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1.
REE geochemistry of surface sediments in the Chukchi Sea   总被引：4，自引：0，他引：4  
Rare earth elements (including the lanthanides and Y) have analogical chemical properties and low solubility, and they are not easy to transfer and take inter-element fractionation during geological processes such as weathering, disintegration, transporta…  相似文献   

2.
Organochlorine compounds (OCs) in surface and core sediments collected from Lake Maryut, Egypt, were examined to elucidate their distribution, ecological risk and historical trend. To our knowledge, this is the first study on residue levels of OCs in sediments from Lake Maryut. Concentrations of PCBs and DDTs were higher than other OCs, ranging from 3.06 to 388 and from 0.07 to 106 ng/g dry wt., respectively. The highest concentrations of OCs were found at stations near the discharge point of sewage and close to industrial areas. The distribution of DDT and its metabolites suggest no recent inputs into the lake environment. Contamination levels of sedimentary PCBs and DDTs, can be categorized moderate to high compared to other urbanized regions worldwide. Temporal trends in OCs levels were influenced by input pathways at two sites. Evaluation of ecotoxicological risks suggests that adverse biological effects are expected mainly in the main basin area.  相似文献   

3.
The isotopic composition and concentration of Pb was measured in suspended particulate matter of the Irish Sea. Aerosol, surficial and pre-industrial sediment was also analysed to provide information on sources terms. Concentrations of Pb in suspended sediments were lower than previously reported which presumably reflects the international effort to reduce Pb inputs to the environment. Lead concentrations were highest in Liverpool Bay and lowest in the western Irish Sea. A significant negative relationship between Pb and salinity suggests that present inputs and the resuspension of relict lead associated with particles in areas significantly affected by freshwater discharges are the predominant sources of Pb to the Irish Sea. The isotopic composition of Pb in the stratified region of the western Irish Sea demonstrates that atmospheric sources are also significant to this region, which is consistent with current knowledge on the hydrography. Pb isotopic ratios show that water entering the Irish Sea through St George's Channel is significantly influenced by anthropogenic inputs prior to additional contamination by direct inputs to the Irish Sea.  相似文献   

4.
The article gives the results of studying the concentration and composition of aliphatic and polycyclic aromatic hydrocarbons in suspension in surface waters at sections from the English Channel and Skagerak Strait to various regions of the Baltic Sea (2010–2015) and in water and bottom sediments of the southeastern part of the sea in the water area of the Kravtsovskoe field (2008–2015). In recent years, the surface waters of open areas of the Baltic Sea showed a decrease in hydrocarbon concentrations down to background levels (12–33 μg/L). The maximal concentration of hydrocarbons (in excess of the MAC) was recorded in different seasons in navigation areas, including the English Channel and Pregola R. mouth. In the zone of the Kravtsovskoe field, the concentration and composition of hydrocarbons in water depends on their inflow from the bank, and the same characteristics in bottom sediments, on the rate of their leakage from sediment stratum. A decline in these processes have led to a decrease in hydrocarbon concentrations in the sediments of a local area near D-6 platform to background levels (5–7 μg/g) and to the predominance of terrigenous, rather than petroleum, alkanes in hydrocarbon compositions.  相似文献   

5.
Iodine is a trace element playing an important role in vital activities of organisms. It is im-portant for human bodys thyroid gland. Deficient or excessive iodine will not only influence hu-man health but also cause feeblemindedness, so great attention h…  相似文献   

6.
In this paper, the spatial distribution and source of the PCBs in surface sediments of the Southern Yellow Sea (SYS) and influencing factors, such as the sediment characteristics (components, relative proportions and total organic carbon contents), and hydrodynamic conditions were analyzed. PCB concentrations in the surface sediments ranged from 518-5848 pg/g, with average values of 1715 pg/g decreasing sharply compared to last year. In the study area, the PCB pollution level in the middle area was the highest, followed by that of the east coast and the west coast, respectively. Although the PCB level in the coastal areas was lower than that in the middle areas, it was proven in our study that the Yellow Sea obtained PCBs by virtue of river inputs. There was a positive and pertinent correlation between the clay proportion and PCB concentrations, and the increase of the PCB concentrations was directly proportional to the increase of TOC contents, with r=0.61, but it was contrary to the sediment grain size. Consequently, the factors controlling PCB distribution had direct or indirect relationships with sediment grain size; moreover, the hydrodynamic conditions determined the sediment components and grain size. In conclusion, hydrodynamic conditions of the Yellow Sea were the most important influencing factors effecting the distribution of PCBs in the surface sediments of the SYS.  相似文献   

7.
《国际泥沙研究》2016,(2):164-172
The ecological risk assessment for Al,Zn,Cu,Ni,V,Pb,Cd,and Hg in surface sediment collected from the Egyptian Red Sea coast was evaluated using the Geo-accumulation Index(I_(geo)).Sediment Enrichment Factor(SEF) and Potential Ecological Risk Index(PERI) methods.The predominant heavy metal,aluminum,showed high concentrations along both of Aqaba Gulf(4378.8 ± 2554.1 μg/g) and southern part of the Red Sea(2972.8 + 1527.5 μg/g).while it recorded the lowest concentration in Suez Gulf(829.7 ± 398.2 μg/g).The determined heavy metal concentrations had the order of Al Zn -Ni V Pb Cu Cd Hg.The statistical analyses showed some correlations among the heavy metals contents.Several international sediment quality guidelines were used to estimate the quality of the collected sediments.Interestingly,the recorded average heavy metals concentrations were lower than those of the permissible contents for sediment quality guidelines.The Geo-accumulation index calculations(I_(geo)) proved that the investigated region could be classified as an unpolluted area.Sediment Enrichment Factor(K_(SEF)) study showed high values in Suez Gulf region.The single pollution index analysis of heavy metals in the sediments(C~i_f) indicated that Al,Zn,V,and Pb were of natural origin,while Ni,Cd and Hg were seriously affected by human activities.Interestingly,amongst,all the determined heavy metals,Cd and Hg gave moderate ecological risk indicators.  相似文献   

8.
The polycyclic aromatic hydrocarbons (PAHs) pollution in the Sarno River and its environmental impact on the Gulf of Naples (Tyrrhenian Sea, Central Mediterranean Sea) were estimated. The 16 PAHs identified by the USEPA as priority pollutants and perylene were determined in the water dissolved phase (DP), suspended particulate matter (SPM) and sediments. Total PAHs concentrations ranged from 23.1 to 2670.4 ng L(-1) in water (sum of DP and SPM) and from 5.3 to 678.6 ng g(-1) in sediment samples. Source analysis revealed that PAHs mainly came from combustion process. Contaminant discharges of PAHs into the sea were calculated in about 8530 gd(-1) showing that this river should account as one of the main contribution sources of PAHs to the Tyrrhenian Sea.  相似文献   

9.
The sedimentology of the floor of the Amvrakikos Gulf, a river influenced, semi-enclosed relatively shallow-silled embayment, lying along the northeastern Hellenic coast of the Ionian Sea (eastern Mediterranean Sea), is investigated with respect to its origin (terrigenous and/or biogenic), the prevailing oceanographic conditions and human interference. Nearshore (water depths approximately <10 m) sediments, especially along the northern margin of the Gulf, consist mostly of biogenic sands, as the result of water exchange between the freshwater lagoonal waters and the surface waters of the Gulf. An exception to this is the mouth area of the Arachthos River, which is dominated by the terrigenous riverine sediment influx. The offshore (water depths >10 m) bottom surficial sediments are fine-grained (silty and clayey) of terrigenous origin (>70%); this is attributed to the inter-seasonal, strong two-layer stratification of the water column in the Gulf which restricts benthic productivity by inhibiting the downward flux of surface eutrophic waters and the development of nearbed disoxic conditions in water depths >40 m. River damming has reduced also the riverine terrigenous sediment supply; this is more profound in the case of the Arachthos River where not only the deltaic evolution has been affected, but also the textural character of the seabed sediments of the mouth area has been altered; this is expected to influence the benthic communities of prodeltaic surficial sediment.  相似文献   

10.
Organochlorine contaminants including 12 polychlorinated biphenyl (PCB) congeners and 18 insecticides were determined in water, pore water and sediments of the Jiulong River Estuary and Western Xiamen Sea, China. The results showed that the levels of the total PCBs ranged from non-detectable to 1500 ng l−1 in water, from 209 to 3870 ng l−1 in pore water, and from 2.78 to 14.8 ng g−1 dry weight in sediments. Total organochlorine insecticide concentrations were from below the limit of detection to 2480 ng l−1 in water, from 267 to 33400 ng l−1 in pore water, and from 4.22 to 46.3 ng g−1 dry weight in sediments. Concentrations of PCBs and insecticides in pore water were significantly higher than those in surface water, due to the high affinity of these hydrophobic compounds for sediment phase. The PCB congeners with the highest concentrations were CB153, CB180 and CB194, which together accounted for 68–87% of total PCBs in water, pore water and sediment. Among the hexachlorocyclohexane (HCH) compounds, beta-HCH was found to be a major isomer. Analysis of 1,1,1-trichloro-2,2-bis-chlorophenyl-ethane (DDT) and its metabolites showed that 1,1-dichloro-2[o-chlorophenyl]-2[p-chlorophenyl]-ethylene (DDE) was dominant in the group. In comparison to a 1998 study in the Western Xiamen Sea, levels of organochlorines were enhanced due probably to recent inputs and changes in sediments.  相似文献   

11.
Bakan G  Ariman S 《Marine pollution bulletin》2004,48(11-12):1031-1039
The aim of this study is to determine aspects of water and surface sediment quality in the coastal zone of the mid-Black Sea, and of rivers discharging into it, by analyzing their organochlorine pesticides (OC) levels. Surface sediment samples and water samples were collected from 14 sites from the rivers Ye?ilirmak, Abdal, Mert, Kürtün, Engiz and Kizilirmak. In sediments, Aldrin ranged from 19.3 to 87.3 ng/g and p,p'-DDT ranged from 18.6 to 31.0 ng/g.  相似文献   

12.
Organochlorine compounds (OCs) were determined in the five species of sturgeons collected from coastal waters of Caspian Sea in Kazakhstan, Azerbaijan, Turkmenistan and Iran during 2001 and 2002 to understand their status of contamination and accumulation features. Among OCs examined, concentrations of DDTs (DDT and its metabolites) were predominant in all the sturgeon samples with concentrations ranging from 73 to 31,000 ng/g on lipid weight basis, followed by PCBs, CHLs, HCHs, HCB, dieldrin, TCPMOH, and heptachlor epoxide in order. The concentrations of OCs in beluga (Huso huso) were the highest among all the five species. When comparing residue levels among same species, OC residues were highest in sturgeons from Azerbaijan and Kazakhstan and lowest in Turkmenistan. However, the concentrations of HCHs, dieldrin, and heptachlor epoxide in sturgeons showed less geographical variability.  相似文献   

13.
Surface sediment samples in the Laptev Sea have average 137Cs content of 7.1 Bq kg(-1), a value intermediate between that of the western Kara Sea (23 Bq kg(-1) and the East Siberian Sea (4.2 Bq kg-'). Both surface sediment content and sediment inventory of 137Cs in the Laptev Sea sediments show significant variability, and the influence of a variety of environmental factors.137Cs concentrations in the Laptev Sea surface sediments range from 0.8 to 16 Bq kg(-1). There is a marked increase in 137Cs content of surface sediment samples collected near the Lena River delta, and a local enrichment in the 137Cs inventories at these sites is also evident. Fine-grained mixed-layer illite/ smectite rich sediments in the estuary provide effective adsorption sites to fix 137Cs, in spite of desorption processes associated with low salinities in estuarine mixing. The Lena River-Laptev Sea mixing zone is a major site of sea-ice production. River and shelf sediments are incorporated into sea-ice formed in this region (Holmes and Creager, 1974). The irregular 137Cs activity profiles of the Lena River estuary cores indicate disturbance or removal of 137Cs-laden sediments via sea-ice related processes. Lena River and Estuary sediments may have served as a secondary source (i.e. other than direct fallout) of 137Cs in sea-ice. North-east of the Lena River estuary, sediment contains a thin layer of 137Cs-bearing material over an erosion surface. The 137Cs-laden surface layer may be the result of transient deposition of estuarine sediments being delivered by sea-ice or spring floods.  相似文献   

14.
Six marine sediment cores from the Gulf of Lions continental slope (700-1700 m water depth) were analyzed for stable lead isotopes and (210)Pb geochronology in order to reconstruct lead atmospheric fallout pattern during the last century. The detrital lead contribution is 25 microg g(-1) and the mean sediment anthropogenic inventory is 110+/-7 microg cm(-2), a little bit higher than atmospheric deposition estimate. Anthropogenic lead accumulation in sediments peaked in early 1970s (1973+/-2) in agreement with lead emissions features. For the period 1986-1997, the sediment signal also reflect the decrease of atmospheric lead described by independent atmospheric fallout investigations. The anthropogenic Pb deposition in the late 1990s was similar to the 1950s deposition, attesting thus of the output of European environmental policies.  相似文献   

15.
The data given are the results of many-year studying the distribution of the concentrations of main oil components (hydrocarbons, surfactants, and asphaltene-tarry substances) in the water mass, vertically settling particulate matter, and bottom sediment cores taken from the section Lower Don-The Gulf of Taganrog-Russian sector of the Sea of Azov in summer and autumn periods in 2006–2011. Spatial and seasonal regularities in the distributions of the total concentration of oil components and the values of their ratios in water, as well as the spatial and annual features of their accumulation in bottom sediments have been established. Radiological methods have been used for layer-by-layer dating of bottom sediment cores and determine the thickness of the layer that had formed under the maximal anthropogenic impact on ecosystems. The presence of considerable amounts of hydrocarbons of modern biological origin has been revealed in all components of examined aquatic complexes.  相似文献   

16.
The distributions of dissolved and of particulate iron in the Dead Sea during the period which preceeded its overturn and thereafter (1977–1980) are reported. During 1977–1978, the vertical profiles of the iron phases revealed facets of the mixing pattern: the progressive deepening of the pycnocline, restricted mixing within the upper water mass and penetration of surface waters into the deepest layer. The inventories of particulate iron suggest resuspension of bottom sediments in November 1978 and after the overturn the gradual disappearance from the water column of iron sulfides and iron oxy-hydroxides. Fluxes of iron from and to the lake in the undisturbed meromictic Dead Sea have been estimated: it appears that diffusion of divalent iron from bottom sediments was the major source for the standing crop of iron in the lower water mass. Low settling velocities of solid particles in the dense and viscous Dead Sea is one of the causes for the relatively large concentrations of particulate iron. The rate constant for oxidation of divalent iron in Dead Sea sediment interstitial waters is larger by two orders of magnitude than in other natural waters.  相似文献   

17.
Surficial sediments from 31 stations on the northeastern Chukchi Sea, Alaskan Arctic were analysed by AAS and ICP-AES for Si, Al, Fe, Mn, Cu, Cr, Co, Zn, Ni and V. The metal concentrations are related to the sediment granulometry and show no correlations with organic carbon. Presumably all the heavy metals, except Cr and Co, are either adsorbed on clays and/or coprecipitated with ferrimanganic hydroxide. Cobalt is partitioned in an unknown mineral phase within the sand fraction.

Comparison of the heavy metal concentrations in muds of the Chukchi Sea with those of the high arctic shelves of Russia, East Greenland and the Beaufort Sea shows relatively lower levels of most metals in the Chukchi. Presumably these disparities are related to regional differences in sediment chemistries inherited from natural terrigenous sources rather than to any enhanced pollution in the non-Chukchi areas.

It is suggested that the concentrations and accumulation rates of the heavy metals reported here can serve as reliable baselines to monitor metal pollution in the Chukchi Sea.  相似文献   


18.
The concentrations of two greenhouse gases, nitrous oxide (N2O) and methane (CH4), and the bacterial processes involved in their production (nitrification and denitrification for N2O, and methanogenesis for CH4), were determined in surface waters of two coastal areas under the influence of freshwater inputs, on one part in the Gulf of Lions and the Rhone River plume, in northwestern Mediterranean Sea, and on the other part in the inner Thermaikos Gulf, in Aegean Sea, eastern Mediterranean Sea. High concentrations of dissolved CH4 and N2O were recorded in the surface waters of Gulf of Lions and Gulf of Thermaikos, up to 1300 nM for CH4, and 40 nM for N2O. No direct relationship could be found between the concentration and production of the biogases, as they may also be produced in deep water or bottom sediment in shallow areas, or derived from anthropogenic activity or ship contamination in polluted areas. Irrespective of the origin of CH4 and N2O, the presence of extremely high concentrations of these two gases in superficial seawater implies that they can easily escape to the atmosphere; consequently, these nearshore waters enriched in greenhouse gases may play an important role in the increase in atmospheric concentration of both CH4 and N2O.  相似文献   

19.
Four end members were inverted from surface sediment grain size data from the South Yellow Sea by using the end member (EM) model. The sediment provenance and hydrodynamic meanings of each EM were discussed based on the frequency and spatial distributions of the EMs. EM1 and EM2 reflect the dynamic transport and sorting processes of the terrigenous sediment, and EM3 and EM4 reflect the modification of relic sand. The ocean front mainly affected transport of relatively coarse terrigenous sediment in the South Yellow Sea, and the fine terrigenous sediments were generally unaffected by the ocean front. Fine sediment could pass through the ocean front and deposit in the central South Yellow Sea under weak tidal condition to form most part of the Central Yellow Sea Mud (CYSM). The CYSM extended toward northwest and southwest. The sediment in the north part of the CYSM mainly consisted of sediment from the Yellow River (Huanghe) in the northwest, and the sediment in the southwest part of CYSM mainly consisted of Subei coastal sediments from both the Yangtze River (Changjiang) and the Yellow River. Compared to the traditional method of sediment grain size analysis, the EM model can determine the EMs and provide better explanations of the sediment provenance and dynamic regional sedimentary environment in the study area.  相似文献   

20.
The Semi-enclosed Mediterranean Sea records various signals of high anthropic pressures from surrounding countries and the industrialized European countries. This is particularly true for oil pollution. Although accounting for 1% of the world's ocean surface, it receives about 25% of the petroleum inputs to the ocean. To achieve a global budget we need to collect information from different parts of the Mediterranean. Particularly, we focus in this paper on the Southern Mediterranean, where data are presently very scarce. In this context, the University of Sfax has undertaken an estimation of hydrocarbon pollution along the coasts of Sfax and Gabès Gulf. Non-aromatic hydrocarbons were analysed in 8 surface sediments by FT/IR and GC/MS. Non-aromatic hydrocarbon concentrations vary in the range 310-1406 microg g(-1) sediments dry weight, which is high, compared to other Mediterranean sites. GC/MS data indicate a large group of unresolved compounds suggesting a petroleum contamination, confirmed by the identification of hopanes with predominant C29 and C30alpha,beta compounds and steranes with predominance of C27 over C28) and C29 compounds.  相似文献   

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