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1.
Inversion of local earthquake travel times and joint inversion of receiver functions and Rayleigh wave group velocity measurements were used to derive a simple model for the velocity crustal structure beneath the southern edge of the Central Alborz (Iran), including the seismically active area around the megacity of Tehran. The P and S travel times from 115 well-located earthquakes recorded by a dense local seismic network, operated from June to November 2006, were inverted to determine a 1D velocity model of the upper crust. The limited range of earthquake depths (between 2 km and 26 km) prevents us determining any velocity interfaces deeper than 25 km. The velocity of the lower crust and the depth of the Moho were found by joint inversion of receiver functions and Rayleigh wave group velocity data. The resulting P-wave velocity model comprises an upper crust with 3 km and 4 km thick sedimentary layers with P wave velocities (Vp) of ～5.4 and ～5.8 km s?1, respectively, above 9 km and 8 km thick layers of upper crystalline crust (Vp ～6.1 and ～6.25 km s?1 respectively). The lower crystalline crust is ～34 km thick (Vp ～ 6.40 km s?1). The total crustal thickness beneath this part of the Central Alborz is 58 ± 2 km.  相似文献   

2.
Modeling of multimode surface wave group velocity dispersion data sampling the eastern and the western Ganga basins, reveals a three layer crust with an average Vs of 3.7 km s?1, draped by ～2.5 km foreland sediments. The Moho is at a depth of 43 ± 2 km and 41 ± 2 km beneath the eastern and the western Ganga basins respectively. Crustal Vp/Vs shows a felsic upper and middle crust beneath the eastern Ganga basin (1.70) compared to a more mafic western Ganga basin crust (1.77). Due to higher radiogenic heat production in felsic than mafic rocks, a lateral thermal heterogeneity will be present in the foreland basin crust. This heterogeneity had been previously observed in the north Indian Shield immediately south of the foreland basin and must also continue northward below the Himalaya. The high heat producing felsic crust, underthrust below the Himalayas could be an important cause for melting of midcrustal rocks and emplacement of leucogranites. This is a plausible explanation for abundance of leucogranites in the east-central Himalaya compared to the west. The uppermost mantle Vs is also significantly lower beneath the eastern Ganga basin (4.30 km s?1) compared to the west (4.44 km s?1).  相似文献   

3.
Electrical conductivity and seismic velocity are studied for plausible pore geometries in the Earth's interior for reliable quantitative analysis of experimental data such as seismic tomography and magnetotelluric explorations. Electrical conductivity of a two-phase system with equilibrium, interfacial energy-controlled phase geometry is calculated for the dihedral angles θ = 40°–100° that are typical for rock–aqueous fluid and θ = 20°–60° for rock–melt systems of lower crust and upper mantle for the case of tetrakaidecahedral grains. Electrical conductivity vs. seismic velocity correlations are acquired by combining of the simulated electrical conductivities with the seismic velocity calculated with the help of equilibrium geometry model Takei [Takei, Y., Effect of pore geometry on VP/VS: From equilibrium geometry to crack. J. Geophys. Res. 107 (2002): 10.1029/2001JB000522.] for the same pore geometries. The results show that electrical conductivity gradually decreases reaching zero when seismic velocities reach seismic velocities of intact rock for rock–melt systems, while for rock–aqueous fluid systems with θ ≥ 60° conductivity drops to zero at velocities up to 10% smaller. This can explain the seeming discrepancy of the low seismic velocity region, attributed to the high fluid fraction, and the low electrical conductivity of the same region, which is sometimes faced at collocated electromagnetic and seismic experiments.  相似文献   

4.
Mid-latitude Digisonde Doppler velocities, auroral electrojet (AE) indices and cloud-to-ground (CG) lightning strokes during August 2003–2004 were used to study the perturbations in the F-region vertical drift associated with terrestrial thunderstorms. A superposed epoch analysis (SEA) showed that the F-region vertical drifts Vz had a net descent of ～0.6 m s?1 peaking ～3 h after lightning. Stronger downward perturbations of up to ～0.9 m s?1 were observed in the afternoon on the day prior to lightning days. The perturbations were less significant on the day after and insignificant during the remaining intervals up to 144 h on either side of the lightning. The stronger responses on the day before are consistent with causality because the lightning times were merely proxies for the physical mechanisms involved. The actual causes are unclear, but we discuss the possible roles of lightning-induced ionisation enhancements, intense electric fields penetrating upward from electrified clouds, and atmospheric gravity waves (AGWs) radiated from thunderstorms or from the accompanying tropospheric fronts. There is no doubt that the behaviour of the mid-latitude F-region is controlled by the thermospheric winds and the solar wind-magnetosphere electrical generators, but our results suggest that electrified clouds also account for a significant, albeit relatively small component of the ionospheric variability.  相似文献   

5.
The late Triassic to early Tertiary Coast Mountains Batholith (CMB) of British Columbia provides an ideal locale to study the processes whereby accreted terranes and subduction-related melts interact to form stable continental crust of intermediate to felsic composition and complementary ultramafic residuals. Seismic measurements, combined with calculated elastic properties of various CMB rock compositions, provide a window into the deep-crustal lithologies that are key to understanding the processes of continental growth and evolution. We use a combination of seismic observations and petrologic modeling to construct hypothetical crustal sections at representative locations across the CMB, then test the viability of these sections via forward modeling with synthetic seismic data. The compositions that make up our petrologic forward models are based on calculations using the free energy minimization program Perple_X to predict mineral assemblages at depth for the bulk compositions of exposed plutonic rocks collected in the study area. Seismic data were collected along two transects in west-central British Columbia: a southern line that crossed the CMB near the town of Bella Coola (near 52° N), and a northern line centered on the towns of Terrace and Kitimat (near 54° N). Along both transects, seismic receiver functions reveal high Vp/Vs ratios near the Insular/Intermontane terrane boundary and crustal thickness increasing from 26 ± 3 km to 34 ± 3 km (at the 1 sigma certainty level) from west to east across the Coast Shear Zone (CSZ). On the southern line, we observe an anomalous region of complex receiver functions and diminished Moho signals beneath the central portion of the CMB. Our petrologic and seismic profiles show that observed seismic data from much of the CMB can be well-matched in terms of crustal thickness and structure, average Vp/Vs, and amplitude of the Moho converted phase, without including ultramafic residual material in the lower crust.  相似文献   

6.
Two-dimensional crustal velocity models are derived from passive seismic observations for the Archean Karelian bedrock of north-eastern Finland. In addition, an updated Moho depth map is constructed by integrating the results of this study with previous data sets. The structural models image a typical three-layer Archean crust, with thickness varying between 40 and 52 km. P wave velocities within the 12–20 km thick upper crust range from 6.1 to 6.4 km/s. The relatively high velocities are related to layered mafic intrusive and volcanic rocks. The middle crust is a fairly homogeneous layer associated with velocities of 6.5–6.8 km/s. The boundary between middle and lower crust is located at depths between 28 and 38 km. The thickness of the lower crust increases from 5–15 km in the Archean part to 15–22 km in the Archean–Proterozoic transition zone. In the lower crust and uppermost mantle, P wave velocities vary between 6.9–7.3 km/s and 7.9–8.2 km/s. The average Vp/Vs ratio increases from 1.71 in the upper crust to 1.76 in the lower crust.The crust attains its maximum thickness in the south-east, where the Archean crust is both over- and underthrust by the Proterozoic crust. A crustal depression bulging out from that zone to the N–NE towards Kuusamo is linked to a collision between major Archean blocks. Further north, crustal thickening under the Salla and Kittilä greenstone belts is tentatively associated with a NW–SE-oriented collision zone or major shear zone. Elevated Moho beneath the Pudasjärvi block is primarily explained with rift-related extension and crustal thinning at ∼2.4–2.1 Ga.The new crustal velocity models and synthetic waveform modelling are used to outline the thickness of the seismogenic layer beneath the temporary Kuusamo seismic network. Lack of seismic activity within the mafic high-velocity body in the uppermost 8 km of crust and relative abundance of mid-crustal, i.e., 14–30 km deep earthquakes are characteristic features of the Kuusamo seismicity. The upper limit of seismicity is attributed to the excess of strong mafic material in the uppermost crust. Comparison with the rheological profiles of the lithosphere, calculated at nearby locations, indicates that the base of the seismogenic layer correlates best with the onset of brittle to ductile transition at about 30 km depth.We found no evidence on microearthquake activity in the lower crust beneath the Archean Karelian craton. However, a data set of relatively well-constrained events extracted from the regional earthquake catalogue implies a deeper cut-off depth for earthquakes in the Norrbotten tectonic province of northern Sweden.  相似文献   

7.
The spectral attenuation of solar irradiation was measured during summer in two types of coastal waters in southern Chile, a north Patagonian fjord (Seno Reloncaví) and open coast (Valdivia). In order to relate the light availability with the light requirements of upper subtidal seaweeds, the saturating irradiance for photosynthesis (Ek) from P–I curves was measured. In addition the UV risk was assessed. Based on the z1% of PAR, the lower limit of the euphotic zone in the studied systems averaged 21 m (Kd 0.24 m?1) in Seno Reloncaví and 18 m (Kd 0.27 m?1) in the coast of Valdivia. Photosynthesis of the studied seaweeds was saturated at markedly lower irradiances than found in their natural depths at the time of the study. Solar radiation penetrating into these depths at both locations largely supports the light requirements for the photosynthesis of subtidal species: 50–160 μmol m?2 s?1 for seaweeds from Seno Reloncaví (7 m tidal range) and 20–115 μmol m?2 s?1 for Valdivia assemblages (2 m tidal range). Optimal light conditions to saturate photosynthesis (Ek) were present at 10–16 m water depth. The attenuation of solar irradiation did not vary significantly between the fjord and coastal sites of this study. However, the underwater light climates to which seaweeds are exposed in these sites vary significantly because of the stronger influence of tidal range affecting the fjord system as compared with the open coastal site. The patterns of UV-B penetration in these water bodies suggest that seaweeds living in upper littoral zones such as the intertidal and shallow subtidal (<3 m) may be at risk.  相似文献   

8.
Characterization of shallow structures was performed by using different approaches analysing both P- and S-wave seismic data with different resolution. The refraction tomography provided P and S velocity models of the first 80 m, while the reflection seismic processing gives a reasonable stacking velocity field until 300 m depth for both P- and S-wave data. So, we estimated the Vp/Vs ratio and an empirical relationship between the two velocities. We characterised the shallow layers using tomographic velocity models and the deeper layers using seismic images with different resolution. The seismic images were obtained by conventional CMP reflection seismic processing and by a novel multi-refractor imaging technique.  相似文献   

9.
We report experimental observation of a sizable elastic anisotropy in a polycrystalline sample of ferromagnesian silicate in post-perovskite (ppv) structure. Using a novel composite X-ray transparent gasket to contain and synthesize ppv in a panoramic diamond-anvil cell along with oblique X-ray diffraction geometry, we observed the anisotropic lattice strain and {1 0 0} or {1 1 0} slip-plane texture in the sample at 140 GPa. We deduced the elasticity tensor (cij), orientation-dependent compressional wave velocities, polarization-dependent shear-wave velocities, and the velocity anisotropy of the silicate ppv. Our results are consistent with calculations and indicate that with sufficient preferred orientation, the elastic anisotropy of this phase can produce large shear-wave splitting.  相似文献   

10.
The liquefaction potential of soils is traditionally assessed through geotechnical approaches based on the calculation of the cyclical stress ratio (CSR) induced by the expected earthquake and the ‘resistance’ provided by the soil, which is quantified through standard penetration (SPT), cone penetration (CPT), or similar tests. In more recent years, attempts to assess the liquefaction potential have also been made through measurement of shear wave velocity (VS) in boreholes or from the surface. The latter approach has the advantage of being non-invasive and low cost and of surveying lines rather than single points. However, the resolution of seismic surface techniques is lower than that of borehole techniques and it is still debated whether it is sufficient to assess the liquefaction potential.In this paper we focus our attention on surface seismic techniques (specifically the popular passive and active seismic techniques based on the correlation of surface waves such as ReMiTM, MASW, ESAC, SSAP, etc.) and explore their performance in assessing the liquefaction susceptibility of soils. The experimental dataset is provided by the two main seismic events of ML=5.9 and 5.8 (MW=6.1, MW=6.0) that struck the Emilia-Romagna region (Northern Italy) on May 20 and 29, 2012, after which extensive liquefaction phenomena were documented in an area of 1200 km2.The CPT and drillings available in the area allow us to classify the soils into four classes: A) shallow liquefied sandy soils, B) shallow non-liquefied sandy soils, C) deep non-liquefied sandy soils, and D) clayey–silty soils, and to determine that on average class A soils presented a higher sand content at the depth of 5–8 m compared to class B soils, where sand was dominant in the upper 5 m. Surface wave active–passive surveys were performed at 84 sites, and it was found that they were capable of discriminating among only three soil classes, since class A and B soils showed exactly the same VS distribution, and it is possible to show both experimentally and theoretically that they appear not to have sufficient resolution to address the seismic liquefaction issue.As a last step, we applied the state-of-the art CSR–VS method to assess the liquefaction potential of sandy deposits and we found that it failed in the studied area. This might be due to the insufficient resolution of the surface wave methods in assessing the Vs of thin layers and to the fact that Vs scales with the square root of the shear modulus, which implies an intrinsic lower sensitivity of Vs to the shear resistance of the soil compared to parameters traditionally measured with the penetration tests. However, it also emerged that the pure observation of the surface wave dispersion curves at their simplest level (i.e. in the frequency domain, with no inversion) is still potentially informative and can be used to identify the sites where more detailed surveys to assess the liquefaction potential are recommended.  相似文献   

11.
Outcrops of the Cretaceous Upper sandstone formation some 375 km to the East of Addis Ababa on the motor Highway to Harar was paleomagnetically investigated. About seventy core samples were collected at various stratigraphic levels from 250–300 meters thick sedimentary formation. After standard sample preparations in the laboratory the resulting specimens were subjected to routine paleomagnetic demagnetization protocol. In the first steps of demagnetizations process the recent and viscous magnetizations were removed by heating until a temperature of level of 300 °C. Further demagnetization of the samples resulted in the isolation of the final magnetization with stable line segments that is directed towards the origin, which is interpreted as Characteristic Remanent Magnetization (ChRM). Rock – magnetic experiments have identified goethite (αFeOOH), hematite (αFe2O3), detritial hematite, and magnetite as the magnetic mineral phases carrying the remanence. The ChRM identified resulted in an average value of (Ds = 0.5°, Is = ?0.7°, α95 = 4.3°, N = 34) for the red sandstones while an average value of (Ds = 335.8°, Is = ?31.8°, α95 = 4.7°, N = 14) for the limestone intercalations. The former ChRM in the red sandstone is determined to be secondary while the latter ChRM is known to be primary. Comparison of these directional results and their pole equivalents with the African plate Apparent Polar Wander Path curve established by Besse and Courtillot (2003) give ages of between 115–130 Million years for the limestone intercalation and ages of 30 million years for red sandstone unit. These are interpreted respectively as estimates of the age of deposition and a later remagnetization respectively.  相似文献   

12.
Large Igneous Province (LIP) eruption sites of the past 300 My lie vertically above 1% slow shear wave velocity (Vs) contours bounding the African and Pacific Large Low Shear Velocity Provinces (LLSVPs) at the core–mantle boundary (CMB), or in the cases of the Siberian and Columbia River LIPs, bounding one or other of two smaller, Low Shear Velocity Provinces (LSVPs). Steep gradients in Vs at the CMB coincide with those 1% slow contours. The sites of 24 active hotspot volcanoes project down to the same narrowly defined borders of the LLSVPs at the CMB. Plumes that have generated LIPs and major hotspot volcanoes have risen only from the immediate neighbourhoods of the 1% slow Vs contours at the CMB which thus define Plume Generation Zones (PGZs). PGZs projected vertically upward approximately match the + 10 m elevation contour of the geoid showing that the LLSVPs are a dominant control on the positively elevated geoid. Minima in the frequency distribution of shear wave velocities in the lowermost mantle near Vs = ? 1% indicate that regions with more negative velocities, forming ～ 2% of total mantle mass, are likely to be of material compositionally different from the rest of the mantle. Because all LIP eruption sites with ages younger than 300 Ma lie above the borders of LLSVPs or LSVPs at the CMB, PGZ footprints are inferred to have remained in the same places for the past 300 My. Because no plumes have risen from the interior of the LLSVPs and because no lithospheric slabs have penetrated those bodies the volumes of the LLSVPs are inferred to have also remained unchanged for the past 300 My. Because the LLSVPs are the dominant control on the positively elevated areas of the geoid those too must have remained as they now are since 300 Ma. The LLSVPs are not rising buoyant objects but stable features of the deep mantle. LIPs have been erupted throughout the past 2.5 Gy indicating that PGZs comparable to those of the past 0.3 Gy and LLSVPs (of which PGZs mark the margins at the CMB) have also existed for at least that long. LLSVPs could thus form the isolated reservoir invoked by some to explain the distinctive isotopic compositions of terrestrial rocks. PGZs lie at places where the boundaries of: (i) The outer core, (ii) one of the LLSVPs or LSVPs, and (iii) the seismically faster part of the deep mantle meet. Horizontal temperature gradients across the steeply inclined margins to the LLSVPs, the interiors of which are hotter than the surrounding mantle, at the CMB are key controls for the generation of plumes. Near the CMB the association of the high temperature of the outer core with an inclined thermal boundary layer at the margins of LLSVPs facilitates the generation of mantle plumes in the PGZs.  相似文献   

13.
Growth, stem morphology and some biochemical parameters were studied of one completely submerged (Myriophyllum spicatum) and two floating leaved macrophytes (Nymphoides peltata and Trapa japonica) under different turbulence velocities. The root mean square velocities of the high, medium and low amount of turbulence that was generated for the experiment were 2.18 ± 0.66, 1.48 ± 0.26 and 0.70 ± 0.07 cm s−1, respectively, in the microcosm. All three experimental plants survived exposed to all turbulence conditions provided, although a decrease in shoot elongation rate was associated with an increase in turbulence. Acceleration of tissue H2O2 generation and MDA content increased during the study period in all plant species. Oxidative enzymatic activities (POD, IAA and CKX) increased with time in plants under medium and high turbulence velocities. The shoot elongation rate, stem and leaf diameter, chlorophyll content and carbohydrate fractionations were found to be affected by this abiotic stress. It is evident from this study that high turbulence velocity inhibits normal metabolic activities of all three plants, while low to medium turbulence does not harm the floating leaved plants. Moreover, floating leaved plants were found to possess highly capable strategies to cope with this mechanical stress than completely submerged species.  相似文献   

14.
We investigated the provenance of organic matter in the inner fjord area of northern Patagonia, Chile (～44–47°S), by studying the elemental (organic carbon, total nitrogen), isotopic (δ13C, δ15N), and biomarker (n-alkanoic acids from vascular plant waxes) composition of surface sediments as well as local marine and terrestrial organic matter. Average end-member values of N/C, δ13C, and δ15N from organic matter were 0.127±0.010, ?19.8±0.3‰, and 9.9±0.5‰ for autochthonous (marine) sources and 0.040±0.018, ?29.3±2.1‰, and 0.2±3.0‰ for allochthonous (terrestrial) sources. Using a mixing equation based on these two end-members, we calculated the relative contribution of marine and terrestrial organic carbon from the open ocean to the heads of fjords close to river outlets. The input of marine-derived organic carbon varied widely and accounted for 13–96% (average 61%) of the organic carbon pool of surface sediments. Integrated regional calculations for the inner fjord system of northern Patagonia covered in this study, which encompasses an area of ～4280 km2, suggest that carbon accumulation may account for between 2.3 and 7.8×104 ton C yr?1. This represents a storage capacity of marine-derived carbon between 1.8 and 6.2×104 ton yr?1, which corresponds to an assimilation rate of CO2 by marine photosynthesis between 0.06 and 0.23×106 ton yr?1. This rate suggests that the entire fjord system of Patagonia, which covers an area of ～240,000 km2, may represent a potentially important region for the global burial of marine organic matter and the sequestration of atmospheric CO2.  相似文献   

15.
To date, studies of the stability of subsurface ice in the McMurdo Dry Valleys of Antarctica have been mainly based on climate-based vapor diffusion models. In University Valley (1800 m), a small glacier is found at the base of the head of the valley, and adjacent to the glacier, a buried body of massive ice was uncovered beneath 20–40 cm of loose cryotic sediments and sandstone boulders. This study assesses the origin and stability of the buried body of massive ice by measuring the geochemistry and stable O–H isotope composition of the ice and applies a sublimation and molecular diffusion model that accounts for the observed trends. The results indicate that the buried massive ice body represents an extension of the adjacent glacier that was buried by a rock avalanche during a cold climate period. The contrasting δ18O profiles and regression slope values between the uppermost 6 cm of the buried massive ice (upward convex δ18O profile and SD-18O = 5.1) and that below it (progressive increase in δ18O and SD-18O = 6.4) suggest independent post-depositional processes affected the isotope composition of the ice. The upward convex δ18O profile in the uppermost 6 cm is consistent with the ice undergoing sublimation. Using a sublimation and molecular diffusion model, and assuming that diffusion occurred through solid ice, the sublimation rate needed to fit the measured δ18O profile is 0.2 ? 10? 3 mm yr? 1, a value that is more similar to net ice removal rates derived from 3He data from cobbles in Beacon Valley till (7.0 ? 10? 3 mm yr? 1) than sublimation rates computed based on current climate (0.1–0.2 mm yr?1). We suggest that the climate-based sublimation rates are offset due to potential ice recharge mechanisms or to missing parameters, particularly the nature and thermo-physical properties of the overlying sediments (i.e., temperature, humidity, pore structure and ice content, grain size).  相似文献   

16.
The UV camera is becoming an important new tool in the armory of volcano geochemists to derive high time resolution SO2 flux measurements. Furthermore, the high camera spatial resolution is particularly useful for exploring multiple-source SO2 gas emissions, for instance the composite fumarolic systems topping most quiescent volcanoes. Here, we report on the first SO2 flux measurements from individual fumaroles of the fumarolic field of La Fossa crater (Vulcano Island, Aeolian Island), which we performed using a UV camera in two field campaigns: in November 12, 2009 and February 4, 2010. We derived ~ 0.5 Hz SO2 flux time-series finding fluxes from individual fumaroles, ranging from 2 to 8.7 t d?1, with a total emission from the entire system of ~ 20 t d?1 and ~ 13 t d?1, in November 2009 and February 2010 respectively. These data were augmented with molar H2S/SO2, CO2/SO2 and H2O/SO2 ratios, measured using a portable MultiGAS analyzer, for the individual fumaroles. Using the SO2 flux data in tandem with the molar ratios, we calculated the flux of volcanic species from individual fumaroles, and the crater as a whole: CO2 (684 t d?1 and 293 t d?1), H2S (8 t d?1 and 7.5 t d?1) and H2O (580 t d?1 and 225 t d?1).  相似文献   

17.
The temporal variability in currents, temperature, and particulate matter concentration were measured in the Mississippi Canyon axis where the thalweg was 300 m deep from May–July and August–November 1998 using current meters, thermographs, a light-scattering sensor, and sediment traps. Canyon sediments were sampled by coring and observed using an ROV video camera. Currents in the upper Mississippi Canyon generally oscillated up/down canyon with diurnal periodicity and were bottom-intensified. Mean current speed at 3.5 mab was approximately 8 cm s?1 during both deployments, reaching maximum speeds of over 50 cm s?1 under normal conditions. Based on current velocities, critical bed shear stress for resuspension of canyon-floor sediments was exceeded about 30% of the time during both deployments. In late September, Hurricane Georges passed 150 km NE of the study site, significantly intensifying current velocities, bed shear stress, resuspension, trap fluxes and temperature fluctuations. As the hurricane passed, maximum current speed reached 68 cm?s and temperature decreased ～7 °C in less than two hours. Critical bed shear stress for sediment resuspension was exceeded approximately 50% of the time during the five days of hurricane influence. Further evidence for sediment resuspension was the five-fold (and perhaps 70–130 fold) increase in trap fluxes and compositional similarities between canyon surface sediment and material collected by traps.  相似文献   

18.
Seventeen sporadic Na (Nas) layers were observed from ~150 h of the 8-s Na density profiles obtained by lidar measurements at Wuhan, China. Each of them consists of a sequence of small-timescale density enhancement bursts. The burst intensity ranges from 200 to 10,400 cm?3. The burst duration and interval vary between 16 and 112 s. The instantaneous growth and decay rates often have an order of 100 cm?3 s?1. This suggests that there exists a very rapid atom removal process corresponding to the dramatic burst density enhancement if the advection effect by large-scale wind could be ignored. These results provide a new clue for explaining the formation mechanism of sporadic metal layers.  相似文献   

19.
Parallel factor analysis of fluorescence excitation emission matrices of surface water samples of a globally large river (Yangtze River, China) watershed identified three classes of fluorescent dissolved organic matter (FDOM) that had ex/em = 280/330 nm, 305/385 nm and 350/450 nm respectively, resembling “peak T”, “peak M” and “peak C” commonly identified in natural water, respectively. Peak T (a tyrosine/tryptophan-like FDOM) did not show correlations to peak M or C which were humic-like substances, while a positive correlation (r = 0.935, p < 0.001) was present between the natural log-transformed maximum fluorescence intensity (Fmax) of peaks T and M indicating a tight link during their production and processing. Fmax values (in Raman unit nm?1) normalized to dissolved organic carbon (DOC) concentration were low, varying in ranges 15.93–85.95, 29.83–83.54 and 19.73–51.05 × 10?5 nm?1 (μmol/L)?1 for peaks T, M and C, respectively, in line with the history of strong photobleaching of the water samples as indicated by fairly high absorption spectral slope ratios (0.75–1.53 with a mean 1.03). Intermediate fluorescence index (FI) (1.46–1.83 with a mean 1.61) and small specific absorption at 254 nm (0.64–1.93 with a mean 1.15 m?1 mg?1 L) of the water samples, indicated the presence of both aquatic microbial DOM (e.g. peak T) and soil DOM (e.g. peak C). Peak C could be substantially removed by UV-A (320–400 nm) irradiation, while peak M was slightly increased when a microbe-containing water was exposed to the same UV-A irradiation. Taken together, peak C was attributed to diffuse soil source while peak M was likely attributed to joint effects of microbial activities and solar irradiation on the chromophores in the sample.  相似文献   

20.
The relation of magma and crustal activity has been studied from spatial distribution of 3He/4He ratios of gas and/or water samples over the Izu Peninsula, where significant crustal deformation associated with seismic swarm activities has been observed since 1970s. The air-corrected values of 3He/4He ratios ranged from 3.5 to 8.2 RA, where RA is the atmospheric 3He/4He ratio = 1.4 × 10? 6, indicating that helium is mostly of magmatic origin. Among the three pressure sources proposed to explain the crustal deformation, two inflation sources beneath the inland of northeast and the mid east coast of the Izu Peninsula locate in the broad distribution of high 3He/4He ratios, which supports relation of magma to the crustal uplift. In contrast, the distribution of 3He/4He ratios around the tensile fault assumed in the area of seismic swarms appears not to indicate existence of significant amount of magma below the tensile fault. Alternatively, the results suggest magma below a point several kilometers south of the tensile fault. The seismic swarms are explained either by fluid pressurization of thermal water heated by this magma or by intrusion of magma to the tensile fault moved obliquely from the deep magma reservoir.  相似文献   

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