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1.
《Journal of Geodynamics》2010,49(3-5):247-252
Enceladus, one of Saturn's moons, shows significant volcanic activity identified by the Cassini spacecraft. The aim of the present study is to investigate – with the adaptation of mathematical tools used in geodynamics – the extent of tidal heating due to the mean motion resonance with Dione. For the purpose of calculations a two-layer model of Enceladus was used. The inner part of the model is a “rocky core” with a relative radius 0.55, while the outer part is composed of water ice. The results of model calculations show that the effective tidal heating is not uniformly distributed within Enceladus. It was found for the selected model of Enceladus, that the tidal heating is maximum within the depth interval (25–75) km. Due to the inhomogeneity within Enceladus, 85% of the tidal energy is generated in a volume that contains just 39% of its mass. In time intervals of 3.0 × 108 and 5.3 × 108 years the temperature increase in the relative depth range 0.70 ≤ r/aE ≤ 0.90 is approximately 270 and 370 K, respectively.  相似文献   

2.
High precision Mg isotope measurements by multi-collector ion microprobe show that refractory olivines from the Allende chondrite, either olivines isolated in the matrix (2 samples studied) or olivines in type I chondrules (6 samples studied), have variable δ26Mg* enrichments and deficits (calculated in permil as the 26Mg deviation from the instrumental mass fractionation line) relative to the Earth. Most average δ26Mg* (noted δ26Mg*av) values (between 10 and 20 analyses per chondrule) are negative but the total range is from ?0.029 (± 0.010) ‰ (2 sigma errors) to + 0.011 (± 0.011) ‰ with an exception of one olivine at + 0.043 (± 0.023) ‰. These variations in δ26Mg*av reflect the formation of the olivines from reservoirs enriched in various amounts of 26Mg by the decay of short-lived 26Al (T1/2 = 0.73 Ma). Similarly, 30 analyses of olivines from the Eagle Station pallasite show a δ26Mg*av value of ?0.033 ± 0.008‰, as negative as some olivines from Allende chondrules and the Solar system initial δ26Mg* value of ?0.038 ± 0.004‰ (defined at the time of formation of type B Ca–Al-rich inclusions – CAIs – when 26Al/27Al = 5.23 × 10?5, Jacobsen et al., 2008).Because olivines are Al-poor and because their Mg isotopic compositions are not reset during the chondrule forming events, their δ26Mg*av can be used to calculate model crystallization ages relative to various theoretical Mg isotope growth curves. The two end-member scenarios considered are (i) a “nebular” growth in which the Al/Mg ratio remains chondritic and (ii) a “planetary” growth in which a significant increase of the Al/Mg ratio can be due to, for instance, olivine magmatic fractionation. The low δ26Mg*av value of olivines from the Eagle Station pallasite demonstrate that metal-silicate differentiation occurred as early as ~ 0. 15- 0. 23+ 0. 29 Ma after CAIs in either of the growth scenarios. Similarly the variable δ26Mg*av values of refractory olivines can be understood if they were formed in planetesimals which started to differentiate as early as the Eagle Station parent body. Accretion of these planetesimals must have been coeval to the formation of CAIs and their disruption could explain why their fragments (Mg-rich olivines) were distributed in the chondrule forming regions of the disk.  相似文献   

3.
Combining cosmogenic 3He and 21Ne (3Hec and 21Nec) measurements on both pyroxene and olivine from the Pleistocene Bar Ten flows (85–107 ka) greatly increases our ability to evaluate the accuracy of 3Hec and 21Nec production rates and, therefore, 3Hec and 21Nec surface exposure ages. Comparison of 3Hec and 21Nec age-pairs yielded by experimentally determined production rates and composition-based model calculations indicates that the former give more accurate surface exposure ages than the latter in this study. However, experimental production rates should be adjusted to the composition of the minerals being analyzed to obtain the best agreement between 3Hec and 21Nec ages for any given sample. 21Nec/3Hec values are 0.400 ± 0.029 and 0.204 ± 0.014 for olivine and pyroxene, respectively, in Bar Ten lava flows, in agreement with previously published values, and indicate that 21Nec/3Hec in olivine and pyroxene is not affected by erosion and remains constant with latitude, elevation, and time (up to 10 Myr). Samples with 21Nec/3Hec that do not agree with these values may indicate the presence of non-cosmogenic helium and/or neon. The neon three-isotope diagram can also indicate whether or not all excess neon in mineral separates comes from cosmogenic sources. An error-weighted regression for olivine defines a spallation line [y = (1.033 ± 0.031)x + (0.09876 ± 0.00033)], which is indistinguishable from that for pyroxene (Schäfer et al., 1999). We have derived a production rate of 25 ± 8 at/g/yr for 21Nec in clinopyroxene (En43–44) based on the 40Ar/39Ar age of the upper Bar Ten flow. Our study indicates that the production rate of 21Nec in olivine may be slightly higher than previously determined. Cosmogenic 3He and 21Ne remain extremely useful, particularly when paired, in determining accurate eruption ages of young olivine- and pyroxene-rich basaltic lava flows.  相似文献   

4.
《Journal of Geodynamics》2010,49(3-5):331-339
The Free Core Nutation (FCN) is investigated with the help of its resonance effect on the tidal amplitudes in Superconducting Gravimeter (SG) records of the GGP network. The FCN resonance parameters are combined in a resonance equation involving the Earth's interior parameters. The sensitivity of the FCN parameters to the diurnal tidal waves demonstrates that the quality factor of the FCN is strongly dependent on the accuracy of the imaginary part estimates of the gravimetric factors close to the resonance. The weak amplitude of Ψ1 tidal wave on the Earth, which is the closest in frequency to the FCN, in addition to errors in ocean loading correction, explains the poor determination of the quality factor Q from surface gravimetric data. The inversion of tidal gravimetric factors leads to estimates of the period, Q and resonance strength of the FCN. We show that, by inverting log(Q) instead of Q, the results using the least-squares method optimized using the Levenberg–Marquardt algorithm are in agreement with the Bayesian probabilistic results and agree with the results obtained from VLBI nutation data. Finally, a combined inversion of 7 GGP European SG data is performed giving T = 428 ± 3 days and 7762 < Q < 31,989 (90% C.I.). An experimental estimate of the internal pressure Love number is also proposed.  相似文献   

5.
《Journal of Geodynamics》2010,49(3-5):253-259
We observe the Earth tidal fields at diurnal and semi-diurnal periods using Kinematic Precise Point Positioning (KPPP) GPS analysis. Our KPPP GPS solutions compare well with super-conducting gravimeter (SG) observations and a theoretical Earth tidal model, that includes both ocean tide loading model and body tides. We make a high resolution map of the observed Earth tidal response fields using the Japanese GEONET GPS network which consists of 1200 sites. We find that: (1) the average phase of GPS data lags 0.11 ± 0.04° from our theoretical Earth tidal model, (2) the average amplitude ratio between GPS and the theoretical Earth tidal model is 1.007 ± 0.003, (3) the amplitude in the Kyushu district is about 1.0–1.5 ± 0.3% larger than in the Hokkaido district, and (4) the amplitude at the Japan Sea side is about 0.5 ± 0.2% larger than that at the Pacific Ocean side. These results suggest that we may be able to place constraints on Earth structure using GPS-derived tidal information.  相似文献   

6.
A fine grid tidal modeling experiment is carried out in order to investigate the tidal regimes for major five tidal constituents, the nonlinear tidal phenomena in terms of M4 and MS4 generation, and the independent tide by the tide generating force in the Yellow and East China Seas (YECS). In this study a two-dimensional numerical model based upon a subgrid-scale (SGS) stress modeling technique is used with the tide generating force included. The model was validated with recently observed tide and current data. The calculated tidal charts for tidal elevation show a generally good agreement with existing ones, with more accurate feature of the M2 cotidal chart in comparison with both the observed data and the existing tidal charts. A careful comparison of the computed diurnal amplitude with observations suggests that the diurnal constituents seem to be overdamped especially in the Kyunggi Bay region, for the case when quadratic bottom friction law is used.Propagation features of the M4(MS4) tides are discussed in the YECS, based upon the analyses of the observed and calculated results. The amphidromic system of the M4 is quite complicated and one noticeable characteristic is that the propagation direction of the M4 tidal wave along the west coast of Korean peninsula is opposite to that of the M2 tidal wave. This result coincides with observations. The propagation feature of the MS4 is almost similar to that of the M4, but with lesser amplitude. The responses of the M4 tidal features to momentum diffusion term and depth-dependent form of the friction coefficient are also discussed.It is also shown that when the independent tide (Defant, 1960) arising from tide generating force (TGF) coexists with tidal waves (co-oscillating tide) arising from external boundary forcing, the TGF tidal waves are dissipated and their amphidromes tend to move westward. This may be interpreted as a process whereby the incident and reflected TGF tidal waves are damped by co-oscillating tide arising from external force at open boundaries. The TGF amplitude is found to be up to 10 cm and 4 cm in the Kyunggi Bay for the M2 and S2 constituents while those for all diurnal constituents are less than 1 cm over the entire model domain.  相似文献   

7.
We analyzed records of eight seismic stations of the autonomous broadband seismograph network of a joint project between Utrecht University (the Netherlands), California Institute of Technology, and Centro de Investigación Científica y de Estudios Superiores de Ensenada (CICESE). These stations recorded the Mw 5.6 earthquake that occurred on 12 November 2003 at Salsipuedes basin in the middle of the Gulf of California 2 km west of the island Angel de la Guarda. This event was located at 29.16º N and 113.37º W, 30 km northeast of Bahia de los Angeles. A foreshock and hundreds of aftershocks were recorded in the 48 hours after its origin time. With the location of 29 earthquakes we identified the active segment, perpendicular to the main transform fault NW–SE of Canal de Ballenas, representing the transtensional boundary between the Pacific and North American plates. The direction of the active fault described is consistent with the normal fault mechanism reported by the National Earthquake Information Center (strike=39º, dip=34º, slip=–44º).From the duration magnitude of 456 aftershocks, we calculated a b-value of 1.14±0.28; furthermore, we calculated a seismic moment of (3.5 ±3.3) X1017Nm, a source radius of 3.7 ± 2.63 km, and a static stress drop of 3.94 ± 1.15 MPa (39.4 ± 11.5 bar.).  相似文献   

8.
Equivalent dose (De) values were measured by using medium aliquots of different grain size quartz fractions of five lakeshore sediments from the arid region of north China. There are two different relationships between De values and grain sizes of these five samples. The first relationship is that the De values obtained from various grain sizes are in agreement within 1 delta errors. The second relationship is that De values are similar to each other for fractions between 125 and 300 μm, while the De value of the 63–90 μm fraction is 40～55% smaller than others. For example, the De values obtained for sample #3 are 20.15 ± 1.19 Gy, 19.80 ± 0.83 Gy and 20.93 ± 1.06 Gy for fractions of 90–125, 125–150 and 250–300 μm respectively, but are 10.79 ± 0.84 Gy for the 63–90 μm fraction. The second relationship can't be interpreted by previous studies of both dosimetry and heterogeneous bleaching. It is deduced for sample #2, #3 and #6 that fine particles (<90 μm) intruded after the dominant sedimentation. Comparison of OSL ages from different grain size fractions of sample #2 with a radiocarbon age from the same lithologic layer supports that fractions coarser than 125 μm yield more reliable burial ages, while the fraction finer than 90 μm yields underestimated ages for some lakeshore sediments from this arid region.  相似文献   

9.
A double-spike method was used to obtain Mo isotope data for sediments and waters of the seasonally anoxic Chesapeake Bay, and its primary tributary, the Susquehanna River. The dissolved Mo distribution in the estuary is non-conservative, reflecting minor Mo loss to the sediments, although removal of Mo to the sediments does not have a large influence on the isotopic composition of the water column. The δ98Mo of dissolved Mo in most of the estuary is dominated by seawater. Six samples with salinity > 15 have an average δ98Mo = + 2.17‰ (± 0.12), which agrees well with a δ98Mo value for the CASS-4 seawater standard of + 2.23‰. A single sample of Susquehanna River water has a δ98Mo of + 1.02‰, consistent with recent findings of positive δ98Mo in rivers worldwide. Susquehanna river sediments, in contrast, have δ98Mo ～ ? 0.1‰. The difference between the river water and sediment values implies that isotopic fractionation occurs within the river basin. The δ98Mo values for estuarine sediments are offset from values in the overlying water. Most samples deposited before 1925 have δ98Mo less than 0‰, similar to the Susquehanna sediments. Subsequently, there is an increase in the variability of δ98Mo, with values ranging up to + 0.8‰. The transition to increased variability coincides with the onset of authigenic Mo deposition, which was previously attributed to escalating summertime anoxia. Authigenic Mo concentrations correlate poorly with δ98Mo in core samples, suggesting that independent mechanisms influence the two parameters. Authigenic Mo concentrations may be controlled by shifting pore water H2S levels, while δ98Mo may be primarily affected by annual variations in Mn refluxing.  相似文献   

10.
《Continental Shelf Research》1999,19(15-16):1905-1932
The M2 tidal component of the flow in the Dover Straits is reconstructed using a natural combination of two independent data sources: HF Ocean Surface Current Radar (HF OSCR) system and coastal tidal measurements. The method used is the variational data assimilation technique into a quasi-linearized finite element tidal model. The model uses triangular elements with horizontal resolution varying from 800 to 1200 m. It is controlled by the boundary conditions at open boundaries, which are adjusted to fit the available data in an optimal way. A “weak” formulation of the dynamical constraints is used. The interpolation scheme allows small (0.01%) deviations from the exact dynamics specified by the model. The optimal state of M2 parameters (sea surface elevation and depth-averaged velocities) is used to map both the M2 tidal flux through the strait and the M2 energy flux. The respective values obtained are the tidal flux amplitude 1.18±0.09×106 m3 s−1, the net residual transport (Stoke's drift) 40±3×103 m3 s−1, and the net energy flux 1.19±0.09×1010 W. These figures within the statistically estimated error band are in the close agreement with those obtained by Prandle et al., 1993. A rigorous error analysis is performed using an explicit inversion of the Hessian matrix, associated with the assimilation scheme. As a result, error charts for M2 velocities and sea surface elevation are obtained. It is shown that OSCR data combined with coastal level measurements and constrained by dynamics is able to provide quite accurate velocity estimates whose errors vary within the range of 0.05–0.45 m s−1 depending upon the location. Error maps also enable us to determine areas requiring better coverage by data, thus forming a basis of optimization approach to the design of the HFR measurements. The use of variational assimilation technique in providing integrated interpolation patterns from various sources of data demonstrates its capabilities in relation to future oceanographic monitoring systems of shelf circulation.  相似文献   

11.
The single backscattering model was used to estimate total attenuation of coda waves (Qc) of local earthquakes recorded on eight seismological stations in the complex area of the western continental Croatia. We estimated Q0 and n, parameters of the frequency dependent coda-Q using the relation Qc = Q0fn. Lapse time dependence of these parameters was studied using a constant 30 s long time window that was slid along the coda of seismograms. Obtained Qc were distributed into classes according to their lapse time, tL. For tL = 20–50 s we estimated Q0 = 45–184 and n = 0.49–0.94, and for tL = 60–100 s we obtained Q0 = 119–316 and n = 0.37–0.82. There is a tendency of decrease of parameter n with increasing Q0, and vice versa. The rates of change of both Q0 and n seem to decrease for lapse times larger than 50–80 s, indicating an alteration in rock properties controlling coda attenuation at depths of about 100–160 km. A very good correlation was found between the frequency dependence parameter n and the Moho depths for lapse times of 50, 60 and 70 s.  相似文献   

12.
We report new high-precision laser fluorination three-isotope oxygen data for lunar materials. Terrestrial silicates with a range of δ18O values (− 0.5 to 22.9‰) were analyzed to independently determine the slope of the terrestrial fractionation line (TFL; λ = 0.5259 ± 0.0008; 95% confidence level). This new TFL determination allows direct comparison of lunar oxygen isotope systematics with those of Earth. Values of Δ17O for Apollo 12, 15, and 17 basalts and Luna 24 soil samples average 0.01‰ and are indistinguishable from the TFL. The δ18O values of high- and low-Ti lunar basalts are distinct. Average whole-rock δ18O values for low-Ti lunar basalts from the Apollo 12 (5.72 ± 0.06‰) and Apollo 15 landing sites (5.65 ± 0.12‰) are identical within error and are markedly higher than Apollo 17 high-Ti basalts (5.46 ± 0.11‰). Evolved low-Ti LaPaz mare-basalt meteorite δ18O values (5.67 ± 0.05‰) are in close agreement with more primitive low-Ti Apollo 12 and 15 mare basalts. Modeling of lunar mare-basalt source composition indicates that the high- and low-Ti mare-basalt mantle reservoirs were in oxygen isotope equilibrium and that variations in δ18O do not result from fractional crystallization. Instead, these differences are consistent with mineralogically heterogeneous mantle sources for mare basalts, and with lunar magma ocean differentiation models that result in a thick feldspathic crust, an olivine–pyroxene-rich mantle, and late-stage ilmenite-rich zones that were convectively mixed into deeper portions of the lunar mantle. Higher average δ18O (WR) values of low-Ti basalts compared to terrestrial mid ocean ridge basalts (Δ=0.18‰) suggest a possible oxygen isotopic difference between the terrestrial and lunar mantles. However, calculations of the δ18O of lunar mantle olivine in this study are only 0.05‰ higher than terrestrial mantle olivine. These observations may have important implications for understanding the formation of the Earth–Moon system.  相似文献   

13.
The tropospheric zenith total delay (ZTD) derived from very long baseline interferometry (VLBI) is an important parameter of the atmosphere, reflecting various atmosphere-related processes and variations. In this paper, ZTD time series of the IVS rapid combined tropospheric product (2002–2006) with a 1-h resolution are used for the first time to investigate the diurnal and semidiurnal oscillations. Significant diurnal and semidiurnal variations of ZTD are found at all VLBI stations. The amplitude of the diurnal cycle S1 is 0.6–1.2 mm at most of the VLBI stations, and the amplitude of the semidiurnal cycle S2 is 0.2–1.9 mm, which nearly accord with the surface pressure tides S1/S2 and co-located GPS estimated S1/S2. The results indicate that the S1 and S2 behaviors are mainly dominated by the hydrostatic component, namely pressure tides. In general, the semidiurnal S2 amplitudes are slightly larger than the diurnal S1. While S1 shows no clear dependency on site altitude, S2 has a regular distribution with VLBI site altitude. The results are in accordance with predictions of the classic tidal theory [Chapman, S., Lindzen, R.S., 1970. Atmospheric Tides, Gordon and Breach, New York].  相似文献   

14.
Tektites are terrestrial natural glasses produced during a hypervelocity impact of an extraterrestrial projectile onto the Earth's surface. The similarity between the chemical and isotopic compositions of tektites and terrestrial upper continental crust implies that the tektites formed by fusion of such target rock. Tektites are among the driest rocks on Earth. Although volatilization at high temperature may have caused this extreme dryness, the exact mechanism of the water loss and the behavior of other volatile species during tektite formation are still debated. Volatilization can fractionate isotopes, therefore, comparing the isotope composition of volatile elements in tektites with that of their source rocks may help to understand the physical conditions during tektite formation.For this study, we have measured the Zn isotopic composition of 20 tektites from four different strewn fields. Almost all samples are enriched in heavy isotopes of Zn compared to the upper continental crust. On average, the different groups of tektites are isotopically distinct (listed from the isotopically lightest to the heaviest): Muong-Nong type indochinites (δ66/64Zn = 0.61 ± 0.30‰); North American bediasites (δ66/64Zn = 1.61 ± 0.49‰); Ivory Coast tektites (δ66/64Zn = 1.66 ± 0.18‰); the Australasian tektites (others than the Muong Nong-type indochinites) (δ66/64Zn = 1.84 ± 0.42‰); and Central European moldavites (δ66/64Zn = 2.04 ± 0.19‰). These results are contrasted with a narrow range of δ66/64Zn = 0–0.7‰ for a diverse spectrum of upper continental crust materials.The elemental abundance of Zn is negatively correlated with δ66/64Zn, which may reflect that isotopic fractionation occurred by evaporation during the heating event upon tektite formation. Simple Rayleigh distillation predicts isotopic fractionations much larger than what is actually observed, therefore, such a model cannot account for the observed Zn isotope fractionation in tektites. We have developed a more realistic model of evaporation of Zn from a molten sphere: during its hypervelocity trajectory, the molten surface of the tektite will be entrained by viscous coupling with air that will then induce a velocity field inside the molten sphere. This velocity field induces significant radial chemical mixing within the tektite that accelerates the evaporation process. Our model, albeit parameter dependent, shows that both the isotopic composition and the chemical abundances measured in tektites can be produced by evaporation in a diffusion-limited regime.  相似文献   

15.
Silica alteration zones and cherts are a conspicuous feature of Archaean greenstone belts worldwide and provide evidence of extensive mobilisation of silica in the marine environment of the early Earth. In order to understand the process(es) of silicification we measured the silicon and oxygen isotope composition of sections of variably silicified basalts and overlying bedded cherts from the Theespruit, Hooggenoeg and Kromberg Formations of the Barberton Greenstone Belt, South Africa.The δ30Si and δ18O values of bulk rock increase with increasing amount of silicification from unsilicified basalts (?0.64‰ < δ30Si < ?0.01‰ and + 8.6‰ < δ18O < + 11.9‰) to silicified basalts (δ30Si and δ18O values as high as + 0.81‰ and + 15.6‰, respectively). Cherts generally have positive isotope ratios (+ 0.21‰ < δ30Si < + 1.05‰ and + 10.9 < δ18O < + 17.1), except two cherts, which have negative δ30Si values, but high δ18O (up to + 19.5‰).The pronounced positive correlations between δ30Si, δ18O and SiO2 imply that the isotope variation is driven by the silicification process which coevally introduced both 18O and 30Si into the basalts. The oxygen isotope variation in the basalts from about 8.6‰ to 15.6‰ is likely to represent temperature-dependent isotope fractionation during alteration. Our proposed model for the observed silicon isotope variation relies on a temperature-controlled basalt dissolution vs. silica deposition process.  相似文献   

16.
Hot springs in the Marsyandi Valley, Nepal, vent CO2 sourced from metamorphic fluids that mix with shallow groundwaters before degassing near the Earth's surface. The δ13C of spring waters ranges up to + 13‰, while that of the coexisting free gas phase is close to ? 4‰. Empirical and thermodynamic modelling of this isotopic fractionation suggests > 97 ± 1% CO2 degassing. The calculated minimum total CO2 degassing in the Marsyandi catchment is 5.4 × 109 mol/yr from a Cl-based estimate of the spring water discharge to the Marsyandi River and the fraction of CO2 degassed. Extrapolated to the whole of the Himalayas, this implies a probable minimum metamorphic CO2 flux of 0.9 × 1012 mol/yr, or ～ 13% of solid Earth CO2 degassing. The calculated flux is a factor of three greater than the estimated CO2 drawdown by silicate weathering in the Himalayas. Himalayan metamorphic degassing contributes a significant fraction of the global solid Earth CO2 flux and implies that metamorphism may cause changes in long-term climate that oppose those resulting from the orogenic forcing of chemical weatherability.  相似文献   

17.
The spectral attenuation of solar irradiation was measured during summer in two types of coastal waters in southern Chile, a north Patagonian fjord (Seno Reloncaví) and open coast (Valdivia). In order to relate the light availability with the light requirements of upper subtidal seaweeds, the saturating irradiance for photosynthesis (Ek) from P–I curves was measured. In addition the UV risk was assessed. Based on the z1% of PAR, the lower limit of the euphotic zone in the studied systems averaged 21 m (Kd 0.24 m?1) in Seno Reloncaví and 18 m (Kd 0.27 m?1) in the coast of Valdivia. Photosynthesis of the studied seaweeds was saturated at markedly lower irradiances than found in their natural depths at the time of the study. Solar radiation penetrating into these depths at both locations largely supports the light requirements for the photosynthesis of subtidal species: 50–160 μmol m?2 s?1 for seaweeds from Seno Reloncaví (7 m tidal range) and 20–115 μmol m?2 s?1 for Valdivia assemblages (2 m tidal range). Optimal light conditions to saturate photosynthesis (Ek) were present at 10–16 m water depth. The attenuation of solar irradiation did not vary significantly between the fjord and coastal sites of this study. However, the underwater light climates to which seaweeds are exposed in these sites vary significantly because of the stronger influence of tidal range affecting the fjord system as compared with the open coastal site. The patterns of UV-B penetration in these water bodies suggest that seaweeds living in upper littoral zones such as the intertidal and shallow subtidal (<3 m) may be at risk.  相似文献   

18.
《Marine pollution bulletin》2008,56(10-12):505-511
Specimens of Nassarius nitidus were collected in seven stations of the Venice Lagoon to assess the levels of tributyltin (TBT) and its metabolites monobutyltin and dibutyltin in the tissues and monitor their effect on organisms, in particular the phenomenon of imposex (superimposition of male sexual characteristics on females). The following values of population indices were found: vas deferens sequence: 1.2 ± 0.7–4.0 ± 0.5; relative penis length: 6–47%. The least impacted station was situated in the northern part of the Lagoon, where females without imposex were found and Butyltin (BuTs) concentrations in the organisms (average sum of BuTs = 43 ± 14 ng Sn g−1 w.) were significantly lower than in the other stations (range of average sum of BuTs: 101 ± 22–217 ± 27 ng Sn g−1 d.w.). Population indices were found to be related to the TBT content in the tissues. In particular VDSI had a significant logarithmic correlation: r = 0.95, n = 8, p < 0.05.  相似文献   

19.
The oxygen isotope composition of fossil roots that have been permineralized by hematite are presented from eight different stratigraphic levels spanning the Upper Pennsylvanian and Lower Permian strata of north-central Texas. Hematite δ18O values range from − 0.4% to 3.7%. The most negative δ18O values occur in the upper Pennsylvanian strata, and there is a progressive trend toward more positive δ18O values upward through the lower Permian strata. This stratigraphic pattern is similar in magnitude and style to δ18O values reported for penecontemporaneous authigenic palaeosol phyllosilicates and calcites, suggesting that all three minerals record similar paragenetic histories that are probably attributed to temporal palaeoenvironmental changes across the Late Pennsylvanian and Early Permian landscapes.Palaeotemperature estimates based on paired δ18O values between penecontemporaneous hematite and phyllosilicate samples suggest these minerals co-precipitated at relatively low temperatures that are consistent with a supergene origin in a low-latitude soil-forming environment. Hematite–phyllosilicate δ18O pairs indicate (1) relatively low soil temperatures (∼ 24 ± 3 °C) during deposition of the upper Pennsylvanian strata followed by (2) a considerable rise in soil temperatures (∼ 35–37 ± 3 °C) during deposition of the lowermost Permian strata. Significantly, δD and δ18O values of contemporaneous phyllosilicates provide single mineral palaeotemperature estimates that are analytically indistinguishable from temperature estimates based on hematite–phyllosilicate oxygen isotope pairs. The results between the two temperature-proxy methods suggest that the inferred large temperature change across the Upper Pennsylvanian–Lower Permian boundary might be taken seriously. If real, such a significant climate change would have undoubtedly had far-reaching ecological effects within this region of Pangaea. Notably, there are important lithological and palaeobotanical changes, such as disappearance of coal and coal swamp floras, across the Upper Pennsylvanian–Early Permian boundary of north-central Texas that may be consistent with major climatic change toward warmer conditions.  相似文献   

20.
The Ca isotope compositions of 37 late Mesozoic skeletal carbonates, belemnites and brachiopods, from the Tethyan realm were analyzed by thermal (TIMS) and plasma (MC-ICP-MS) ionization mass spectrometry. A poor correlation between δ44/40Ca and δ18O values of belemnites suggests only a weak temperature dependency for the Ca isotope composition of belemnites, likely less than 0.02‰/°C. The δ44/40Ca record of belemnites was therefore used to reconstruct the Ca isotope composition of paleo-seawater (δ44/40CaSW), based on an experimentally determined fractionation factor between seawater Ca and belemnite calcite (αCC–SW) of ∼ 0.9986. The inferred δ44/40CaSW record, with an average stratigraphic resolution of 1 Ma, shows systematic temporal variation of ∼ 0.5‰ with the Middle/Late Jurassic (∼ 154 Ma) minimum of ∼ 1.4‰ and a subsequent general increase to the Early Cretaceous (∼ 124 Ma) maximum of ∼ 1.9‰. The global nature of the δ44/40CaSW record is supported by identical Ca isotope compositions of coeval (Kimmeridgian) belemnites collected from two distinct paleogeographic regions, the southern (New Zealand) and northern (Germany) margin of the Tethys Ocean. The observed late Mesozoic δ44/40CaSW record was simulated using a simple Ca isotope mass balance model, and the results indicate that the variation in δ44/40CaSW record can be explained by changes in oceanic input fluxes of Ca that were independent of the carbonate ion fluxes, such as the hydrothermal Ca flux or the release of Ca to the oceans via dolomitization of marine carbonates.  相似文献   

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