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1.
Drop calorimetry measurements between 900 and 1850 K are reported for amorphous anorthite, andesine, wollastonite, diopside, cordierite and pyrope. The isobaric heat capacities of the glassy and liquid phases of these materials, and the enthalpies of fusion of the minerals have been derived. The calorimetric entropies of fusion of these substances and of other oxide minerals are generally consistent with the calculated volume changes on melting and with the observed pressure dependences of the melting points. The thermodynamics of mixing of liquid plagioclases have been examined, and it is concluded that their enthalpies of mixing are markedly different from the values derived directly from solution calorimetry measurements at 985 K. 相似文献
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Michael O. Garcia Diane Hanano Ashton Flinders Dominique Weis Garrett Ito Mark D. Kurz 《Bulletin of Volcanology》2012,74(6):1445-1463
The size, shape, and magmatic history of the most recently discovered shield volcano in the Hawaiian Islands, Mahukona, have been controversial. Mahukona corresponds to what was thought to be a gap in the paired sequence (Loa and Kea trends) of younger Hawaiian volcanoes (<4?Ma). Here, we present the results of marine expeditions to Mahukona where new bathymetry, sidescan sonar, gravity data, and lava samples were collected to address these controversies. Modeling of bathymetric and gravity data indicate that Mahukona is one of the smallest Hawaiian volcanoes (～6,000?km3) and that its magmatic system was not focused in a long-lived central reservoir like most other Hawaiian volcanoes. This lack of a long-lived magmatic reservoir is reflected by the absence of a central residual gravity high and the random distribution of cones on Mahukona Volcano. Our reconstructed subsidence history for Mahukona suggests it grew to at least ～270?m below sea level but probably did not form an island. New 40Ar–39Ar plateau ages range from 350 to 654?ka providing temporal constraints for Mahukona’s post-shield and shield stages of volcanism, which ended prematurely. Mahukona post-shield lavas have high 3He/4He ratios (16–21?Ra), which have not been observed in post-shield lavas from other Hawaiian volcanoes. Lava compositions range widely at Mahukona, including Pb isotopic values that straddle the boundary between Kea and Loa sequences of volcanoes. The compositional diversity of Mahukona lavas may be related to its relatively small size (less extensive melting) and the absence of a central magma reservoir where magmas would have been homogenized. 相似文献
3.
The Mill Run watershed is a structurally-controlled synclinal basin on the eastern limb of the Massanutten Mountain complex of northwestern Virginia. Bedrock contacts are obscured by coarse sandstone debris from exposures near basin divides. Colluvium blankets more than half the basin, masking geomorphic surfaces, affecting vegetation patterns, and contributing to the convexity of the alluvial, terrace, pediment and erosion surfaces. Examination of the bedrock geology, geomorphology, soils and vegetation shows distinct distributional correspondences. Vegetation is strongly interdependent with geomorphology, bedrock geology, and soils. On convex colluvial slopes, mixed hardwood forests are most common. In concave coves and deep gorges, mixed hardwoods are replaced by conifers. In thin colluvium, in poorly developed soils, and on blockfields, chestnut oak is singularly prevalent. Conifers dominate shaley bedrock areas. Soils and surficial sediments have a major effect on near-surface hydrology. During wet seasons, cemented horizons in the subsurface cause temporary saturation in the superjacent horizons; lateral movement of soil-water effectively eliminates a vertical component of ground-water recharge. Vegetation is strongly dependent on water availability and thus reflects the distribution of subsurface barriers and sediment-soil fades changes. 相似文献
4.
Dynamics of dissolved major (Na,K, Ca,Mg, and Si) and trace (Al,Fe, Mn,Zn, Cu,and Cr) elements along the lower Orinoco River 
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下载免费PDF全文 Abrahan Mora Jürgen Mahlknecht Juan Carlos Baquero Alain Laraque Juan A. Alfonso Daniel Pisapia Laura Balza 《水文研究》2017,31(3):597-611
This study addresses the changes in dissolved major and trace element concentrations along the Orinoco River, including the mixing zone between the Orinoco and Apure Rivers. Water samples from the Apure and Orinoco Rivers were collected monthly in four sectors over a period of 15 months. Auxiliary parameters (pH, dissolved oxygen, conductivity, and temperature), total suspended sediments, dissolved organic carbon (DOC), and major (Na, K, Ca, Mg, and Si) and trace (Al, Fe, Mn, Zn, Cu, and Cr) element concentrations were measured in all sectors. The relative contribution of both rivers after the Apure–Orinoco confluence was determined using Ca as a tracer. Moreover, a mixing model was developed to determine whether dissolved species exhibit a conservative behavior during mixing. The results indicate that DOC is removed from waters during the Apure–Orinoco mixing, probably due to absorption of DOC on mineral phases supplied by the Apure River. Dissolved Na, Ca, and Mg behave conservatively during the mixing processes, and their concentrations are controlled by a dilution process. The anomaly in the temporal pattern of K in the Orinoco is caused by the input of biogenic K originating from the Apure River during the high‐water stage. The loss of dissolved Si during the low‐water stage can be explained by the uptake of Si by diatoms. Dissolved Mn, Zn, Al, and Fe showed a non‐conservative behavior during the Apure–Orinoco mixing. The removal of Mn and Zn from the dissolved phase can be explained by the formation of Mn‐oxyhydroxides and the scavenging of Zn onto Mn oxides. Dissolved Fe is controlled by redox processes, although the removals of Fe and Al due to the preferential adsorption of large organometallic complexes by mineral surfaces after the Apure–Orinoco confluence can affect the mobility of both elements during transport. The conservative behavior shown by Cu and Cr can be related to the tendency of both elements to be complexed with small organic colloids, which are not preferentially adsorbed by clays. 相似文献
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In this study, we experimentally established the relationship between physical properties, vitrinite reflectance, and microstructure of coal, Taiyuan Formation, Qinshui Basin, China using representative coal samples collected from three different mines via the rock mechanics testing system (MTS). We analyzed the organic macerals, vitrinite reflectance, and microstructure of 11 coal samples using petrography and scanning electron microscopy (SEM). The experimental results suggest that (1) the elastic parameters can be described by linear equations, (2) both P-and S-wave velocities display anisotropy, (3) the anisotropy negatively correlates with vitrinite reflectance, and (4) the acoustic velocities and Young’s modulus are negatively correlated with the volume of micropores. The derived empirical equations can be used in the forward modeling and seismic inversion of physical properties of coal for improving the coal-bed methane (CBM) reservoir characterization. 相似文献
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Abu Sayeed Shafiuddin Ahmed Mohammad Belal Hossain Saad Mohammad Omar Faruque Babu Moshiur Rahman Jun Sun Mohammad Shafiqul Islam Sarker 《国际泥沙研究》2022,37(1):83-96
Sediment samples from the Gomti River basin were investigated to determine and evaluate trace metal concentrations,their biological effect,and potential ecological and human health risks for adults and children.The mean concentrations of trace metals were organized in the descending order of mercury(Hg)(0.08 mg/kg)>chromium(Cr)(0.06 mg/kg)>lead(Pb)(0.05 mg/kg)>arsenic(As)(0.02 mg/kg)>cadmium(Cd)(0.01 mg/kg).The current study illustrated that metals were attributed to the area from natural sources and different anthropogenic sources especially from industries.However,the concentration levels were lower than the sediment quality guidelines(SQGs)based on the effect-range classifications of threshold effect concentration(TEC)and probable effect concentration(PEC).Therefore,the concentration of the elements showed no adverse biological effects on aquatic organisms.The evaluated potential ecological risk index also revealed the low toxicity to the aquatic environment.Moreover,the applied sediment quality indices,geo-accumulation index(Igeo),contamination factor(CF),and contamination severity index(CSI)suggested that the contamination levels of the elements were in the acceptable range,and the contamination had not notably impacted on the sediment quality.The risk index(HI)concerning age groups was significantly less than the threshold limit of 1 indicating that the contamination had no non-carcinogenic risk effect.The total carcinogenic risk(TCR)was less than a risk value of 1×104.Hence,the current study suggests that immediate remediation is not required due to an absence of alarming conditions in the study area.Proper monitoring of the attribution of the metal elements should be done for the betterment of human and environmental health。 相似文献
7.
Geology and isotopic composition of helium,neon, xenon and metallogenic age of the Jinding and Baiyangping ore deposits,northwest Yunnan,China 总被引：23，自引：0，他引：23
TheJindingoredeposit,locatedinthenorthwestYunnanProvince,isthelargestPb-Zndeposit(Pb Zn>15Mt1),averagingZn=6.08%andPb/Zn=1/4.7)inChinaatpresent.Toitsnorth,alargeCu-Co-AgdeposithasbeenfoundatBaiyangpingrecently1).TheJindingPb-Zndepositishostedinsandstonesa… 相似文献
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《Journal of Geodynamics》2007,43(1):170-186
Stratigraphic and sedimentological studies indicate that Iceland has experienced over 20 glaciations during the last 4–5 Myr, in reasonable agreement with the number of glaciations reconstructed from the ∂18O record in deep-sea sediment. The pattern of glacial erosion was to a large part controlled by constructive volcanic processes resulting in increased topographic relief after 2.5 Myr. Between 2.5 and 0.5 Ma valleys up to 400 m deep were excavated into the Tertiary basalts of eastern and south Iceland with an average erosion rate of 10–20 cm ka−1. During the last 0.5 million years rates of erosion increased to 50–175 cm ka−1, with an additional 200 to over 1000 m of valley excavation. Previous estimates of the rate of landscape erosion during the Holocene vary widely, from 5 to 70,000 cm ka−1. We present new studies that define the rates of landscape denudation during the major part of the Holocene (the last 10,200 years): one based on the Iceland shelf sediment record, the other from the sediment record in the glacier-fed lake, Hvítárvatn. Both studies indicate average Holocene erosion rates of about 5 cm ka−1 similar to our erosion rate estimate for 4–5 Ma old strata that has not been subjected to regional glaciation. 相似文献
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Bulletin of Volcanology - 相似文献
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Facets of uncertainty: epistemic uncertainty,non-stationarity,likelihood, hypothesis testing,and communication 总被引：1，自引：1，他引：0
Keith Beven 《水文科学杂志》2016,61(9):1652-1665
ABSTRACTThis paper presents a discussion of some of the issues associated with the multiple sources of uncertainty and non-stationarity in the analysis and modelling of hydrological systems. Different forms of aleatory, epistemic, semantic, and ontological uncertainty are defined. The potential for epistemic uncertainties to induce disinformation in calibration data and arbitrary non-stationarities in model error characteristics, and surprises in predicting the future, are discussed in the context of other forms of non-stationarity. It is suggested that a condition tree is used to be explicit about the assumptions that underlie any assessment of uncertainty. This also provides an audit trail for providing evidence to decision makers.
Editor D. Koutsoyiannis; Associate editor S. Weijs 相似文献
13.
M. J. Defant S. Sherman R. C. Maury H. Bellon J. de Boer J. Davidson P. Kepezhinskas 《Journal of Volcanology and Geothermal Research》2001,107(1-3)
Saba is the northernmost volcano along the Lesser Antilles island-arc chain. The Lesser Antilles arc results from the west-northwest subduction of the Atlantic lithosphere beneath the Caribbean Plate. Sediment thickness along the trench decreases northward away from sediment sources on the continent of South America. We focused our attention on Saba precisely because it is the furthest away from documented geochemical effects in the southern arc volcanics of the large sediment thicknesses — normally attributed to both source or upper level contamination (i.e. assimilation).Field mapping, petrology, mineralogy, K–Ar dating, and geochemical analyses (major and trace element) indicate a complex history of magma petrogenesis including crystal fractionation, magma mixing, and, surprisingly, crustal assimilation. This is the first time assimilation has been documented in the northern section of the Lesser Antilles arc. Magma mixing shows up in the field as banded pumice and petrographically and mineralogically as complex zoning in phenocrysts (such as reverse zoning in plagioclase), disequilibrium mineral assemblages (e.g. quartz and olivine), and disequilibrium between minerals and whole-rock compositions (e.g. forsterite content of olivine). Mass-balance modeling of major and trace elements support our contention that crystal fractionation (including amphibole) played an important role in magma evolution. However, various geochemical trends can only be explained by assimilation-fractional crystallization based on the fact that the trends of various trace elements and trace-element ratios vary with increasing silica. Finally, we could find no evidence of sediment source contamination in the most mafic rocks. It may exist but is overprinted by the later assimilation effects. 相似文献
14.
The Denchai Basalt of northern Thailand is part of a large continental alkalic basaltic province extending through Thailand into Laos, Kampuchea, and Vietnam. It covers an area of about 70 km2 and consists of seven flows, all with reversed magnetic polarity. The uppermost flow has yielded an age of 5.64 ± 0.28 Ma by the K-Ar method. During the igneous activity, magmas were apparently erupted from only one vent area, but changed in chemical composition from “hawaiite” (transitional to continental tholeiite) to true hawaiite and then to basanite. The basanite is the probable source of gem-quality zircon and sapphire mined from placer deposits associated with the basalts. 相似文献
15.
Spivak A. A. Ovtchinnikov V. M. Rybnov Yu. S. Riabova S. A. Kharlamov V. A. 《Izvestiya Physics of the Solid Earth》2022,58(4):493-506
Izvestiya, Physics of the Solid Earth - Abstract—Disturbances of seismic noise, magnetic field, electrical characteristics of the surface atmosphere and microbaric variations caused by the... 相似文献
16.
Concentrations of Cd, Cr, Cu, Ni and Pb were determined in filtered water, suspended particulate matter, and bottom sediments from a 2000 km section of the Ob and Irtysh Rivers. Dissolved Cd, Cr, Cu and Ni concentrations are similar to, or higher than, results from other Russian Arctic and large world river-estuaries. Concentrations of Cd, Cr, Cu, Ni and Pb in suspended particulate matter are generally comparable to results from other Russian Arctic and large world rivers and estuaries. Comparison of trace metal ratios in crustal material and suspended particulate matter and bottom sediment suggests that the source of Cr, Cu and Ni is continental weathering. Particulate Cd and Pb are elevated relative to their crustal abundance, suggesting a source of these metals to the Ob-Irtysh in addition to continental weathering. 相似文献
17.
René W. Barendregt Randolph J. Enkin Dez L. Tessler 《Studia Geophysica et Geodaetica》2012,56(3):705-724
Two new records of glacial stratigraphy obtained from borecores collected in southcentral Saskatchewan are compared to previously published records from Wellsch Valley and Swift Current Creek in southern Saskatchewan. The comparisons are based on magnetostratigraphy and tephrochronology, and describe preglacial, glacial, and interglacial deposits. The new stratigraphy is compared to the composite global marine oxygen isotope record. Although the ages and extents of late Pleistocene continental glaciations are relatively well constrained, they are less well defined for the middle and early Pleistocene. Data presented here highlight recent studies carried out from borecores and outcrops of extensive pre-Illinoian (pre-Saalian) glacial deposits. Based on this new data, at least seven Laurentide (continental) glaciations are recognized in Saskatchewan, and these records are the most extensive to date in the Northern Interior Plains of Canada. The magnetostratigraphic records from the Sutherland Overpass and Wascana Creek sites provide the first evidence of reversely magnetized glacial deposits in the Canadian Prairies. These deposits can be assigned to the latest Matuyama (MIS 20) and indicate that Laurentide (continental) glaciations did not impact southern Saskatchewan until the late Early Pleistocene. 相似文献
18.
Fractals,fault-gouge,and friction 总被引：5，自引：0，他引：5
The particle-size distribution of a natural fault-gouge has been determined over the range from 5 m to 40 cm. The gouge is self-similar over the range from 5 m to 1 cm having a fractal dimension of 2.60±0.11. The lower and upper fractal limits were also determined. The lower fractal limit occurs at a dimension of about 1–10 m where mineral cleavage and intergranular porosity dominate the cataclasis. The upper fractal limit occurs at particle sizes on the order of 1 cm where the scaled particle density decreases abruptly by a factor of about three. By analogy to soil-mechanics shear box tests and laboratory rock friction experiments, it is argued that the upper fractal limit of the gouge determines the characteristic displacement parameter in stick-slip friction models. A characteristic displacement on the order of 1 cm is consistent with estimates based on numerical simulations of faulting. 相似文献
19.
Monsoon and arid regions in the Asia-Africa-Australia(A-A-A) realm occupy more than 60% of the total area of these continents. Geological evidence showed that significant changes occurred to the A-A-A environments of the monsoon and arid regions, the land-ocean configuration in the Eastern Hemisphere, and the topography of the Tibetan Plateau(TP) in the Cenozoic. Motivated by this background, numerical experiments for 5 typical geological periods during the Cenozoic were conducted using a coupled ocean-atmosphere general circulation model to systemically explore the formations and evolutionary histories of the Cenozoic A-A-A monsoon and arid regions under the influences of continental drift and plateau uplift. Results of the numerical experiments indicate that the timings and causes of the formations of monsoon and arid regions in the A-A-A realm were very different. The northern and southern African monsoons existed during the mid-Paleocene, while the South Asian monsoon appeared in the Eocene after the Indian Subcontinent moved into the tropical Northern Hemisphere. In contrast, the East Asian monsoon and northern Australian monsoon were established much later in the Miocene. The establishment of the tropical monsoons in northern and southern Africa, South Asia, and Australia were determined by both the continental drift and seasonal migration of the Inter-Tropical Convergence Zone(ITCZ), while the position and height of the TP were the key factor for the establishment of the East Asian monsoon. The presence of the subtropical arid regions in northern and southern Africa,Asia, and Australia depended on the positions of the continents and the control of the planetary scale subtropical high pressure zones, while the arid regions in the Arabian Peninsula and West Asia were closely related to the retreat of the Paratethys Sea. The formation of the mid-latitude arid region in the Asian interior, on the other hand, was the consequence of the uplift of the TP.These results from this study provide insight to the important roles played by the earth's tectonic boundary conditions in the formations and evolutions of regional climates during geological times. 相似文献
20.
The volcanic sequences in three vertical sections (starting from m.s.l.) of the Deccan trap flows around Mahape, Mumbra and Kalyan have been demarcated into zones, mainly based on the megascopic texture and the degree of abundance of vesicles and amygdules. Petrographic, mineralogical and modal study of twelve samples indicate that the basalts are tholeiitic and are characterised by lateral inhomogeneities. Petrochemical data are suggestive of limited differentiation, a hyperferric iron enrichment, a Hawaiian trend and an affinity to alkalic and high-alumina basalt. 相似文献