首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 421 毫秒
1.
Extraordinary blowing snow transport events in East Antarctica   总被引：1，自引：1，他引：0  
In the convergence slope/coastal areas of Antarctica, a large fraction of snow is continuously eroded and exported by wind to the atmosphere and into the ocean. Snow transport observations from instruments and satellite images were acquired at the wind convergence zone of Terra Nova Bay (East Antarctica) throughout 2006 and 2007. Snow transport features are well-distinguished in satellite images and can extend vertically up to 200 m as first-order quantitatively estimated by driftometer sensor FlowCapt?. Maximum snow transportation occurs in the fall and winter seasons. Snow transportation (drift/blowing) was recorded for ~80% of the time, and 20% of time recorded, the flux is >10?2 kg m?2 s?1 with particle density increasing with height. Cumulative snow transportation is ~4 orders of magnitude higher than snow precipitation at the site. An increase in wind speed and transportation (~30%) was observed in 2007, which is in agreement with a reduction in observed snow accumulation. Extensive presence of ablation surface (blue ice and wind crust) upwind and downwind of the measurement site suggest that the combine processes of blowing snow sublimation and snow transport remove up to 50% of the precipitation in the coastal and slope convergence area. These phenomena represent a major negative effect on the snow accumulation, and they are not sufficiently taken into account in studies of surface mass balance. The observed wind-driven ablation explains the inconsistency between atmospheric model precipitation and measured snow accumulation value.  相似文献   

2.
Ground-based aerosol instrumentation covering particle size diameters from 25 nm to 32 µm was deployed to determine aerosol concentration and cloud condensation nuclei (CCN)-activation properties at water vapor supersaturations in the range of S = 0.20–1.50 % in the remote Brazilian northeast semi-arid region (NEB) in coastal (maritime) and continental (inland) regimes. The instruments measured aerosol number concentration and activation spectra for CCN and revealed that aerosol properties are sensitive with respect to the sources as a function of the local wind circulation system. The observations show that coastal aerosol total number concentrations are above 3,000 cm?3 on average, exhibiting concentration peaks depending on the time of the day in a consistent daily pattern. The variation on aerosol concentration has also influences on the fraction of particles active as CCN. At 1.0 % water vapor supersaturation, the fraction can reach as high as 80 %. Inland aerosol total concentrations were about 1,800–1,900 cm?3 and did not show much diurnal variation. The fraction of particles active as CCN observed inland depend on the history of the air masses, and was much higher when air masses were originated over the sea. It was found that (NH4)2SO4 and NaCl are the major soluble inorganic fraction of the aerosols at the coast. The major fraction of NaCl was present in the coarse mode, while ammonium sulfate dominates the inorganic fraction at the submicron range, with about 10 % of the total aerosol mass at 0.32 µm. Inorganic compounds are almost absent in particles with sizes around 0.1 μm. The study suggests that the air masses with high concentration of CCN originate at the sea. The feasible explanation lies in the fact that the NEB’s beaches have a particular morphology that produces a wide surf zone and creates a large load of aerosols when combined with strong and permanent winds of the region.  相似文献   

3.
利用GRAPES模式研究气溶胶对云和降水过程的影响   总被引：5，自引：3，他引：2  
石荣光  刘奇俊  马占山 《气象》2015,41(3):272-285
在GRAPES中尺度模式的双参数微物理方案中加入了气溶胶活化参数化过程,实现了对云滴数浓度的预报。选取不同季节两个降水过程进行模拟,并分别开展了不同气溶胶背景下的两个试验进行对比分析,研究气溶胶对云和降水可能的影响。结果表明:气溶胶浓度增加后,因为活化产生了更多尺度较小的云滴,抑制了云雨的自动转化,使大气中滞留了更多的云水,暖云降水减小;另一方面,云水的增加会使冰相粒子,尤其是雪和霰通过碰并云水等过程而增大,最后融化成雨增加冷云降水,同时冰相粒子增加会释放更多的潜热,促进上升气流的发展,进一步增加冷云降水。气溶胶对降水的影响存在空间不一致性,暖云较厚的地方暖雨过程受到的抑制明显,使地面降水减小,冷云厚度相对较厚时,冷云降水的增加会大于暖云降水的抑制,使地面降水增加。同时由于在云降水发展的不同阶段冷暖云的变化,气溶胶对降水的影响也存在着时间不一致性。  相似文献   

4.
In recent years, an increase in the number of anthropogenic aerosol particles has raised the global mean content of aerosol particles in the atmosphere from that of preindustrial times. The indirect effects of aerosols on weather and climate cannot be ignored. In this paper, the fifth generation Pennsylvania State University (PSU)?CNational Center of Atmospheric Research (NCAR) Nonhydrostatic Mesoscale Model (MM5) is used to simulate Typhoon Chanchu (international designation: 0601), which affected the northwest Pacific. Simulations are conducted in three two-way nested domains with Mercator map projection. The horizontal grid resolutions of the three domains are 27, 9, and 3?km. A period of 60?h is simulated. Surface and rawinsonde conventional observation data and ocean wind data are additionally incorporated into the initialization data. A control (CTL) experiment is run to produce a reasonable forecast. We change the parameter of the cloud condensation nuclei (CCN) concentration (CNP) in the Reisner-2 scheme of the CTL experiment (the default value is 100?cm?3) to conduct two sensitivity experiments. They are the very clean marine (VCM) CNP experiment (CNP?=?25?cm?3) and the severe contamination (SC) CNP experiment (CNP?=?1,000?cm?3). We investigate the effects of the CNP on Typhoon Chanchu by comparing and analyzing the simulation results of the three experiments in terms of the track, intensity, precipitation, vertical structure, and microphysical processes. The main results show that Typhoon Chanchu slightly weakens as the CNP increases. Increasing the CCN to 1,000?cm?3 results in less graupel, rainwater, and cloud ice but more cloud water. However, the mixing ratio of snow does not distinctly change as the CNP changes. Increasing the CCN leads a rapid decrease in the autoconversion of cloud water to rainwater. There is no autoconversion of cloud water to rainwater in a seriously polluted continental air mass. As the CNP increases, there is more condensation, evaporation, accretion of cloud water by rainwater, and precipitation fallout. Finally, a seriously polluted continental air mass can result in distinctly lower precipitation efficiency.  相似文献   

5.
Laboratory experiments were carried out in the Mainz vertical wind tunnel to determine the retention of the trace gases ammonia and sulfur dioxide dissolved in supercooled cloud droplets during riming. The conditions during riming were similar to the ones in atmospheric mixed phase clouds: temperatures from ?18 °C to ?5 °C, liquid water contents between 1 and 1.5 g m?3, liquid drop radii between 10 and 20 μm, liquid phase concentrations from 1 to 22 mg/l. As collectors, floating ice particles and snow flakes with diameters between 6 mm and 1.5 cm were used. After riming the retention coefficients, i.e. the fractions of the species which remained in the ice phase after freezing were determined. Retention coefficients lying between 0.1 and 1.0 were measured depending on the solubility and dissociation of the trace gas, liquid phase concentration, ambient air temperature, and shape of rimed collector. This can be explained from the chemists’ point of view by the effective Henry’s law constant of the species and physically with the rate of latent heat removal from the rimed collector during freezing. Parameterizations derived from the different experimental cases describe the retention coefficients as a function of temperature. In general, an average retention of ammonia of 92?±?21 % was determined independently of liquid phase concentration while mean values for sulfur dioxide were 53?±?10 % at low liquid phase concentrations and 29?±?7 % at high liquid phase concentrations.  相似文献   

6.
The photochemical activation of chlorine by dissolved iron in artificial sea-salt aerosol droplets and by highly dispersed iron oxide (Fe2O3) aerosol particles (mainly hematite, specific surface ~150 m2 g?1) exposed to gaseous HCl, was investigated in humidified air in a Teflon simulation chamber. Employing the radical-clock technique, we quantified the production of gaseous atomic chlorine (Cl) from the irradiated aerosol. When the salt aerosol contained Fe2O3 at pH 6, no significant Cl production was observed, even if the dissolution of iron was forced by “weathering” (repeatedly freezing and thawing for five times). Adjusting the pH in the stock suspension to 2.6, 2.2, and 1.9 and equilibrating for one week resulted in a quantifiable amount of dissolved iron (0.03, 0.2, and 0.6 mmol L?1, respectively) and in gaseous Cl production rates of ~1.6, 6, and 8?×?1021 atoms cm?2 h?1, respectively. In a further series of experiments, the pure Fe2O3 aerosol was exposed to various levels of gaseous hydrogen chloride (HCl). The resulting Cl production rates ranged from 8?×?1020 Cl atoms cm?2 h?1 (at ~4 ppb HCl) to 5?×?1022 Cl atoms cm?2 h?1 (at ~350 ppb HCl) and confirmed the uptake and conversion of HCl to atomic Cl (at HCl to Cl conversion yields of 2–5 %, depending on the relative humidity). The Fe2O3 experiments indicate that iron-induced Cl formation may be important for highly soluble combustion-aerosol particles in marine environments in the presence of gaseous HCl.  相似文献   

7.
Data from a long term measurement of Micro Rain Radar (MRR) at a mountain site (Daegwallyeong,DG, one year period of 2005) and a coastal site (Haenam, HN, three years 2004–2006) in South Korea were analyzed to compare the MRR measured bright band characteristics of stratiform precipitation at the two sites. On average, the bright band was somewhat thicker and the sharpness (average gradient of reflectivity above and below the reflectivity peak) was slightly weaker at DG, compared to those values at HN. The ...  相似文献   

8.
To characterize atmospheric particulate matter equal or less than 2.5 μm in diameter (PM2.5) over the Tropical Atlantic Ocean, aerosol sampling was carried out in Puerto Rico during August and September, 2006. Aerosols were analyzed by ion chromatography for water-soluble inorganic and organic ions (including Na+, NH4 +, Mg2+, Ca2+, K+, Cl?, SO4 2?, NH4 +, F?, methanesulfonate (MSA), and oxalate), by inductive coupled plasma mass spectrometry (ICPMS) for trace elements (Al, Fe, Zn, Mn, Cu, Ni, V, Pb, Cr, Sb, Co, Sc, Cd), and by scanning electron microscopy for individual aerosol particle composition and morphology. The results show that the dominant cations in aerosols were Na+, (mean: 631 ng m?3), accounting for 63.8 % of the total cation and NH4 + (mean: 164 ng m?3), accounting for 13.8 % of the total cation measured in this study. The main inorganic anions were Cl? (576 ng m?3, 54.1 %) and SO4 2? (596 ng m?3, 38.0 %). The main organic anion was oxalate (18 ng m?3). Crustal enrichment factor calculations identified 62 % of the trace elements measured (Cu, Ni, V, Co, Al, Mn, Fe, Sc, and Cr) with crustal origin. Single particle analysis demonstrated that 40 % of the aerosol particles examined were Cl? rich particles as sodium chloride from seawater and 34 % of the total particles were Si-rich particles, mainly in the form of aluminosilicates from dust material. Based on the combination of air-mass trajectories, cluster analysis and principal component analysis, the major sources of these PM2.5 particles include marine, Saharan dust and biomass burning from West Africa; however, volcanic emissions from the Soufriere Hills in Montserrat had significant impact on aerosol composition in this region at the time of sample collection.  相似文献   

9.
为全面了解水汽在气溶胶影响雷暴云电过程中的作用,本研究在已有的二维雷暴云起、放电模式基础上,通过改变相对湿度和气溶胶初始浓度（文中气溶胶浓度均指气溶胶数浓度）进行敏感性数值模拟试验。结果表明:（1）随着气溶胶浓度升高,雷暴云产生更多的小云滴,降水过程受到抑制。而当水汽含量升高时,云滴数浓度的增长速度更快,雨滴数浓度升高,缓解了降水变弱的趋势。（2）水汽含量较低时,随着气溶胶浓度升高,更多小云滴被带入冻结层形成大量小冰晶,霰粒含量升高,雷暴云起电过程增强。气溶胶浓度升高至一定的量级（3000 cm?3）时,冰晶尺度减小和雨滴浓度降低抑制霰粒生长,雷暴云起电过程受到削弱。感应起电和非感应起电过程随气溶胶浓度升高呈先增强后减弱的趋势。水汽含量的升高促进了冰相粒子的增长,起电过程呈现持续增强的趋势,气溶胶浓度为3000 cm?3时起电率达到极值,电荷密度的增幅扩大。（3）水汽含量较低时,雷暴云难以发展成深厚的系统,气溶胶浓度变化对其影响不明显,电荷结构由三极性发展,在消散期演变为偶极性电荷结构;水汽含量较高时,雷暴云迅速发展成深厚的系统,随着气溶胶浓度升高,在雷暴发展旺盛阶段电荷分布表现为多层复杂结构。研究显示水汽含量在气溶胶浓度变化对雷暴云微物理、起电过程及电荷结构的作用中扮演重要角色。   相似文献   

10.
Using the multi-source observation data from wind-profiling radar, microwave radiometer, Doppler weather radar, etc. during the blizzard event in 19–20 March 2012 in Urumqi, this paper analyzed the detailed characteristics of the atmospheric dynamics, thermodynamics, intensity and water vapor during the process of this blizzard weather. The findings suggest: (1) in the course of the blizzard weather, the near-surface atmosphere is mainly dominated by northwest airflows, the wind speed and relative humidity increase rapidly, temperature drops and air pressure ascends; (2) the blizzard weather this time is accompanied by cold front system whose entering time is about 16:00 BT 19 March; the shear line that develops from low to high is the position height of the frontal zone, and the variation of the high-level frontal zone directly reflects the altitude and layers where cold and warm air masses interact; (3) the radar equivalent reflectivity factor of the snowstorm process changes within the range 8–25 dBZe and its large-value zone is correlated well with the blizzard duration, the height for the formation of rain (snow) particles and the snow intensity; (4) before the occurrence of the blizzard, atmosphere is in the state of high temperature and high humidity, the maximum vapor density is around 6 g m?3, water vapor mainly stays under the height of 5,000 m; affected by cold front system, cold airs gradually lift warm and moist airs so that the vapor condenses and deposits into water drops and snow particles, forming the snowstorm in the end.  相似文献   

11.
Temporal variations in atmospheric hydrogen sulphide concentrations and its biosphere-atmosphere exchanges were studied in the World’s largest mangrove ecosystem, Sundarbans, India. The results were used to understand the possible contribution of H2S fluxes in the formation of atmospheric aerosol of different size classes (e.g. accumulation, nucleation and coarse mode). The mixing ratio of hydrogen sulphide (H2S) over the Sundarban mangrove atmosphere was found maximum during the post-monsoon season (October to January) with a mean value of 0.59?±?0.02 ppb and the minimum during pre-monsoon (February to May) with a mean value of 0.26?±?0.01 ppb. This forest acted as a perennial source of H2S and the sediment-air emission flux ranged between 1213?±?276 μg S m?2 d?1(December) and 457?±?114 μg S m?2 d?1 (August) with an annual mean of 768?±?240 μg S m?2d?1. The total annual emissions of H2S from the Indian Sundarban were estimated to be 1.2?±?0.6 Tg S. The accumulation mode of aerosols was found to be more enriched with non-sea salt sulfate with an average loading of 5.74 μg m?3 followed by the coarse mode (5.18 μg m?3) and nucleation mode (1.18 μg m?3). However, the relative contribution of Non-sea salt sulfate aerosol to total sulfate aerosol was highest in the nucleation mode (83%) followed by the accumulation (73%) and coarse mode (58%). Significant positive relations between H2S flux and different modes of NSS indicated the likely link between H2S, a dominant precursor for the non-sea salt sulfate, and non-sea sulfate aerosol particles. An increase in H2S emissions from the mangrove could result in an increase in enhanced NSS in aerosol and associated cloud albedo, and a decrease in the amount of incoming solar radiation reaching the Sundarban mangrove forest.  相似文献   

12.
周志敏  崔春光  胡扬  康兆萍 《大气科学》2021,45(6):1292-1312
梅雨锋暴雨中的云微物理过程对降水的演变有着重要影响。本文通过WRF模式（3.4.1版本）,针对2018年6月29～30日一次梅雨锋背景下的暴雨过程进行数值模拟,分别采用了Morrison、Thompson和MY云微物理参数化方案进行对比分析,结果发现:（1）三个方案模拟的背景场在天气尺度上,都与ERA5再分析资料一致,能够模拟出有利于强降水发生的环流场。云微物理过程对梅雨期暴雨的局地环流有着显著影响,不同方案存在明显差异,本次过程中,Thompson方案模拟出更强的局地环流系统变率和上升气流。三个方案的模拟降水均有所夸大,小时降水率始终大于观测值。冰相粒子融化或雨滴搜集云滴的高估可能是造成降水模拟值偏强的重要原因之一,总体来看,Morrison方案的模拟效果相对最优。（2）冰相粒子融化、雨滴搜集云滴是雨滴增长的关键源项,蒸发则是其最重要的汇项。总的来说,雨滴对云滴的搜集量大于冰相粒子融化。但上述过程在不同方案中存在空间上的差异,从而使得模拟降水的空间分布存在差异。（3）Thompson方案中,冰相粒子融化量最大,雨滴蒸发项显著大于其它两个方案,在底层表现得最为明显。同时,该方案水汽凝结效应最强,使得雨滴搜集更多云滴。该方案模拟的雨滴最多,降水最强。该方案中凝华的主要产物为雪,且其在与过冷水碰并增长过程中占主导地位,故模拟的雪最多。（4）Morrison方案中,水汽主要凝华为雪和少量霰（冰晶忽略不计）;Thompson方案中水汽基本凝华为雪,其它冰相粒子极少;MY方案中,水汽主要凝华为雪和冰晶,冰晶总量略少于雪,但显著大于其它方案。（5）云滴在凇附过程中的总体贡献大于雨滴。Morrison和MY方案中,霰粒子搜集云滴增长的量均最大。Morrison方案中,其它凇附过程不同程度发挥作用,而MY方案中,其它凇附过程几乎可忽略不计。并且,霰粒子搜集云滴的增长量大于凝华过程产生的雪粒子总量。贝吉龙及凇附效应的差异,是不同方案中冰相粒子分布差异的关键原因之一。  相似文献   

13.
Global aerosol and ozone distributions and their associated radiative forcings were simulated between 1850 and 2100 following a recent historical emission dataset and under the representative concentration pathways (RCP) for the future. These simulations were used in an Earth System Model to account for the changes in both radiatively and chemically active compounds, when simulating the climate evolution. The past negative stratospheric ozone trends result in a negative climate forcing culminating at ?0.15 W m?2 in the 1990s. In the meantime, the tropospheric ozone burden increase generates a positive climate forcing peaking at 0.41 W m?2. The future evolution of ozone strongly depends on the RCP scenario considered. In RCP4.5 and RCP6.0, the evolution of both stratospheric and tropospheric ozone generate relatively weak radiative forcing changes until 2060–2070 followed by a relative 30 % decrease in radiative forcing by 2100. In contrast, RCP8.5 and RCP2.6 model projections exhibit strongly different ozone radiative forcing trajectories. In the RCP2.6 scenario, both effects (stratospheric ozone, a negative forcing, and tropospheric ozone, a positive forcing) decline towards 1950s values while they both get stronger in the RCP8.5 scenario. Over the twentieth century, the evolution of the total aerosol burden is characterized by a strong increase after World War II until the middle of the 1980s followed by a stabilization during the last decade due to the strong decrease in sulfates in OECD countries since the 1970s. The cooling effects reach their maximal values in 1980, with ?0.34 and ?0.28 W m?2 respectively for direct and indirect total radiative forcings. According to the RCP scenarios, the aerosol content, after peaking around 2010, is projected to decline strongly and monotonically during the twenty-first century for the RCP8.5, 4.5 and 2.6 scenarios. While for RCP6.0 the decline occurs later, after peaking around 2050. As a consequence the relative importance of the total cooling effect of aerosols becomes weaker throughout the twenty-first century compared with the positive forcing of greenhouse gases. Nevertheless, both surface ozone and aerosol content show very different regional features depending on the future scenario considered. Hence, in 2050, surface ozone changes vary between ?12 and +12 ppbv over Asia depending on the RCP projection, whereas the regional direct aerosol radiative forcing can locally exceed ?3 W m?2.  相似文献   

14.
飞机观测是云中粒子相态、分布和转化特征的重要探测技术。我国云降水物理飞机观测开始于20世纪60年代,经过60多年的发展,在飞机平台、机载测量技术、云微物理结构和降水形成机制认识等方面均取得了长足进步。发现积层混合云中对流泡区具有更高的过冷水含量,凇附增长起重要作用,符合“播撒-供给”降水形成机制,而在层云区,当云厚度较小时,过冷水含量很少,冰雪晶的凝华、聚并增长起主导作用,并不符合“播撒-供给”降水形成机制,而当云厚度较大时,过冷水含量较为丰富,凝华、聚并和凇附增长起主导作用,基本符合“播撒-供给”降水形成机制;我国北方冬季降雪过程的形成机制主要是凝华-聚并机制,只有在水汽非常充足、云较厚的情况下,凇附增长过程才具有重要作用。近年虽然在人工影响天气播撒效应、数值模式云物理过程验证、卫星及雷达遥感数据检验、对流云结构观测等方面也取得了一些进展,但仍较薄弱,亟待加强。  相似文献   

15.
This study is based on ground-based measurements of downward surface shortwave irradiance (SW), columnar water vapour (wv), and aerosol optical depth (τ) obtained at Thule Air Base (Greenland) in 2007–2010, together with MODIS observations of the surface shortwave albedo (A). Radiative transfer model calculations are used in combination with measurements to separate the radiative effect of A (ΔSWA), wv (ΔSWwv), and aerosols (ΔSWτ) in modulating SW in cloud-free conditions. The shortwave radiation at the surface is mainly affected by water vapour absorption, which produces a reduction of SW as low as ?100 Wm?2 (?18%). The seasonal change of A produces an increase of SW by up to +25 Wm?2 (+4.5%). The annual mean radiative effect is estimated to be ?(21–22) Wm?2 for wv, and +(2–3) Wm?2 for A. An increase by +0.065 cm in the annual mean wv, to which corresponds an absolute increase in ΔSWwv by 0.93 Wm?2 (4.3%), has been observed to occur between 2007 and 2010. In the same period, the annual mean A has decreased by ?0.027, with a corresponding decrease in ΔSWA by 0.41 Wm?2 (?14.9%). Atmospheric aerosols produce a reduction of SW as low as ?32 Wm?2 (?6.7%). The instantaneous aerosol radiative forcing (RFτ) reaches values of ?28 Wm?2 and shows a strong dependency on surface albedo. The derived radiative forcing efficiency (FEτ) for solar zenith angles between 55° and 70° is estimated to be (?120.6 ± 4.3) for 0.1 < A < 0.2, and (?41.2 ± 1.6) Wm?2 for 0.5 < A < 0.6.  相似文献   

16.
华东地区夏季云微物理结构的飞机观测分析   总被引：1，自引：1，他引：0  
利用飞机搭载云粒子探头对2014年8月12-28日华东地区云的空间分布特征进行了探测,分析了云的垂直结构和水平分布特征,结合同时探测的气溶胶数据,探讨了云与气溶胶的相互作用关系。探测结果表明,安徽地区层状云云滴平均数浓度在24~297 cm^-3,液态含水量在0.04~0.13 g·m^-3,云滴数浓度随云底高度升高而减小,云滴粒径则随云底升高而增大。层积云(Sc)和雨层云(Ns)的云滴数浓度在云底最高,随高度上升浓度下降,液态含水量在云中部最高,云顶和云底处较低,高层云(As)云滴数浓度和液态含水量峰值均出现在云中上部。云的水平分布不均匀,云粒子双峰分布区域对应液态含水量高值区。Ns对气溶胶清除作用明显,清除方式以活化清除为主、碰并清除为辅。  相似文献   

17.
A 10-months long monitoring experiment to investigate the diurnal and seasonal variation of aerosol size distribution at Nagarkot (1,900 m asl) in the Kathmadu Valley was carried out as part of a study on katabatic and anabatic influence on pollution dispersion mechanisms. Seasonal means show total aerosol number concentration was highest during post-monsoon season (775 ± 417 cm?3) followed by pre-monsoon (644 ± 429 cm?3) and monsoon (293 ± 205 cm?3) periods. Fine particle concentration (0.25 μm ≤ DP ≤ 2.5 μm) dominated in all seasons, however, contribution by coarse particles (3.0 μm ≤ DP ≤ 10.0 μm) is more significant in the monsoon season with contributions from particles larger than 10.0 μm being negligible. Our results show a regular diurnal pattern of aerosol concentration in the valley with a morning and an evening peak. The daily twin peaks are attributed to calm conditions followed by transitional growth and break down of the valley boundary layer below. The peaks are generally associated with enhancement of the coarse particle fraction. The evening peak is generally higher than the morning peak, and is caused by fresh evening pollution from the valley associated with increased local activities coupled with recirculation of these trapped pollutants. Relatively clean air masses from neighbouring valleys contribute to the smaller morning peak. Gap flows through the western passes of the Kathmandu Valley, which sweep away the valley pollutants towards the eastern passes modulated by the mountain - valley wind system, are mainly responsible for the dominant pollutant circulation patterns exhibited within the valley.  相似文献   

18.
分析了乌鲁木齐地区冬季降雪和云水的pH值与化学成分。降雪pH值平均为5.7。云水pH值为4.0左右，与采集云水同时段观测的地面降雪pH值为6.0。气团内部生成的低云云水的离子浓度比系统性降水云高约两个量级。初步分析结果表明，雪增长的微物理过程和雪粒下降过程中所捕集的大气气溶胶粒子特性可能对降雪雪水酸度有重要影响。  相似文献   

19.
Particle-associated polycyclic aromatic hydrocarbons (PAHs) in outflow from East Asia were observed at Cape Hedo, Okinawa, Japan between 2005 and 2008. The filter samples of the total suspended particles were analyzed by means of gas chromatography-mass spectrometry. The total concentration of fourteen 3–7-ring PAHs was 0.01–24 ng m?3 (average 1.6 ng m?3). The average PAH concentration increased in the winter-spring season and decreased in the summer-fall season. The average benzo(a)pyrene to benzo(e)pyrene ratio was 0.49 in the winter-spring season and was lower than the literature values for East Asian cities in the same season. This result shows that aging of organic aerosol particles proceeds during long-range transport from East Asia. In the Asian Pacific region, these pollutants are transported from East Asia in the winter-spring season, whereas clean air mass is transported from the Pacific Ocean in the summer-fall season.  相似文献   

20.
Inorganic seed particles have relatively large surface area, and play an important role in the formation and aging of secondary organic aerosol (SOA). The effects of dry (NH4)2SO4 which is the most commonly found in urban atmosphere on the aged benzene SOA were qualitatively studied utilizing aerosol laser time-of-flight mass spectrometer (ALTOFMS) coupled with Fuzzy C-Means (FCM) clustering algorithm in this study. Experimental results indicated that nitrophenol, oxocarboxylic acid, epoxide products are the predominant components in the aged benzene SOA in the presence of low concentration (about 10 μg m?3) of dry (NH4)2SO4. These aged products are the same as the previously obtained aged benzene SOA without (NH4)2SO4 seed aerosol, indicating that low concentration of dry (NH4)2SO4 acts just as the nucleation or condensation center of the SOA, and do not affect the chemical composition of SOA. However, 1 H-imidazole, 1 H-imidazole-2-carbaldehyde, hydrated 1 H-imidazole-2-carbaldehyde, 2,2′-biimidazole, hydrated N-glyoxal substituted 1 H-imidazole, N-glyoxal substituted hydrated 1 H-imidazole-2- carbaldehyde, hydrated mono glyoxal substituted hydrated 1 H-imidazole-2-carboxaldehyde, mono glyoxal substituted 2,2-biimidazole and hydrated glyoxal dimer substituted imidazole which are formed from ammonium ion reaction with glyoxal are the major particulate products in the aged benzene SOA in the presence of high concentration (about 100 μg m?3) of dry (NH4)2SO4. The retention of water on the dry (NH4)2SO4 particles creates ammonium ion, which can promote the formation of high-molecular-weight (HMW) products through multiphase reactions such as hydration and polymerization of aldehydes form from OH-initiated oxidation of benzene.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号