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1.
S. Kaul 《洁净——土壤、空气、水》1984,12(1):81-91
The wetland of 56 ha is situated at a height of 1565 m in the valley of the Jehlum river. Among macrophytes prevail Typha, Phragmites, Scirpus and Sparganium, and they are investigated at eight stations in the annual cycle. The mineral composition of the aboveground and belowground biomass and of the sediment was determined. The mean total biomass shows considerable variations, but also a pronounced annual variation with the summer maximum of 1445 g/m2 above-ground and 1550 g/m2 below-ground. The mineral constituents show clearly decreasing concentrations during the season of vegetation as far as potassium, calcium, magnesium and nitrogen are concerned, the nutrient contents lying between 0.041 and 1.9% P or 0.57 and 1.65 % N. In a regression analysis the biomasses show significant multiple regressions to concentrations of chloride-ions, nitrogen and partly TPP and oxygen in the water and sediment. 相似文献
2.
This study of litter decomposition was part of an extensive project examining the partitioning of rainfall, the associated chemistry, and litterfall in a dry sclerophyll eucalypt forest and a Pinus radiata plantation in southeastern Australia. The eucalypt species studied were Eucalyptus rossii, E. mannifera and E. dives. The components tested were Pinus radiata needles, leaves of the three eucalypt species, and the bark of E. rossii and E. mannifera. During the first 16 weeks of the decomposition experiment there was a rapid decrease in the concentrations of potassium, magnesium, sodium and phosphorus; this was attributed to leaching. During this period, concentrations of nitrogen and calcium increased for most components. After this period, decomposition became the dominant process, during which the concentrations of most elements increased. By the end of the experiment there was, compared with the initial values, a marked reduction in concentrations of sodium, magnesium and potassium for all eucalypt and pine litter. Calcium concentrations increased through time, with eucalypt bark showing a mid‐period decline. Phosphorus concentrations decreased for the eucalypt leaves but increased substantially for the pine needles and the eucalypt bark. For all components of both the eucalypts and pines, total nitrogen concentrations rose consistently throughout the decomposition period. This was attributed to the formation of nitrogen‐substituted lignin, which was more resistant to decomposition than the other nitrogen‐containing compounds, as well as some nitrogen being stored in the micro‐organisms responsible for decomposition. Because of loss of fragmented litter from the litter bags after 16 weeks, the weight changes could not be confidently measured after this period. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
3.
以洞庭湖典型湿地植物辣蓼为目标植物,短尖苔草为邻近植物,通过控制实验研究不同水位(30、0和-30 cm)和竞争(无竞争、全部竞争、地上竞争和地下竞争)模式下目标植物生长及生态化学计量特征的变化.结果表明:水位处理显著影响不同竞争模式下的生物量积累,辣蓼生物量随水位增加显著降低;-30 cm水位无竞争模式下生物量最大,为10.84±1.52 g.在30 cm和0 cm水位梯度下,不同竞争模式下的生物量间无显著差异.但-30 cm水位下,地下竞争模式下的辣蓼生物量积累较全竞争模式和地上竞争模式下显著增多,说明非胁迫条件下,辣蓼和苔草的竞争以地上竞争为主.水位处理对辣蓼叶片、茎和根的氮、磷含量影响显著,30 cm水位下,叶片氮、磷含量显著高于其他水位下的含量.在-30cm水位下,叶片C∶N和C∶P显著高于其他水位下的比值,分别为48.08±3.85、590.3±43.4.相比于对照处理(无竞争),竞争作用下的辣蓼总氮含量降低,而C∶N值增加,N∶P值降低,这可能是因为竞争作用导致辣蓼对氮的吸收减少所致. 相似文献
4.
The dose-response relationship between No. 2 fuel oil and the growth of the salt marsh grass,Spartina alterniflora 总被引：1，自引：0，他引：1
The effect of No. 2 fuel oil on the biomass production of the salt marsh plant, Spartina alterniflora, was studied in a greenhouse dose-response experiment. S. alterniflora were transplanted into soil with 10 dosage levels of No. 2 fuel oil ranging from 0 to 456 mg g(-1) dry soil. Three months after transplantation, values for plant biomass, stem density, and shoot height decreased significantly with increasing fuel oil level in a dose-response fashion. Evapo-transpiration rates were correlated with the total biomass response. Relative to the control, a significant decrease in total (above- plus below-ground) plant biomass was observed at concentrations above 57 mg g(-1) dry soil. Within the 3-month experimental period, detrimental effects on below-ground biomass accumulation and bioluminescence of the marine bacterium Viberio fisheri in the Microtox Solid Phase Test were observed at oil concentrations >29 mg g(-1) dry soil, suggesting that biological effects of oil within the sediment matrix may be more pronounced than on above-ground biomass, requiring a dosage 228 mg g(-1) dry soil to elicit a significant detrimental effect. Hence, measurements of oil effects with biological end-points based solely on above-ground responses may underestimate the potential impacts of petroleum hydrocarbon spills, especially when the oil has penetrated the soil. While S. alterniflora was proved to be relatively tolerant to the No. 2 fuel oil spills, its effectiveness in phytoremediation operations may be limited at fuel oil levels 228 mg g(-1) dry soil, as both plant growth and microbial activity may be constrained. 相似文献
5.
A. M. Nikanorov D. N. Gar’kusha E. A. Zubkov O. B. Bartsev L. I. Minina 《Water Resources》2018,45(2):205-212
Seasonal dynamics of the mineralization, ionic composition, and the concentrations of specific pollutants in subsoil water are studied in populated localities in the southern Rostov oblast. Four major water types are identified: hydrocarbonate–sulfate (sulfate–hydrocarbonate), sulfate, chloride–sulfate (sulfate–chloride), and mixed type of subsoil water. The quality of subsoil water was found to fail to meet the sanitarytoxicological standards in terms of many characteristics. The values of MAC are exceeded for calcium, magnesium, sodium, chloride and sulfate ions, oil products, cadmium, total iron, silicon, and nitrate and ammonium nitrogen. Relationships were found to exist between the concentrations in water of cadmium, potassium, and phosphorus ions; oil products; pH values; water mineralization and total hardness; and seasonal variations of subsoil water levels. The identified relationships were substantiated. 相似文献
6.
比较了毛竹、石栎和山胡椒叶片的理化属性,采用粗网叶袋法研究了三种落叶在太湖流域上游西苕溪中的分解过程,探讨了毛竹叶成为溪流优势外来能源后对溪流生态过程和底栖动物群落结构的影响.三种落叶的氮、磷含量及叶片厚度都存在显著差异,毛竹叶的氮含量(30.23 g/kg)远高于石栎(20.98 g/kg)和山胡椒(9.69 g/kg),其中毛竹叶的分解速率最快(k=0.00592 d-1),山胡椒(0.00297 d-1)和石栎叶(0.00212 d-1)较慢.三种落叶叶袋间的大型底栖无脊椎动物包括各取食功能团的多度和生物量无显著差异,而4次采样间的差异很显著.大型底栖动物的取食功能团中,撕食者的数量比例最高(40.3%),生物量比例为41.6%,是落叶分解的重要功能类群.撕食者中,利用阔叶筑巢的鳞石蛾Lepi-dostoma数量最多,占全部底栖动物的14%,是该溪流中主要的撕食者类群.因此,由于毛竹叶具有氮、磷含量较高、叶形较窄,以及两年进行一次换叶的特点,当毛竹叶替代其他阔叶秋季落叶的树种成为源头溪流优势外来能源后,可能会改变源头溪流中的氮磷含量、溪流外来能源的量和滞留时间以及底栖动物群落结构. 相似文献
7.
Hillslope soil water flowpaths and the dynamics of roadside soil cation pools influenced by road deicers 
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下载免费PDF全文 Robert J. Rossi Daniel J. Bain Emily M. Elliott Marion Divers Bridget O'Neill 《水文研究》2017,31(1):177-190
Over the past 60 years, road deicers (i.e. road salt) have been applied to roadways in high latitudes to improve road conditions in winter weather. However, the dissolution of road deicers in highway runoff creates waters with high concentrations of sodium, which can mobilize soil metals via soil cation‐exchange reactions. While several studies have detailed the interactions of road salt‐rich solutions and surface and ground waters, less attention has been given to how local hydrologic flowpaths can impact the delivery of these solutions to near‐road soils. Between 2013 and 2014, soil water samples were collected from a roadside transect of lysimeter nests in Pittsburgh, Pennsylvania (USA). Soil water samples were analysed for metal concentrations and resulting data used to examine cation dynamics. While patterns in soil water calcium and magnesium concentrations follow patterns in soil water sodium concentrations, additional processes influence patterns in soil water potassium concentrations. Specifically, we observe the highest calcium and magnesium concentrations in the deepest lysimeters, suggesting divalent cations are mobilized to, and potentially accumulate in, deeper soil horizons. In contrast, soil water potassium concentrations do not follow this pattern. Additionally, in all examined elements (Ca, Mg, K, Na, and Cl), the timing of concentration peaks appears be influenced by a combination of both distance from the roadside and sampling depth. These relationships not only suggest that multiple soil water flowpaths interact with our study transect but also confirm that road salt plumes persist and migrate following the road salting season. Characterizing the interactions of sodium‐rich solutions and roadside soil cation pools clarifies our understanding of metal dynamics in the roadside environment. A deeper understanding of these processes is necessary to effectively restore and manage watersheds as high total dissolved solid solutions (e.g. road deicing melt, unconventional natural gas brines, and marginal irrigation water) continue to influence hydrological systems. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
8.
Paulo Pereira Xavier Úbeda Deborah Martin Jorge Mataix‐Solera Artemi Cerdà Maria Burguet 《水文研究》2014,28(11):3681-3690
The aim of this work is to study the effects of a wildfire on water‐extractable elements in ash from a Pinus pinaster forest located in Portugal. The pH, electrical conductivity (EC), calcium (Ca2+), magnesium (Mg2+), sodium (Na+), potassium (K+), sodium and potassium adsorption ratio (SPAR), aluminium (Al3+), manganese (Mn2+), iron (Fe2+), zinc (Zn2+), sulphur (S), silica (Si) and phosphorous (P) were analysed in ash sampled from a sloped area burned in a wildfire and from litter from a contiguous unburned area, with similar morphological conditions. The results showed that ash leachates had higher pH and EC, and were significantly richer in water‐extractable Ca2+, Mg2+, Na+, K+, SPAR, S and Si and significantly poorer in water‐extractable Al3+, Fe2+, Mn2+ and Zn2+ than litter solutions. No significant differences were observed in water‐extractable P. The fire changed the ash solute chemistry compared with the unburned litter and increased the sample variability of nutrient distribution with potential implications for plant recovery. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
9.
Kim Vermonden Marion A. A. Hermus Marije van Weperen Rob S. E. W. Leuven Gerard van der Velde Alfons J. P. Smolders Jan G. M. Roelofs A. Jan Hendriks 《水文研究》2009,23(21):3110-3120
The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
10.
阳宗海砷污染背景下浮游植物的时空分布特征及其驱动因子解析 总被引：1，自引：1，他引：0
人类活动导致的重金属污染是湖泊水体面临的主要环境压力之一.云南高原湖泊阳宗海于2008年暴发了砷污染事件且水体砷浓度目前仍然超过生活饮用水卫生标准,严重影响了水安全和生态系统健康.本研究于2015年4月-2016年2月每两月对阳宗海南、中、北部湖区进行采样调查及分析,共鉴定出浮游植物7门44属68种,绿藻门种数最多.蓝藻门占绝对优势,其中伪鱼腥藻（Pseudoanabaena sp.）、浮丝藻（Planktothrix sp.）、束丝藻（Aphanizomenon sp.）为全年的优势种,这与已有调查显示的阳宗海砷污染后浮游植物群落中蓝藻占优的基本特征一致.方差分析结果表明浮游植物生物量在时间尺度上呈现显著的变化特征,最大值出现在8月（14.06 mg/L）,最小值出现在12月（1.23 mg/L）,而空间差异不显著.Pearson相关分析显示,浮游植物总生物量与水温、pH呈显著正相关.而与砷、透明度、锰、钠、钾和总磷浓度呈显著负相关,冗余分析结果表明,水温、砷、钙、锰、钾共同解释了阳宗海浮游植物群落结构变化的57.18%.方差分解的结果进一步表明,水温、钙离子和砷三者作用共同解释了浮游植物群落结构变化的32.05%,其中水温和钙离子分别独立解释了群落变化的12.45%和8.28%,水体砷浓度仅独立解释了2.33%,但与水温共同作用解释了9.46%.因此,我们推测水温的季节性波动导致了湖泊水体热力分层的明显变化,其中水体混合作用的增强可能会促进底泥释放过程并增加表层水体的砷浓度,进而影响了浮游植物群落的季节性变化.研究结果有利于评价重金属污染对湖泊的长期生态效应,并为砷污染湖泊的环境修复提供重要的科学依据. 相似文献
11.
- The present investigation was undertaken to evaluate the effects of three sublethal concentrations (1/10th, 1/15th and 1/20th fractions of 96 h LC50) of phenol (P), dinitrophenol (DNP), pentachlorophenol (PCP) and their antagonistic [(PCP + DNP)/P], additive [(DNP + P)/PCP] and synergistic [(P + DNP)/PCP] combinations, on several organic and inorganic components of haemopoetic systems of Notopterus notopterus after 30 d of exposure.
- Glucose, lactate, total phosphorus, non-protein nitrogen, sodium, potassium, magnesium, calcium, iron and chloride were found to be increased in most cases while protein and cholesterol were found to be decreased.
- It has been concluded that these alterations in blood parameters might be due to a damage or hyperactivity of liver, kidney and endocrine glands, the main centres for controlling the tissue metabolism.
12.
El Misti is a 5822 m strato volcano in southern Peru. The mineralogy of the fumaroles is essentially sulfur, anhydrite, gypsum and ralstonite which are precipitated by acid vapors at 100°C–125°C. There are 2 to 6 parts per thousand chloride concentrations and several parts per million sodium, potassium, magnesium, calcium, iron and zinc concentrations in the condensed vapors. Elemental ratios indicate near complete leaching of the wall rock by the vapors. Arsenic and selenium are contaminants of the sulfur but are absent from the other minerals. Both the gypsum and anhydrite contain strontium and lead and show no tendency to fractionate these metals. The anhydrite alone contains significant thallium and bismuth. Bromine, strontium, thallium and lead are present in the ralstonite. The average δ D and δ O18 ratios from the fumarolic condensates are ?31.4 ‰ and +4.8 ‰ respectively. A marine contaminated heavy water source at depth is indicated as the parent water for the vapors. 相似文献
13.
《Ground Water Monitoring & Remediation》1984,4(3):27-38
More than 40 years of ground water quality monitoring data from the aquifer of the Upper Mad River Valley have been accumulated by various agencies in Ohio. The data consist of concentrations for more than 30 chemical substances found in the ground water. Evaluation of this data using statistical analysis, tables and graphs indicates that there have been moderate increases in total dissolved solids, sulfate, fluoride, calcium, magnesium and potassium. More significant increases were discovered for chloride and sodium. Iron and zinc show a general decline in concentration. The metals arsenic, barium and lead also show increases in recent years. However, large variations in the concentrations and limited data for these metals limit the reliability of the apparent trends shown in the tabulated data.
The increases in chloride and sodium are attributed to the use of road de-icing salt. Increases in sulfate and potassium may be due to use of fertilizers in a region which is largely agricultural. The most recent data may indicate that the ground water quality is improving in terms of these two parameters. Although most of the data indicate increases in concentrations with time, inconsistencies in sampling procedures and difficulties in assessing many factors which affect ground water quality preclude the broad conclusion that urbanization and industrialization have caused regional ground water quality degradation.
The inability to interpret much of the data underlies the need for an integrated environmental monitoring program. Such a program should provide a data base for assessing factors such as air and river quality and historical land use practices so that their impact on ground water quality in the Mad River Valley can be better understood. 相似文献
The increases in chloride and sodium are attributed to the use of road de-icing salt. Increases in sulfate and potassium may be due to use of fertilizers in a region which is largely agricultural. The most recent data may indicate that the ground water quality is improving in terms of these two parameters. Although most of the data indicate increases in concentrations with time, inconsistencies in sampling procedures and difficulties in assessing many factors which affect ground water quality preclude the broad conclusion that urbanization and industrialization have caused regional ground water quality degradation.
The inability to interpret much of the data underlies the need for an integrated environmental monitoring program. Such a program should provide a data base for assessing factors such as air and river quality and historical land use practices so that their impact on ground water quality in the Mad River Valley can be better understood. 相似文献
14.
Hydrological fluxes and associated nutrient budget were studied during a 2 year period (1998–99) in a montane moist evergreen broad‐leaved forest at Ailao Mountain, Yunnan. Water samples of rainfall, throughfall, and stemflow, and of surface runoff, soil water, and stream flow were collected bimonthly to determine the concentration and fluxes of nutrients. Soil budgets were determined from the difference between precipitation input (including nutrient leaching from canopy) and output via runoff and drainage. The forest was characterized by low canopy interception and surface runoff, and high percolation and stream flow. Concentrations of nutrients were increased in throughfall and stemflow compared with precipitation. Surface runoff and drainage water had higher nutrient concentrations than precipitation and stream water. Total nitrogen and NH4+‐N concentrations were higher in soil water than stream water, whereas K+, Ca2+, and Mg2+ concentrations were lower in the former than the latter. Annual nutrient fluxes decreased with soil depth following the pattern of water flux. Annual losses of most nutrient elements via stream flow were less than the corresponding inputs via throughfall and stemflow, except for calcium, for which solute loss was greater than the inputs via precipitation. Leaching losses of that element may be compensated by weathering. Losses of nitrogen, phosphorus, potassium, magnesium, sodium, and sulphur could be replaced through atmospheric inputs. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
15.
M. K. C. Sridhar 《洁净——土壤、空气、水》1988,16(3):293-297
Pistia stratiotes L. obtained from a eutrophic lake in Ibadan, Nigeria was examined for its mineral and trace element composition. The study indicated that the shoot system accumulated more potassium, calcium and magnesium, whereas the root system accumulated significantly more cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, nickel, sodium and zinc. The possible utilization of this aquatic plant for the treatment of polluted waters and industrial effluents is discussed. 相似文献
16.
Virginia Marcon Beth Hoagland Xin Gu Wenjing Liu Jason Kaye Roman A. DiBiase Susan L. Brantley 《地球表面变化过程与地形》2021,46(14):2807-2823
More above-ground biomass (kg m−2) grows in the northern Appalachian Mountains (USA) in forests on shale than on sandstone at all landscape positions other than ridgetops. This has been tentatively attributed to physical (rather than chemical) attributes of the substrates, such as elevation, particle size, and water capacity. However, shales have generally similar phosphorus (P) concentrations to sandstones and, in the Valley and Ridge province, they erode more quickly. This led us to hypothesize that faster replenishment of the lithogenic nutrient P in shale soils through erosion + soil production could instead control the differences in biomass. To test this, soils and foliage from 10 sites on shales and sandstones in the northern Appalachians from roughly the same elevation and aspect were analysed. We discovered that, when controlling for location, concentrations of bioavailable P in soils and P in foliage were higher and P resorbed from senescing red oak leaves was lower on slower-eroding sandstone than on faster-eroding shale. Lower resorption generally can be attributed to lower P limitation for trees. Further investigation of weathering and erosion on one of the sandstone–shale pairs within a larger, paired watershed study revealed that the differences in P concentrations in biomass and foliage between lithologies likely developed because sandstones act as ‘collectors’ that trap nutrients from residual and exogenous sources, while shales erode quickly and thus promote production of soil from bedrock that releases P to ecosystems. We concluded that the combined effects of differential rates of dust collection and erosion results in roughly equal biomass growing on sandstone and shale ridgetops. This work emphasizes the balance between a landscape's capacity to collect dust versus produce soil in controlling bioavailability of nutrients. 相似文献
17.
Peter Herzsprung Elke Bozau Olaf Büttner Anja Duffek Kurt Friese Matthias Koschorreck Martin Schultze Wolf v. Tümpling Katrin Wendt‐Potthoff 《洁净——土壤、空气、水》2006,34(6):593-607
Pore water of sediments plays an important role in aquatic systems as mediator and as the reactive zone between the sediment and surface water. Sediment pore waters with high ionic strength from acidified pit lakes were investigated to obtain information about the influence on the lake water quality. The analysis of soluble reactive phosphorus, nitrate, ammonium, silica, dissolved organic carbon, ferrous iron, sulfate, chloride, sodium, potassium, calcium, magnesium, manganese, and total dissolved iron was predetermined as the dataset required for evaluation of water quality. The data collection procedure was optimised by designing a methodology for stabilisation, dilution of pore water samples and adaptation of analytical methods. The developed methodology was evaluated with respect to the effort required in the laboratory under routine conditions. In the first round of analyses, 72% of 638 individual analyses from a random selection of pore water profiles were found to be within the calibration ranges. Remedial actions to handle the remaining 28% of invalid analytical results are exemplified. Differences between comparative analyses of some ions by continuous flow analysis, ion chromatography, and atomic emission spectroscopy were evaluated. The majority of results measured by ion chromatography differed on a highly significant level from results measured by atomic emission spectroscopy. Possible reasons, originating from the extreme sample matrix, are discussed. Finally, the designed methodology and the results of the method comparison are used to recommend the selection of analytical methods under specific conditions. 相似文献
18.
To evaluate climate and atmospheric deposition induced physical and water chemical changes and their effects on phytoplankton
communities, we used complete time series (14 years, monthly measurements during the growing season) of 18 physical and chemical
variables and phytoplankton data from 13 nutrient-poor Swedish reference lakes along a latitudinal gradient. We found numerous
strong significant changes over time that were most coherent among lakes for sulfate concentrations, conductivity, calcium,
magnesium, chloride, potassium, water color, surface water temperature and the intensity of thermal stratification. Despite
these pronounced coherent physical and water chemical changes over Sweden, the phytoplankton biomass and species richness
of six phytoplankton groups, measured at the same time as the water chemical variables, showed only few and weak significant
changes over time. The only coherent significant change over Sweden, occurring in seven lakes, was observed in the species
richness of chlorophytes. The number of chlorophyte taxa significantly declined over Sweden. Using a partial least square
model for each lake, we attributed the decline primarily to an increase in water temperatures and water color, which were
among the most important variables for the model performance of each lake. All other taxonomic groups were driven primarily
by non-coherent changes in nutrient concentrations, pH and probably also non-coherent grazing pressure. We concluded that
coherent phytoplankton responses can only be achieved for taxonomic groups that are driven primarily by coherent physical/chemical
changes. According to our study, chlorophytes belong to such a group, making them possible global change indicators. Our findings
give new insights into global change effects on different phytoplankton taxonomic groups in nutrient-poor lakes. 相似文献
19.
Marcelo Bevilacqua Remor Silvio César Sampaio Sacha de Rijk Marcio Antônio Vilas Boas Jackeline Tatiane Gotardo Everton Tiago Pinto Fábio Augusto Schardong 《国际泥沙研究》2018,33(4):406-414
The objective of this study was to evaluate the concentration and distribution of heavy metals in the sediments of Paulo Gorski Lake, as well as the metals’ bioavailability and potential ecological risk, and to define the anthropogenic and natural heavy metal contributions to the lake. The chemical elements calcium (Ca), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), sodium (Na), nickel (Ni), lead (Pb), and zinc (Zn) were quantified by flame atomic absorption spectrophotometry with two extraction methods to quantify the bioavailable and non-bioavailable fractions. The data were evaluated using multivariate statistics and sediment quality indices. All sediment collection points (S1, S2, S3, S4 and S5) are different in terms of the concentration of heavy metals, except for S4 and S5, which were statistically equal. The bioavailable fraction of the elements in the sediment follows the sequence Pb>Cu>Mn>Zn>Ni>Cr>phosphorus (P) for all points. The elements Co, Cr, Pb, and Zn showed moderate to considerable contamination at all points. Only points S3 and S5 had moderate ecological risk. Urbanization has been affecting Paulo Gorski Lake via the input of chemical elements, especially Co and Pb. The points most affected by heavy metal contamination are S3 and S5 when the sedimentological sensitivity factor is considered. The lake has high hydrodynamics, causing some of the contaminants that enter the system to leave it, leading to potential negative impacts downstream. 相似文献
20.
《水文科学杂志》2013,58(6):1149-1162
AbstractGroundwater quality problems have emerged in many geographical areas due to natural environmental processes and human intervention in the geosystems. Hydrogeochemical appraisal of fluoride contaminated groundwater in Mehsana District, Gujarat State, India is carried out by means of groundwater quality investigations together with X-ray diffraction analysis of soil samples in the delineated high fluoride areas. Results show that fluoride has negative relationships with calcium, whereas relationships with sodium, alkalinity and sulphate are positive. Results obtained from aqueous speciation modelling using PHREEQC reveal that the groundwater is undersaturated with fluorite and oversaturated with calcite. The factor analysis indicates that sodium plus potassium bicarbonate groundwater have high factor loading for fluoride, whereas that for calcium chloride and magnesium chloride groundwater is low. The plausible geochemical reactions in the study area are precipitation of calcite and dissolution of dolomite, carbon dioxide and sulphate minerals with ion exchange. 相似文献