首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 45 毫秒
1.
Continuous measurements of ozone and its precursors including NO, NO2, and CO at an urban site (32°03′N, 118°44′E) in Nanjing, China during the period from January 2000 to February 2003 are presented. The effects of local meteorological conditions and distant transports associated with seasonal changed Asian monsoons on the temporal variations of O3 and its precursors are studied by statistical, backward trajectory, and episode analyses. The diurnal variation in O3 shows high concentrations during daytime and low concentrations during late night and early morning, while the precursors show high concentrations during night and early morning and low concentrations during daytime. The diurnal variations in air pollutants are closely related to those in local meteorological conditions. Both temperature and wind speed have significant positive correlations with O3 and significant negative correlations with the precursors. Relative humidity has a significant negative correlation with O3 and significant positive correlations with the precursors. The seasonal variation in O3 shows low concentrations in late autumn and winter and high concentrations in late spring and early summer, while the precursors show high concentrations in late autumn and winter and low concentrations in summer. Local mobile and stationary sources make a great contribution to the precursors, but distant transports also play a very important role in the seasonal variations of the air pollutants. The distant transport associated with the southeastern maritime monsoon contributes substantially to the O3 because the originally clean maritime air mass is polluted when passing over the highly industrialized and urbanized areas in the Yangtze River Delta. The high frequency of this type of air mass in summer causes the fact that a common seasonal characteristic of surface O3 in East Asia, summer minimum, is not observed at this site. The distant transports associated with the northern continental monsoons that dominate in autumn and winter are related to the high concentrations of the precursors in these two seasons. This study can contribute to a better understanding of the O3 pollution in vast inland of China affected by meteorological conditions and the rapid urbanization and industrialization.  相似文献   

2.
利用2012~2013年北京中央商务区（Central Business District,CBD）加密观测资料,分析CBD区域城市热岛（Urban Heat Island,UHI）强度日变化和空间变化特征及其影响因子。研究发现,CBD区域气温高于周边自动站气温,平均偏高0.64℃;CBD区域城市热岛强度呈现夜间强、白天弱的现象,中午甚至存在“城市冷岛”现象。季节平均UHI日变化表现为:在夜间,秋季最强,冬季次之,春季和夏季较弱;在白天,夏季最强,冬季次之,春季和秋季较弱。相对于晴朗无风天气,雾、雨、大风等天气对城市热岛有抑制作用,并结合小波分析结果发现,秋季城市热岛强度强于冬季是由于冬季雾、雨、大风等天气过程发生比例较高的缘故。CBD区域城市热岛空间变化特征研究发现,花园、学校等绿地有助于缓解城市热岛效应。雾日、雨日和大风日的CBD区域城市热岛强度空间变化标准差比晴朗无风日小。  相似文献   

3.
Formaldehyde (HCHO), acetaldehyde (CH3CHO) and acetone (CH3COCH3) were measured at Wanqingsha (WQS) in south China during November-December 2008–2010. Carbonyl compound pollution characteristics under the influence of the financial crisis (FC) were studied. Atmospheric carbonyl compound concentrations in the 2008 and 2009 sampling periods were affected by the 2008 FC. The industrial downturn plus the high closing down number of the small enterprises with limited emission treatment during the FC played an important role in the reduction of the industry-related CH3CHO and CH3COCH3. In 2010, the recovery of industrial activities occurred, but affected by traffic restriction enforcement in Guangzhou over the Asian Games period, HCHO concentration (daytime 7.59?±?2.59 μg m?3) was lower than expectation. Carbonyl compounds in WQS site were highly influenced by regional pollution transport from different upwind urban cities and industrial districts in the north-northwest to northeast wind sector in winter. Also, the interaction of the winter monsoon with the warm ocean along the coastline as well as day and night boundary layer mixing height variation affected carbonyl compound concentrations in WQS. The daytime mean dry deposition losses of HCHO and CH3CHO were first time model-estimated for 2009 and 2010. For loss of HCHO in the early afternoon, photolysis was the dominant sink, followed by dry deposition and removal by OH radical (?OH), while for CH3CHO, dry deposition was dominant. For the gain of HCHO and CH3CHO, the production rates during early afternoon in 2009 and 2010 were estimated by an indirect approach.  相似文献   

4.
Campaigns were conducted to measure Organic Carbon (OC) and Elemental Carbon (EC) in PM2.5 during winter and summer 2003 in Beijing. Modest differences of PM2.5 and PM10 mean concentrations were observed between the winter and summer campaigns. The mean PM2.5/PM10 ratio in both seasons was around 60%, indicating PM2.5 contributed significantly to PM10. The mean concentrations of OC and EC in PM2.5 were 11.2±7.5 and 6.0±5.0μg m-3 for the winter campaign, and 9.4±2.1 and 4.3±3.0 μg m-3 for the summer campaign, respectively. Diurnal concentrations of OC and EC in PM2.5 were found high at night and low during the daytime in winter, and characterized by an obvious minimum in the summer afternoon. The mean OC/EC ratio was 1.87±0.09 for winter and Z39±0.49 for summer. The higher OC/EC ratio in summer indicates some formation of Secondary Organic Carbon (SOC). The estimated SOC was 2.8 μg m-3 for winter and 4.2μg m-3 for summer.  相似文献   

5.
根据2007—2013年宁波市每日8次地面观测气象资料,运用罗氏法和统计分析法计算大气混合层高度,分析其在霾日和非霾日的不同日变化特征。结果表明宁波市霾日与非霾日混合层高度均呈白天高,夜晚低的日变化特征,夏季两者差值的日变化波动最明显,波峰时间比其他季节晚3 h。混合层高度日变化趋势与风速、气温、能见度趋于一致,霾等级越重,混合层高度越低。霾日与非霾日的气温差值除冬季呈正变温外,其他季节呈负变温,冬季14时差值最小,夜间加大,春夏季凌晨差值最小,14时最大,秋季波动不明显;风速差值除冬季夜间为正值外,其余季节为负值,秋冬季差值最小、夏季最大。大气处于不稳定状态时,混合层高度随着稳定度增加而逐渐处于稳定状态时,随着稳定度增加而降低,中性大气是宁波易致霾的大气层结。霾日与非霾日大气稳定度表现不一致,中午霾日中性大气占多数,非霾日则是不稳定大气;夜间霾日稳定—弱稳定大气和中性大气所占比例相当,非霾日稳定—弱稳定大气占多数。另外,PM_(2.5)浓度在霾日和非霾日均为白天低、夜间高的日变化特征,但霾日波动大,波峰时间晚于非霾日2 h,峰值浓度也高于非霾日2.7倍;早晨或下午到上半夜是霾日的PM_(2.5)浓度两个上升时段,上午为下降时段;非霾日的两个浓度缓升(降)时段分别出现凌晨和下午(上午和前半夜)。研究成果有助于预报员了解大气混合层高度及其对霾的可能影响,从而提高霾预报预警能力。  相似文献   

6.
利用2016年12月1日～2017年11月30日,地基微波辐射计、L波段探空资料和地面常规气象资料,对四川盆地的水汽和云液态水进行了初步分析。结果表明:(1)探空与微波辐射计反演的水汽含量差值为0.558cm,相关系数为0.787,且通过了α=0.01显著性检验,微波辐射计反演的水汽含量是可信的。(2)基于地基微波辐射计分析四川盆地水汽和云液态水含量的变化特征,可以得出,夏季水汽含量最多,秋季云液态水含量最多;最大值出现在夜晚,最小值出现在白天,夜晚值大于白天。水汽含量和云液态水含量最大值和最小值时间间隔秋季最长(均为16小时),冬季最短(分别为9小时、10小时);水汽含量日较差在秋季最大(1.096cm),冬季最小(0.489cm),云液态水含量日较差在夏季最大(0.908mm),冬季最小(0.311mm)。水汽含量与降水、温度的月变化特征为显著性正相关,相关系数分别为0.842和0.915;与温度日变化特征在春、秋季的11:00～次日01:00为显著性正相关,白天相关性大于夜晚,在夏季01:00～13:00为显著性负相关,日出前相关性最高。(3)水汽和云液态水含量在降水过程开始前1～2h有明显的波动上升,降水结束后,水汽和云液态水含量迅速减少,水汽和云液态水的变化特征对降水天气的预报具有指示意义。   相似文献   

7.
利用瓦里关和上甸子大气本底站观测的月平均CO2浓度数据对GOSAT卫星反演的CO2浓度数据进行验证,结果表明GOSAT产品与台站观测数据有较好的一致性.利用2009年6月—2011年5月GOSAT反演的CO2浓度数据,分析了江苏地区CO2浓度的时空变化特征,结果表明:1)975 hPa高度层CO2浓度高于850 hPa高度层,CO2浓度的水平变化要小于垂直变化;2)在季节变化上,CO2浓度冬季最高,夏季最低,这可能与植被光合作用的强弱变化有关;比较前后两年的CO2浓度数据,夏季和秋季的增速较快,冬季和春季的增速较慢;3)在日变化上,发现徐州和南京站02时CO2浓度最高,14时CO2浓度最低,这可能也与植被光合作用的强弱有关.  相似文献   

8.
李桂红 《湖北气象》2008,27(4):355-358
选用咸宁市金沙区域2006年6月至2007年5月可吸入颗粒物质量浓度监测资料,分析了金沙颗粒物质量浓度时间分布特征。分析结果表明：金沙三种可吸入颗粒物PM10、PM2.5、PM1.0质量浓度变化规律基本一致,年季变化表现为秋冬大,夏春小;日变化呈双峰双谷型周期性变化,白天大于夜间,最大值出现在下午16-19时,最小值出现在清晨03-07时,除秋季外第二峰谷表现不明显。且雨雾天气PM10浓度较晴到多云低。且通过与2006年6月至2007年5月的地面气象要素资料相关分析,发现PM10质量浓度与气温、气压呈显著正相关,与降水、风速、湿度呈显著负相关。  相似文献   

9.
Summary  The carbon dioxide exchange in arctic and subarctic terrestrial ecosystems has been measured using the eddy-covariance method at sites representing the latitudinal and longitudinal extremes of the European Arctic sea areas as part of the Land Arctic Physical Processes (LAPP) project. The sites include two fen (Kaamanen and Kevo) and one mountain birch ecosystems in subarctic northern Finland (69° N); fen, heathland, and snowbed willow ecosystems in northeastern Greenland (74° N); and a polar semidesert site in Svalbard (79° N). The measurement results, which are given as weekly average diurnal cycles, show the striking seasonal development of the net CO2 fluxes. The seasonal periods important for the net CO2 fluxes, i.e. winter, thaw, pre-leaf, summer, and autumn can be identified from measurements of the physical environment, such as temperature, albedo, and greenness. During the late winter period continuous efflux is observed at the permafrost-free Kaamanen site. At the permafrost sites, efflux begins during the thaw period, which lasts about 3–5 weeks, in contrast to the Kaamanen site where efflux continues at the same rate as during the winter. Seasonal efflux maximum is during the pre-leaf period, which lasts about 2–5 weeks. The summer period lasts 6 weeks in NE Greenland but 10–14 weeks in northern Finland. During a high summer week, the mountain birch ecosystem had the highest gross photosynthetic capacity, GP max, followed by the fen ecosystems. The polar semidesert ecosystem had the lowest GP max. By the middle of August, noon uptake fluxes start to decrease as the solar elevation angle decreases and senescence begins within the vascular plants. At the end of the autumn period, which lasts 2–5 weeks, topsoil begins to freeze at the end of August in Svalbard; at the end of September at sites in eastern Greenland; and one month later at sites in northern Finland. Received March 1, 2000 Revised October 2, 2000  相似文献   

10.
In this study, a regional air quality model system (RAQMS) was applied to investigate the spatial distributions and seasonal variations of atmospheric aerosols in 2006 over East Asia. Model validations demonstrated that RAQMS was able to reproduce the evolution processes of aerosol components reasonably well. Ground-level PM10 (particles with aerodynamic diameter ≤10 μm) concentrations were highest in spring and lowest in summer and were characterized by three maximum centers: the Taklimakan Desert (～1000 μg m-3), the Gobi Desert (～400 μg m-3), and the Huabei Plain (～300 μm-3) of China. Vertically, high PM10 concentrations ranging from 100 μg m-3 to 250 μg m-3 occurred from the surface to an altitude of 6000 m at 30o--45oN in spring. In winter, the vertical gradient was so large that most aerosols were restricted in the boundary layer. Both sulfate and ammonium reached their highest concentrations in autumn, while nitrate reached its maximum level in winter. Black carbon and organic carbon aerosol concentrations reached maximums in winter. Soil dust were strongest in spring, whereas sea salt exerted the strongest influence on the coastal regions of eastern China in summer. The estimated burden of anthropogenic aerosols was largest in winter (1621 Gg) and smallest in summer (1040 Gg). The sulfate burden accounted for ～42% of the total anthropogenic aerosol burden. The dust burden was about twice the anthropogenic aerosol burden, implying the potentially important impacts of the natural aerosols on air quality and climate over East Asia.  相似文献   

11.
Upper-level cut-off lows in southern South America   总被引：2，自引：0，他引：2  
Summary This paper presents a statistical study of the spatial and seasonal distribution and duration of cut-off low systems over the southern South American region based on the NCEP- NCAR reanalysis data for the period 1979–1988. Cut-off lows were first objectively determined as minimum geopotential values at the 250 hPa level and then subjectively imposing a cut-off circulation and a cold core. A total of 171 cut-off low events were detected, being more frequent in austral autumn followed by winter, spring and summer. There is a preferential region of occurrence in spring and autumn located between 68°–80° W and 30°–45° S. The Pacific area showed the greatest frequency of occurrence followed by the Atlantic and the continental areas. Most of the cut-off lows last 2 or 3 days (around 90% of the cases) though there is a tendency of the continental events to be longer. The cut-off low event developed upwind the Andes on 22–28 September 1986 was selected as a case study. Low-level cold air advection was the main forcing of the deepening of the upper level low system.  相似文献   

12.
Atmospheric pollutants are controlled not only by their production rates but also by meteorological conditions. The influences of dust storm, sauna weather (haze with high temperature and high humidity), wet precipitation and wind speed on atmospheric carbonyls in Beijing were investigated. During a severe dust episode (April 17, 2006), the mixing ratios of carbonyls were significantly elevated to 13–27 ppbV from 7 to 13 ppbV in the previous non-dust days (April 15 and 16) with the increasing extents of 38–154%. The accumulating effect and the lower photolysis rate in the dust day may be responsible for the increases of carbonyls' levels. Additionally, the contribution from heterogeneous reactions occurring on dust particles to formaldehyde and acetaldehyde cannot be ruled out. During the period of typical sauna weather, the concentrations of atmospheric carbonyls increased to 18–60 ppbV from 10 to 17 ppbV before the sauna days. The air mass over Beijing during the sauna days was controlled by a subtropical anticyclone and the boundary layer became quite stable, which was beneficial to the rapid accumulation of air pollutants including carbonyls. Wet precipitation was found to be an effective removal process to the atmospheric carbonyls. After one-hour of rain in summer, the total concentrations of atmospheric carbonyls decreased to less than half of that before the rainfall. The similar temporal varying patterns of carbonyls and inorganic ions in rainwater indicated that carbonyls were mainly washed out from the atmosphere into rainwater as inorganic ions were. Strong wind could evidently dilute atmospheric carbonyls and a negative correlation was found between wind speeds and the concentrations of carbonyls in spring in Beijing.  相似文献   

13.
In the present study, an attempt has been made to examine the governing photochemical processes of surface ozone (O3) formation in rural site. For this purpose, measurements of surface ozone and selected meteorological parameters have been made at Anantapur (14.62°N, 77.65°E, 331 m asl), a semi-arid zone in India from January 2002 to December 2003. The annual average diurnal variation of O3 shows maximum concentration 46 ppbv at noon and minimum 25 ppbv in the morning with 1σ standard deviation. The average seasonal variation of ozone mixing ratios are observed to be maximum (about 60 ppbv) during summer and minimum (about 22 ppbv) in the monsoon period. The monthly daytime and nighttime average surface ozone concentration shows a maximum (55 ± 7 ppbv; 37 ± 7.3 ppbv) in March and minimum (28 ± 3.4 ppbv; 22 ± 2.3 ppbv) in August during the study period. The monthly average high (low) O3 48.9 ± 7.7 ppbv (26.2 ± 3.5 ppbv) observed at noon in March (August) is due to the possible increase in precursor gas concentration by anthropogenic activity and the influence of meteorological parameters. The rate of increase of surface ozone is high (1.52 ppbv/h) in March and lower (0.40 ppbv/h) in July. The average rate of increase of O3 from midnight to midday is 1 ppbv/h. Surface temperature is highest (43–44°C) during March and April months leading to higher photochemical production. On the other hand, relative humidity, which is higher during the rainy season, shows negative correlation with temperature and ozone mixing ratio. It can be seen that among the two parameters are measured, correlation of surface ozone with wind speed is better (R 2=0.84) in compare with relative humidity (R 2=0.66).  相似文献   

14.
北京气温日变化特征的城郊差异及其季节变化分析   总被引：9，自引：1，他引：8       下载免费PDF全文
杨萍  肖子牛  刘伟东 《大气科学》2013,37(1):101-112
本文利用北京地区近4年67个自动气象站的逐小时气温观测资料,基于北京地区气温的日变化特征,通过分析日最高、最低气温出现时间的概率分布,研究了城区、郊区气温的日变化差异及季节特征.此外,进一步分析研究了不同单位时间间隔变温的日变化特征,及最大变温出现时间的概率分布情况.研究结果表明:平均而言,城区最高温度出现的时间偏晚,而最低温度出现的时间城区偏早于郊区,与郊区相比,北京城区站点温度的日变化特征更为一致,最高(低)温度出现的时间更加集中;温度日变化的特征随季节有明显的变化,最高温度出现时间在秋、冬两季最为集中,在春季和夏季较为分散;而最低温度出现时间在春、夏两季最为集中,在秋季和冬季最为分散.一天中正、负变温过程具有非对称特征,正变温是比较急剧的过程,负变温相对比较缓慢,北京城区站点的变温幅度小于郊区,春、秋和冬季变温幅度较大,夏季变温幅度最小.不同单位时间内变温速率的分析表明,最强的变温过程一般在3小时以内;最大变温出现时间的概率分布分析表明,最大正变温出现时间在冬季最为集中,夏季最为分散;而最大负变温在秋季最为集中,在春季最为分散.最高(低)温度、变温的城、郊特征差异主要是由于城市热容量比郊区大,且具有更多变化的复杂性而形成的.温度日变化的特征和其区域、季节差异性的揭示,不仅有助于更好地认识和理解区域气候特征和城市化对气温的影响,也可以为做好精细化的天气预报提供气候背景参考.  相似文献   

15.
This article presents a complete study of the diurnal chemical reactivity of the biogenic volatile organic compound (BVOC), 2-methyl-3-buten-2-ol (MBO) in the troposphere. Reactions of MBO with OH and with ozone were studied to analyse the respective parts of both processes in the global budget of MBO atmospheric reactivity. They were investigated under controlled conditions for pressure (atmospheric pressure) and temperature (298 ± 2 K) using three complementary European simulation chambers. Reaction with OH radicals was studied in the presence of and in the absence of NO x . The kinetic study was carried out by relative rate study using isoprene as a reference. The rate constant found for this reaction was molecule−1 cm3 s−1. FTIR spectroscopy, DNPH- and PFBHA-derivatisation analyses were performed for reactions with both OH radicals and ozone. In both reactions, the hydroxycarbonyl compound, 2-hydroxy-2-methylpropanal (HMPr) was positively identified and quantified, with a yield of in the reaction with OH, and a yield of and 0.84 ± 0.08 in the reaction with ozone under dry (HR < 1%) and humid conditions (HR = 20%–30%). A primary production of two other carbonyl compounds, acetone , and formaldehyde was found in the case of the dry ozonolysis experiments. Under humid conditions, only formaldehyde was co-produced with HMPr as a primary carbonyl compound, with a yield of . For the reaction with OH, three other carbonyl compounds were detected, acetone , formaldehyde and glycolaldehyde . In addition some realistic photo-oxidation experiments were performed to understand in an overall way the transformations of MBO in the atmosphere. The realistic photo-oxidation experiments were conducted in the EUPHORE outdoor simulation chamber. It was found that this compound is a weak secondary aerosol producer (less than 1% of the carbon balance). But it was confirmed that it is a potentially significant source of acetone, Δ[Acetone]/Δ[MBO] = 0.45. With our experimental conditions ([MBO]0 = 200 ppb, [NO]o = 50 ppb), an ozone yield of Δ[O3]/Δ[MBO] = 1.05 was found.  相似文献   

16.
The concentration of gas-phase peroxides has been measured almost continuously at the Cape Grim baseline station (41° S) over a period of 393 days (7702 h of on-line measurements) between February 1991 and March 1992. In unpolluted marine air a distinct seasonal cycle in concentration was evident, from a monthly mean value of>1.4 ppbv in summer (December) to <0.2 ppbv in winter (July). In the summer months a distinct diurnal cycle in peroxides was also observed in clean marine air, with a daytime build-up in concentration and decay overnight. Both the seasonal and diurnal cycles of peroxides concentration were anticorrelated with ozone concentration, and were largely explicable using a simple photochemical box model of the marine boundary layer in which the central processes were daytime photolytic destruction of ozone, transfer of reactive oxygen into the peroxides under the low-NOx ambient conditions that favour self-reaction between peroxy radicals, and continuous heterogeneous removal of peroxides at the ocean surface. Additional factors affecting peroxides concentrations at intermediate timescales (days to a week) were a dependence on air mass origin, with air masses arriving at Cape Grim from higher latitudes having lower peroxides concentrations, a dependence on local wind speed, with higher peroxides concentrations at lower wind speeds, and a systematic decrease in peroxides concentration during periods of rainfall. Possible physical mechanisms for these synoptic scale dependencies are discussed.  相似文献   

17.
利用2004～2006年杭州主城区环境空气监测资料,研究了O_3、NO_2和CO浓度的分布特征和时间变化规律,结果表明,杭州主城区3年的O_3、NO_2、CO的年均浓度都不大,分别为40、60、1400μg·m~(-3).四季中O_3、NO_2和CO浓度相差较大,O_3是夏季高冬季低,NO_2和CO则是秋季较高,夏季较低.O_3、NO_2和CO浓度日变化也很明显,其中O_3是单峰形态,NO_2和CO为双峰形态.不同天气条件下O_3与烃类的关系研究表明,晴天时烃类浓度减少,O_3浓度明显增加;阴天时O_3浓度较低,烃类浓度较高,它们的变化不大.白天和夜晚不同风速时O_3、C_2-C_(12)的浓度变化不同,白天风速增大时C_2-C_(12)浓度减小,O_3浓度增加;晚上无此变化.  相似文献   

18.
利用葫芦岛观测站1980—2009年观测资料,分析了葫芦岛沿岸海陆风风速的季节特征和日变化规律,以及海陆风环流对沿岸环境的影响。结论如下:1)葫芦岛站点在冬季出现海陆风日数最多,其他依次为秋季、夏季和春季。陆风风速从春季到冬季呈现递减趋势;海风在春季最大,其次为秋季的,冬季的最小。总体上,海陆风日中海风要强于陆风。2)对海陆风风速椭圆拟合结果表明,海陆风在10:32由陆风转化为海风,海风在16:32达到最大,在21:42由海风转化为陆风,陆风在04:32达到最大。3)由于海风的存在,沿岸地带在春夏两季日最高气温在12时出现,秋冬季的在13时出现。4)能见度日变化在四季中表现一致,早晨能见度转好的时刻比最低气温出现时刻滞后约2 h,在海风维持较长时间后空气绝对湿度增加导致能见度开始转差。5)冬季静止型海陆风日比例最高,再循环型海陆风日在秋季出现最多,而夏季通风型海陆风日出现最多。  相似文献   

19.
Summary  Temperature and precipitation records from 1949 to 1998 were examined for 25 stations throughout the State of Alaska. Mean, maxima, and minima temperatures, diurnal temperature range, and total precipitation were analyzed for linear trends using least squares regressions. Annual and seasonal mean temperature increases were found throughout the entire state, and the majority were found to be statistically significant at the 95% level or better. The highest increases were found in winter in the Interior region (2.2 °C) for the 50 year period of record. Decreases in annual and seasonal mean diurnal temperature range were also found, of which only about half were statistically significant. A state-wide decrease in annual mean diurnal temperature range was found to be 0.3 °C, with substantially higher decreases in the South/Southeastern region in winter. Increases were found in total precipitation for 3 of the 4 seasons throughout most of Alaska, while summer precipitation showed decreases at many stations. Few of the precipitation trends were found to be statistically significant, due to high interannual variability. Barrow, our only station in the Arctic region, shows statistically significant decreases in annual and winter total precipitation. These findings are largely in agreement with existing literature, although they do contradict some of the precipitation trends predicted by the CO2-doubling GCM’s. Received August 30, 1999/Revised March 21, 2000  相似文献   

20.
Daily, weekly, and seasonal patterns of O3, NOx x and VOCs and their relationship to meteorological conditions were studied in a semi-urban site near Barcelona by means of five-day long campaigns that included weekend and labor days in December, March, June, and October. The plant protection thresholds for ozone and NO2 were exceeded, respectively, on all the studied days in summer and on all the studied days. Ozone formation was predominantly local and relied on photochemical processes with VOCs playing a controlling role. Formaldehyde, acetaldehyde, methanol, toluene, isoprene, and acetone (in this order) presented the highest O3 formation potential during the studied periods. These results highlight the important role in O3 formation played by VOC species such as acetaldehyde, methanol, and acetone, that all have a significant biogenic component. Thus, these VOCs must be taken into account in the discussion of any ozone abatement strategy.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号