental composition due to hydrological and environmental reasons were found.The use of statistical and chemometric tools enabled objective and effective analysis of the data obtained,both in case of long term observations as well as in terms of interpretation of incidental changes in metal concentrations.The proposed methodology can be useful in:a) dividing monitored territories(lakes,rivers,catchments) into similar and dissimilar areas;b) distinguishing between typical and non-typical contaminants distribution;c) reducing the number of essential analytes and sampling points that should be controlled in the future,without loss of important environmental information.  相似文献   

12.
During surveillance on the toxicity of invertebrates such as bivalves inhabiting the coasts of Hiroshima Bay in 2001 and 2002, the carnivorous gastropod rapa whelk Rapana venosa collected in the estuary of Nikoh River, was found to contain toxins which showed paralytic actions in mice; the maximum toxicities (as paralytic shellfish poison, PSP) were 4.2 MU/g (May 2001) and 11.4 MU/g (April 2002). Their total toxicities were 224 and 206 MU/viscera of one specimen throughout the monitoring period. Attempts were made to identify the toxic principle in the gastropod. The viscera were extracted with 80% ethanol acidified with acetic acid, followed by defatting with dichloromethane. The aqueous layer obtained was treated with activated charcoal and then applied to a Sep-Pak C18 cartridge. The unbound toxic fraction was analyzed by high-performance liquid chromatography techniques. The gastropod toxin was rather unexpectedly identified as PSP. It was comprised of high toxic component (gonyautoxin-3; GTX3, GTX2, saxitoxin; STX) as the major components, which accounted for approximately 91 mol% of all components along with C1 and C2, which are N-sulfocarbamoyl derivatives. Judging from their toxin patterns, it is suggested that the PSP toxification mechanism of the gastropod that PSP toxins produced by phytoplankton such as Alexandrium tamarense, are transferred to and accumulated in plankton feeders such as the short-necked clam, and then transferred to this carnivorous rapa whelk R. venosa through predation.  相似文献   

13.
The concentrations and distribution of polychlorinated biphenyls were determined in water, surface sediments and fishes from the estuaries of Pearl River, PR China. The results showed that the concentrations ranged from 2.47 ng l-1 to 6.75 ng l-1 in water, from 11.13 ng g-1 to 23.23 ng g-1 in sediments (dry weight) and from 68.64 ng g-1 to 316.85 ng-1 in fish (lipid weight). It was found that the feeding habits of fish were very significant in the accumulation of polychlorinated biphenyls and pattern of congeners. Carnivorous and benthic fishes such as eel (Anguilla japonica) and Chinese sea catfish (Arius sinensis) were found to have high concentrations of polychlorinated biphenyls and of high-chlorinated congeners, while herbivores such as shad (Clupanodon punctatus) and mullet (Mugil cephalus) exhibited an opposite trend. Congeners IUPAC Nos. 153, 138, 118, 87/81, 170 and 52 were found frequently in most samples (both sediment and fish). In comparison with other places in the world, the concentration of polychlorinated biphenyls in sediment and fish from the estuary of Pearl River were low.  相似文献   

14.
Organochlorine (OCs) and butyltin (BTs) residues were determined in deep-sea organisms collected from the western North Pacific, off-Tohoku, Japan. Among OCs, concentrations of polychlorinated biphenyls (PCBs) and DDTs (DDTs and its metabolites) were the highest in deep-sea organisms (maximum concentrations of 6700 and 13,000 ng/g lipid wt, respectively). Chlordane compounds (CHLs) were the next most abundant OCs, and hexachlorocyclohexanes (HCHs) and hexachlorobenzene (HCB) were the lowest. BTs were also detected at maximum concentrations of 570 ng/g wet wt. Concentrations of PCBs, CHLs and BTs in deep-sea organisms collected from the western North Pacific, off-Tohoku, were generally lower than those in deep-sea and shallow water organisms from Japanese coastal waters. On the other hand, considerable variations in the concentrations of OCs were found among deep-sea organisms analyzed. Several carnivorous fishes such as snubnosed eel, lanternshark and grenadiers accumulated some OCs such as PCBs, DDTs and CHLs at high concentrations of up to a few μg/g levels. In addition, the residue pattern of OCs and BTs in fishes showed a specific trend according to the sampling depth; higher concentrations of PCBs, DDTs and CHLs and lower concentrations of HCHs, HCB and BTs were found in fishes collected from greater depth (1000 m) compared to those from shallower waters. This trend is consistent with the results of our earlier study on mesopelagic myctophid fishes. Results of this study suggest vertical transport of hydrophobic OCs such as PCBs, DDTs and CHLs and its accumulation in benthic deep-sea organisms.  相似文献   

15.
During surveillance of the distribution of the paralytic shellfish poison (PSP)-producing dinoflagellate in 2003, 2004 and 2005 along the coastlines of the Seto Inland Sea, Hiroshima Prefecture, Japan, some species of toxic phytoplankton were isolated from the eastern coasts, Bingo-Nada, the central regions of the Seto Inland Sea. It was rather unexpectedly revealed from the basis of the morphological characteristics that they were unambiguously identified as Alexandrium tamiyavanichii and Alexandrium catenella. Two strains (ATY041106, ATY051018) of A. tamiyavanichii showed a specific toxicity of 38.7 x 10(-6) and 111.5 x 10(-6)MU/cell, respectively. These values seemed to be several times or much higher than that of A. catenella (AC030816, AC040614), having a specific toxicity of 4.5 x 10(-6) and 4.1 x 10(-6)MU/cell, respectively, isolated in the same area. From the results of HPLC-furuorometric analysis, it revealed that the toxins in ATY041106 exist almost exclusively as beta-epimers (C2, GTX3, GTX4), which accounted for 72.7 mol%. The toxin profiles of this strain are featured by the presence of a large amount of GTX3 (59.1 mol%) and a small amount (20.6%) of C1 and 2 in comparison with the PSP compositions of A. tamarense, which is isolated as the main responsible species in Hiroshima Bay, a western part of coastal sea in Hiroshima Prefecture. On the other hand, it revealed that the toxin profiles of two strains (AC030816, AC040614) of A. catenella exist almost exclusively as beta-epimers (C2, GTX3, GTX4), which accounted for 81.8 and 56.5 mol%, as the same manner. The toxin profiles of these two strains are featured by the presence of a large amount of C2 (80.5 and 46.3 mol%) in comparison with the PSP compositions of A. tamiyavanichii. To our knowledge, this is the first record to show the distribution and harmful influence of A. tamiyavanichii and A. catenella in Bingo-Nada in Hiroshima Prefecture. Though contamination of bivalves with these PSP-producing planktons in this area has not occurred yet so far, attention should be paid to this species as well as the other causative dinoflagellate from the stand point of public health and food hygiene.  相似文献   

16.
Submarine groundwater discharge (SGD) on the reef flat of Bolinao, Pangasinan (Philippines) was mapped using electrical resistivity, 222Rn, and nutrient concentration measurements. Nitrate levels as high as 126 μM, or 1-2 orders of magnitude higher than ambient concentrations, were measured in some areas of the reef flat. Nutrient fluxes were higher during the wet season (May-October) than the dry season (November-April). Dissolved inorganic nitrogen (DIN=NO3+NO2+NH4) and soluble reactive phosphorus (SRP) fluxes during the wet season were 4.4 and 0.2 mmoles m(-2) d(-1), respectively. With the increase population size and anthropogenic activities in Bolinao, an enhancement of SGD-derived nitrogen levels is likely. This could lead to eutrophic conditions in the otherwise oligotrophic waters surrounding the Santiago reef flat.  相似文献   

17.
Deep (> 5 m) sheeting fractures in the Navajo sandstone are evident at numerous sites in southern Utah and derive from tectonic stresses. Strong diurnal thermal cycles are, however, the likely triggers for shallow (< 0.3 m) sheeting fractures. Data from subsurface thermal sensors reveal that large temperature differences between sensors at 2 and 15 cm depth on clear summer afternoons are as great as those that trigger sheeting fractures in exposed California granite. Extensive polygonal patterns in the Navajo sandstone are composed of surface-perpendicular fractures and were produced by contractile stresses. Numerous studies have shown that porewater diminishes the tensile strength of sandstone. Based on our thermal records, we propose that cooling during monsoonal rainstorms triggers polygonal fracturing of temporarily weakened rock. On steep outcrops, polygonal patterns are rectilinear and orthogonal, with T-vertices. Lower-angle slopes host hexagonal patterns (defined by the dominance of Y-vertices). Intermediate patterns with rectangles and hexagons of similar scale are common. We posit that outcropping fractures are advancing downward by iterative steps, and that hexagons on sandstone surfaces (like prismatic columns of basalt) have evolved from ancestral orthogonal polygons of similar scale. In lava flows, fractures elongate intermittently as they follow a steep thermal gradient (the source of stress) as it rapidly moves through the rock mass. In our model, a steep, surficial thermal gradient descends through unfractured sandstone, but at the slow pace of granular disintegration. Through time, as the friable rock on stable slopes erodes, iterative cracking advances into new space. Hexagonal patterns form as new fractures, imperfectly guided by the older ones, propagate in new directions, and vertices drift into a configuration that minimizes the ratio of fracture length to polygon area. © 2020 John Wiley & Sons, Ltd.  相似文献   

18.
In this work, a transient rainfall infiltration and grid‐based regional slope‐stability model (TRIGRS) was implemented in a case study of Yan'an City, Northwest China. In this area, widespread shallow landslides were triggered by the 12 July 2013 exceptional rainstorm event. A high‐resolution DEM, soil parameters from in‐situ and laboratory measurements, water table depths, the maximum depth of precipitation infiltration and rain‐gauge‐corrected precipitation of the event, were used as inputs in the TRIGRS model. Shallow landslides triggered on the same day were used to evaluate the modeling results. The summarized results are as follows: (i) The characteristics and distribution of thirty‐five shallow landslides triggered by the 12 July 2013 rainfall event were identified in the study area and all were classified as shallow landslides with the maximum depth, area and volume less than 3 m, 200 m2 and 1000 m3, respectively, (ii) Four intermediate factor of safety (FS) maps were generated using the TRIGRS model to represent the scenarios 6, 12, 18 and 24 hours after the storm event. The area with FS < 1 increased with the rainfall duration. The percentage of the area with FS < 1 was 0.2%, 3.3%, 3.8% and 5.1% for the four stages, respectively. Twenty‐four hours after the rainstorm, TRIGRS predicted that 1255 grid cells failed, which is consistent with the field data. (iii) TRIGRS generated more satisfactory results at a given precipitation threshold than SINMAP, which is ideal for landslide hazard zoning for land‐use planning at the regional scale. Comparison results showed that TRIGRS is more useful for landslide prediction for a certain precipitation threshold, also in the regional scale. (iv) Analysis of the responses of loess slope prone to slope failure after different precipitation scenarios revealed that loess slopes are particularly sensitive to extended periods of heavy precipitation. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

19.
《Marine pollution bulletin》2014,78(1-2):137-145
To examine the influence of habitat alteration by tideflat reclamation on the physiological ecology of Ruditapes philippinarum, seasonal variations in its condition, gross biochemical composition, and reproductive cycle were compared for a yearly cycle between a reclaimed flat (Gomsohang, GS) and a natural flat (Hajun, HJ) in Gomso Bay, Korea. Concentrations of chlorophyll a and seston (as well as its energy value as food available to the clam) were consistently higher at HJ than at GS. Condition, dry tissue weight, and energy reserves (proteins and carbohydrates) of the clams were much higher at HJ than at GS during spring–summer, when fast growth and gametogenic development occur. Furthermore, their spring gametogenic development and spawning were advanced at HJ compared with GS. Our results suggest that the Manila clam encounters nutritionally stressful environmental conditions in altered habitats after tideflat reclamation that lead to lowered nutrient accumulation and a changing reproductive cycle.  相似文献   

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