Deeply subducted carbonate rocks from the Kokchetav massif (Northern Kazakhstan) recrystallised within the diamond stability field (P = 4.5–6.0 GPa; T ≈ 1000 °C) and preserve evidence for ultra high-pressure carbonate and silicate melts. The carbonate rocks consist of garnet and K-bearing clinopyroxene embedded in a dolomite or magnesian calcite matrix. Polycrystalline magnesian calcite and polyphase carbonate–silicate inclusions occurring in garnet and clinopyroxene show textural features of former melt inclusions. The trace element composition of such carbonate inclusions is enriched in Ba and light rare earth elements and depleted in heavy rare earth elements with respect to the matrix carbonates providing further evidence that the inclusions represent trapped carbonate melt. Polyphase inclusions in garnet and clinopyroxene within a magnesian calcite marble, consisting mainly of a tight intergrowth of biotite + K-feldspar and biotite + zoisite + titanite, are interpreted to represent two different types of K-rich silicate melts. Both melt types show high contents of large ion lithophile elements but contrasting contents of rare earth elements. The Ca-rich inclusions display high REE contents similar to the carbonate inclusions and show a general trace element characteristic compatible with a hydrous granitic origin. Low SiO2 content in the silicate melts indicates that they represent residual melts after extensive interaction with carbonates. These observations suggest that hydrous granitic melts derived from the adjacent metapelites reacted with dolomite at ultra high-pressure conditions to form garnet, clinopyroxene – a hydrous carbonate melt – and residual silicate melts. Silicate and carbonate melt inclusions contain diamond, providing evidence that such an interaction promotes diamond growth. The finding of carbonate melts in deeply subducted crust might have important consequences for recycling of trace elements and especially C from the slab to the mantle wedge. 相似文献
It is a consensus that marine carbonate archives the isotopic composition of seawater dissolved inorganic carbon(DIC,δ~(13)C_(sw)),the largest active C reservoir in the hydrosphere.Carbonate carbon isotope(δ~(13)C_(carb)) excursions have been used to reflect perturbations of the global carbon cycle and related environmental change.However,the deep time δ~(13)C_(carb) records indicate faster and more pronounced perturbations of the carbon cycle compared to the present day.Here,we report δ~(13)C_(carb) and elemental compositions of Late Paleozoic carbonate sections from South China,showing negative correlations between δ~(13-)C_(carb) and Fe~(2+) content of carbonate(Fe_(carb)).We suggest that,because Late Paleozoic carbonate was mainly produced by benthic carbonate-secreting organisms,δ~(13)C_(carb)recorded the isotopic composition near the seafloor,where benthic flux derived from anaerobic organic matter degradation delivers both Fe~(2+) and ~(13)C-depleted DIC from porewater.The binary mixing between seawater and benthic flux would result in the deviation of δ~(13)C_(carb) fromδ~(13)C_(sw).The negative correlation implies that δ~(13)C_(carb) is influenced by benthic flux and is affected by the seafloor redox and sedimentation rate.The deep time spatially heterogeneous and temporally oscillatory δ~(13)C_(carb) records in the basin-scale could be alternatively attributed to the variations of local environmental factors rather than aδ~(13)C_(sw) depth-gradient.Thus,the seafloor carbonate precipitation is continuously affected by diagenetic reactions in sediments,suggesting that δ~(13)C_(carb) recording the seawater DIC composition is conditional.Our study urges that the interpretation of δ~(13)C_(carb) should also consider the sedimentary process and depositional environment of marine carbonate. 相似文献
Reduced silicon alloyed with Fe metal was shown to chemically react with FeCO3 siderite at pressures of 10–25 GPa and temperatures of 1700–1800 °C according to2 FeCO3siderite+3 Si in metal=2 Fe in metal+3 SiO2 stishovite+2 CdiamondSince no carbon seeds were introduced, the only source of carbon for diamond formation was the carbonate phase. This observation provides a mechanism of diamond formation, possibly relevant to the early Earth. Thermodynamic modelling of the observed reactions shows that the stishovite/silicon oxygen fugacity buffer is far more reducing than the carbonate/diamond equilibrium, implying that, at Earth mantle conditions, no silicon-bearing metal can coexist with carbonates. Diamond formation by reactions between carbonates and highly reducing metal phases containing significant amounts of silicon might have occurred in the early Earth upon mixing of oxidized and reduced accretion components at pressures and temperature exceeding 10 GPa and 1700 °C. 相似文献
The very diverse types of ground‐water behavior in carbonate terrains can be classified by relating the flow type to a particular hydrogeologic environment each exhibiting a characteristic cave morphology. The ground water may move by diffuse flow, by retarded flow, or by free flow. Diffuse flow occurs in less soluble rocks such as extremely shaley limestones or crystalline dolomites. Integrated conduits are rare. Caves tend to be small, irregular, and often little more than solutionally widened joints. Retarded flows occur in artesian environments and in situations where unfavorable stratigraphy forces ground water to be confined to relatively thin beds. Network cave patterns are characteristic since hydrodynamic forces are damped by the external controls. Solution occurs along many available joints. Free flowing aquifers are those in which solution has developed a subsurface drainage system logically regarded as an underground extension of surface streams. These streams may have fully developed surface tributaries as well as recharge from sinkholes and general infiltration. Characteristic cave patterns are those of integrated conduit systems which are often truncated into linear, angulate, and branchwork caves. Free Flow aquifers may be further subdivided into Open aquifers lying beneath karst plains and Capped aquifers in which significant parts of the drainage net lie beneath an insoluble cap rock. Other geologic factors such as structure, detailed lithology, relief, and locations of major streams, control the details of cave morphology and orientation of the drainage network. 相似文献
The analytic element method (AEM) has been applied to a 15,000-km2 area of the Paleozoic carbonate rock terrain of Nevada. The focus is the Muddy River springs area, which receives 1.44 m3/s (51 ft3/s) of regionally derived ground water, and forms the Muddy River. The study was undertaken early in 2000 to support the development of a cooling water supply for a gas-fired generation facility 20 km south of the Muddy River springs. The primary objectives of the AEM modeling were to establish a better understanding of regional fluxes and boundary conditions and to provide a framework for examination of more local transient effects using MODFLOW. Geochemical evidence available in 2000 suggested two separate flow fields, one in the north discharging at the springs, and a southern area of small hydraulic gradients. To be conservative, however, hydraulic continuity between the two areas was maintained in the 2000 AEM model. Using new monitoring well data collected in the south, and analyses confirming that seasonal pumping effects in the north are not propagated to the south, a later AEM model that included a barrier calibrated with relative ease. The analytic element model was well suited for simulating an area larger than the immediate area of interest, was easy to modify as more information became available, and facilitated the stepwise development of multiple conceptual models of the site. 相似文献
The solubility of silica in water has been determined by Vinogradov in 1966 and shown to be dependent on pH, but he did not investigate the alkaline side, and there is also the interesting problem of bicarbonates, which though mildly alkaline in pH, are potentially capable of reacting with silicates to form silica and a normal carbonate. Many natural waters exist which do contain appreciable amounts of silica and bicarbonate. It is therefore of interest to know just how close these may be to precipitating silica. This has been determined experimentally. 相似文献
Nearly 200 analyses of meltwaters, ice and snow from three alpine glacial sites in carbonate terrain are summarized and discussed in terms of sources of solutes and kinetic controls on the progress of weathering reactions. Most data derive from the Swiss Glacier de Tsanfleuron which is based on Cretaceous and Tertiary pure and impure limestones. Two other sites (Marmolada, Italian Dolomites and the Saskatchewan Glacier, Alberta) are based on a mixed calcitic-dolomitic substrate. Most solutes originate from carbonate dissolution; moreover, where pyrite is present its oxidation supplies significant sulphate and forces more dissolution of carbonate. The ratios Sr2+/Ca2+ and Mg2+/Ca2+ are much higher in Tsanfleuron melt-waters than local bedrock, a phenomenon that can be reproduced in the laboratory at small percentages of dissolution. These anomalous ratios are attributed to incongruent dissolution of traces of the metastable carbonates Mg-calcite and aragonite. These phases also provide Na+ to solution. K+ is argued to originate mainly by ion-exchange on clays with solute Ca2+. Quartz and very minor feldspar dissolution are also inferred. Locally enhanced input from atmospheric sources is recognized by high Cl? and associated Na+. The progress of weathering reactions has been evaluated by the trends in the data, computer modelling and some simple laboratory experiments. The most dilute samples show a trend towards removal of CO2 to low partial pressures (c. 10?5.5 atmospheres), reflecting initially rapid carbonate dissolution and relatively slow dissolution of gaseous CO2. Later addition of atmospheric CO2 or acid from pyrite oxidation allows further carbonate dissolution, but solutions show a wide range of saturations, and CO2 pressures as high as 10?2.2 where pyrite oxidation is important. In a carbonate terrain, measurement of electroconductivity (corrected to 25°C) and alkalinity in the field allows the following preliminary deductions (where meq stands for milliequivalents): where S is the minimum meq(Ca2+ + Mg2+) produced by simple dissolution of carbonate unconnected with pyrite oxidation. As with any proxy method, these deductions do not remove the need for chemical analysis of waters in a given study area. 相似文献
Cyclic triaxial tests have been carried out on a skeletal carbonate sand from the west coast of Eire. Results are presented for undrained cyclic shear tests on samples with 80% of relative density consolidated under both isotropic and anisotropic conditions. Failure was defined as a 5% double amplitude cyclic strain and a 5% peak axial strain for stress-reversal and non-reversal stress conditions, respectively. Using this definition the cyclic strength for isotropically consolidated samples was affected by the confining pressure although the angular platey nature of the sand resulted in higher cyclic strengths than for a comparable silica sand. For anisotropically consolidated samples the cyclic strength increased with increasing initial static shear stress while on the other hand the cyclic strength normalised in the usual way with respect to the initial confining pressure decreased as this pressure increased. 相似文献
Burial stress on a sediment or sedimentary rock is relevant for predicting compaction or failure caused by changes in, e.g., pore pressure in the subsurface. For this purpose, the stress is conventionally expressed in terms of its effect: “the effective stress” defined as the consequent elastic strain multiplied by the rock frame modulus. We cannot measure the strain directly in the subsurface, but from the data on bulk density and P‐wave velocity, we can estimate the rock frame modulus and Biot's coefficient and then calculate the “effective vertical stress” as the total vertical stress minus the product of pore pressure and Biot's coefficient. We can now calculate the elastic strain by dividing “effective stress” with the rock frame modulus. By this procedure, the degree of elastic deformation at a given time and depth can be directly expressed. This facilitates the discussion of the deformation mechanisms. The principle is illustrated by comparing carbonate sediments and sedimentary rocks from the North Sea Basin and three oceanic settings: a relatively shallow water setting dominated by coarse carbonate packstones and grainstones and two deep water settings dominated by fine‐grained carbonate mudstones and wackestones. 相似文献
A tracer test in a carbonate aquifer is analyzed using the method of moments and two analytical advection-dispersion models (ADMs) as well as a numerical model. The numerical model is a coupled continuum-pipe flow and transport model that accounts for two different flow components in karstified carbonate aquifers, i.e., rapid and often turbulent conduit flow and Darcian flow in the fissured porous rock. All techniques employed provide reasonable fits to the tracer breakthrough curve (TBC) measured at a spring. The resulting parameter estimates are compared to investigate how each conceptual model of flow and transport processes that forms the basis of the analyses affects the interpretation of the tracer test. Numerical modeling results suggest that the method of moments and the analytical ADMs tend to overestimate the conduit volume because part of the water discharged at the spring is wrongly attributed to the conduit system if flow in the fissured porous rock is ignored. In addition, numerical modeling suggests that mixing of the two flow components accounts for part of the dispersion apparent in the measured TBC, while the remaining part can be attributed to Taylor dispersion. These processes, however, cannot reasonably explain the tail of the TBC. Instead, retention in immobile-fluid regions as included in a nonequilibrium ADM provides a possible explanation. 相似文献
A great variety of man's activities on the coast result in metal contamination of the sea. Investigations at three sites, two in Florida and one in Bermuda reveal trace metals in sediments. In all three cases these accumulations can be ascribed to local human activities, though their nature varies widely from one site to another. 相似文献
Analysis of the morphology of dissolution-bedform assemblages and hydraulically-transported sediments found within conduits in carbonate aquifers in North America and the British Isles has allowed the hydraulic conditions under which conduit flows occur to be established. Mean values of flow velocity, boundary-shear stress, conduit Reynolds number, conduit Froude number, boundary friction factor, boundary roughness and flow power have been calculated. The values obtained are in agreement with other evidence in the conduits and are comparable to those obtained from other, similar, hydraulic systems. 相似文献
In this study, a new method-the asymmetric dipole-flow test-is proposed and tested for characterization of conductive properties and structure of fractured aquifers. Analytical solutions were developed and then used for interpretation of a modification of the dipole-flow test with a single packer at the Bissen Quarry test site (Wisconsin, USA). The asymmetric dipole-flow tests were conducted by packing a well at various elevations, and fluids were pumped from the upper section (chamber) of the well to the lower section (chamber). The head was then monitored at 11 observation points and in both sections of the well, and the conductivities of the well segments were determined. The tests at seven packer elevations in the well were rapid (less than one hour to reach steady state). The asymmetric dipole-flow test demonstrates the potential to quantify heterogeneities of a fractured aquifer and delineate the applicability of the continuum and discrete approaches for conceptualization of ground water flow. 相似文献
We study the relationships among precipitation, vegetation, and morphological characteristics of watersheds draining either side of the Dhofar Mountains in southeastern Oman to understand the geomorphic signature of water availability in a semi-arid carbonate landscape. Water availability is expressed in terms of vegetation and cloud cover. The integral and the statistical moments of the hypsometric curve were used to determine whether hyper-arid, inland-draining watersheds are significantly different from seasonally wet watersheds on the coast side of the mountain range. We demonstrate that the vegetation and cloud cover are correlated, with locations with longer cloud periods also having a longer period with a vegetation canopy. The analysis shows that the hypsometric curve and its statistical moments capture the morphological difference between wet watersheds shaped by groundwater sapping and dry watersheds with fluvial morphology. Specifically, the curves exhibit two shapes: watersheds with more vegetation and cloud cover are characterized by higher convexity, and those with less vegetation and cloud cover are characterized by higher concavity. A variance analysis of cloud cover, vegetation, and hypsometric integral shows that they are significantly different between the wet and dry watersheds. The link between hydrology and morphology is not strong at the scale of a single watershed, but it is significant when the watersheds are aggregated in zones. The statistical moments of the hypsometric curve in the range of values of the integral and skewness show good separation between watersheds dominated by sapping and fluvial erosion processes. We can separate the watersheds draining the mountain range in two distinct groups on the basis of their bimodal hydrological and morphological characteristics. Our findings support other studies that hypothesize a trade-off from chemical- to mechanical-dominated denudation in carbonate terranes as precipitation decreases. 相似文献
Characterizing the pore space of rock samples using three‐dimensional (3D) X‐ray computed tomography images is a crucial step in digital rock physics. Indeed, the quality of the pore network extracted has a high impact on the prediction of rock properties such as porosity, permeability and elastic moduli. In carbonate rocks, it is usually very difficult to find a single image resolution which fully captures the sample pore network because of the heterogeneities existing at different scales. Hence, to overcome this limitation a multiscale analysis of the pore space may be needed. In this paper, we present a method to estimate porosity and elastic properties of clean carbonate (without clay content) samples from 3D X‐ray microtomography images at multiple resolutions. We perform a three‐phase segmentation to separate grains, pores and unresolved porous phase using 19 μm resolution images of each core plug. Then, we use images with higher resolution (between 0.3 and 2 μm) of microplugs extracted from the core plug samples. These subsets of images are assumed to be representative of the unresolved phase. We estimate the porosity and elastic properties of each sample by extrapolating the microplug properties to the whole unresolved phase. In addition, we compute the absolute permeability using the lattice Boltzmann method on the microplug images due to the low resolution of the core plug images. In order to validate the results of the numerical simulations, we compare our results with available laboratory measurements at the core plug scale. Porosity average simulations for the eight samples agree within 13%. Permeability numerical predictions provide realistic values in the range of experimental data but with a higher relative error. Finally, elastic moduli show the highest disagreements, with simulation error values exceeding 150% for three samples. 相似文献
Carbonate sediments of mid-Cretaceous platforms on Allison and Resolution Guyots, Mid-Pacific Mountains (ODP Leg 143, Sites 865, 866, 867 and 868) and those of upper Oligocene to Pliocene reefs of the Kita-daito-jima Borehole were studied. The mid-Cretaceous platforms abound with abiotic (?) precipitates (ooids) and microbial carbonate grains/sediments (oncoids and ‘algal’ laminites), whereas the Cenozoic reefs consist mainly of coral and non-geniculate coralline algae, major frame-builders, benthic foraminifers and codiacean alga (Halimeda). There exists a remarkable difference in a mode of calcification between the mid-Cretaceous platforms and Cenozoic reefs. The major reef-builders of Cenozoic reefs precipitated carbonates within closed to semiclosed spaces within their bodies. In contrast, the mid-Cretaceous platforms contain abundant grains/sediments formed by chemical (?) precipitations and biotic extracellular calcification. This contrasting feature reflects different modes of biogeochemical cycles between the mid-Cretaceous and Cenozoic. Increased CO2 (degassed by active volcanism) and resultant high temperature and intensive weathering may have brought high concentration of Ca2+ and HCO3? into the mid-Cretaceous sea, which enhanced abiotic and extracellular calcification. Inverse processes are true for the Cenozoic. 相似文献
South China is the largest continuous distribution area of carbonate rock in the world. The origin of the soils over the bedrock
carbonate rock has long been a controversial topic. Here further exploration is made by taking five soil profiles as examples,
which are developed over the bedrock dolomitite and limestone and morphologically located in upland in karst terrain in the
central, west and north Guizhou as well as west Hunan, and proved to be the weathering profiles of carbonate rock by the research
results of acid-dissolved extraction experiment of bedrock, mineralogy and trace element geochemistry. Field, mineralogical
and trace element geochemical characteristics of weathering and pedogenesis for carbonate rock are discussed in detail. It
is pointed out that weathering and pedogenesis of carbonate rock are important pedogenetic mechanisms for soil resources in
karst area, providing a basis for further researches on the origin of soils widely overlying bedrock carbonate rocks in South
China.
Project supported by the National Natural Science Foundation of China (Grant No. 498330003) and National Key Basic Research
Project (Grant No. 95pre-39). 相似文献
