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1.
Measurements of the Balloon Intercomparison Campaign (BIC), conducted during fall, 1982 (BIC-1) and summer, 1983 (BIC-2), are reported. Results of five remote and two in situ techniques agree (with a few exceptions) within 95% confidence level uncertainties and generally within 15% above 20 km. Weighted mean profiles, which best represent conditions during the capaign, are used as a comparison standard. Accuracies of experiments indicated by BIC generally confirm estimated uncertainites for ECC sondes, UV photometry, and microwave emission experiments, are somewhat better for far IR emission and IR absorption experiments, and are somewhat worse for IR emission and solar UV absorption experiments. The large collection of BIC measurements confirms a problem reported earlier with current theoretical modeling of ozone near 40 km where transport is negligible and the chemistry is believed to be simpler.  相似文献   

2.
The Balloon Intercomparison Campaign (BIC) was set up to intercompare remote sensing measurements of a number of compounds other than water vapor; however, water vapor has strong absorption features throughout the infrared and mm wave regions of the spectrum. Therefore many of the investigators involved in BIC have absorption or emission features due to water vapor in the data they obtained during the balloon flights made under the campaign. These features have been used by the investigators to determine the stratospheric water vapor profiles which are compared in this paper. The profiles allow comparison of a wide range of remote sensing techniques involving both emission and absorption in the mid-infrared and emission techniques in the far infrared.  相似文献   

3.
All of the techniques used to measure stratospheric HCl during the two BIC campaigns involved high resolution infrared spectroscopy. The balloon-borne instruments included five different spectrometers, three operating in the solar absorption mode and two in emission (at distinctly different wavelengths). Ground-based and aircraft correlative measurements were made close to the balloon locations, again by near-infrared spectroscopy.Within this set of results, comparisons between different techniques (absorption vs emission) viewing the same airmass (i.e., on the same gondola) were possible, as were comparisons between the same technique used on different gondolas spaced closely in time and location. The final results yield a mean profile of concentration of HC1 between 18 and 40 km altitude; an envelope of ±15% centered on this profile encompasses all of the results within one standard deviation of their individual mean values. The absolute accuracy of the final profile is estimated to be no worse than 10%. It is concluded also that the measurement techniques for HCl have reached a level of performance where a precision of 10% to 15% can be confidently expected.  相似文献   

4.
Methane emitted into the atmosphere from sources located in the Urengoi natural gas field is estimated from direct methane concentration measurements in the atmospheric boundary layer and modeling. The results of direct profile measurements in the summer-fall season of 2003 are generalized versus the data from the previous field studies and background monitoring of greenhouse gases in the northern polar region. The use of models for calculating the intensity of emission from sources located in the field area together with a set of methane concentration measurements at three altitudes allowed the authors to develop a method of verification of emission from a specific source, a deposit. The method estimates the emission both from part of the field area and from the whole field with an irregular distribution of the intensity of sources across the deposit area.  相似文献   

5.
应用初步建立的全球二维大气化学模式,对工业革命以来甲烷的长期变化进行了模拟研究。模式将CH4、CO和NOx排放源方案进行了参数化。在考虑了CH4排放源以及对OH浓度有重要影响的CO和NOx排放源的长期变化的基础上,模拟了CH4和OH浓度自1840年到20世纪90年代的长期变化趋势。结果表明,工业革命前的大气甲烷体积分数和年排放总量分别为760×10-9和280Tg,1991年大气甲烷的体积分数和年排放总量分别为1611.9×10-9和533.9Tg。而对流层中OH的数密度则由1840年的7.17×105cm-3变化到1991年的5.79×105cm-3,下降了19%。如果CH4、CO及NOx这三种排放源继续按给定的方案增长,那么到2020年大气甲烷的体积分数和年排放总量将增加为2090.7×10-9和966.2Tg,而OH的数密度将为5.47×105cm-3,比1840年降低24%。  相似文献   

6.
该文讨论了用双He-Ne激光监测环境大气中甲烷的差分吸收方法，在实验室测量了甲烷对He-Ne激光波长的吸收系数，并且用3.3922 μm和3.3912 μm线在室外进行了甲烷浓度的测量。测量获得当地近地面自然大气中的甲烷平均浓度值为1.78 ppm，标准偏差σx=0.238 ppm。  相似文献   

7.
Results of measuring methane emissions from the Lammin-Suo oligotrophic bog massif are considered. It is shown that emission intensity depends on the methane transport from the active layer of the peat bed. The highest emission intensity is observed in the sedge-sphagnum microlandscape and over swampy hollows of the hummock-ridge complex. It is found that the methane flux intensity approaches zero when the wetland level drops by 30–35 cm from the bog surface. Spatial methane emission variability is estimated within dominating bog landscapes. The methane emission reaches its maximum values (207%) in microlandscapes with oriented microrelief (hummock-ridge complex); in the central bog (sphagnum-suffrutescent-cottongrass landscape afforested with pine), it reaches its lowest level (76%). A model of methane emissions from bogs is developed. The model has been verified from the observational data. The comparison of model calculations with experimental data is indicative of their good agreement, which makes it possible to use the model in different calculations and assessments of the influence of natural factors on the methane emission intensity.  相似文献   

8.
Presented is a detailed comparison of CH4 and δ13C–CH4 measurements with simulations of the global transport model TM3. Experimental data were obtained during campaigns along the Trans-Siberian railroad in the framework of the TROICA project. Two summer (1999 and 2001) and one spring (2003) expeditions are evaluated. Model simulations include sensitivity tests to further investigate the isotopic composition of natural gas and emissions from Siberian wetlands. Comparison of the average mixing ratio of methane and its isotopic composition (δ13C) has been performed for different geographic zones, including the European part of Russia, Western Siberia and Central Siberia. Simulations are in reasonable agreement with the measurements for the European part of Russia and confirm a high contribution of natural gas to the observed methane levels. An increase of emission from bogs shifts the simulated methane isotopic composition closer to the observations. The relative importance of the Western Siberia emissions in current inventories is underestimated in comparison with other wetland regions in the former USSR. Simulated average mixing ratios are in a good agreement with the observations in Central Siberia, while 13C(CH4) values tend to be higher than measured in all considered scenarios. These results point to a bias in the modeled source mixture over Russia, which could be repaired by shifting emissions from isotopically heavy methane sources (e.g. coal, oil or biomass burning) to light sources (e.g. wetlands, ruminants, waste treatment). Alternatively, the average isotopic signature of Siberian wetlands may be lighter than expected.  相似文献   

9.
In the rice field methane is produced in the soil layer with depths of 2-25 cm. The vertical profile of methane production rate in the paddy soil during the water covering period differs from that in the paddy soil in dry phase. Only a small part, about 30%. of the produced methane is emitted to the atmosphere through rice plant, air bubbles, and molecular diffusion. Therefore, the methane emission rate from the rice field depends not only on the methane production rate in the soil, but also on the transport efficiency of the rice plant, air bubble formation that in turn depends on the production rate, and molecular diffusion.Field measurements show that methane emission rates from a particular rice field have very large diurnal, seasonal and interannual variations, which are related to soil characteristics, water regime, farming procedure, local climate, and rice growing activities. The relationship between the methane emission rate and the above mentioned factors is very complicated. The emission rate  相似文献   

10.
稻田甲烷排放的初级模式   总被引：11，自引：1，他引：11       下载免费PDF全文
丁爱菊  王明星 《大气科学》1995,19(6):733-740
本文建立了一个区域尺度稻田生态系统CH4排放的初步模式，该模式能从理论上反映稻田CH4产生、传输与排放的机理，并提供了一种估计不同区域气候和土壤条件下稻田生态系统CH4排放总量的有效方法。模式主要包括三个部分:水稻的生长、土壤有机物的分解和CH4的产生、传输及排放过程。模式分别模拟了早稻和晚稻CH4的排放，模拟结果与实测比较接近，CH4的季平均排放量，模拟值与实测值的偏差在10% 左右。模式的敏感性实验表明，温度是稻田CH4排放规律的主要控制因子。  相似文献   

11.
甲烷作为油气生产中的主要气态污染物和增温潜势较强的一类温室气体,其逃逸排放检测与核算是中国油气行业温室气体控制与减排过程中的首要问题。通过比较国内外油气行业逃逸甲烷排放核算方法,以及总结当前国内外油气田现场开展的甲烷排放检测研究,对油气行业企业级温室气体清单编制提出了建议。在甲烷逃逸排放核算方面,由于生产过程、工艺等出现的变化,建议加快建立符合我国油气生产实际情况的排放因子,纳入放空气燃烧的周期变化、绿色完井措施使用、陆上/海上油气生产等内容,鼓励油气生产企业通过设备组件统计、现场实测等方式进行排放因子更新。针对逃逸甲烷现场检测数据不足,影响核算结果对比的现状,在开展油气生产过程现场检测时,建议自下而上与自上而下检测方法相结合,保证检测结果的可验证性、可重复性,并谨慎看待针对部分油气生产区块的检测结果进行大尺度区域甲烷逃逸排放量的推算结果。  相似文献   

12.
Results of more than 800 new measurements of methane (CH4) concentrations in the Southern Hemisphere troposphere (34–41° S, 130–150° E) are reported. These were obtained between September 1980 and March 1983 from the surface at Cape Grim, Tasmania, through the middle (3.5–5.5 km) to the upper troposphere (7–10 km). The concentration of CH4 increased throughout the entire troposphere over the measurement period, adding further support to the view that CH4 concentrations are currently increasing on a global scale. For data averaged vertically through the troposphere the rate of increase found was 20 ppbv/yr or 1.3%/yr at December 1981. In the surface CH4 data a seasonal cycle with a peak to peak amplitude of approximately 28 ppbv is seen, with the minimum concentration occurring in March and the maximum in September–October. A cycle with the same phase as that seen at the surface, but with a significantly decreased amplitude, is apparent in the mid troposphere but no cycle is detected in the upper tropospheric data. The phase and amplitude of the cycle are qualitatively in agreement with the concept that the major sink for methane is oxidation by hydroxyl radicals. Also presented is evidence of a positive vertical gradient in methane, with a suggestion that the magnitude of this gradient has changed over the period of measurements.  相似文献   

13.
Ｍｏｄｅｌ　ｆｏｒ　Ｍｅｔｈａｎｅ　Ｅｍｉｓｓｉｏｎ　ｆｒｏｍ　Ｒｉｃｅ　Ｆｉｅｌｄｓ　ａｎｄ　Ｉｔｓ　Ａｐｐｌｉｃａｔｉｏｎ　ｉｎ　Ｓｏｕｔｈｅｒｎ　ＣｈｉｎａＤｉｎｇＡｉｊｕａｎｄＷａｎｇＭｉｎｇｘｉｎｇ（ＩｎｓｔｉｔｕｔｅｏｆＡｔｍｏｓｐｈｅｒ...  相似文献   

14.
The methane emission flux from rice paddies was simultaneously measured with automatic and manual methods in the suburban of Suzhou. Both methods were based on the static chamber/ GC-FID techniques. Detail analysis of the experimental results indicates: a) The data of methane emission measured with the automatic method is reliable. b) About 11 or 19 o’clock of local time is recommended as the optimum sampling time for the manual spot measurement of methane emission from rice paddies. The methane emission fluxes measured by manual sampling at local time other than the optimum time have to be corrected. The correction coefficient may be determined by automatic and continuous measurement. c) In order to get a more accurate result, an empirical correction factor, such as 18%, is recommended to correct the seasonally total amount of measured methane emission by enlarging the au-tomatically measured data or reducing the manually measured ones.  相似文献   

15.
A high resolution tunable diode laser absorption spectrometer (TDLAS) was used to measure the broadening effect of water vapor and other gases (dry air, nitrogen, oxygen, hydrogen and helium) on three methane lines in the v4 fundamental. The effects on methane eddy correlation flux measurements amount to a few percent for the least broadened line for expected H2O fluxes, to 10% for the most broadened line for higher H2O and lower CH4 fluxes likely to be encountered. The broadening coefficients of methane measured for air, N2, O2, and He are in good agreement with recently published values.  相似文献   

16.
Very few studies have conducted long-term observations of methane (CH4) flux over forest canopies. In this study, we continuously measured CH4 fluxes over an evergreen coniferous (Japanese cypress) forest canopy throughout 1?year, using a micrometeorological relaxed eddy accumulation (REA) system with tuneable diode laser spectroscopy (TDLS) detection. The Japanese cypress forest, which is a common forest type in warm-temperate Asian monsoon regions with a wet summer, switched seasonally between a sink and source of CH4 probably because of competition by methanogens and methanotrophs, which are both influenced by soil conditions (e.g., soil temperature and soil moisture). At hourly to daily timescales, the CH4 fluxes were sensitive to rainfall, probably because CH4 emission increased and/or absorption decreased during and after rainfall. The observed canopy-scale fluxes showed complex behaviours beyond those expected from previous plot-scale measurements and the CH4 fluxes changed from sink to source and vice versa.  相似文献   

17.
利用自行研制的一台用于探测大气成分的太阳红外光谱仪 ,在地面连续自动地记录了晴天的太阳红外光谱。用逐线积分法计算了整层大气的吸收 ,发现在 3.42 8μm波段主要是大气甲烷的吸收 ,从记录的该波段的太阳红外光谱中反演出整层大气中甲烷的总含量 ,经过近一年半的观测 ,得到了合肥地区大气甲烷垂直柱含量的季节变化规律。发现其变化规律与北半球背景对流层空气采样分析法测量的甲烷季节变化规律基本相同。文中详细介绍了测量仪器、测量原理和部分测量结果 ,并对结果进行了简单的讨论。  相似文献   

18.
New data on the diurnal variability of methane emission in summer (2013-2014) from West Siberia peatland ecosystems are presented. It is demonstrated that diurnal variations in methane emission differ much depending on a peatland ecosystem under study. Diurnal variations in methane emission in the fens and hollows of the ridge-hollow complex (RHC) are revealed as well as their reproducibility in 2013-2014. The maximum emission is registered in the daytime, and the minimum is observed at night. There is no diurnal variation in methane emission in ryams (pine bogs) and ridges of RHC. It is revealed that in the upper layer of peat (at the depth up to 10 cm for hollows and at the depth of 2 and 5 cm for fens) the contribution of temperature variability to methane emission variations in fens and hollows is 15-20%. The multiple linear regression with peat temperature at several depths allows explaining 44-54% of the variability of methane flux from peatlands. No significant correlation between methane fluxes and the temperature of peat and air was identified in the diurnal cycle in ryams and ridges.  相似文献   

19.
农田生态系统温室气体排放研究进展   总被引：39，自引：0，他引：39  
自1985年起,中国科学院大气物理研究所利用自行设计制造的自动观测仪器系统,历时十六年先后对我国四大类主要水稻产区的甲烷排放规律及其与土壤、气象条件和农业管理措施的关系进行了系统野外观测实验,并对稻田甲烷产生、转化和输送机理进行了理论研究,探讨了控制稻田甲烷排放的实用措施,建立了估算和预测稻田甲烷排放的数值模型.在甲烷排放的时空变化规律和转化率研究方面有一系列新的发现,在稻田甲烷产生率、排放率及其与环境条件的关系方面取得一系列新的成果,以充分证据改变了国际上关于全球和中国稻田甲烷排放总量的估算.在对稻田甲  相似文献   

20.
采用静态箱-气相色谱法在江汉平原开展早稻、晚稻、中稻、虾稻和再生稻5种稻作类型温室气体排放监测试验,研究不同稻作模式下稻田CH4和N2O排放特征、总增温潜势及温室气体排放强度,为准确评估稻田生态系统温室气体排放提供参考依据。结果表明:CH4排放集中在水稻前期淹水阶段,排放峰值最高为虾稻（85.7 mg·m-2·h-1）,较其他稻作模式高71.7%~191.5%。N2O排放峰值主要出现于中期晒田和施肥阶段,排放峰值最高为再生稻（1100.7 μg·m-2·h-1）,较其他稻作模式高16.8%~654.9%。CH4累积排放量从大到小依次为虾稻、再生稻、早稻、晚稻、中稻;N2O累积排放量从大到小依次为再生稻、早稻、晚稻、中稻、虾稻;总增温潜势从大到小依次为虾稻、再生稻、早稻、晚稻、中稻;温室气体排放强度从大到小依次为虾稻、早稻、再生稻、晚稻、中稻。CH4排放占比为82.9%~99.0%,稻虾田高排放主要原因为持续淹水时间长、秸秆还田和饲料投入,探究该模式CH4减排举措最为关键;中稻由于水旱轮作,稻田温室气体排放最低,可作为低碳减排的主要稻作类型。  相似文献   

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