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1.
Particle number size distribution(PNSD) between 10 nm and 20 μm were measured in the Pearl River Delta(PRD) region in winter 2011.The average particle number concentration of the nucleation mode(10-20 nm),Aitken mode(20-100 nm),accumulation mode(100 nm-1μm) and coarse mode(1-20 μm) particles were 1 552,7 470,4 012,and 19 cm-3,respectively.The volume concentration of accumulation mode particles with peak at 300 nm accounted for over 70% of the total volume concentration.Diurnal variations and dependencies on meteorological parameters of PNSD were investigated.The diurnal variation of nucleation mode particles was mainly influenced by new particle formation events,while the diurnal variation of Aitken mode particles correlated to the traffic emission and the growth process of nucleation mode particles.When the PRD region was controlled by a cold high pressure,conditions of low relative humidity,high wind speed and strong radiation are favorable for the occurrence of new particle formation(NPF) events.The frequency of occurrence of NPF events was 21.3% during the whole measurement period.Parameters describing NPF events,including growth rate(GR) and source rate of condensable vapor(Q),were slightly larger than those in previous literature.This suggests that intense photochemical and biological activities may be the source of condensable vapor for particle growth,even during winter in the PRD. 相似文献
2.
Optical Observations on Propagation Characteristics of Leaders in Cloud-to-Ground Lightning Flashes 
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下载免费PDF全文 LU Weitao ZHANG Yijun LI Jun ZHENG Dong DONG Wansheng CHEN Shaodong WANG Fei 《Acta Meteorologica Sinica》2008,22(1):66-77
Using 2 high-speed cameras, we have recorded 14 negative cloud-to-ground (CG) lightning flashes, half of which are natural and the others are artificially triggered. The two-dimensional (2D) propagation speed of different type leaders and the luminosity of lightning channel are analyzed in detail. Bidirectional leader processes are observed during the initial processes of two altitude triggered negative lightning (ATNL)flashes. The analysis shows: the propagation speed of the upward positive leader (UPL) before the initiation of the downward negative leader (DNL) is at the order of 104-105 m s-1; the UPL can be intensified by the initiation and development of the DNL in the way that the luminosity is enhanced and the speed is sped up; after initiation, the DNL in one ATNL flash propagates downward three times intermittently with interval of about 1 ms, while that in the other ATNL flash propagates downward continuously with a speed at the order of 105 m s-1. In the five classical triggered negative lightning (CTNL) flashes, the propagation speeds of the UPLs vary between 0.35×105 and 7.71×105 m s-1, and the variations of their luminosities and speeds are quite complex during the development processes. Among the four observed natural negative lightning flashes occurred on the land, three have only one return stoke (RS) each and all of their DNLs have many branches with an average speed at the order of 105 m s-1; while the another one has 13 RSs.In the CG flash with 13 RSs, the DNL before the first RS has no obvious branch below 1.4 km above the ground, and its speed ranges from 2.2×105 to 2.3×105 m s-1 between the heights of 0.7 and 1.4 km and exceeds 3.9×106 m s-1 below 0.7 km; preceding the 4th RS, an attempted leader is observed with a speed ranging from 1.1×105 to 1.1×106 m s-1 between 0.8 and 1.5 km. As for the three observed natural negative lightning flashes occurred on the sea, each has only one RS, and each DNL preceding the RS has a few branches, two of which have an average propagation speed at the order of 105 m s-1, and the other of 106m s-1, respectively. All the DNLs contained in the observed natural negative lightning flashes, except the attempted leader, propagate with gradually increasing luminosity and increasing speed in whole. 相似文献
3.
In this study, ideal but realistic numerical experiments are performed to explore the relative effects of changes in land use and emission distribution on air quality in the Pearl River Delta (PRD) region in winter. The experiments are accomplished using the Lagrangian particle transport and dispersion model FLEXPART coupled with the Weather Research and Forecasting model under different scenarios. Experiment results show that the maximum changes in daily mean air pollution concentration (as represented by SO2 concentration) caused by land use change alone reaches up to 2?×?10?6 g m?3, whereas changes in concentrations due to the anthropogenic emission distribution are characterized by a maximum value of 6?×?10?6 g m?3. Such results reflect that, although the impacts of land use change on air quality are non-negligible, the emission distribution exerts a more significant influence on air quality than land use change. This provides clear implications for policy makers to control urban air pollution over the PRD region, especially for the urban planning in spatial arrangements for reasonable emissions. 相似文献
4.
The binary water–sulphuric acid nucleation has long been considered an important path for new particle formation in the atmosphere. The formation rate depends nonlinearly on temperature and vapour concentrations. We aim to find out if atmospheric small scale and mesoscale spatial and temporal variability can increase the nucleation rate significantly. Simultaneous and separate effects of variation in temperature, humidity and sulphuric acid concentration on the mean nucleation rate have been modelled. We have assumed that the distributions of variables are Gaussian and compare the mean of simulated nucleation rates with the nucleation rate in mean conditions without variation. According to our studies the atmospheric variability can increase the mean nucleation rate by orders of magnitude but the significant effect is limited to specific conditions. The effect seems to be more important in the lower troposphere than in the upper troposphere, where temperature and sulphuric acid concentrations are lower. In addition, our model simulations indicate that the atmospheric variability can only explain part of the difference between measured and theoretically required sulphuric acid concentrations in conditions where particle formation has been observed. We have parametrised the effect of atmospheric variability as a simple correction factor for the effect of temperature and humidity variation. 相似文献
5.
《Atmospheric Research》2007,83(3-4):503-513
The binary water–sulphuric acid nucleation has long been considered an important path for new particle formation in the atmosphere. The formation rate depends nonlinearly on temperature and vapour concentrations. We aim to find out if atmospheric small scale and mesoscale spatial and temporal variability can increase the nucleation rate significantly. Simultaneous and separate effects of variation in temperature, humidity and sulphuric acid concentration on the mean nucleation rate have been modelled. We have assumed that the distributions of variables are Gaussian and compare the mean of simulated nucleation rates with the nucleation rate in mean conditions without variation. According to our studies the atmospheric variability can increase the mean nucleation rate by orders of magnitude but the significant effect is limited to specific conditions. The effect seems to be more important in the lower troposphere than in the upper troposphere, where temperature and sulphuric acid concentrations are lower. In addition, our model simulations indicate that the atmospheric variability can only explain part of the difference between measured and theoretically required sulphuric acid concentrations in conditions where particle formation has been observed. We have parametrised the effect of atmospheric variability as a simple correction factor for the effect of temperature and humidity variation. 相似文献
6.
华北秋季一次低槽冷锋积层混合云宏微物理特征与催化响应分析 总被引：2，自引：0，他引：2
利用2013年10月13日机载粒子测量系统（PMS）在张家口涞源地区对积层混合云中上部进行的增雨探测数据,分析了云的垂直微物理结构、云区的可播性和作业前后液态云粒子、冰晶及降水粒子的微物理变化。结果表明,此次降水性积层混合云的垂直结构由冷、暖两层云配置,云层发展厚实,冷云区云粒子浓度平均为62 cm-3,液态水含量最大0.05 g/m3;2DC和2DP探测的冰晶及降水粒子平均浓度分别为1.9和2.2 L-1;暖云内云粒子数浓度集中在300 cm-3左右,液态水含量约0.1 g/m3。探测区域云粒子数浓度的水平分布不均匀。利用云内过冷水含量和冰晶浓度等参数判断,该降水性积层混合云的播撒作业层具有强可播性。对比作业前后云中粒子浓度及平均直径发现,云粒子在作业前时段内的平均浓度为31 cm-3,远高于作业后平均浓度（17.6 cm-3）;但平均直径变化不大。作业后冰晶粒子通过贝吉龙过程消耗过冷水长大,浓度由之前的0.86 L-1增至4.27 L-1,平均直径也增至550 μm。冰晶粒子逐渐长大形成降水,降水粒子浓度也相应有所升高,谱明显变宽。 相似文献
7.
The kinetics of the S(IV) oxidation by oxygen in the presence of Mn(II) ions and acetic acid has been studied. Experiments were carried out at 25°C, 3.5?≤?pH?≤?5.0, [S(IV)]≈1?×?10?3 mol/dm3, 1?×?10?6 mol/dm3?≤?[Mn(II)]?≤?1?×?10?5 mol/dm3, 1?×?10?6 mol/dm3?≤?[CH3COOH]?≤?1?×?10?4 mol/dm3. Based on the experimental results, rate constants and orders of the reactions were determined. Depending on the reaction conditions, the observed rate constants for the Mn(II)-catalysed S(IV) oxidation ranged between 3.91?×?10?8 and 8.89?×?10?7 (mol/dm3) s?1, and in the presence of acetic acid they ranged between 2.95?×?10?8 and 7.45?×?10?7 (mol/dm3) s?1. The reaction order in S(IV) was zero for both reactions. The effect of Mn(II) ion and acetic acid concentrations as well as an initial pH of the solution on the S(IV) oxidation rate was discussed. It was found that the rate of the S(IV) oxidation depends on the initial pH of the solution but it is independent of the pH change during the reaction. Acetic acid has a weak inhibiting effect on the Mn(II)-catalysed S(IV) oxidation. Under the experimental conditions the S(IV) oxidation rate decreased no more than twice. 相似文献
8.
Roger Kwok Jimmy C. H. Fung Alexis K. H. Lau Zion S. Wang 《Journal of Atmospheric Chemistry》2012,69(1):1-22
The Tagged Species Source Apportionment (TSSA) algorithm is applied to study contributions to pollutants PM sulfate, SO2 and elemental carbon (EC) in Hong Kong by emitting sectors as well as non-emitting sources within and beyond the Pearl River Delta (PRD) region. We look at three areas of Hong Kong: western new towns, central downtown, and eastern countryside. Pollutant transport from beyond the PRD influenced all three areas during January and October 2004 but the source sectors impacting the three areas were different. Specifically, power plant SO2 from Hong Kong and Shenzhen, and vehicle EC from Shenzhen contribute to 11?~?66?% of SO2 concentration, and 33?~?75?% of EC concentration in the western new towns, respectively. Ships in and around Hong Kong contribute 8?~?56?% to the sulfate concentration in the downtown area, while local moving vehicles take up 28?~?81?% of the EC concentration there. The study also shows that diurnal variation of planetary boundary layer (PBL) causes day-night difference in SO2 by as much as 50?%. In addition, 13?~?38?% of all SO2 emissions have been converted to PM sulfate. 相似文献
9.
北京大气中SO2浓度变化特征 总被引：11，自引：0，他引：11
作为酸雨和细粒子的前体物,SO2对空气质量和人体健康乃至气候与环境的影响十分重要,特别是在不利于扩散的气象条件下,SO2可造成城市短时间严重污染事件。作者以2006年北京325 m气象塔15 m观测平台SO2观测数据为基础,结合同步气象资料分析研究发现：1) SO2浓度冬季高、夏季低;全年日均值为(22.5±22.1)×10-9,最大日均值能达到113×10-9。日变化呈现双峰型,峰值出现在北京时间08:00和22:00;并且季节差异明显,冬季浓度为夏季的4.5倍,采暖期为非采暖期的3.2倍。2) 风向、风速与SO2扩散和输送密切相关,高浓度SO2在东北、东、西方向上出现频率分别为25.8%、13.8%和11.8%;而西北、北方向上的风速越大对SO2清除效果越好。3)利用平均晴空指数划分采暖期阴霾天和晴天,发现阴霾天混合层高度与平均风速仅为(376±204) m和1.1 m·s-1,容易造成SO2累积。4) SO2污染过程呈现周期性的局地累积—清除特征,地形、静风和暖低压是造成北京2006年1月一次重污染事件的成因。 相似文献
10.
海洋是地表环境中最重要的碳库,准确估算CO2在海洋与大气之间的交换对于进一步阐明其变化过程机理具有重要意义。利用南海2011—2020年的海温、风速、海平面气压等多种遥感反演数据,基于海-气分压差算法,构建了海-气CO2通量遥感估算模型,并分析其时空变化特征。结果表明：（1） 遥感估算模型在整个南海海域具有较好的通用性,对比实测区域数据,估算结果的平均绝对误差和均方根误差分别为1.04和1.37 mmol/(m2·d);对于源汇区的识别准确率达到90.63%。（2） 南海总体表现为弱碳源,CO2通量的季节变化呈现出夏秋季高、冬春季低的特征,夏季和冬季分别为全年最高和最低。空间分布特征为南北部差异大。碳汇高值区始终位于北部,且冬季为强碳汇,而碳源高值区夏季出现在中南半岛东南部,秋季则转移到南海东北部。（3） 南海三种典型区（北部陆架陆坡、中部海盆、南部陆坡）的CO2通量随时间推移均呈现降低的趋势,且北部下降速度最快。2011—2020年,南海年均向大气净释放碳1.51×107 t,但其碳释放量呈降低趋势,降低速度为2.03×106 t/a,南海总体的“碳源”强度有所减弱。研究结果可为制定碳排放及碳交易政策提供科学参考。 相似文献
11.
K过程是闪电放电过程中的一种放电事件。该文使用两套VHF宽带干涉仪2010年夏季在广州从化地区获取的3次云闪三维闪电辐射源定位数据,分析其中的K过程时空发展特征与地面电场特征。结果表明:宽带干涉仪观测到的K过程主要由快速发展的负极性放电事件组成,按定位结果的分布可划分为3个阶段:负极性反冲先导发生在云闪起始区域下方,沿正先导一端已有路径向闪电起始区域传播;部分反冲先导能进入之前负先导建立的通道并快速发展;反冲先导将原有通道激活后进一步促进负先导继续发展。同时使用辐射源三维定位数据计算了8次反冲先导的平均发展速度,反冲先导的发展速度为106~107 m·s-1量级,与负地闪中的负极性直窜先导相似,但均小于回击速度。 相似文献
12.
Seasonal variations in total particle concentrations at five remote Southern Hemisphere sites in Samoa, Tasmania and Antarctica are compared. The dominant particle production mechanism is deduced to be photochemical, with concentrations dictated by the availability of radiation in the eight months centred on the winter solstice. There is little variation with latitude in the mean summer concentrations. The middle troposphere is shown to act as an important reservoir of photochemically-produced particles in Tasmania and probably in the Antarctic. It is suggested that primary-particle production is mainly through the oxidation of dimethyl sulphide and that these particles then act as centres of condensation for sulphuric acid formed by the oxidation of sulphur dioxide. 相似文献
13.
In-situ Measurements of Tropospheric Hydroxyl Radicals by Folded Long-Path Laser Absorption During the Field Campaign POPCORN 总被引：1，自引：0，他引：1
Uwe Brandenburger Theo Brauers Hans-Peter Dorn Martin Hausmann Dieter H. Ehhalt 《Journal of Atmospheric Chemistry》1998,31(1-2):181-204
Absolutely calibrated in-situ measurements of tropospheric hydroxyl radicals, formaldehyde, sulfur dioxide, and naphthalene (C10H8) were performed by long-path laser absorption spectroscopy during the field campaign POPCORN. The absorption light path was folded into an open optical multiple reflection cell with a mirror separation of 38.5 m. Using a light path length of 1848 m and an integration time of 200 s, the average 1-detection limits of OH, HCHO, SO2 and C10H8 during POPCORN were 8.7 · 105 cm–3, 8.3 · 109 cm–3, 2.4 · 109 cm–3, 1.5 · 108 cm–3, respectively. In total, 392 identifications of OH in air spectra were made in a rural environment between August 5 and August 23, 1994. We present and discuss OH absorption spectra and diurnal OH concentration profiles of three days which are representative for measurements under different pollution conditions during POPCORN. The observed maximum and median OH radical concentrations are 1.3 · 107 OH/cm3 and 4.0 · 106 OH/cm3, respectively. The measured diurnal variation of the OH concentration shows a good correlation with the primary formation reaction of OH radicals which is the photolysis of ambient ozone. Deviations from this correlation in the morning and evening hours, when the OH concentration is higher than expected from the ozone photolysis, demonstrate the importance of other photochemical HOx production pathways during POPCORN. 相似文献
14.
Frank Arnold Joachim Curtius Stefan Spreng Terry Deshler 《Journal of Atmospheric Chemistry》1998,30(1):3-10
The first direct in situ measurements of the sulfuric acid contained in stratospheric aerosol particles were made using a novel balloon-based Ion Molecule Reaction Mass Spectrometer instrument (IMRMS) equipped with an aerosol vaporizer. The IMRMS method employed offers direct aerosol sulfuric acid measurements with high spatial resolution. The balloon flight took place on 23 October 1995 in middle latitudes (44°N) and reached a maximum altitude of 24 km. Measured molecular number densities of aerosol sulfuric acid decreased with increasing altitude from about 2.9 × 109 cm-3 at 15km altitude to about 2.4 × 108 cm-3 at 21 km. Corresponding mass mixing ratios are 2.5 and 0.6 ppbm, respectively. Calculated sulfuric acid mixing ratios from aerosol volumes inferred from aerosol size distribution measurements on the same balloon agree well with the IMRMS data using standard assumption aerosol composition. 相似文献
15.
Abstract The optical parameters of Arctic haze, such as the scattering and the absorption coefficients and the asymmetry factor, have been estimated using a theoretical haze model. The Aden and Kerker solution for spherical nuclei coated with a spherical shell was employed to account for the observed sulphuric acid coating on Arctic aerosols. Six original aerosol materials are considered; four are natural and two are anthropogenic in origin (sulphuric acid and soot). The relative humidity is varied between 0 and 99% and the effects of anthropogenic substances are examined. Carbonaceous material can increase the absorption coefficient by up to a factor 5 in the visible range, while sulphuric acid significantly increases the growth of particles and affects all of the optical parameters. The haze model is found to be consistent with available measurements of aerosol characteristics and optical parameters. The haze model is then used to convert a vertical profile of the extinction coefficient to a profile of particle concentration. 相似文献
16.
《Atmospheric Research》2005,73(1-2):131-148
The effect of pollution-derived sulphuric acid aerosols on wintertime arctic lower atmospheric ice crystals is investigated. These anthropogenic aerosols differ from natural background aerosols by their number concentration, strong solubility and reduced homogeneous freezing temperature when internally mixed with other compounds. Furthermore, observations suggest that the ice-forming nuclei concentration is reduced by one to four orders of magnitude when the sulphuric acid aerosol concentration is high.Simulations performed using a column model and analysis of observed data for the period of 1991–1994 at Alert (82° 30'N, 62°20'W) are used to assess the changes of the boundary layer cloud characteristics by sulphuric acid aerosols and the potential effect on arctic climate. Results show that aerosol acidification leads to depletion of the ice crystal number concentration and an increase of its mean size. As a result, low-level precipitating ice crystals occur more frequently than ice fog and thick nonprecipitating clouds during high concentration of pollution-derived aerosols. This result is in agreement with observations that indicate an increase by more than 50% of the frequency of precipitating ice crystals when the weight proportion of sulphuric acid is greater than its mean value of 20% of the total aerosol mass. Consequently, the ice crystal size increases and number decreases, and the sedimentation flux of ice crystals and the dehydration rate of the lower troposphere are accelerated in the presence of high sulphuric acid aerosol concentration. As a result, the infrared radiation flux reaching the surface and the greenhouse effect are decreased. This process is referred to as the dehydration–greenhouse feedback. One-dimensional simulation for Alert during the period of 1991 to 1994 shows that a negative cloud radiative forcing of −9 W m−2 may occur locally as a result of the enhanced dehydration rate produced by the aerosol acidity. 相似文献
17.
Many weather radar networks in the world have now provided polarimetric radar data(PRD)that have the potential to improve our understanding of cloud and precipitation microphysics,and numerical weather prediction(NWP).To realize this potential,an accurate and efficient set of polarimetric observation operators are needed to simulate and assimilate the PRD with an NWP model for an accurate analysis of the model state variables.For this purpose,a set of parameterized observation operators are developed to simulate and assimilate polarimetric radar data from NWP model-predicted hydrometeor mixing ratios and number concentrations of rain,snow,hail,and graupel.The polarimetric radar variables are calculated based on the T-matrix calculation of wave scattering and integrations of the scattering weighted by the particle size distribution.The calculated polarimetric variables are then fitted to simple functions of water content and volumeweighted mean diameter of the hydrometeor particle size distribution.The parameterized PRD operators are applied to an ideal case and a real case predicted by the Weather Research and Forecasting(WRF)model to have simulated PRD,which are compared with existing operators and real observations to show their validity and applicability.The new PRD operators use less than one percent of the computing time of the old operators to complete the same simulations,making it efficient in PRD simulation and assimilation usage. 相似文献
18.
采用FNL1°×1°和CPC0.5°×0.5°再分析资料,通过对比分析夏季哈萨克斯坦不同区域的3次强降水过程的环流特征,揭示了诱发强降水的环流结构。结果表明：哈萨克斯坦各区域出现强降水时,西部和东部的强降水中心位于高空急流带入口区右侧,北部位于出口区左侧,辐散抽吸作用利于上升运动发展;强降水的影响系统主要为500 hPa低涡,强降水中心位于低涡槽线前部西南气流带上,中层温度平流对强降水发生有促进作用,西部和北部强降水中心位于低层冷平流大值区,东部则位于东北冷平流南侧的气旋性辐合区;除哈萨克斯坦东部强降水受地形影响地面系统尺度较小外,西部和北部强降水时地面有明显的冷锋,并存在气旋性的辐合切变,冷暖汇合形成的辐合线是强降水的主要中尺度触发系统;哈萨克斯坦强降水的水汽源地主要为地中海、黑海、波斯湾和北冰洋,经长途输送在强降水区形成强的水汽辐合,辐合值＞40×10-6 g?cm-1?s-1。 相似文献
19.
The factors which affect the formation of new sulphuric acid particles in different atmospheric conditions are investigated. An atmospheric chemistry gas phase box model coupled to a three mode integral aerosol dynamics model is used. The simulations show the dependence of the concentration of nucleation mode particles on initial pre-existing particles, the intensity of UV radiation, the emissions of dimethylsulphide (DMS) and the ratio of emissions of hydrocarbons (HC) and NOx present in the atmosphere. Eight different basic cases are simulated in urban, rural and marine conditions. The effects of pre-existing particles as a sink of sulphuric acid are clearly seen. The increased UV radiation is also seen to enhance particle formation via sulphuric acid route significantly. 相似文献