The influence of pH on Mg/Ca ratios is negligible at ambient seawater pH (8.1 to 8.3). However, we observe a dominating pH control on shell Mg/Ca when the pH of seawater is lower than 8.0. Sr/Ca in G. ruber shows a significant positive correlation with average growth rate. Presumably, part of the variability in shell Sr/Ca in the geological record is linked to changes in growth rates of foraminifera as a response to changing environmental conditions.  相似文献   

12.
青藏高原湖泊Mg~(2+)、Ca~(2+)和Mg/Ca盐度指示意义的初步分析   总被引:1,自引:0,他引:1  
王海雷  王云生 《湖泊科学》2010,22(6):894-900
总结了青藏高原地区400多个湖泊湖水的Mg2+、Ca2+和Mg/Ca等水化指标与湖水盐度的相关关系,以及这种关系随着湖水变化(不同采样时间和采样点以及自然蒸发)而产生的变化规律.结果表明:青藏高原湖泊湖水的Mg2+浓度与盐度具有较为稳定的正相关关系,而Ca2+和Mg/Ca与盐度的相关性较弱.在对于某一特定水化学类型的湖泊,一般碳酸盐型湖泊的Mg2+、Ca2+以及Mg/Ca等指标与盐度均没有明显的相关性;硫酸盐型湖泊中Mg2+浓度和盐度呈现较高的正相关关系,而Ca2+以及Mg/Ca与盐度的相关性仍很弱;而在氯化物型湖泊中,Mg2+浓度与盐度呈更高的正相关性,Ca2+浓度也与盐度呈一定的正相关性,Mg/Ca这一指标与盐度的相关性依然很弱.而对某一特定湖泊,在不同演化阶段或不同的采样地点,Mg2+浓度与盐度仍然保持明显的正相关关系,而Ca2+以及Mg/Ca与盐度的相关性仍然不稳定或很弱.在青藏高原作古环境重建应用的时候,湖水Mg2+浓度是古盐度一个较好的转换指标,而Ca2+以及Mg/Ca的古盐度指示意义相对较弱.  相似文献   

13.
High precision glacial–interglacial benthic foraminiferal Sr/Ca records from the eastern equatorial Atlantic Ocean and Caribbean Sea     
Chuan-Chou Shen  David W. Hastings  Typhoon Lee  Chin-Hsin Chiu  Meng-Yang Lee  Kuo-Yen Wei  R. Lawrence Edwards 《Earth and Planetary Science Letters》2001,190(3-4):197-209
Glacial–interglacial variation in the marine Sr/Ca ratio has important implications for coral Sr thermometry [J.W. Beck et al., Science 257 (1992) 644–647]. A possible variation of 1–3% was proposed based on ocean models [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118]. Subsequently, studies have used fossil foraminifera to test this prediction [P.A. Martin et al., Geochem. Geophys. Geosyst. 1 (1999); H.M. Stoll et al., Geochim. Cosmochim. Acta 63 (1999) 3535–3547; H. Elderfield et al., Geochem. Geophys. Geosyst. 1 (2000)]. But whether some component of foraminiferal Sr/Ca variation can be uniquely ascribed to seawater Sr variation is still not clear. To address this question, we developed cleaning and analysis techniques and measured Sr/Ca ratios on individual shells of the modern benthic foraminifer Cibicidoides wuellerstorfi. We showed that different size shells have different Sr/Ca ratios; however, samples with shell sizes of 355–500 μm appear to have normally distributed Sr/Ca ratios (1σ=1.8%). For multi-shell measurements (with estimated errors of 0.12–0.39%), the ratio varied by as much as 7.2±0.5% during the last glaciation for two Caribbean records at the same site and by 3.7±0.5% over the past 40,000 yr for one record from the Sierra Leone Rise in the eastern equatorial Atlantic. The two Caribbean records are very similar indicating that the behavior of shell Sr uptake was identical locally and that the shell Sr/Ca ratio faithfully reflects the local environment. The Atlantic record differs from the Caribbean records by as much as several percent. Thus, the foraminiferal Sr/Ca changes cannot be solely due to changes in seawater Sr/Ca unless the glacial deep ocean had spatial variation in Sr/Ca well in excess of the modern ocean. Certain similarities between the three records do exist. Notably, the rate of change of Sr/Ca is similar between 9 and 0 ka (−0.25%/kyr) and between 25 and 16 ka (+0.16%/kyr). This suggests that during these intervals, benthic foraminiferal Sr/Ca was affected by similar large-scale variables. One of these variables may be the average marine Sr/Ca ratio; however, comparison with model predictions [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118] suggests other factors must also be considered. The discrepancies between the two sites may be related to the different water mass histories for the Caribbean and eastern Atlantic. Our results suggest that variation of the seawater Sr budget only partially contributed to C. wuellerstorfi Sr/Ca records, while other significant factors still need to be quantified. At present we cannot confidently determine past seawater Sr/Ca variation from our foraminiferal records.  相似文献   

14.
P/Ca in coral skeleton as a geochemical proxy for seawater phosphorus variation in Daya Bay, northern South China Sea     
Chen T  Yu K 《Marine pollution bulletin》2011,62(10):2114-2121
The P/Ca ratio in coral skeletons is considered to be a direct proxy for the nutrient P in seawater. We examined the reliability of this proxy by analyzing P/Ca in a Porites coral collected from a eutrophic area in the northern South China Sea. P concentrations were significantly higher compared to previously reported values from pristine and open seas, corresponding to the elevated nutrients from the study site. We compared coral P/Ca against recent in-situ records of seawater P concentrations. Our results show that P/Ca was primarily a function of TP sw rather than PO4sw, and that the signal of skeletal P included not only phosphate, but also organic phosphorus. Besides the form of skeletal P, sub-sampling and analytical procedures and the distinctive nutrient regime were the most reasonable explanations for our results. We suggest that total P in coral skeletons may be an efficient proxy for seawater P variations and associated phytoplankton dynamics in eutrophic environments.  相似文献   

15.
First-principles investigation of the concentration effect on equilibrium fractionation of Ca isotopes in forsterite     
Yahui Song  Yonghui Li  Wenzhong Wang  Zhongqing Wu 《Acta Geochimica》2019,(4):497-507
Previous theoretical studies have found that the concentration variations within a certain range have a prominent effect on inter-mineral equilibrium isotope fractionation(10^3 lna).Based on the density functional theory,we investigated how the average Ca–O bond length and the reduced partition function ratios(10^3 lnb)and103lna of 44 Ca/40 Ca in forsterite(Fo)are affected by its Ca concentration.Our results show that Ca–O bond length in forsterite ranges from 2.327 to 2.267 A with the Ca/(Ca+Mg)varying between a narrow range limited by an upper limit of 1/8 and a lower limit of 1/64.However,outside this narrow range,i.e.,Ca/(Ca+Mg)is lower than1/64 or higher than 1/8,Ca–O bond length becomes insensitive to Ca concentration and maintains to be a constant.Because the 10^3 lnb is negatively correlated with Ca–O bond length,the 10^3lnb significantly increases with decreasing Ca/(Ca+Mg)when 1/64相似文献   

16.
Calcium isotope fractionation in coccoliths of cultured Calcidiscus leptoporus, Helicosphaera carteri, Syracosphaera pulchra and Umbilicosphaera foliosa     
Nikolaus Gussone  Gerald Langer  Markus Geisen  Blair A. Steel  Ulf Riebesell 《Earth and Planetary Science Letters》2007,260(3-4):505-515
Four species of marine calcifying algae, the coccolithophores Calcidiscus leptoporus, Helicosphaera carteri, Syracosphaera pulchra and Umbilicosphaera foliosa were grown in laboratory cultures under temperatures varying between 14 and 23 °C, and one species, C. leptoporus, under varying [CO32−], ranging from 105 to 219 μmol/kg. Calcium isotope compositions of the coccoliths resemble in both absolute fractionation and temperature sensitivity previous calibrations of marine calcifying species e.g. Emiliania huxleyi (coccolithophores) and Orbulina universa (planktonic foraminifera) as well as inorganically precipitated CaCO3, but also reveal small species specific differences. In contrast to inorganically precipitated calcite, but similar to E. huxleyi and O. universa, the carbonate ion concentration of the medium has no statistically significant influence on the Ca isotope fractionation of C. leptoporus coccoliths; however, combined data of E. huxleyi and C. leptoporus indicate that the observed trends might be related to changes of the calcite saturation state of the medium. Since coccoliths constitute a significant portion of the global oceanic CaCO3 export production, the Ca isotope fractionation in these biogenic structures is important for defining the isotopic composition of the Ca sink of the ocean, one of the key parameters for modelling changes to the marine Ca budget over time. For the present ocean our results are in general agreement with the previously postulated and applied mean value of the oceanic Ca sink (Δsed) of about − 1.3‰, but the observed inter- and intra-species differences point to possible changes in Δsed through earth history, due to changing physico-chemical conditions of the ocean and shifts in floral and faunal assemblages.  相似文献   

17.
Constraints of authigenic carbonates on trace elements (Sr, Mg) of lacustrine ostracod shells in paleoenvironment reconstruction and its mechanism     
Guang Hu  ZhangDong Jin  Fei Zhang 《中国科学D辑(英文版)》2008,51(5):654-664
Molar ratios of Mg/Ca and Sr/Ca were measured in two species of ostracod shells preserved in the upper core (15-55 m) of the Heqing Basin in Yunnan Province, southwest China. By correlating the molar ratios between Mg/Ca and Sr/Ca and comparing them with Sr concentrations of the sediments, we suggested that: (1) the molar Mg/Ca and Sr/Ca ratio variations in respective ostracod primo re- flected the changes in its ambient water composition and ecology; (2) the molar Sr/Ca ratios responded better to the salinity change linearly than Mg/Ca without aragonite precipitation in the system, and otherwise there was no linear relation between them; and (3) the molar Sr/Ca ratios were mainly con- trolled by salinity and authigenic carbonate precipitation, whereas the molar Mg/Ca ratios were related to both salinity and temperature. In fact, the rate of ostracod growth owing to temperature controls the fluctuation of Mg/Ca in shells. Here, more attentions should be paid to the constraint of authigenic mineral precipitation processes on the trace elements in ostracod shells and to the correlation between these trace elements in biogenic carbonates and compositions of the sediments in systems and in fu- ture in vitro experiments.  相似文献   

18.
The solar Na/Ca and S/Ca ratios: A close comparison with carbonaceous chondrites     
Hartmut Holweger 《Earth and Planetary Science Letters》1977,34(1):152-154
Solar abundances based on recent laboratory oscillator strengths confirm the relationship between solar matter and carbonaceous chondrites. Within spectroscopic uncertainties (typically±40%) these meteorites contain refractory and volatile elements in solar proportions. Significant improvement of accuracy at present seems restricted to a few abundant elements having reliable quantum-mechanical oscillator strengths, and necessitates strictly differential spectrum analysis. Taking this into account, the solar abundance ratios Na/Ca and S/Ca have been determined to an accuracy of±15%. The results are:Na/Ca= 0.91and S/Ca= 6.8. These volatile/refractory ratios just match type 1 carbonaceous chondrites, but contrast with other types.These and related interstellar abundance features place constraints on the condensation process and a potential heterogeneity of the solar nebula. There is evidence that no drastic pre-solar separation of interstellar gas and grains has occurred, but minor imbalance may be a common mechanism co-determining stellar metal content.  相似文献   

19.
Anomalous drip in the Punkva caves (Moravian Karst): relevant implications for paleoclimatic proxies          下载免费PDF全文
Pavel Pracný  Jiří Faimon  Ondra Sracek  Ludvík Kabelka  Jiří Hebelka 《水文研究》2016,30(10):1506-1520
The anomalous drip in the Punkva caves (Moravian Karst) shows specific hydrogeochemical properties such as low SIcalcite ~ 0.14 ± 0.11 (standard deviation), low mineralization (4.53 ± 0.42) × 10?3 mol l?1, and enhanced values of δ13C (?7.85 to ?8.35‰ VPDB), Mg/Ca × 1000 ratio (45.7 ± 3.3), and Sr/Ca × 1000 ratio (0.65 ± 0.06). By these properties, the anomalous drip significantly differs from other regular drips in the same cave and other caves in the region. The study suggests that the anomalous drip properties are a consequence of prior calcite precipitation or/and water mixing along the water flow path. As the former processes are spatially controlled, the knowledge of dripwater flow path seems to be necessary for correct paleoclimatic/paleoenvironmental reconstructions. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

20.
生物壳体锶地球化学恢复盆地古水文——以泥河湾盆地为例   总被引:5,自引:0,他引:5  
刘秀明  贾玉鹤  王世杰 《湖泊科学》2001,13(3):211-219
本文以著名的泥河湾盆地小渡口剖面28层为实例,通过有孔虫,介形虫,腹足类微体生物壳体87Sr/86Sr比值与盆地汇水区域Sr同位素地层分布特征对比分析以及生物壳体Sr/Ca国度的相关性,来重塑沉积盆地汇水来源变更,湖水变化等古水文要素,进而可以反演区域构造-气候变化,实例研究结果表明,生物壳体87Cr/86Sr 及Sr/Ca比值等地球化学方法是恢复盆地古水文条件的重要手段。  相似文献   

  首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 62 毫秒
1.
赣东北蛇绿混杂岩带中硅质岩的地球化学特征及构造意义   总被引:18,自引:0,他引:18  
李献华 《中国科学D辑》2000,30(3):284-290
赣东北蛇绿混杂岩带中含晚古生代放射虫硅质岩的SiO_2含量变化范围为 78.40%~ 89.28%,Si/Al= 6.3~23,Si/Al比和Al_2O_3呈很好的负相关关系,表明它们含有 较高比例的陆源泥质沉积物.硅质岩样品的Al_2O_3/(Al_2O_3+Fe_2O_3)=0.51~0.90,Ce/Ce~·= 0,91~1.22, La_n/Ce_n= 0.76~1.11, V<M20μg/g,V/Y<2.6,Ti/V>40,一致表明这些硅质 岩形成于与大陆地壳物质输入密切相关的大陆边缘环境,而与大洋盆地、洋中脊环境无 关.因此,这些晚古生代硅质岩既不属于~ 1.0Ga蛇绿岩套“三位一体”中的一部分,也 不支持晚古生代扬子和华夏两个块体之间存在深海大洋盆。  相似文献   

2.
百草枯和H2O2预处理提高盐泽螺旋藻对铅的耐受性   总被引:9,自引:1,他引:8  
用10μmol.L^-1的百草枯(Paraquat)和2mmol.L^-1的H2O2对盐泽螺旋藻(Spirulina subsalsa)作预处理,以诱导提高藻细胞内超氧物歧化酶(SOD),过氧化氢酶(CAT)和过氧化物酶(POD)的活性,随后用40mg.L^-1的Pb^2+进行肋迫试验,实验结果表明,预处理组的藻细胞生长量和光合速率的下降幅度明显较未预处理组小;预处理组的SOD、CAT活性虽有衰减  相似文献   

3.
利用中国数字地震台网(CDSN)兰州台短周期数字地震仪的记录资料,研究了1995年甘肃永登MS5.8地震前后,发生在永登地区小地震的S波波谱参数,获得以下结果:(1)在永登地震前2年左右,该地区小地震的SC波波谱拐角频率fC逐渐下降,由原来的2.4Hz下降到1.8Hz.(2)直达波Sg和地壳内中间层反射波SC的波谱高频衰减斜率比值γ则先逐渐上升,在临震前16个月逐渐下降,在下降过程中发生了永登地震,以后又逐渐恢复.(3)用直达横波Sg的谱参数求出的介质品质因数QSg在永登地震前后有较明显的异常变化  相似文献   

4.
由峰值速度估算地震应力降   总被引:7,自引:1,他引:7       下载免费PDF全文
根据Brune(1970)提出的震源位错模式,用发生在滇西地震实验场区鹤庆MS=5.3中强地震的地震数字化监测资料,计算了S波谱,测定了鹤庆地震序列的震源参数.在此基础上研究了地面运动峰值速度参数(r.v)对地震应力降Δσ的依赖性.由地震标定关系给出(r.v)∝Δσ2/3,导出了用峰值速度参数求地震应力降的3个关系:lg(r.v)=d1+(1/3)lgM0+(2/3)lgΔσ;lg(r.v)=d2+(1/3)ML+(2/3)lgΔσ;lgΔσ=-1.0+1.5lg(r.v).假定对大小地震的平均应力降取3.0MPa,由鹤庆地震序列的观测资料定出常数d1=-3.88和d2=-0.38.序列震源参数测定结果给出,地震矩为1011~1015N·m,破裂半径a=200~600m.根据峰值速度测定的应力降Δσ=0.1~10MPa,平均为3.7MPa.用这些标度关系求出的应力降结果与Brune模式求应力降的结果比较一致.本文的研究结果还表明,地面运动峰值速度参数对地震应力降的依赖性比对地震矩的依赖性更强.  相似文献   

5.
浙赣皖相邻地区A2型花岗岩   总被引:5,自引:0,他引:5  
浙赣皖相邻地区燕山期大茅山、铜山、里山岭、黄山、伏岭等岩体主要由黑云母花岗岩组成,其中斜长石属钠长石和富钠更长石,黑云母呈它形填隙状,结晶晚于浅色矿物。岩石化学成分富SiO2(73.92-77.55%)、富碱(Na2O+K2O为7.81-8.67%),贫CaO(0.26%-0.92%)、MgO(0-0.45);微量元素中富集Y、Nb、Zr等HFSE,贫过渡元素及Sr、Ba;稀土配分曲线呈“海鸥型”  相似文献   

6.
中国黄土与红色粘土记录的地磁极性界限及地质意义   总被引:13,自引:0,他引:13       下载免费PDF全文
本文报道由蓝田、陕县、洛川、西峰、平凉、兰州及靖远等剖面获得的古地磁研究结果.主要结论为:1.中国黄土剖面记录了Brunhes正极性带与Matuyama负极性带,Brunhes/Matuyama极性转换过程位于第8层黄土(L8).在段家坡黄土剖面该转换过程对应的地层厚度为0.375m,持续时间约6000a.转换过程由3次极性变化构成,每次经历的时间约为400a.2.Jaramillo正极性亚带(J)位于标志层L9至L15之间,大约S10-S13位置.3.Olduvai正极性亚带(O)对应的地层为S27-S334.Reunion正极性亚带(R)由两部分组成,在蓝田段家坡黄土剖面分别位于L36和S385.Matuyama负极性带与Gauss正极性带界限(M/Ga)位于黄土和红色粘土交界处,中国黄土的底界年龄为2.48Ma左右.黄土与红色粘土为整合接触关系.6.黄土下伏的红色粘土记录了Gauss正极性带,Gilbert负极性带和古地磁年表编号5(Epoch5).  相似文献   

7.
根据德国卫星激光测距(SLR)数据分析中心GFZ对1980年1月-1991年7月获取的SLR观测数据处理后得到的41个SLR站的站速度,解算了北美、欧亚、太平洋、南美和澳大利亚板块之间的相对运动欧拉矢量,得到了第1个SLR实测的板块运动模型SPMM1.与地学板块模型RM2和NUVEL-1的比较指出,SPMM1大体上与地学模型一致,与NUVEL-1更为接近;SPMM1的欧亚与北美板块相对运动欧拉极与NUVEL-1的相应极很接近,但旋转速率明显偏小.还分析了各板块上SLR站的局部形变特征.欧亚板块东部和西部存在10-20mm/a的相对运动;板块边界附近SLR站的残差站速度基本上反映了该边界的构造形变特征.  相似文献   

8.
震源破裂类型的划分及预报意义   总被引:1,自引:0,他引:1  
陈立德 《华南地震》1998,18(3):10-15
对地表有反映震源破裂方式构造形迹的强震,提出按倾向滑动分量(S1)与走向滑动分量(S2)的比值r(r=S1/S2)大小的分类原则,命名时次要成份在前,主要成份在后,研究还表明,不同震源破裂类型,其中短期前兆特征无明显区别。对M≥7.5级大震余震序列的研究表明,最大余震强度、主震与最大余震震级差以及Ms≥5.0级地震累计频次等方面,与震源破裂方式有关。一般是走滑型破裂最大余震的强度小,与主震震级差大  相似文献   

9.
云南省泸沽湖,洱海^210Pbex的垂直分布受Fe,Mn循环下^210P;o和^210Pb沉积后再迁移的影响,分别表现为三种不同的剖面分布特征,^210Pbex计年的没积物堆积速率分别为0.050-0.051g.cm^-2a^-1和0.044-0.046g.cm^-2a^-1,反映百年时间尺度上的堆积结果,泸沽湖,洱海^137Cs的垂直剖面分布虽然受分子扩散作用的影响,并没有改变其峰值位置。  相似文献   

10.
赵孟为 《地球物理学报》1996,39(Z1):237-248
对鄂尔多斯盆地磷灰石裂变径迹资料深入分析表明.最迟23Ma以来盆地发生了一期由于快速抬升剥蚀引起的冷却事件.盆地东部以95m/Ma的速率抬升,造成约2000m的剥蚀量;而盆地西部则以56m/Ma的速率抬升,导致了约1000m的剥蚀量.盆地东、西部的差异抬升剥蚀导致了盆地现今微微西倾的构造面貌.这一抬升剥蚀事件是印度板块与欧亚板块碰撞引起亚洲构造运动形式以挤压为主,转换为中新世以来以地壳增厚为主的结果.K-Ar年龄和镜质体反射率资料分析表明,盆地在170-160Ma(中侏罗末)曾发生一期热事件,使古地温梯度达57℃/km,古热流值达96-109mw/m.  相似文献   

11.
Mg/Ca and Sr/Ca ratios were determined on a single species of planktonic foraminiferan, Globigerinoides ruber (white), collected from the Gulf of Eilat and cultured in seawater at five different salinities (32 to 44), five temperatures (18 to 30 °C) and four pH values (7.9 to 8.4). The Mg/Ca-temperature calibration of cultured G. ruber (with an exponential slope of 8 ± 3%/°C) agrees well with previously published calibrations from core-tops and sediment traps. However, the dependence of Mg/Ca on salinity (with an exponential slope of 5 ± 3%/psu) is also significant and should be included in the calibration equation. With this purpose, we calculated a calibration equation for G. ruber dependent on both temperature and salinity within the 95% confidence limits:
Mg/Ca(mmol/mol)=exp[0.06(±0.02)*S(psu)+0.08(±0.02)*T(°C)−2.8(±1.0)],R2=0.95
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号