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1.
Electrical resistance heating (ERH) is a thermal treatment technology that involves passing electrical current through soil to increase subsurface temperatures. In addition to volatizing and recovering contaminant mass in the gas phase, heating the subsurface has the potential to decompose contaminants by increasing the rate of degradation reactions. Prior laboratory studies using convective heating demonstrated that the rate of tetrachloroethene (PCE) degradation was not sufficient to cause substantial in situ PCE mass destruction. However, similar experiments have not been performed using ERH, which has the potential to degrade PCE in reaction with the heating electrodes and electrochemically. Thus, the objective of this study was to determine the extent of PCE degradation during thermal treatment of PCE‐contaminated soil using a bench‐scale ERH system. The contaminated soil, a silty clay loam, was collected from a single borehole at a former dry cleaning facility prior to undergoing ERH treatment. After 30 days of ERH, 52% of the initial PCE mass was recovered, potentially indicating that 48% of the PCE was degraded during ERH. Although potential degradation products such as carbon dioxide were observed, their presence was attributed to the degradation of soil organic carbon and carbonates rather than PCE destruction. A second ERH experiment was conducted to assess the potential benefit of adding the heat‐activated oxidant, sodium‐persulfate, during treatment. After 19 days of ERH and three persulfate injections, 93% of the initial PCE was recovered, with 3% PCE destruction based on chloride evolution. However, the difference in mass recovery between the first and second experiments could have been due to differences in the initial mass of PCE, even though soil from the same core was used in both experiments. The results of this work suggest that the majority of mass recovered during ERH of the PCE‐contaminated soil at the former dry cleaning facility will be due to volatilization and gas phase extraction rather than abiotic degradation, even with the addition of sodium persulfate.  相似文献   

2.
Before 1900, the Missouri–Mississippi River system transported an estimated 400 million metric tons per year of sediment from the interior of the United States to coastal Louisiana. During the last two decades (1987–2006), this transport has averaged 145 million metric tons per year. The cause for this substantial decrease in sediment has been attributed to the trapping characteristics of dams constructed on the muddy part of the Missouri River during the 1950s. However, reexamination of more than 60 years of water‐ and sediment‐discharge data indicates that the dams alone are not the sole cause. These dams trap about 100–150 million metric tons per year, which represent about half the decrease in sediment discharge near the mouth of the Mississippi. Changes in relations between water discharge and suspended‐sediment concentration suggest that the Missouri–Mississippi has been transformed from a transport‐limited to a supply‐limited system. Thus, other engineering activities such as meander cutoffs, river‐training structures, and bank revetments as well as soil erosion controls have trapped sediment, eliminated sediment sources, or protected sediment that was once available for transport episodically throughout the year. Removing major engineering structures such as dams probably would not restore sediment discharges to pre‐1900 state, mainly because of the numerous smaller engineering structures and other soil‐retention works throughout the Missouri–Mississippi system. Published in 2009 by John Wiley & Sons, Ltd.  相似文献   

3.
Being an essentially open system, cages are usually characterized by a high degree of interaction with environment and cage systems are highly likely to produce large bulk of wastes that are released directly into the environment. Therefore, large-scale cage aquaculture development has been put into question and concerns have been raised that cage aquaculture produces large bulk of wastes that are rich in organic matter and nutrients and are released into coastal and nearshore environment. Recent information on cage aquaculture nutrient budget is scarce and most published reports are dated. This paper reviews cage aquaculture nutrient budget and nutrient loadings and propose a model for nutrient (nitrogen, N and phosphorus, P) budget in a hypothetical cage aquaculture farm with values of feed loss, FCR (feed conversion ratio) and nutrient contents in feed and fish taken from published literature in order to calculate the amount (kg) of N and P produced and released to the environment for each ton of fish produced. The paper proposes, in addition, a critically analyzed nutrient budget based on the dry matter conversion rate instead of the usual feed conversion rate. The conceptual model shows that 132.5 kg N and 25.0 kg P are released to the environment for each ton of fish produced; these values are as high as 462.5 kg N and 80.0 kg P when calculated on the basis of dry matter conversion rate instead of usual feed conversion rate. Thus, the annual global N and P loadings from cage aquaculture (10,000 tons fish and 3000 tons dry matter) are 1325 tons N and 250 tons P and 1387.5 tons N and 240.0 tons P based on usual feed conversion rate and dry matter conversion rate respectively. The paper also proposes, by analyzing the existing data, an FCR-based regression model for predicting nutrient loadings for a given diet. Finally, attempt was made to calculate the annual global loading and release of N and P from cage aquaculture to the coastal and marine environment, the potential impacts of nutrient loading on the ecosystem were discussed and critical points to be considered for minimizing nutrient output in cage aquaculture were suggested.  相似文献   

4.
The removal of biofouling from vessels during hull cleaning can pose a biosecurity threat if viable, non-indigenous organisms are released into the aquatic environment. However, the effect of cleaning on biofouling organism viability in different types of cleaning operations has been poorly studied. We compared the effects of hull cleaning on biofouling organisms removed from 36 marine vessels during in-water (without capture of cleaning waste) and shore-based (with capture, and treatment of cleaning waste) cleaning. In-water cleaning resulted in higher proportions of viable biofouling organisms surviving cleaning (62.3 ± 7.1% of all organisms examined) compared to dry dock (37.8 ± 8.6%) and haul-out (20.1 ± 5.3%) operations. For shore-based facilities with effluent treatment systems, concentrations of organisms and/or their propagules in cleaning effluent was reduced by ≥ 98.5% compared to initial hydro-blast effluent concentrations. These results can be used in guidance for hull cleaning operations to minimize associated biosecurity risk.  相似文献   

5.
Groundwater contamination by tetrachloroethene and its dechlorination products is present in two partially intermingled plumes in the surficial aquifer near a former dry‐cleaning facility at Site 45, Marine Corps Recruit Depot, Parris Island, South Carolina. The northern plume originates from the vicinity of former above‐ground storage tanks. Free‐phase tetrachloroethene from activities in this area entered the groundwater. The southern plume originates at a nearby, new dry‐cleaning facility, but probably was the result of contamination released to the aquifer from a leaking sanitary sewer line from the former dry‐cleaning facility. Discharge of dissolved groundwater contamination is primarily to leaking storm sewers below the water table. The strong influence of sanitary sewers on source distribution and of storm sewers on plume orientation and discharge at this site indicates that groundwater‐contamination investigators should consider the potential influence of sewer systems at their sites.  相似文献   

6.
The emission of large amounts of solvent vapors with exhaust air from industrial production into the environment is a serious problem. In Germany, industry‐sector‐specific threshold values are applied and technical measures for pollution reduction are required. Different techniques for exhaust air cleaning are in use but still posing problems concerning costs and reliability. For these reasons, the development of processes for exhaust air treatment is the subject of the current research. A new concept for exhaust air cleaning is introduced that combines absorption of a solvent vapor by an organic fluid and a subsequent adsorption by a molecular sieve placed in the absorber. It was managed to close the loops of solvent recovery and sorbents regeneration. In laboratory‐scale experiments it was possible to reduce an initial ethylacetate pollution of 800 mg/m3 or 349 mg C/m3 below the limit value of 75 mg C/m3 over 60 h duration. Thermogravimetric measurements assisted to define optimum conditions for solvent recovery at 180°C from the molecular sieve. One unexpected positive finding was the considerable increase in the solvent release in the presence of the absorption fluid while adsorption isotherms revealed first insight into this process.  相似文献   

7.
The effect of recent drilling operations (fluid and well cuttings) on polychaete feeding guilds from the continental shelf off Atlantic City, New Jersey, was examined. Although there were some adverse effects on macrobenthos from 2160 metric tons of cuttings and mud solids discharged into the marine environment, the composition of polychaete feeding guilds remained essentially unchanged. This key trophic relationship between polychaetes and the changing environment due to the drilling operation was apparently uninterrupted. This relationship remains to be examined in other natural and perturbed habitats.  相似文献   

8.
Sediment samples were collected from 12 locations of Kaohsiung Harbor, Taiwan and analyzed for polycyclic aromatic hydrocarbons (PAHs). Total PAH concentrations varied from 472 to 16,201 ng g(-1) dry weight. The highest PAH concentrations were from the industrial zone docks situated in south Kaohsiung Harbor. Diagnostic ratios showed that the possible source of PAHs in the industrial zone dock could be coal combustion while in the other zones it could be petroleum combustion. The toxic equivalent concentrations (TEQcarc) of PAHs varied from 55 to 1964 ng TEQ g(-1) dry weight. Higher total TEQcarc values were found at industrial zone docks (from 1404 to 1964 ng TEQ g(-1) dry weight). As compared with the US Sediment Quality Guidelines (SQGs), the observed levels of PAHs at industrial zone docks exceeded the effects range low (ERL), and could thus cause acute biological damage. However, the lower levels of PAHs at the other zones would probably not exert adverse biological effects.  相似文献   

9.
Emissions from construction products may have a significant impact on the quality of indoor air, particularly in energy‐efficient buildings, where the normal rate of air exchange with fresh ambient air may be limited. In this context, reduction strategies to mitigate the concentration of chemicals in the indoor environment have become even more important. German authorities wanted to foster the development of low‐emission products, and as a result it was necessary to quantify and qualify these emissions in a reliable and objective manner. The core principles for evaluation of the standardized measurements in emission tests were established by the “Committee for Health‐Related Evaluation of Building Products” (AgBB) and published in the so‐called “AgBB scheme”. Relevant for evaluation are: (i) Assessment of the emission levels of substances with known toxicological properties; (ii) limits for non‐assessable or unknown substances; (iii) limits for the total amount of chemical emissions. This review describes the stepwise implementation of the test procedure in Germany and the experience gained in evaluation of product emissions over the years. A comprehensive overview of the philosophy, history, current practices, and future directions of the German AgBB scheme for VOC emissions is also provided. Special emphasis is given to the evaluation of a list of about 170 single substances which have an agreed “lowest concentration of interest” (LCI) value for the indoor environment – values that are updated periodically according to present toxicological knowledge.  相似文献   

10.
The active crater of Nakadake at Aso Volcano, southwestern Japan, has been occupied by a lake during its dormant periods. Multiple ash emissions were observed from the crater lake between July 2003 and August 2005. The largest events occurred on 10 July 2003 and 14 January 2004. On 10 July 2003, ash (41 tons) was dispersed throughout an area extending 14 km east-northeast of the vent, and on 14 January 2004 ash (32 tons) extended 8 km to the east-southeast. Thereafter, small ash emissions were frequent at the crater lake, in which the water level fell considerably from April to August 2005. During this period major ash emitting events, producing mostly white aggregated ash, occurred on June 10–12, June 21 (4.2 tons) and July 25 (1.2 tons). Ash emissions at the Nakadake crater in 2003–2005 were classified into three types: gentle release of white aggregated ash from fumaroles inside the crater lake (e.g. daytime of 14 April, 10–12 June and 25 July 2005); emission of black ash from an almost dried-up vent (21 June 2005); and short-time (ca. 20 s) small-explosion-triggered gas-and-ash emission through the crater lake (10 July 2003, 14 January 2004 and 14 April 20h41m 2005). All products from these ash emissions consisted of fine-grained (< 1 mm) glass shards, crystals and lithic fragments, and contained neither lapilli nor blocks. Although the glass shards show varying degrees of crystallization and alteration, clear glass shards, which appear fresh, are probably juvenile materials. These observations suggest that the 2003–2005 ash emissions from the crater lake of Nakadake Volcano are related to newly ascending magma.  相似文献   

11.
Casey Lee  Guy Foster 《水文研究》2013,27(10):1426-1439
In‐stream sensors are increasingly deployed as part of ambient water quality‐monitoring networks. Temporally dense data from these networks can be used to better understand the transport of constituents through streams, lakes or reservoirs. Data from existing, continuously recording in‐stream flow and water quality monitoring stations were coupled with the two‐dimensional hydrodynamic CE‐QUAL‐W2 model to assess the potential of altered reservoir outflow management to reduce sediment trapping in John Redmond Reservoir, located in east‐central Kansas. Monitoring stations upstream and downstream from the reservoir were used to estimate 5.6 million metric tons of sediment transported to John Redmond Reservoir from 2007 through 2010, 88% of which was trapped within the reservoir. The two‐dimensional model was used to estimate the residence time of 55 equal‐volume releases from the reservoir; sediment trapping for these releases varied from 48% to 97%. Smaller trapping efficiencies were observed when the reservoir was maintained near the normal operating capacity (relative to higher flood pool levels) and when average residence times were relatively short. An idealized, alternative outflow management scenario was constructed, which minimized reservoir elevations and the length of time water was in the reservoir, while continuing to meet downstream flood control end points identified in the reservoir water control manual. The alternative scenario is projected to reduce sediment trapping in the reservoir by approximately 3%, preventing approximately 45 000 metric tons of sediment from being deposited within the reservoir annually. This article presents an approach to quantify the potential of reservoir management using existing in‐stream data; actual management decisions need to consider the effects on other reservoir benefits, such as downstream flood control and aquatic life. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

12.
This work focuses on the site‐specific assessment of source zone natural attenuation (SZNA) at chlorinated aliphatic hydrocarbon (CAH)‐impacted sites. The approach is similar in some ways, but different in other ways from recently proposed SZNA assessment paradigms for petroleum‐impacted sites. The similarities lie in the organization of the approach around determining: (1) whether or not SZNA is occurring, (2) the current SZNA rate, and (3) what is the future projection for SZNA rate changes and the final state of the source zone. Differences lie in how those rates are determined, especially with respect to the quantities measured and data reduction. Petroleum‐impacted site SZNA approaches emphasize quantifying fluxes of electron acceptors, while the proposed CAH assessment approach emphasizes quantifying parent and daughter compound fluxes. A paradigm for assessing SZNA at CAH sites is presented and its use is illustrated, for example former dry cleaner site, where the SZNA rate was approximately 3.5 kg/year as tetrachloroethylene (PCE) with about 80% of the mass loss attributed to groundwater flow and 20% attributed to vapor transport.  相似文献   

13.
Microbiological degradation of perchloroethylene (PCE) under anaerobic conditions follows a series of chain reactions, in which, sequentially, trichloroethylene (TCE), cis‐dichloroethylene (c‐DCE), vinylchloride (VC) and ethene are generated. First‐order degradation rate constants, partitioning coefficients and mass exchange rates for PCE, TCE, c‐DCE and VC were compiled from the literature. The parameters were used in a case study of pump‐and‐treat remediation of a PCE‐contaminated site near Tilburg, The Netherlands. Transport, non‐equilibrium sorption and biodegradation chain processes at the site were simulated using the CHAIN_2D code without further calibration. The modelled PCE compared reasonably well with observed PCE concentrations in the pumped water. We also performed a scenario analysis by applying several increased reductive dechlorination rates, reflecting different degradation conditions (e.g. addition of yeast extract and citrate). The scenario analysis predicted considerably higher concentrations of the degradation products as a result of enhanced reductive dechlorination of PCE. The predicted levels of the very toxic compound VC were now an order of magnitude above the maximum permissible concentration levels. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

14.
A seismic loss assessment for structural, non-structural, contents and business interruption is presented for precast reinforced concrete industrial buildings located in Italy. The correlation that exists between the performances of such spatially distributed buildings (i.e. spatial correlation) given a seismic event should be considered when estimating losses at a local or regional level. Loss assessment is thus performed herein using the OpenQuake-engine, an open-source tool capable of including the spatial correlation of ground-motion residuals and uncertainty in building vulnerability. The annual probability of structural collapse is employed as an initial risk measure, in which each industrial facility is considered as an individual asset. Then the economic loss for 300 buildings in the province of Arezzo is computed using a probabilistic event-based risk approach and presented in terms of annual average losses and losses at given annual rates of exceedance. The impact of the losses due to business interruption is also explored, and the extent of customer base is used as a prioritization metric for risk mitigation. It is observed that risk reduction should be applied as a priority in the facilities that are compromising the current level of acceptable risk, and the results show that business interruption has a significant contribution for economic losses, whose repercussions go beyond the regional level. Although this application is confined to the province of Arezzo, the same methodology can be used in other regions in Italy with similar building stock.  相似文献   

15.
The tetrachloroethene (PCE) source zone at a site in Endicott, New York had caused a dissolved PCE plume. This plume was commingled with a petroleum hydrocarbon plume from an upgradient source of fuel oil. The plume required a system for hydraulic containment, using extraction wells located about 360 m downgradient of the source. The source area was remediated using in situ thermal desorption (ISTD). Approximately 1406 kilograms (kg) of PCE was removed in addition to 4082 kg of commingled petroleum‐related compounds. The ISTD treatment reduced the PCE mass discharge into the plume from an estimated 57 kg/year to 0.07 kg/year, essentially removing the source term. In the 5 years following the completion of the thermal treatment in early 2010, the PCE plume has collapsed, and the concentration of degradation products in the PCE‐series plume area has declined by two to three orders of magnitude. Anaerobic dechlorination is the suspected dominant mechanism, assisted by the presence of a fuel oil smear zone and a petroleum hydrocarbon plume from a separate source area upgradient of the PCE source. Based on the post‐thermal treatment groundwater monitoring data, the hydraulic containment system was reduced in 2014 and discontinued in early 2015.  相似文献   

16.
River deltas are the major repositories of terrestrial sediment flux into the world's oceans. Reduction in riverine inputs into the deltas due to upstream damming might lead to a relative dominance of waves, tides and currents that are especially exacerbated by coastal subsidence and sea‐level rise ultimately affecting the delta environment. Analysis of multi‐date satellite imagery and maps covering the Krishna and Godavari deltas along the east coast of India revealed a net erosion of 76 km2 area along the entire 336‐km‐long twin delta coast during the past 43 years (1965–2008) with a progressively increasing rate from 1·39 km2 yr?1 between 1965 and 1990, to 2·32 km2 yr?1 during 1990–2000 and more or less sustained at 2·25 km2 yr?1 during 2000–2008. At present the Krishna has almost become a closed basin with decreased water discharges into the delta from 61·88 km3 during 1951–1959 to 11·82 km3 by 2000–2008; and the suspended sediment loads from 9 million tons during 1966–1969 to as low as 0·4 million tons by 2000–2005. In the case of the Godavari delta, although the water discharge data do not show any major change, there was almost a three‐fold reduction in its suspended sediment loads from 150·2 million tons during 1970–1979 to 57·2 million tons by 2000–2006. A comparison of data on annual sediment loads recorded along the Krishna and Godavari Rivers showed consistently lower sediment quantities at the locations downstream of dams than at their upstream counterparts. Reports based on bathymetric surveys revealed considerable reduction in the storage capacities of reservoirs behind such dams. Apparently sediment retention at the dams is the main reason for the pronounced coastal erosion along the Krishna and Godavari deltas during the past four decades, which is coeval to the hectic dam construction activity in these river basins. Copyright © 2010 John Wiley and Sons, Ltd.  相似文献   

17.
A suite of instruments was deployed in a coastal wetland ecosystem in the Albemarle estuarine system, North Carolina (USA), to characterize wind‐driven transport of saltwater through a constructed (man‐made) channel. Flow velocity, electrical conductivity, and stage were measured in a representative channel over a 2‐month period from May to July 2014, during which 4 wind tides were observed. Collected data show that thousands of metric tons of salt were advected through the channel into coastal wetlands during each event, which lasted up to 4 days. The results reveal that as much as 36% of advected salts accumulated in the wetlands, suggesting that the cumulative effects of these events on the health of coastal wetlands in the Albemarle system may be substantial due to the abundance of constructed channels and the frequency of wind‐driven tidal events. This study is the first to quantify wind‐driven salt fluxes through constructed channels in coastal wetland settings.  相似文献   

18.
Cleaning with hierarchy of CO2‐based solvents is advantageous from an environmental point of view because CO2 is non‐flammable, virtually inert, and abundant. After cleaning, the only waste stuffs generated are the contaminants that are removed from the cleaned parts. The technology is especially well suited for precision cleaning applications in which parts have intricate geometries or for applications in which parts are sensitive to water or high temperature. This review will first introduce aqueous cleaning concepts and mechanism, which is helpful to understand how to design cleaning systems using high pressure CO2. Recent microelectronic processes for cleaning and rising of circuit wafers using CO2‐based solvents are the main focus of the review. Additional cleaning topics include dry cleaning, separation of dyestuffs, and extraction of contaminations from soils and regeneration of catalysts.  相似文献   

19.
Human activities can modify naturally occurring radioactive material (NORM) into technologically enhanced naturally occurring radioactive material (TENORM) as a result of industrial activities. Most of these industries do not intend to work with radioactive material a priori. However, whenever a uranium- or thorium-bearing mineral is exploited, NORM-containing by-products and TENORM-contaminated wastes are created. The industrial use of NORM can result in non-negligible radiation exposure of workers and members of the public, exceeding by far the radiation exposure from nuclear technologies. For decades, millions of tons of NORM have been released into the environment without adequate control or even with the lack of any control. Various technologies have been developed for the control of NORM wastes. The paper discusses the merits and limitations of different NORM-waste management techniques, such as Containment, Immobilization, Dilution/Dispersion, Natural Attenuation, Separation, and - as an alternative - Cleaner Technologies. Each of these methods requires a comprehensive risk-benefit-cost analysis.  相似文献   

20.
Most rivers in Taiwan are intermittent rivers with relatively steep slopes and carry rapid sediment‐laden flows during typhoon or monsoon seasons. A series of field experiments was conducted to collect suspended load data at the Tzu‐Chiang Bridge hydrological station of the lower Cho‐Shui River, which is a major river with the highest sediment yield in Taiwan. The river reach was aggrading with a high aspect ratio during the 1980s. Because of sand mining and extreme floods, it was incised and has had a relatively narrow main channel in recent years. The experimental results indicated that typical sediment transport equations can correctly predict the bed material load for low or medium sediment transport rates (e.g. less than about 1000 tons/day‐m). However, these equations far underestimate the bed material load for high sediment transport rates. The effects of cross‐sectional geometry change (i.e. river incision) and earthquakes on the sediment load were investigated in this study. An empirical sediment transport equation with consideration of the aspect ratio was also derived using the field data collected before and after river incision. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

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