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1.
Summary A simple method of representing cumulative frequency distributions ofk-day period amounts of precipitation (30k1800), deduced from observations at Hoofddorp during 87 years and from observations at Winterswijk during 73 years, by means of cumulative Poisson distributions, had been developed. Poisson's constant appeared to depend linearly onk only, while the Poisson unitq appeared to be only proportional to the annual variation.In this paper it is shown that the representation of observed cumulative frequency distributions with the aid of Poisson distributions is true for any station in The Netherlands in the interval 30k1800. A map with isopleths of -values fork=360 presents a simple picture, so that for any station an -value fork=360 can be estimated. For the process of representation the meank-day period amount of precipitation is also necessary. This value may be obtained from a map for each of the 12 months, each map covered with isohyetal lines, which give a distribution of the monthly precipitation.
Zusammenfassung Es wurde eine Methode entwickelt, um in einfacher Weise Summenfunktionen vonk-tägigen Niederschlagsmengen (30k1800), welche aus Beobachtungen in Hoofddorp während 87 Jahren und in Winterswijk während 73 Jahren angestellt worden sind, durch kumulative Poissonsche Häufigkeitsverteilungen darzustellen. Dabei ergab sich, daß die Poissonsche Konstante nur linear vonk abhängig ist, während die Poissonsche Einheitq sich als proportional zum Jahresgang erwies.In der vorliegenden Untersuchung wird nun gezeigt, daß die Darstellung der beobachteten kumulativen Häufigkeitsverteilungen mit Hilfe von Poisson-Verteilungen für irgendeine Station in den Niederlanden im Bereich von 30k1800 gültig ist. Eine Karte mit Isoplethen der -Werte fürk=360 ergibt ein einfaches Bild, aus dem für jede beliebige Station ein -Wert fürk=360 abgelesen werden kann. Für eine solche Darstellung muß auch die Niederschlagsmenge derk-tägigen Perioden bekannt sein; diese Werte erhält man aus monatlichen Isohyeten-Karten, die die monatliche Niederschlagsverteilung wiedergeben.
Résumé On avait développé une méthode pour représenter d'une façon simple les distributions des sommes cumulées dek jours (30k1800) des quantités de précipitations déduites des observations faites à Hoofddorp pendant 87 ans et à Winterswijk pendant 73 ans. On avait démontré que la constante de Poisson ne dépend dek que linéairement et que l'unité de Poissonq est proportionnelle à la variation annuelle.De la présente étude ressort que, dans l'intervalle de 30k1800, la représentation des distributions des fréquences cumulées observées au moyen des formules de Poisson est valable pour une station quelconque aux Pays-Bas. Une carte d'isoplèthes de la valeur pourk=360 donne une image suffisamment simple pour que la valeur d'une station quelconque aux Pays-Bas puisse être déterminée sans difficulté. Pour une telle représentation il faut connaître également les moyennes des quantités des périodes dek jours de la précipitation. Ces valeurs peuvent se déduire de cartes mensuelles des isohyètes moyennes.

With 1 Figure

Dedicated to Dr.Anders K. Ångström on the occasion of his 70th birthday.  相似文献   

2.
We have postulated a simple model for the spectral tensor ij (k) of an anisotropic, but homogeneous turbulent velocity field. It is a simple generalization of the spectral tensor inf ij piso(k) for isotropic turbulence and we show how in the limit of isotropy, ij (k) becomes equal to inf ij piso(k). Whereas inf ij piso(k) is determined entirely by one scalar function of k = ¦k¦, namely the energy spectrum, we need three independent scalar functions of k to specify ij (k). We show how it is possible by means of the three stream-wise velocity component spectra to determine the three scalar functions in ij (k) by solving two uncoupled, ordinary linear differential equations of first and second order. The analytic form of the component spectra each has a set of three parameters: the variance and the integral length scale of the velocity component and a dimensionless parameter, which governs the curvature of the spectrum in the transition domain from the inertial subrange towards lower wave numbers. When the three sets of parameters are the same, the three spectra correspond to isotropic turbulence and they are all interrelated and related to the energy spectrum. We show how it is possible to obtain these spectral forms in the neutral surface layer and in the convective boundary layer from data reported in the literature. The spectral tensor is used to predict the lateral coherences for all three velocity components and these predictions are compared with coherences obtained in two experiments, one using three masts at a horizontally homogeneous site in Denmark and one employing two aircraft flying in formation over eastern Colorado. Comparison shows reasonable agreement although with considerable experimental scatter.The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   

3.
In a recent paper, the author introduced a new viscous boundary layer, called the mesolayer, in turbulent shear flow. Its importance stems from its location between the inner and outer regions which are controlled by the law of the wall and Reynolds number similarity, respectively. This intrusion prevents the classical overlap assumption which appears to be fundamental in the derivation of the classical logarithmic behavior. The mesolayer has a thickness proportional to Taylor's microscale . This, and the analogy between the energy equation for the spectrum function of isotropic turbulence and the momentum equation for shear flow, suggest the existence of a similar region in wavenumber space with wavenumber k ~ -1. This mesoregion separates the inner region k ~ k s(where k s-1 and is the Kolmogorov length) and the outer region k k e(where k e -1 and l is the energy-containing eddy size) and again invalidates the overlap assumption which appears to be fundamental in the derivation of the classical k -5/3-behavior of the inertial subrange.Incorporation of the mesoregion into the argument leads to a new theory with k -5/3-behavior in two regions (-1 k k s) and (k e k -1) although with two different coefficients of proportionality (Kolmogorov constants). This leads to a wandering of the spectrum curve about the classical k -5/3 line similar to a wandering in turbulent shear flow about the logarithmic curve. This is clearly indicated by the data for the variation of the Kolmogorov constant.Other data support the new theory. In particular, the location of the point k mwhere the curve of the nonlinear energy-transfer function goes through zero shows agreement with the theory, i.e., k m-1.  相似文献   

4.
The inertial dissipation technique has been successfully employed for many years to measure the wind stress, especially over the open ocean. This method is based on Kolmogorov's theoretical prediction of universality in the inertial wavenumber range. The theory was developed under the assumption of locally isotropic turbulence, and the dissipation technique has been criticized as lacking justification in a boundary-layer shear flow. In this paper, Kolmogorov's theory is explicitly applied to the anisotropic conditions prevailing in the atmosphere. It is shown that the inertial dissipation method relies on the homogeneity and isotropy of the spectrum ii(k) for k in the inertial range. This is a weaker condition than Kolmogorov's assumption of isotropy of the correlation function Bij(r). In high-Reynolds-number shear flows, isotropy of ii(k) is realized to a good approximation, whereas isotropy of Bij(r) is not. Some consequences for the experimental implementation are discussed; in particular, sampling times (block lengths) not exceeding the order of the eddy life time are recommended in the calculation of spectra.  相似文献   

5.
A comprehensive model for the prediction of concentration fluctuations in plumes dispersing in the complex and highly disturbed wind flows in an urban environment is formulated. The mean flow and turbulence fields in the urban area are obtained using a Reynolds-averaged Navier-Stokes (RANS) flow model, while the standard k-ϵ turbulence model (k is the turbulence kinetic energy and ϵ is the viscous dissipation rate) is used to close the model. The RANS model provides a specification of the velocity statistics of the highly disturbed wind flow in the urban area, required for the solution of the transport equations for the mean concentration and concentration variance (both of which are formulated in the Eulerian framework). A physically-based formulation for the scalar dissipation time scale t d , required for the closure of the transport equation for , is presented. This formulation relates t d to an inner time scale corresponding to “internal” concentration fluctuation associated with relative dispersion, rather than an outer time scale associated with the entire portion of the fluctuation spectrum. The two lowest-order moments of concentration ( and ) are used to determine the parameters of a pre-chosen functional form for the concentration probability density function (clipped-gamma distribution). Results of detailed comparisons between a water-channel experiment of flow and dispersion in an idealized obstacle array and the model predictions for mean flow, turbulence kinetic energy, mean concentration, concentration variance, and concentration probability density function are presented.  相似文献   

6.
The turbulent flow inside dense canopies is characterized by wake production and short-circuiting of the energy cascade. How these processes affect passive scalar concentration variability in general and their spectral properties in particular remains a vexing problem. Progress on this problem is frustrated by the shortage of high resolution spatial concentration measurements, and by the lack of simplified analytical models that connect spectral modulations in the turbulent kinetic energy (TKE) cascade to scalar spectra. Here, we report the first planar two-dimensional scalar concentration spectra (ϕ cc ) inside tall canopies derived from flow visualization experiments. These experiments were conducted within the deeper layers of a model canopy composed of densely arrayed cylinders welded to the bottom of a large recirculating water channel. We found that in the spectral region experiencing wake production, the ϕ cc exhibits directional scaling power laws. In the longitudinal direction (x), or the direction experiencing the largest drag force, the ϕ cc (k x ) was steeper than and followed an approximate at wavenumbers larger than the injection scale of wake energy, where k x is the longitudinal wavenumber. In the lateral direction (y), the spectra scaled as up to the injection scale, and then decayed at an approximate power law. This departure from the classical inertial subrange scaling (i.e., k −5/3) was reproduced using a newly proposed analytical solution to a simplified scalar spectral budget equation. Near the velocity viscous dissipation range, the scalar spectra appear to approach an approximate k −3, a tantalizing result consistent with dimensional analysis used in the inertial-diffusive range. Implications to subgrid modelling for large-eddy simulations (LES) inside canopies are briefly discussed.  相似文献   

7.
We present a new model of the structure of turbulence in the unstable atmospheric surface layer, and of the structural transition between this and the outer layer. The archetypal element of wall-bounded shear turbulence is the Theodorsen ejection amplifier (TEA) structure, in which an initial ejection of air from near the ground into an ideal laminar and logarithmic flow induces vortical motion about a hairpin-shaped core, which then creates a second ejection that is similar to, but larger than, the first. A series of TEA structures form a TEA cascade. In real turbulent flows TEA structures occur in distorted forms as TEA-like (TEAL) structures. Distortion terminates many TEAL cascades and only the best-formed TEAL structures initiate new cycles. In an extended log layer the resulting shear turbulence is a complex, self-organizing, dissipative system exhibiting self-similar behaviour under inner scaling. Spectral results show that this structure is insensitive to instability. This is contrary to the fundamental hypothesis of Monin--Obukhov similarity theory. All TEAL cascades terminate at the top of the surface layer where they encounter, and are severely distorted by, powerful eddies of similar size from the outer layer. These eddies are products of the breakdown of the large eddies produced by buoyancy in the outer layer. When the outer layer is much deeper than the surface layer the interacting eddies are from the inertial subrange of the outer Richardson cascade. The scale height of the surface layer, z s, is then found by matching the powers delivered to the creation of emerging TEAL structures to the power passing down the Richardson cascade in the outer layer. It is z s = u * 3 /ks, where u * is friction velocity, k is the von Kármán constant and s is the rate of dissipation of turbulence kinetic energy in the outer layer immediately above the surface layer. This height is comparable to the Obukhov length in the fully convective boundary layer. Aircraft and tower observations confirm a strong qualitative change in the structure of the turbulence at about that height. The tallest eddies within the surface layer have height z s, so z s is a new basis parameter for similarity models of the surface layer.  相似文献   

8.
The spatial variability of turbulent flow statistics in the roughness sublayer (RSL) of a uniform even-aged 14 m (= h) tall loblolly pine forest was investigated experimentally. Using seven existing walkup towers at this stand, high frequency velocity, temperature, water vapour and carbon dioxide concentrations were measured at 15.5 m above the ground surface from October 6 to 10 in 1997. These seven towers were separated by at least 100m from each other. The objective of this study was to examine whether single tower turbulence statistics measurements represent the flow properties of RSL turbulence above a uniform even-aged managed loblolly pine forest as a best-case scenario for natural forested ecosystems. From the intensive space-time series measurements, it was demonstrated that standard deviations of longitudinal and vertical velocities (u, w) and temperature (T) are more planar homogeneous than their vertical flux of momentum (u* 2) and sensible heat (H) counterparts. Also, the measured H is more horizontally homogeneous when compared to fluxes of other scalar entities such as CO2 and water vapour. While the spatial variability in fluxes was significant (>15 %), this unique data set confirmed that single tower measurements represent the canonical structure of single-point RSL turbulence statistics, especially flux-variance relationships. Implications to extending the moving-equilibrium hypothesis for RSL flows are discussed. The spatial variability in all RSL flow variables was not constant in time and varied strongly with spatially averaged friction velocity u*, especially when u* was small. It is shown that flow properties derived from two-point temporal statistics such as correlation functions are more sensitive to local variability in leaf area density when compared to single point flow statistics. Specifically, that the local relationship between the reciprocal of the vertical velocity integral time scale (Iw) and the arrival frequency of organized structures (/h) predicted from a mixing-layer theory exhibited dependence on the local leaf area index. The broader implications of these findings to the measurement and modelling of RSL flows are also discussed.  相似文献   

9.
Summary The integral aerosol optical depths (k ) at the hour of 08:20 Local Standard Time (LST), are compared with those calculated previously at 11:20 and 14:20 LST, for clear days during summer in Athens over the period 1962–1988. The mean values at 08:20 LST were consistently lower than the values at 11:20 and 14:20 LST. The influence of the vertical wind profile on the values ofk was also investigated. A comparison was made of the wind profiles at 02:00 and 14:00 LST, for days in which the 11:20 and 14:20 LST values ofk were 0.200 andk 0.350, respectively. The corresponding bulk wind shear s was also found for the period 1980–1988. The most significant results occurred with the first category of days. The resultant wind velocities from the surface to the 900 hPa level, in each hour were higher by 2–4 m·s–1 with respect to the corresponding values for the second category. At 02:00 LST the bulk wind shear showed a considerable difference (1.8) between the two categories of days in the surface to 700 hPa layer at 02:00 LST. Finally, the associated weather conditions that appear to initiate a period of low values ofk (k 0.200) at 11:20 and 14:20 LST were examined for the period 1980–1988. Fifteen such cases were identified and it was found that they all occurred after the passage of weak cold fronts.With 6 Figures  相似文献   

10.
A Random Displacement Model (RDM) and a Langevin Equation Model (LEM) are used to simulate point releases in a complex flow around a building. The flow field is generated by a three-dimensional finite element model that uses the standardk- model to parameterize the turbulence. The RDM- and LEM-calculated concentration fields are compared, with particular emphasis on the structure in regions with high turbulence and/or recirculation. RDM and LEM results are similar qualitatively, but RDM tends to predict lower concentration levels. In part this is due to the higher early-time diffusion. However, the expected convergence at later times is prevented by the interaction of the diffusion with the strongly inhomogeneous mean flow.Notation a i coefficient in the Langevin equation - b ij coefficient in the Langevin equation - C 0 the universal constant associated with the Lagrangian structure function - H building height (22.5 m) - K eddy viscosity - K k eddy viscosity used in the definition of the off-diagonal Reynolds stresses - k turbulent kinetic energy - LEM Langevin Equation Model - p 1 local unit vector in thexy-plane, orthogonal tos - p 2 local unit vector, orthogonal to boths andp 1 - RDM Random Displacement Model - s local unit vector in the streamline direction - T local decorrelation time (Lagrangian time scale) - U magnitude of the local Eulerian mean wind velocity - u s total velocity in the streamline direction - u 1 velocity component in thexy-plane, orthogonal to the streamline direction - u 2 velocity component orthogonal to bothu s andu 1 - i mean Eulerian wind velocity - W i stochastic vector-valued Wiener process - x unit vector inx-direction - y unit vector iny-direction - z unit vector inz-direction - angle between thexy-plane and the mean wind streamline - angle between the projection in thexy-plane of the streamline and thex-axis - ij the Kronecker delta function - rate of turbulence dissipation - i/ga the part ofa i that contains mean wind and turbulence gradients - ij inverse of a Reynolds stress tensor component - ij shorthand for a quantity that defines a part of i/ga - i shorthand for a quantity that defines a part of i/ga - ij Reynolds stress tensor component  相似文献   

11.
The I-atom sensitised decomposition of ozone in air at 1 atm pressure and ambient temperature has been investigated. Iodine atoms were produced by photolysis of I2 using visible light or of CH3I using ultraviolet light. In both cases, the quantum yield for O3 decomposition was 1.25 (±0.11) per I atom. An important role is proposed for the self-reaction of IO radicals leading to higher oxides of iodine, IO+IO(+M)I2O2(+M)higher oxides, which predominated over the bimolecular reaction leading to regeneration of I atoms, IO+IO2I+O2, with k 2a/k 2b4. Simple computer modelling calculations indicate that reaction (2a) may be important in determining the fate of photolabile iodine species in the atmosphere. The consequences for the behaviour of radioiodine releases are also discussed.  相似文献   

12.
During spring and autumn, many lakes in temperate latitudes experience intensive convective mixing in the vertical, which leads to almost isothermal conditions with depth. Thus the regime of turbulence appears to be similar with that characteristic of convective boundary layers in the atmosphere. In the present paper a simple analytical approach, based on boundary-layer theory, is applied to convective conditions in lakes. The aims of the paper are firstly to analyze in detail the temperature distribution during these periods, and secondly to investigate the current system, created by the horizontal temperature gradient and wind action. For these purposes, simple analytical solutions for the current velocities are derived under the assumption of depth-constant temperatures. The density-induced current velocities are shown to be small, in the order of a few mm/sec. The analytical model of wind-driven currents is compared with field data. The solution is in good qualitative agreement with observed current velocities under the condition that the wind field is steady for a relatively long time and that residual effects from former wind events are negligible.The effect of the current system on an approximately depth-constant temperature distribution is then checked by using the obtained current velocity fields in the heat transfer equation and deriving an analytical solution for the corrected temperature field. These temperature corrections are shown to be small, which indicates that it is reasonable to describe the temperature distribution with vertical isotherms.Notation T temperature - t time - x, y, z cartesian coordinates - molecular viscosity - h , v horizontal and vertical turbulent viscosity - K h ,K v horizontal and vertical turbulent conductivity - Q heat flux through the water surface - D depth - u, v, w average current velocity components inx, y andz directions - f Coriolis parameter - p pressure - density - g gravity acceleration - a constant in the freshwater state equation - h s deviation from the average water surface elevation - L *,H * length and depth scale - U *,W * horizontal and vertical velocity scale - T temperature difference scale - bottom slope - u * friction velocity at the water surface - von Karman constant - L Monin-Obukhov length scale - buoyancy parameter - l turbulence length scale - C 1,C 2,C 3 dimensionless constants in the expressions for the vertical turbulent viscosity - , dimensionless vertical coordinate and dimensionless local depth - angle between surface stress direction andx-axis - T bx ,T by bottom stress components - c bottom drag coefficient  相似文献   

13.
Summary Interannual modes are described in terms of three-month running mean anomaly winds (u,v), outgoing longwave radiation (OLR), and sea surface temperature (T * ). Normal atmospheric monsoon circulations are defined by long-term average winds (u n,v n) computed every month from January to December. Daily winds are grouped into three frequency bands, i.e., 30–60 day filtered winds (u L,v L); 7–20 day filtered winds (u M,v M); and 2–6 day filtered winds (u S,v S). Three-month running mean anomaly kinetic energy (signified asK L , K M , andK S , respectively) is then introduced as a measure of interannual variation of equatorial disturbance activity. Interestingly, all of theseK L , K M , andK S perturbations propagate slowly eastward with same phase speed (0.3 ms–1) as ENSO modes. Associated with this eastward propagation is a positive (negative) correlation between interannual disturbance activity (K L , K M , K S ) and interannualu (OLR) modes. Namely, (K L , K M , K S ) becomes more pronounced than usual nearly simultaneously with the arrival of westerlyu and negativeOLR (above normal convection) perturbutions. In these disturbed areas with (K L , K M , K S >0), upper ocean mixing tends to increase, resulting in decreased sea surface temperature, i.e.T * 0. Thus, groups (not individual) of equatorial disturbances appear to play an important role in determiningT * variations on interannual time scales. HighestT * occurs about 3 months prior to the lowestOLR (convection) due primarily to radiational effects. This favors the eastward propagation of ENSO modes. The interannualT * variations are also controlled by the prevailing monsoonal zonal windsu n, as well as the zonal advection of sea surface temperature on interannual time scales. Over the central Pacific, all of the above mentioned physical processes contribute to the intensification of eastward propagating ENSO modes. Over the Indian Ocean, on the other hand, some of the physical processes become insignificant, or even compensated for by other processes. This results in less pronounced ENSO modes over the Indian Ocean.With 10 FiguresContribution No. 89-6, Department of Meteorology, University of Hawaii, Honolulu, Hawaii.  相似文献   

14.
Results of field measurements of the swell-induced undulation of the wind speed taken from a Black Sea platform are presented. The wind speed and its fluctuations were measured at several heights between 1.3 and 21 m above the mean sea level under various wind and swell conditions. Parameters of the swell-induced undulations were derived from cross spectra of the wind-speed fluctuations and the sea-surface displacement. As found, the phase and the amplitude of the wind speed undulation in the layer from k p z = 0.1 to k p z = 3 (k p is the swell wavenumber) are in good agreement with the theory of inviscid shear flow over a wavy surface. The main feature of the vertical profile of the swell-induced undulation is the exponential attenuation of its amplitude with height typical for the potential flow over the fast running waves. At the lowest levels the potential undulations are significantly distorted by the wind-speed variations caused by the vertical displacements of the shear airflow relative to a fixed sensor. No direct impact of swell on the mean properties of the turbulent boundary layer at k p z > 0.1 is revealed. In particular, the mean wind-speed profile and spectra of the horizontal velocity in the inertial subrange obey Monin-Obukhov similarity theory.  相似文献   

15.
A numerical model of convective heat transfer due to isolated thermals in the atmospheric boundary layer is used to describe the temperature profile transformation in undisturbed conditions as a result of intensive dry free convection. Based on some assumptions, the heat transfer Equation (2) is transformed to the form (14) in which the coefficients and the function F are expressed by (d/dz)(ln ) and by parameters of thermals. Equation (14) has been solved numerically with the help of Equation (15) obtained from the statics equation because of Equation (8). The size distribution function f(z, r, t) of the thermals is discrete (Table I), according to Vulf'son (1961). On Figures 1 and 2 are plotted successive temperature profiles for a ground inversion, transformed due to free convection and turbulence (Figures 1a and 2a), and due to turbulence only (Figures 1b and 2b). The profiles are computed from Equation 14 (Figures 1a and 2a) and Equation 16 (Figures 1b and 2b) for k z= 1 m2 s–1 (Figure 1) and k z= 10 m2 s–1 (Figure 2). On Figure 3 the real temperature profiles in Sofia for June 22nd 1976 are compared with the profiles computed using the real initial profile for 4.30 h local time. Good qualitative agreement can be seen.  相似文献   

16.
Wind velocities within a plant canopy are much more strongly skewed than those of the air flow above. We have examined the governing Eulerian equations for the velocity products u i, u j uk using data from a wind tunnel study with an artificial canopy consisting of an array of 5 cm lengths of monofilament fishing line, and from measurements in corn (Zea mays L).Simple parameterizations for pressure-velocity correlations, and for the quadruple velocity products allowed reasonably accurate calculations of the third moments using measured profiles of the mean velocity, variance and covariance fields. Comparisons of individual terms in the rate equations for ovu i, u j u krevealed that diffusion (from above) and mean shear were most important in creating large skewness in the canopy. A drag term also contributed but was of lesser importance. These terms were balanced by return-to-isotropy and a turbulence interaction term. A quasi-Gaussian approximation considerably underestimated the magnitude of the fourth moments within the canopy.  相似文献   

17.
The activation of Br- and Cl- to atomic Br and Cl in sea-spray aerosol was investigated in smog-chamber experiments. In the presence of O3, hydrocarbons and NaCl aerosol alone no activation was observed. By adding Br- to the aerosol, the chain reaction: Br + O3 BrO, BrO + HO2 HOBr, HOBr HOBr(aq), HOBr(aq) + H+ + Br- Br2 (6), HOBr(aq) + H+ + Cl- BrCl (7) was verified. The step from reaction (6) to (7) is accompanied by a decrease of the Br-/Cl- ratio from 1/600 to less than 1/2000. In the absence of sulphate, the chain is initiated by the reaction of OH(aq) with Br-. The pH value decreases to less than 2 during the first minutes of the experiment and later on to almost 1 (in the absence of NOx or SO2). This is caused by the formation of oxalic acid from alkanes and toluene. In stopped flow experiments, the reduction of Br2 by oxalic acid was observed to occur through a two-step mechanism: HC2O4 - + Br2 Br- + BrC2O4H (k22, k-22), BrC2O4H Br- + H+ + 2 CO2 (23) with the following rate constants and ratios of rate constants, k ± 2: k22k-23 / k-22 = (2.9 ± 0.3) · 10-4 s-1, k-22 / k-23 = 7000 ± 3000 13000 M-1, k22 = 2 ±-1 4 M-1 s-1, and k-23 > 0.1 s-1, k-22 > 600 M-1 s-1. Oxalic acid may be responsible for the inhibition of the chain reaction observed at the end of the experiments.  相似文献   

18.
Zusammenfassung Vergleichsmessungen zwischen Lithiumchlorid-Feuchtefühlern und Assmann-Psychrometern im Gelände zeigen, daß die im vorliegenden Falle verwendeten Lithiumchlorid-Feuchtefühler infolge Wärmeabgabe an die Umgebung zu niedrige Meßwerte gegenüber den Assmann-Psychrometern ergeben. Unter besonderen Bedingungen kann durch Nebeltröpfchen, die am Lithiumchlorid-Feuchtefühler abgesetzt werden, der Taupunkt über den im bodennahen Bereich der Atmosphäre möglichen Wert [°C]t[°C] angehoben werden. Der Einfluß von auf dem Schutzgehäuse der Lithiumchlorid-Feuchtefühler verdunstendem Tauniederschlag auf die Taupunktanzeige wird an einem Beispiel gezeigt.
Summary A comparison of data derived from field-measurements with lithiumchlorine dew cells and with Assmann-psychrometers proves, that the tested LiCl dew cells furnish lower dew point temperatures than the Assmann-psychrometers due to loss of heat to the environment. Under special conditions, fog particles can be precipitated at the LiCl dew cells, causing the dew point in the air near the ground to exceed the limiting value [°C]t[°C]. The influence of dew precipitation on the records of dew point is demonstrated by an example.
Résumé On a comparé des mesures de l'humidité effectuées sur le terrain, mesures faites avec un psychromètre Assmann et un hygromètre au chlorure de lithium. On a pu constater que le second appareil indiquait des valeurs inférieures à celles du premier et cela par suite d'une déperdition de chaleur vers le milieu ambiant. Dans certaines conditions particulières, les gouttelettes de brouillard qui se déposent sur le capteur d'humidité au chlorure de lithium peuvent relever le point de rosée pres du sol au-dessus de la valeur [°C]t[°C]. Par un exemple, on démontre l'effet perturbateur sur l'indication du point de rosée de la rosée s'évaporant sur le bâti protecteur du capteur.

Mit 7 Abbildungen

Herrn Prof. Dr.Walter Dammann zum 60. Geburtstag gewidmet.  相似文献   

19.
We address some of the methodological challenges associated with the measurement of turbulence and use of scintillometers in the urban roughness sublayer (RSL). Two small-aperture scintillometers were located near the roof interface in a densely urbanized part of Basel, Switzerland, as part of the Basel Urban Boundary-Layer Experiment (BUBBLE) in the summer of 2002. Eddy correlation instruments were co-located near the mid-point of each scintillometer path for data verification purposes. The study presents the first values of the inner length scale of turbulence (l 0) and the refractive index structure parameter of air for a city and demonstrates the influence of mechanical driven turbulence on dissipation. Comparison of dissipation values determined from the two approaches show large scatter that is possibly due to the spatial inhomogeneity of the turbulence statistics within the RSL. Velocity and temperature spectra display a −2/3 slope in the inertial subrange, although the spectral ratio is less than the theoretical prediction of 4/3 expected for isotropy. Conventional Monin–Obukhov equations used to calculate fluxes from the scintillometer were replaced with urban forms of the equations. The results suggest that the scintillometer may be an appropriate tool for the measurement of sensible heat flux (Q H ) above the rooftops given a suitable determination of the effective measurement height.  相似文献   

20.
Further laboratory studies of emission by O(1 S) and by O2 A 3 u + ,A3 u andc 1 u – in the oxygen afterglow lead to the conclusion that Barth's mechanism for the excitation of the auroral green line O 2 * +O(3P=O2+O(1S)–(1) is correct and that levelsv=6 and 7 of O2 A 3 u + are Barth precursors. The value ofk 1=7×10–11 cm3 s–1 deduced for these levels is shown to be in fair agreement with atmospheric measurements.  相似文献   

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