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1.
Abstract The amphibolites occur sporadically as thin layers and blocks throughout the Sulu Terrane, eastern China. All analyzed amphibolite from outcrop and drill cores from prepilot drill hole CCSD‐PP1 and CCSD‐PP2, Chinese Continental Scientific Drilling Project in the Sulu Terrane, are retrograded eclogites overprinted by amphibolite‐facies retrograde metamorphism, with characteristic mineral assemblages of amphibole + plagioclase + epidote ± quartz ± biotite ± ilmenite ± titanite. However, coesite and coesite‐bearing ultrahigh‐pressure (UHP) mineral assemblages are identified by Raman spectroscopy and electron microprobe analysis as inclusions in zircons separated from these amphibolites. In general, coesite and other UHP mineral inclusions are preserved in the cores and mantles of zircons, whereas quartz inclusions occur in the rims of the same zircons. The UHP mineral assemblages consist mainly of coesite + garnet + omphacite + rutile, coesite + garnet + omphacite, coesite + garnet + omphacite + phengite + rutile + apatite, coesite + omphacite + rutile and coesite + magnesite. Compositions of analyzed mineral inclusions are very similar to those of matrix minerals from Sulu eclogites. These UHP mineral inclusion assemblages yield temperatures of 631–780°C and pressures of ≥2.8 × 103 MPa, representing the P–T conditions of peak metamorphism of these rocks, which are consistent with those (T = 642–726°C; P ≥ 2.8 × 103 MPa) deduced from adjacent eclogites. These data indicate that the amphibolites are the retrogressive products of UHP eclogites.  相似文献   

2.
Abstract Eclogites occur in three districts of the northern and southern parts of Tien-Shan. Three eclogites collected from the Aktyuz, Makbal and Atbashy districts were analyzed; the P-T paths of three eclogites were estimated by analyzing compositional growth zoning and retrograde reaction of garnet and omphacite. Aktyuz and Makbal eclogites have not preserved the prograde path. An Aktyuz eclogite that underwent a quartz eclogite facies metamorphism (about T = 600°C, P = 12 kbar) has recorded three stages of retrograde metamorphism. Four stages of retrograde metamorphism were recognized in a Makbal eclogite; the garnet-omphacite geothermometer gave about T = 560°C at 20 kbar as the highest metamorphic condition. Garnet from a garnetchloritoid-talc schist of the Makbal district includes quartz pseudomorphs after coesite; some units evidently underwent a low-temperature part of coesite eclogite fades metamorphism. Prograde and retrograde paths were recognized in an Atbashy eclogite; five stages of metamorphic reaction were observed in the Atbashy sample. The prograde path from stage I to stage III has been recorded in garnet and omphacite in which quartz pseudomorphs after coesite are included. The peak metamorphism of stage III took place at about 660°C at 25 kbar. The stages IV and V are retrograde. UHP eclogite facies metamorphism took place twice in Kyrghyzstan. The Aktyuz and Atbashy eclogites gave Rb-Sr mineral-isochron ages of about 750 Ma and 270 Ma, respectively. The K-Ar age of paragonite from the Makbal eclogite is about 480 Ma.  相似文献   

3.
Abstract In the first extensive, systematic study of inclusions in zircons from ultrahigh-pressure (UHP) and high-pressure (HP) metamorphic rocks of the Kokchetav Massif of Kazakhstan (separated from 232 rock samples from all representative lithologies and geographic regions), we identified graphite, quartz, garnet, phengite, phlogopite, rutile, albite, K-feldspar, amphibole, zoisite, kyanite, calcite, dolomite, apatite, monazite, omphacite and jadeite, as well as the diagnostic UHP metamorphic minerals (i.e. microdiamond and coesite) by laser Raman spectroscopy. In some instances, coesite + quartz and diamond + graphite occur together in a single rock sample, and inclusion aggregates also comprise polycrystalline diamond crystals overgrowing graphite. Secondary electron microscope and cathodoluminescence studies reveal that many zircons display distinct zonation textures, which comprise core and wide mantle, each with distinctive inclusion microassemblages. Pre-UHP metamorphic minerals such as graphite, quartz, phengite and apatite are common in the core, whereas diamond, coesite, garnet and jadeite occupy the mantle. The inclusions in core are irrelevant to the UHP metamorphism. The zircon core is of detrital or relatively low-grade metamorphic origin, whereas the mantle is of HP to UHP metamorphic origin. The zonal arrangement of inclusions and the presence of coesite and diamond without back-reaction imply that aqueous fluids were low to absent within the zircons during both prograde and retrograde metamorphism, and that the zircon preserves a prograde pressure–temperature record of the Kokchetav metamorphism which, elsewhere, has been more or less obliterated in the host rock.  相似文献   

4.
Abstract To investigate the regional thermobaric structure of the diamondiferous Kokchetav ultrahigh‐pressure and high‐pressure (UHP–HP) massif and adjacent units, eclogite and other metabasites in the Kulet and Saldat–Kol regions, northern Kazakhstan, were examined. The UHP–HP massif is subdivided into four units, bounded by subhorizontal faults. Unit I is situated at the lowest level of the massif and consists of garnet–amphibolite and acidic gneiss with minor pelitic schist and orthogneiss. Unit II, which structurally overlies Unit I, is composed mainly of pelitic schist and gneiss, and whiteschist locally with abundant eclogite blocks. The primary minerals observed in Kulet and Saldat–Kol eclogites are omphacite, sodic augite, garnet, quartz, rutile and minor barroisite, hornblende, zoisite, clinozoisite and phengite. Rare kyanite occurs as inclusions in garnet. Coesite inclusions occur in garnet porphyroblasts in whiteschist from Kulet, which are closely associated with eclogite masses. Unit III consists of alternating orthogneiss and amphibolite with local eclogite masses. The structurally highest unit, Unit IV, is composed of quartzitic schist with minor pelitic, calcareous, and basic schist intercalations. Mineral assemblages and compositions, and occurrences of polymorphs of SiO2 (quartz or coesite) in metabasites and associated rocks in the Kulet and Saldat–Kol regions indicate that the metamorphic grades correspond to epidote–amphibolite, through high‐pressure amphibolite and quartz–eclogite, to coesite–eclogite facies conditions. Based on estimations by several geothermobarometers, eclogite from Unit II yielded the highest peak pressure and temperature conditions in the UHP–HP massif, with metamorphic pressure and temperature decreasing towards the upper and lower structural units. The observed thermobaric structure is subhorizontal. The UHP–HP massif is overlain by a weakly metamorphosed unit to the north and is underlain by the low‐pressure Daulet Suite to the south; boundaries are subhorizontal faults. There is a distinct pressure gap across these boundaries. These suggest that the highest grade unit, Unit II, has been selectively extruded from the greatest depths within the UHP–HP unit during the exhumation process, and that all of the UHP–HP unit has been tectonically intruded and juxtaposed into the adjacent lower grade units at shallower depths of about 10 km.  相似文献   

5.
An introduction to ultrahigh-pressure metamorphism   总被引:6,自引:0,他引:6  
Abstract Ultrahigh-pressure (UHP) metamorphism refers to mineralogical and structural readjustment of supracrustal protoliths and associated mafic-ultramafic rocks at mantle pressures greater than ∼ 25 kbar (80-90 km). Typical products include metapelite, quartzite, marble, granulite, eclogite, paragneiss and orthogneiss; minor mafic and ultramafic rocks occur as eclogitic-ultramafic layers or blocks of various dimensions within the supracrustal rocks. For appropriate bulk compositions, metamorphism at great depths produces coesite, microdiamond and other characteristic UHP minerals with unusual compositions. Thus far, at least seven coesite-bearing eclogitic terranes and three diamond-bearing UHP regions have been documented. All lie within major continental collision belts in Eurasia, have similar supracrustal protoliths and metamorphic assemblages, occur in long, discontinuous belts that may extend several hundred kilometers or more, and typically are associated with contemporaneous high-P blueschist belts. This paper defines the P-T regimes of UHP metamorphism and describes mineralogical, petrological and tectonic characteristics for a few representative UHP terranes including the western gneiss region of Norway, the Dora Maira massif of the western Alps, the Dabie Mountains and the Su-Lu region of east-central China, and the Kokchetav massif of the former USSR. Prograde P-T paths for coesite-bearing eclogites require abnormally low geothermal gradients (approximately 7°C/km) that can be accomplished only by subduction of cold, oceanic crust-capped lithosphere ± pelagic sediments or an old, cold continent. The preservation of coesite inclusions in garnet, zircon, omphacite, kyanite and epidote, and microdiamond inclusions in garnet and zircon during exhumation of an UHP terrane requires either an extraordinarily fast rate of denudation (up to 10 cm/year) or continuous refrigeration in an extensional regime (retreating subduction zone).  相似文献   

6.
J. Liu  J. G. Liou 《Island Arc》1995,4(4):334-346
Abstract Kyanite-anthophyllite schist preserves the first record of high pressure in the amphibolite-facies unit of the SW Dabie Mountains, whereas ultrahigh- and high-pressure (UHP and HP) metamorphism has been well documented by the occurrence of coesite, diamond and mafic eclogite in the SE Dabie Mountains. Textural evidence indicates that minerals of the kyanite-anthophyllite schist formed mainly in two stages: (i) garnet + kyanite + antho-phyllite + rutile formed at pressure in excess of 1.2 GPa at T < 650°C; (ii) cordierite±staurolite formed by reaction of anthophyllite + kyanite at P < 0.5 GPa, T∼530°C. Plagioclase and ilmenite replaced garnet and rutile respectively during decompression. In a still later stage, secondary biotite recrystallized, accompanied by sillimanite replacing kyanite, and spinel replacing staurolite. The P-T information suggests that the amphibolite unit in the SW Dabie Mountains is part of the Triassic collision belt between the Sino-Korean and Yangtze cratons. The P-T paths of the UHP eclogite in the eastern Dabie Mountains and the HP kyanite-anthophyllite schist in the SW Dabie Mountains show similar decompression and equivalent late stage Barrovian-style metamorphism. Emplacement of voluminous granitoid at middle crustal levels between 134–118 Ma contributed to the development of the Barrovian-type metamorphism in the Dabie Mountains.  相似文献   

7.
Abstract The Maksyutov Complex, situated in the southern Ural Mountains of Russia, is the first location where quartz aggregates within garnets exhibiting radial fractures were identified as coesite pseudomorphs (Chesnokov & Popov 1965). The complex consists of two tectonic units: a structurally lower eclogite-bearing schist unit and an overlying meta-ophiolite unit. Both units show evidence for multiple stages of metamorphism and deformation. The high-pressure metamorphism of the eclogite-bearing schist unit, discussed in this report, is suspected to be related to a collision between the Russian platform and a fragment of the Siberian continent during the early Cambrian. At least three stages of metamorphism (M1-3) and two stages of deformation (S1 and S2) were observed in thin sections: M1) garnet (Alm55-60, Prp22-28, Grs16-20) + omphacite (Jd46-56) + phengite (Si ≅ 3.5) + rutile; M2) garnet + glaucophane ± lawsonite + white mica; and M3) epidote + chlorite ± albite ± actinolite + white mica. Observed mineral parageneses define a retrograde P-T path for the eclogite. Mineral assemblages within the most representative eclogite from the lower unit of the Maksyutov Complex indicate minimum peak pressures of 15 kbar at temperatures of approximately 600°C. If the presence of coesite pseudomorph is confirmed, the peak ultrahigh-pressure metamorphism may be as high as 27 kbar at 615°C.  相似文献   

8.
Shunsuke Endo 《Island Arc》2010,19(2):313-335
Evidence for eclogite‐facies metamorphism is widespread in the Western Iratsu body of the oceanic subduction type Sanbagawa Belt, Southwest Japan. Previous studies in this region focused on typical mafic eclogites and have revealed the presence of an early epidote‐amphibolite facies metamorphism overprinted by a phase of eclogite facies metamorphism. Ca‐rich and titanite‐bearing eclogite, which probably originated from a mixture of basaltic and calc‐siliceous sediments, is also relatively common in the Western Iratsu body, but there has been no detailed petrological study of this lithology. Detailed petrographic observations reveal the presence of a relic early epidote‐amphibolite facies metamorphism preserved in the cores of garnet and titanite in good agreement with studies of mafic eclogite in the area. Thermobarometric calculations for the eclogitic assemblage garnet + omphacite + epidote + quartz + titanite ± rutile ± phengite give peak‐P of 18.5–20.5 kbar at 525–565°C and subsequent peak‐T conditions of about 635°C at 14–16 kbar. This eclogite metamorphism initiated at about 445°C/11–15 kbar, implying a significantly lower thermal gradient than the earlier epidote‐amphibolite facies metamorphism (~650°C/12 kbar). These results define a PT path with early counter‐clockwise and later clockwise trajectories. The overall PT path may be related to two distinct phases in the tectono‐thermal evolution in the Sanbagawa subduction zone. The early counter‐clockwise path may record the inception of subduction. The later clockwise path is compatible with previously reported PT paths from the other eclogitic bodies in the Sanbagawa Belt and supports the tectonic model that these eclogitic bodies were exhumed as a large‐scale coherent unit shortly before ridge subduction.  相似文献   

9.
The presence of relics of high-pressure and ultra-high pressure metamorphic assemblages in metasedi-ments and granitoid gneisses provides important evi-dence for deep subduction of continental crust (litho-sphere), and also an important criteria on "in situmetamorphism" and "tectonic emplacement" relation-ship between gneisses and enclosed eclogites. In re-cent years, eclogite and garnet peridotite lenses en-closed within quartz-feldspathic gneisses or peliticgneisses were discovered separately…  相似文献   

10.
Wei  Lin  Masaki  Enami 《Island Arc》2006,15(4):483-502
Abstract Jadeite‐bearing eclogites and associated blueschists locally crop out in a greenschist facies area at Kuldkourla, near the Akeyazhi River in the western Chinese Tianshan region, northwestern China. Garnet in these metamorphic rocks shows prograde zoning with increasing Mg and decreasing Mn from the crystal center towards the rim, and is divided into Ca‐poor/Fe‐rich core and Ca‐rich/Fe‐poor mantle parts. The garnet cores include the assemblages of (i) jadeite/omphacite (Xjd = 0.34–0.96) + barroisite/taramite; and (ii) omphacite + barroisite/pargasite, with paragonite, epidote, rutile and quartz as major phases with rare albite. The garnet mantles rarely contain inclusions of omphacite, glaucophane, epidote, rutile and quartz. Major matrix phases of the pre‐exhumation stage are omphacite, glaucophane, paragonite, rutile and quartz. These mineral parageneses give pressure (P)‐temperature (T) conditions of 0.9 GPa/390°C?1.4 GPa/560°C for the stage of the garnet core formation, 1.8 GPa/520°C for the stage of the garnet mantle formation, and 2.2 GPa/495°C‐2.4 GPa/535°C for the peak eclogite facies assemblage in the matrix. The estimated P‐T conditions and continuous changes of mineral parageneses imply a counterclockwise P‐T path which is a combination of (i) an early prograde stage of high‐pressure/low‐temperature (HP/LT) blueschist facies and/or LP/LT eclogite facies; (ii) a later prograde stage involving compression with minimal heating; and (iii) a climax‐of‐subduction stage characterized by a slight decrease of temperature with increasing pressure. The negative dP/dT of the latest subduction stage is possibly a record of the following events after a continuous subduction and ridge approach: (i) material migration within the upper part of the subducting slab, which has an inverse thermal gradient caused by ductile flow and/or slab break during subduction; and/or (ii) temporary cooling of the wedge mantle–slab interface by continuous subduction of a relatively cold slab following subduction of a hotter ridge.  相似文献   

11.
M. Ebanu  A. Nagasaki 《Island Arc》1999,8(4):459-474
Kyanite-bearing ultrahigh-pressure (UHP) eclogites occur as blocks in orthogneisses at Yangzhuang, in the Junan area of the southwestern Sulu province, eastern China. Eclogites have variable bulk rock compositions, with Al2O3 = 16–27 wt%, FeO* + MgO = 6–22 wt% and CaO = 9–13 wt%. Major minerals are garnet, omphacite, phengitic white mica, zoisite, kyanite, rutile and an SiO2 phase. Fe-rich staurolite (Mg ? Mg# = 0.24 ± 0.01) and paragonite–margarite aggregates are rarely included in the cores of prograde zoned garnet. Metamorphic conditions ranged from 520 to 650°C and <1.4 GPa at an early prograde stage, and mostly reached 660–830°C and 2.7–3.5 GPa at the peak UHP stage. The estimated dP/dT of the prograde P–T path is less than 0.25 GPa/100°C at earlier stages and increases to 0.7–1.4 GPa/100°C just before the UHP stage. The kink of the prograde P–T path closely resembles the steady-state P–T paths proposed, assuming a two-parameter brittle-plastic shear stress model. The estimated P–T path adequately explains the absence of prograde lawsonite and sodic amphibole and the common occurrence of coexisting zoisite, kyanite and sodic-calcic amphibole in the UHP eclogites throughout the Sulu province. Simple clockwise prograde P–T paths for Sulu UHP eclogites proposed in earlier studies should be carefully re-examined.  相似文献   

12.
H. Tabata  S. Maruyama  & Z. Shi 《Island Arc》1998,7(1-2):142-158
The ultrahigh- and high-pressure (UHP–HP) metamorphic belt of the Dabie Mountains, central China, formed by the Triassic continental subduction and collision, is divided into four metamorphic zones; from south to north, the greenschist facies zone, epidote amphibolite to amphibolite facies zone, quartz eclogite zone, and coesite eclogite zone, based on metabasite mineral assemblages. Most of the coesite-bearing eclogites consist mainly of garnet and omphacite with homogeneous compositions and have partially undergone hydration reactions to form clinopyroxene + plagioclase + calcic amphibole symplectites during amphibolite facies overprinting. However, the least altered eclogites sometimes contain garnet and omphacite that preserve compositional zoning patterns which may have originated during their growth at peak temperature conditions of ∼ 750 °C, suggesting a short duration of UHP metamorphic conditions and/or consequent rapid cooling during exhumation. Systematic investigation on peak metamorphic temperatures of coesite eclogite have revealed that, contrary to the general trend of metamorphic grade in the southern Dabie unit, the coesite eclogite zone shows rather flat thermal structure (T = 600 ± 50 °C) with the highest temperature reaching up to 850 °C and no northward increase in metamorphic temperature, which is opposed to the previous interpretations. This feature, along with the preservation of compositional zonation, implies complicated differential movement of each eclogite mass during UHP metamorphism and the return from the deeper subduction zone at mantle depths to the surface.  相似文献   

13.
Ultrahigh-pressure (UHP) eclogites often show strong plastic deformation and anisotropy of seismic properties. We report in this paper the seismic velocity and anisotropy of eclogite calculated from the crystallographic preferred orientations (CPOs) of constituent minerals (garnet, omphacite, quartz and rutile) and single crystal elastic properties. We also compared the calculated results with the measured results in similar eclogites. Our results suggest that (1) Except that garnet is a seismically quasi-isotropic mineral, omphacite, quartz, coesite and rutile all have strong seismic anisotropies (AVp = 23.0%―40.9%, Max. AVs = 18.5%―47.1%). They are the major sources for anisotropy in eclogite. The average seismic velocities are fast in garnet and rutile, moderate in omphacite and coesite, and slow in quartz. (2) The deformed eclogites have the maximum Vp (8.33―8.75 km/s) approximately parallel to foliation and lineation, the minimum Vp (8.25―8.62 km/s) approximately normal to foliation and lineation and the Vp anisotropies of 1.0―1.7%. Their Vs are 4.93―4.97 km/s. The corresponding maximum anisotropies (0.73%―1.78%) of Vs are at 45° to both foliation and lineation and the minimum anisotropies at positions normal to lineation on the foliation plane. The Vs1 polarization planes are approximately parallel to foliation. The mean Vp and Vs of eclogite under UHP peak metamorphism conditions (P = 3―5 GPa, T = 900―1100℃) are estimated to be 3.4%―7.2% and 6.3%―12.1% higher than those at ambient pressure and temperature conditions, respectively. (3) Omphacite component dominates the anisotropy of eclogite while garnet component reduces the anisotropy and increases the seismic velocities. Quartz component has a small effect on the anisotropy but reduces the seismic velocities of eclogite. The effect of rutile component is negligible on seismic properties of eclogite due to its trivial volume fraction. (4) The increase of volume fraction of omphacite in eclogite will reduce the seismic velocities and increase the anisotropy. Omphacitite has seismic velocities reduced by 6%―8% and anisotropies increased to 3%―4% compared to those of garnetite. Our results suggest that the seismic properties calculated with single crystal elastic properties and CPOs are equivalent to those measured in laboratory. Moreover, it provides insights into the mineral physical interpretations of eclogite seismic properties.  相似文献   

14.
The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω1 > 8.5 cm?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (PT) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.  相似文献   

15.
R. Y. Zhang    J. G. Liou  W. G. Ernst 《Island Arc》1995,4(4):293-309
Abstract Altered quartz-rich and nearly quartz-free eclogitic rocks and completely retrograde quartz-rich garnet amphibolites occur as blocks or lenses in gneisses at Weihai, northeastern tip of the Sulu ultrahigh-P belt. Eclogitic rocks with assemblage garnet ± clinopyroxene ± coesite + rutile have experienced three-stage metamorphic events including ultrahigh-pressure eclogite, granulite and amphibolite facies. Granulite metamorphic event is characterized by formation of the hypersthene + salite + plagioclase ± hornblende corona between garnet and quartz + clinopyroxene. P-T conditions for the three-stage recrystallization sequence are 840 ± 50°C, >28 kbar, about 760±50°C, 9 kbar, and ~650°C, <8 kbar respectively. Most country rock gneisses contain dominant amphibolite-facies assemblages; some garnet-bearing clinopyroxene gneisses recrystallized under granulite-facies conditions at about 740±50°C and 8.5 kbar; similar to granulite-facies retrograde metamorphism of the enclosed eclogitic blocks. Minor cale-silicate lenses within gneisses containing an assemblage grossular + salite + titanite + quartz with secondary zoisite and plagioclase may have formed within a large pressure range of 14-35 kbar. Eclogitic boudins and quartzo-feldspathic country rocks may have experienced coeval in situ UHP and subsequent retrograde metamorphism. The established nearly isothermal decompression P-T path suggests that this area may represent the interior portion of a relatively large subducted sialic block. The recognized UHP terrane may extend eastward across the Yellow Sea to the Korean Peninsula.  相似文献   

16.
Hideki Masago 《Island Arc》2000,9(3):358-378
Abstract In the Barchi–Kol area, located at the westernmost part of the Kokchetav ultrahigh pressure (UHP) to high-pressure (HP) massif, northern Kazakhstan, metabasites from the epidote amphibolite (EA) facies to the coesite eclogite (CEC) facies are exposed. Based on the equilibrium mineral assemblages, the Barchi–Kol area is divided into four zones: A, B, C and D. Zone A is characterized by the assemblage: epidote + hornblende + plagioclase + quartz, with minor garnet. Zone B is characterized by the assemblage: garnet + hornblende + plagioclase + quartz + zoisite. Zone C is defined by the appearance of sodic–augite, with typical assemblage: garnet + sodic–augite + tschermakite–pargasite + quartz ± plagioclase ± epidote/clinozoisite. Zone D is characterized by the typical eclogite assemblage: garnet + omphacite + quartz + rutile, with minor phengite and zoisite. Inclusions of quartz pseudomorph after coesite were identified in several samples of zone D. Chemical compositions of rock-forming minerals of each zone were analyzed and reactions between each zone were estimated. Metamorphic P-T conditions of each zone were estimated using several geothermobarometers as 8.6 ± 0.5 kbar, 500 ± 30 °C for zone A; 11.7 ± 0.5 kbar, 700 ± 30 °C for zone B; 12–14 kbar, 700–815 °C for zone C; and 27–40 kbar, 700–825 °C for zone D.  相似文献   

17.
Two unusual diamonds were studied from kimberlites from China, which contain both ultramafic and eclogitic mineral inclusions in the same diamond hosts. Diamond L32 contains seven Fe-rich garnets, four omphacites and one olivine inclusion. Four olivine, one sanidine and one coesite were recovered from diamond S32. Both garnet and omphacite inclusions have similar compositions as those from other localities of the world, and show basaltic bulk composition. All the garnet and omphacite inclusions in diamond L32 have positive Eu anomalies (Eu/Eu*1.64 1.79). These observations support the proposal that mantle eclogite is the metamorphic product of subducted ancient oceanic crust. The Mg/(Mg + Fe) ratio of the olivine inclusions from the two diamonds (91-92) are evidently lower than the normal olivine inclusions in diamonds from the same kimberlite pipe (92-95). The following model is proposed for the formation of diamonds with “mixed” mineral inclusions. Ascending diamond-bearing eclogite (recycled oceanic crust) entrained in mantle plumes may experience extensive partial melting, whereas the ambient peridotite matrix remains subsolidus in the diamond stable field. This provides a mechanism for the transport of diamond from its original eclogitic host to an ultramafic one. Subsequent re-growth of diamond in the new environment makes it possible to capture mineral inclusions of different lithological suites. Partial melts of basaltic sources may interact with the surrounding peridotite, resulting in the relatively lower Mg/(Mg + Fe) ratios of the coexisting olivine inclusions from the studied diamonds. Diamonds with “mixed” mineral inclusions demonstrate that plume activity also occurred in the Archean cratons.  相似文献   

18.
Abstract The Kokchetav Massif of northern Kazakhstan is unique because of the abundant occurrence of microdiamond inclusions in garnet, zircon and clinopyroxene of metasediments. In order to determine precise pressure–temperature (P–T) conditions, we have systematically investigated mineral inclusions and the compositions of major silicates in Ti–clinohumite–garnet peridotite and diamond-grade eclogite from Kumdy–Kol. It was found that garnet peridotites from Kumdy–Kol contain assemblages of garnet, olivine, Ti–clinohumite and ilmenite. The garnet contains inclusions that are indicative of both ultrahigh pressure (UHP) and retrograde conditions. Inclusions of hydrous phases such as chlorite, amphibole and zoisite were formed at the post-UHP stage. The study also found that eclogite from Kumdy–Kol contains albite–augite symplectites after omphacitic pyroxene. The core of pyroxene (sodic augite) contains high K2O (up to 1wt%; average 0.24wt%). Phengite is included in the core. Applying the K2O-in-augite geobarometry, which is based on recent experiments, and the garnet–clinopyroxene (Grt–Cpx) geothermometer for peak metamorphism, the eclogites yield P–T estimates of > 6 GPa and > 1000 °C, and the diamond-grade eclogites yield lower temperature estimates at 900–1000 °C and 5 GPa.  相似文献   

19.
In Yuka-Luofengpo area of the north Qaidam Mountains, eclogitic metapelites are recognized. The metapelites enclosed lenses of eclogites, and locally intercalated with eclogites. Their typical mineral assemblages are garnet+kyanite+chloritoid+phengite+quartz+rutile. Strong growth zoning is preserved in garnets of metapelites, and phengite contains up to 3.4 Si per formula units. The petrographic observations and textural relations testify to the following sequence of mineral assemblages connected to three metamorphic stage: (1) Grt+ChlI+CldI +PheI ± StI+Qtz; (2) Grt+Ky+PheII±CldII+Qtz; and (3) Grt+CldIII+ChlII+PheIII+StII ± ky+ Qtz. Applying THERMOCALC Program, Grt-Phe thermometer and Grt-Ky-Phe-Qtz barometry, P-T conditions for three metamorphic stages were obtained: P=1.07±0.31GPa, T=564±22? (prograde stage); P=2.3–3.1GPa, T=615–700°C-(peak stage); and P =1.22 ± 0.26GPa, T=581±20°C (retrograde stage). A hairpin shape P-T path similar to that of adjacent eclogite is inferred. In combination with eclogitic mineral relics in marbles and orthogneisses enclosing eclogites, we thought that the relationship between eclogites and country rocks is “in situ” rather than “tectonic emplacement”.  相似文献   

20.
Garnet grains in Sanbagawa quartz eclogites from the Besshi region, central Shikoku commonly show a zoning pattern consisting of core and mantle/rim that formed during two prograde stages of eclogite and subsequent epidote–amphibolite facies metamorphism, respectively. Garnet grains in the quartz eclogites are grouped into four types (I, II, III, and IV) according to the compositional trends of their cores. Type I garnet is most common and sometimes coexists with other types of garnet in a thin section. Type I core formed with epidote and kyanite during the prograde eclogite facies stage. The inner cores of types II and III crystallized within different whole‐rock compositions of epidote‐free and kyanite‐bearing eclogite and epidote‐ and kyanite‐free eclogite at the earlier prograde stage, respectively. The inner core of type IV probably formed during the pre‐eclogite facies stage. The inner cores of types II, III, and IV, which formed under different P–T conditions of prograde metamorphism and/or whole‐rock compositions, were juxtaposed with the core of type I, probably due to tectonic mixing of rocks at various points during the prograde eclogite facies stage. After these processes, they have shared the following same growth history: (i) successive crystal growth during the later stage of prograde eclogite facies metamorphism that formed the margin of the type I core and the outer cores of types II, III, and IV; (ii) partial resorption of the core during exhumation and hydration stage; and (iii) subsequent formation of mantle zones during prograde metamorphism of the epidote–amphibolite facies. The prograde metamorphic reactions may not have progressed under an isochemical condition in some Sanbagawa metamorphic rocks, at least at the hand specimen scale. This interpretation suggests that, in some cases, material interaction promoted by mechanical mixing and fluid‐assisted diffusive mass transfer probably influences mineral reactions and paragenesis of high‐pressure metamorphic rocks.  相似文献   

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