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1.
We present here in situ measurements obtained between 1991 and 2011 in outer-vortex conditions by the ELHYSA balloon-borne frost-point hygrometer. The frost-point hygrometer profiles are used for comparisons with the satellite data from version 19 (v19) and version 3.3 (v3.3) of the HALogen Occultation Experiment (HALOE) and the Microwave Limb Sounder (MLS) respectively. Potential Vorticity mapping is applied to all data sets to remove contributions of transient tropical intrusions and polar vortex air masses and hence ensure consistent comparisons between the balloon and satellite observations. Our selected balloon in situ observations are too sparse to directly infer mid-latitude stratospheric time series for continuous comparisons with HALOE and MLS records or derive water vapour trends but can be used to validate the satellite data. A mean difference of ?0.83?±?1.58 % (?0.04?±?0.07 ppmv) is obtained between HALOE v19 data and the balloon frost-point observations (with respect to HALOE) over the 30–80 hPa altitude range. The hygrometer-HALOE differences appear time-dependent as already presented in the literature. The mean difference reaches 2.80?±?0.96 % (0.13?±?0.04 ppmv) for MLS v3.3, with MLS systematically wetter than the balloon data reflecting a systematic bias between both datasets. We use our balloon data as reference to provide some information about the HALOE-MLS difference. From post-2000 ELHYSA-HALOE and ELHYSA-MLS comparisons, we find a HALOE-MLS difference matching the expected bias, with MLS v3.3 6.60?±?2.80 % (0.27?±?0.11 ppmv) wetter than HALOE v19. From the results obtained from our balloon-satellite data comparisons, we finally discuss the issue about merging the HALOE and MLS data sets to provide stratospheric water vapour trends.  相似文献   

2.
Using a database of spectra collected with an airborne infrared spectrometer between 1978 and 2005, the longest record of this type, we have searched for a temporal trend in the stratospheric OCS amount. The total column above 200 hPa, in latitudes from 30° to 60°N, shows a change of about 0.77 ± 0.80% per year relative to the 2010 value which is 1.34 × 1015 molecules cm−2; thus not a significant change. Observations are made from the base of the stratosphere and are uniquely suited to determining the stratospheric OCS abundance.  相似文献   

3.
In the winter of 1994/95 the TRANSALL research aircraft performed several flights in the region of the Arctic vortex during the period of low stratospheric temperatures. The results of simultaneous measurements of HNO3 column amounts by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) and of aerosol backscatter profiles by the Ozone Lidar EXperiment (OLEX) are presented for two typical flight scenarios across the polar vortex boundary on December 17, 1994 and January 11/12, 1995. On December 17 and January 12, the column amounts of gaseous HNO3 decreased significantly in regions with low stratospheric temperatures. This decrease was correlated with the extent of the polar stratospheric clouds. Depolarisation measurements showed that type Ib PSCs were observed primarily, but equilibrium calculations for H2SO4/HNO3/H2O aerosols seem to underestimate the observed HNO3 sequestering.  相似文献   

4.
The effects of E1Nifio Modoki events on global ozone concentrations are investigated from 1980 to 2010 E1 Nifio Modoki events cause a stronger Brewer-Dobson （BD） circulation which can transports more ozone-poor air from the troposphere to stratosphere, leading to a decrease of ozone inthe lower-middle stratosphere from 90~S to 90~N. These changes in ozone concentrations reduce stratospheric column ozone. The reduction in stratospheric column ozone during E1 Nifio Modoki events is more pronounced over the tropical eastern Pacific than over other tropical areas because transport of ozone-poor air from middle-high latitudes in both hemispheres to low latitudes is the strongest between 60°W and 120°W. Because of the decrease in stratospheric column ozone during E1 Nifio Modoki events more UV radiation reaches the tropical troposphere leading to significant increases in tropospheric column ozone An empirical orthogonal function （EOF） analysis of the time series from 1980 to 2010 of stratospheric and tropospheric ozone monthly anomalies reveals that： E1 Nifio Modoki events are associated with the primary EOF modes of both time series. We also found that E1 Nifio Modoki events can affect global ozone more significantly than canonical E1 Nifio events. These results imply that E1 Nifio Modoki is a key contributor to variations in global ozone from 1980 to 2010.  相似文献   

5.
Airborne measurements of stratospheric ozone and N2O from the SCIAMACHY (Scanning Imaging Absorption Spectrometer) Validation and Utilization Experiment (SCIA-VALUE) are presented. The campaign was conducted in September 2002 and February–March 2003. The Airborne Submillimeter Radiometer (ASUR) observed stratospheric constituents like O3 and N2O, among others, spanning a latitude from 5°S to 80°N during the survey. The tropical ozone source regions show high ozone volume mixing ratios (VMRs) of around 11 ppmv at 33 km altitude, and the altitude of the maximum VMR increases from the tropics to the Arctic. The N2O VMRs show the largest value of 325 ppbv in the lower stratosphere, indicating their tropospheric origin, and they decrease with increasing altitude and latitude due to photolysis. The sub-tropical and polar mixing barriers are well represented in the N2O measurements. The most striking seasonal difference found in the measurements is the large polar descent in February–March. The observed features are interpreted with the help of SLIMCAT and Bremen Chemical Transport Model (CTMB) simulations. The SLIMCAT simulations are in good agreement with the measured O3 and N2O values, where the differences are within 1 ppmv for O3 and 15 ppbv for N2O. However, the CTMB simulations underestimate the tropical middle stratospheric O3 (1–1.5 ppmv) and the tropical lower stratospheric N2O (15–30 ppbv) measurements. A detailed analysis with various measurements and model simulations suggests that the biases in the CTMB simulations are related to its parameterised chemistry schemes.  相似文献   

6.
The current paper introduces an empirical method for estimating the vertical distribution of background stratospheric aerosol extinction profiles covering the latitude bands of 50±5°N,40±5°N,30±5°N,and 20±5°N and the longitude range of 75 135°E based on Stratospheric Aerosol and Gas Experiment (SAGE) II aerosol extinction measurements at wavelengths of 1020 nm,525 nm,452 nm,and 386 nm for the volcanically calm years between 1998 2004.With this method,the vertical distribution of stratospheric aerosol extinction coefficients can be estimated according to latitude and wavelength.Comparisons of the empirically calculated aerosol extinction profiles and the SAGE II aerosol measurements show that the empirically calculated aerosol extinction coefficients are consistent with SAGE II values,with relative differences within 10% from 2 km above the tropopause to 33 km,and within 22% from 33 km to 35 km.The empirically calculated aerosol stratospheric optical depths (vertically integrated aerosol extinction coefficient) at the four wavelengths are also consistent with the corresponding SAGE II optical depth measurements,with differences within 2.2% in the altitude range from 2 km above the tropopause to 35 km.  相似文献   

7.
In this paper we present first-time measurements of ozone profiles from a high altitude station in Quito, Ecuador (0.19°S, 78.4°W, and 2391 masl) taken from June 2014 to September 2015. We interpret ozone observations in the troposphere, tropopause, and stratosphere through a zonal comparison with data from stations in the Atlantic and Pacific (Natal and San Cristobal from the SHADOZ network). Tropospheric ozone concentrations above the Andes are lower than ozone over San Cristobal and Natal for similar time periods. Ozone variability and pollution layers are also reduced in the troposphere above the Andes. We explain these differences in terms of reduced contributions from the boundary layer and from horizontal transport. In the tropical tropopause layer, ozone is well-mixed up to near the cold point tropopause level. In this regard, our profiles do not show constraints to deep mixing above 14 km, as has been consistently observed at other tropical stations. Total column ozone and stratospheric column ozone are comparable among the three sites. However, the contribution of tropospheric column ozone to total column ozone is significantly lower above the Andes. Our comparisons provide a connection between observations from tropical stations in equatorial South America separated by the wide continental mass. Identified differences in ozone throughout the atmospheric column demonstrate the global benefit of having an ozone sounding station at the equatorial Andes in support of global monitoring networks.  相似文献   

8.
Terry Deshler   《Atmospheric Research》2008,90(2-4):223-ICNAA07
Stratospheric aerosol, noted after large volcanic eruptions since at least the late 1800s, were first measured in the late 1950s, with the modern continuous record beginning in the 1970s. Stratospheric aerosol, both volcanic and non-volcanic are sulfuric acid droplets with radii (concentrations) on the order of 0.1–0.5 µm (0.5–0.005 cm− 3), increasing by factors of 2–4 (10–103) after large volcanic eruptions. The source of the sulfur for the aerosol is either through direct injection from sulfur-rich volcanic eruptions, or from tropical injection of tropospheric air containing OCS, SO2, and sulfate particles. The life cycle of non-volcanic stratospheric aerosol, consisting of photo-dissociation and oxidation of sulfur source gases, nucleation/condensation in the tropics, transport pole-ward and downward in the global planetary wave driven tropical pump, leads to a quasi steady state relative maximum in particle number concentration at around 20 km in the mid latitudes. Stratospheric aerosol have significant impacts on the Earth's radiation balance for several years following volcanic eruptions. Away from large eruptions, the direct radiation impact is small and well characterized; however, these particles also may play a role in the nucleation of near tropopause cirrus, and thus indirectly affect radiation. Stratospheric aerosol play a larger role in the chemical, particularly ozone, balance of the stratosphere. In the mid latitudes they interact with both nitrous oxides and chlorine reservoirs, thus indirectly affecting ozone. In the polar regions they provide condensation sites for polar stratospheric clouds which then provide the surfaces necessary to convert inactive to active chlorine leading to polar ozone loss. Until the mid 1990s the modern record has been dominated by three large sulfur-rich eruptions: Fuego (1974), El Chichón (1982) and Pinatubo (1991), thus definitive conclusions concerning the trend of non-volcanic stratospheric aerosol could only recently be made. Although anthropogenic emissions of SO2 have changed somewhat over the past 30 years, the measurements during volcanically quiescent periods indicate no long term trend in non-volcanic stratospheric aerosol.  相似文献   

9.
The present study for the first time reports the global gravity wave activity in terms of their potential energy derived from TIMED/SABER observations right from the stratosphere to the mesosphere lower thermosphere (MLT) region. The potential energy profiles obtained from SABER temperature are validated by comparing them with ground based LIDAR observations over a low latitude site, Gadanki (13.5° N, 79.2° E). The stratospheric and mesospheric global maps of gravity wave energy showed pronounced maxima over high and polar latitudes of the winter hemisphere. The interannual variability of the stratospheric gravity wave activity exhibited prominent annual oscillation over mid-latitudes. The equatorial gravity wave activity exhibited quasi-biennial oscillation in the lower stratosphere and semi-annual oscillation in the upper stratosphere. The MLT region maps revealed summer hemispheric maxima over polar latitudes and secondary maxima over the equatorial region. The results are discussed in the light of present understanding of global gravity wave observations. The significance of the present study lies in emphasizing the importance of satellite measurements in elucidating gravity waves, which is envisaged to have profound impact on parameterizing these waves.  相似文献   

10.
A programme of ground-based stratospheric and total NO2 column measurements was instituted at the Laboratory of Atmospheric Physics (40.5° N, 22.9° E) in August 1985. We present here the results of the first two years of measurements with a modified Canterbury filter photometer, details of which are given in the text. The stratospheric NO2 column, obtained at twilight during low local NO2 levels, shows the seasonal variation with monthly mean values of about 6×10-15 molec. cm-2 in the summertime to about 2.2×10-15 molec. cm-2 in the wintertime. These measurements compare well with measurements obtained with different instruments by other groups at similar latitudes (about 40° N) but in different places. Also, the asymmetry of the evening-to-morning stratospheric NO2 over Thessaloniki was found to be on the average equal to 1.58. Total NO2 column over Thessaloniki has a pronounced seasonal variation with amplitude of 0.68 matm. cm which can be explained partly from measured local NO2 sources which discharge in the mixing layer and partly from photolysis of the NO2 reservoir species.  相似文献   

11.

A Raman lidar system was operated along with the Microtops sunphotometer measurements to carry out the study of the variation of the optical properties of aerosols over Palampur (32.11° N and 76.53° E), India from 17th April to 11th May 2019. The lidar system is furnished with Raman (N2) channel and depolarization channel allowing independent measurement of Lidar Ratio (LR) and linear depolarization ratio. The study reveals that the majority of the aerosols approximately were restricted within the planetary boundary layer (PBL) and very less loading was present in the free troposphere over the study location. The particle loading over the study period was found to be very less with aerosol backscatter coefficient (at 355 nm) ranging from ～0.13 Mm?1sr?1 to ～7.25 Mm?1sr?1 with mean value of 2.67?±?0.82 Mm?1sr?1 and it is well supplemented by the mean aerosol optical depth (AOD) of 0.37?±?0.13 obtained from Microtops Sunphotometer. The average lidar ratio values for 0-1 km altitude (L1) 72?±?13sr, for 1-2 km (L2) altitude 55?±?8sr, for 2-3 km (L3) 54?±?15sr were observed as suggesting dominance of the biomass burning aerosols and anthropogenic aerosols. The particle depolarization ratio (355 nm) values were found from approximately 4.8?±?2.7% to 11.5?±?1.9% with the mean value of 7?±?1.3% suggesting the presence of non-spherical particles. To trace the sources of the pollution, we derived the HYSPLIT trajectory which shows the majority of the movement was from local sources.

  相似文献   

12.
Using a detailed, fully coupled chemistry climate model (CCM), the effect of increasing stratospheric H2O on ozone and temperature is investigated. Different CCM time-slice runs have been performed to investigate the chemical and radiative impacts of an assumed 2 ppmv increase in H2O. The chemical effects of this H2O increase lead to an overall decrease of the total column ozone (TCO) by ～1% in the tropics and by a maximum of 12% at southern high latitudes. At northern high latitudes, the TCO is increased by only up to 5% due to stronger transport in the Arctic. A 2-ppmv H2O increase in the model's radiation scheme causes a cooling of the tropical stratosphere of no more than 2 K, but a cooling of more than 4 K at high latitudes. Consequently, the TCO is increased by about 2%--6%. Increasing stratospheric H2O, therefore, cools the stratosphere both directly and indirectly, except in the polar regions where the temperature responds differently due to feedbacks between ozone and H2O changes. The combined chemical and radiative effects of increasing H2O may give rise to more cooling in the tropics and middle latitudes but less cooling in the polar stratosphere. The combined effects of H2O increases on ozone tend to offset each other, except in the Arctic stratosphere where both the radiative and chemical impacts give rise to increased ozone. The chemical and radiative effects of increasing H2O cause dynamical responses in the stratosphere with an evident hemispheric asymmetry. In terms of ozone recovery, increasing the stratospheric H2O is likely to accelerate the recovery in the northern high latitudes and delay it in the southern high latitudes. The modeled ozone recovery is more significant between 2000--2050 than between 2050--2100, driven mainly by the larger relative change in chlorine in the earlier period.  相似文献   

13.
The radiative impacts of the stratosphere in global warming simulations are investigated using abrupt CO2 quadrupling experiments of the Coupled Model Inter-comparison Project phase 5 (CMIP5), with a focus on stratospheric temperature and water vapor. It is found that the stratospheric temperature change has a robust bullhorn-like zonal-mean pattern due to a strengthening of the stratospheric overturning circulation. This temperature change modifies the zonal mean top-of-the-atmosphere energy balance, but the compensation of the regional effects leads to an insignificant global-mean radiative feedback (?0.02 ± 0.04 W m?2 K?1). The stratospheric water vapor concentration generally increases, which leads to a weak positive global-mean radiative feedback (0.02 ± 0.01 W m?2 K?1). The stratospheric moistening is related to mixing of elevated upper-tropospheric humidity, and, to a lesser extent, to change in tropical tropopause temperature. Our results indicate that the strength of the stratospheric water vapor feedback is noticeably larger in high-top models than in low-top ones. The results here indicate that although its radiative impact as a forcing adjustment is significant, the stratosphere makes a minor contribution to the overall climate feedback in CMIP5 models.  相似文献   

14.
Abstract

The importance of measurements of the vertical distribution of odd nitrogen in studies of ozone chemistry and climate change has long being recognized. In this paper, we use the optimal estimation method developed by Rodgers (1976, 1990) to retrieve NO2 vertical profiles from slant column observations made with a portable ultraviolet (UV)‐visible zenith‐sky spectrometer operated on the ground during the Middle Atmosphere Nitrogen TRend Assessment (MANTRA) balloon campaign carried out at Vanscoy, Saskatchewan, Canada (52°N, 107°W), from 18 to 25 August 1998. Late summer was chosen for the campaign because the stratospheric zonal wind velocity changes sign at that time. Under such conditions the stratospheric winds are at a minimum, leaving the stratosphere in a dynamically quiescent state and closer to photochemical control (Fahey et al., 2001; Fioletov and Shepherd, 2003). The NO2 profile retrieved from the ground‐based observations is compared with the co‐located and simultaneous NO2 profile measured by a balloon‐borne UV‐visible spectrometer during sunrise on 24 August. Good agreement is observed, giving us confidence in the retrieval technique adopted. The retrieved NO2 profiles are also compared with the output of the Model for Evaluating oZONe trends (MEZON) 3D stratospheric chemical transport model. It is observed that, for altitudes below the peak concentration, the model underestimates the NO2 amount, and at the altitude of peak concentration, the model values lie between the values measured from the balloon and those retrieved from the ground‐based measurements. Nevertheless, the model reproduces the general shape of the retrieved profiles, including the altitude of the NO2 maximum, for both sunrise and sunset conditions.  相似文献   

15.
Based on the Stratospheric Aerosol and Gas Experiment (SAGE) II and the Halogen Occultation Experiment (HALOE) ozone profiles and the Total Ozone Mapping Spectrometer (TOMS) total ozone data sets, an empirical model for estimating the vertical distribution of stratospheric ozone over China is proposed. By using this model, the vertical distribution of stratospheric (16–50 km) ozone can be estimated according to latitude, month and total ozone. Comparisons are made between the modeled ozone profiles and the ...  相似文献   

16.
High-quality long-term records of spectral UV irradiance from the Network for the Detection of Atmospheric Composition Change-affiliated Bentham spectroradiometer at the high-mountain site Hoher Sonnblick (47.05° N, 12.95° E, 3,106?m above sea level) from the period 1997?C2011 have been investigated for the existence of trends. Throughout the year, significant upward trends are found at wavelengths of 315?nm and longer. The magnitudes at 315?nm range from +9.3?±?4.5?%/dec at 45° solar zenith angle (SZA) to +14.2?±?3.7?%/dec at SZA 65° for all-sky conditions. The trend estimates at 305?nm are considerably smaller and less significant, yielding between +5.1?±?6.5 and +7.9?±?7.3?%/dec, depending on SZA. Seasonally, the largest trends are found during winter and spring. Total ozone has significantly increased by year-round +1.9?±?1.3?%/dec since 1997 and therefore cannot explain these significant increases. They are rather attributed to decreases in total cloud cover and aerosol optical depth.  相似文献   

17.
A two-step method is employed in this study to retrieve vertical ozone profiles using scattered measure- ments from the limb of the atmosphere. The combination of the Differential Optical Absorption Spectroscopy (DOAS) and the Multiplicative Algebraic Reconstruction Technique (MART) is proposed. First, the limb radiance, measured over a range of tangent heights, is processed using the DOAS technique to recover the effective column densities of atmospheric ozone. Second, these effective column densities along the lines of sight (LOSs) are inverted using the MART coupled with a forward model SCIATRAN (radiative transfer model for SCIAMACHY) to derive the ozone profiles. This method is applied to Optical Spectrograph and Infra Red Imager System (OSIRIS) radiance, using the wavelength windows 571-617 nm. Vertical ozone profiles between 10 and 48 km are derived with a vertical resolution of 1 km. The results illustrate a good agreement with the cloud-free coincident SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) ozone measurements, with deviations less than ± 10% ( ± 5% for altitudes from 17 to 47 km). Furthermore, sensitivities of retrieved ozone to aerosol, cloud parameters and NO 2 concentration are also investigated.  相似文献   

18.
In August 2010, simultaneous enhancements of aerosol optical depth and total columns of carbon monoxide (CO), hydrogen cyanide (HCN), and ethane (C2H6) were observed at the Polar Environment Atmospheric Research Laboratory (PEARL, 80.05°N, ?86.42°W, 0.61 km above sea level, Eureka, Nunavut, Canada). Moderate Resolution Imaging Spectroradiometer (MODIS) hot spots, Ozone Monitoring Instrument (OMI) aerosol index maps, and Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) back-trajectories were used to attribute these enhancements to an intense boreal fire event occurring in Russia. A ground-based Fourier Transform InfraRed (FTIR) spectrometer at PEARL provided vertically integrated measurements of trace gases transported in smoke plumes. We derived HCN and C2H6 equivalent emission ratios with respect to CO of 0.0054?±?0.0022 and 0.0108?±?0.0036, respectively, and converted them into equivalent emission factors of 0.66?±?0.27 g kg?1 and 1.47?±?0.50 g kg?1 (in grams of gas per kilogram of dry biomass burnt, with one-sigma uncertainties). These emission factors add new observations to the relatively sparse datasets available and can be used to improve the simulation of biomass burning fire emissions in chemical transport models. These emission factors for the boreal forest are in agreement with the mean values recently reported in a compilation study.  相似文献   

19.
The European Centre for Medium-Range Weather Forecasts Re-Analysis Interim (ERA-Interim) meteorology and measurements from the Microwave Limb Sounder, High Resolution Dynamics Limb Sounder, and Ozone Monitoring Instrument onboard the Earth Observing System Aura satellite were applied to analyze the dynamical and chemical features of a cutoff low (COL) event over northeast China in early July 2007. The results showed the polar stratospheric origin of an upper-level warm-core cyclone at 100--300 hPa, associated with a funnel-shaped tropopause intruding into the mid-troposphere just above the COL center. The impacts of the stratospheric intrusion on both column ozone and ozone profiles were investigated using satellite measurements. When the intensity of the COL peaked on 10 July 2007, the total column ozone (TCO) increase reached a maximum (40--70 DU). This could be dynamically attributed to both the descent of the tropopause (～75%) and the downward transport of stratospheric ozone across the tropopause (～25%). Analysis of the tropospheric ozone profiles provided evidence for irreversible transport/mixing of ozone-rich stratospheric air across the tropopause near the upper-level front region ahead of the COL center. This ozone intrusion underwent downstream transport by the upper tropospheric winds, leading to further increase in TCO by 12--16 DU over broad regions extending from east China toward the northern Japan Sea via South Korea. Meteorological analysis also showed the precedence of the stratospheric intrusion ahead of the development of cyclones in the middle and lower troposphere.  相似文献   

20.
The first direct in situ measurements of the sulfuric acid contained in stratospheric aerosol particles were made using a novel balloon-based Ion Molecule Reaction Mass Spectrometer instrument (IMRMS) equipped with an aerosol vaporizer. The IMRMS method employed offers direct aerosol sulfuric acid measurements with high spatial resolution. The balloon flight took place on 23 October 1995 in middle latitudes (44°N) and reached a maximum altitude of 24 km. Measured molecular number densities of aerosol sulfuric acid decreased with increasing altitude from about 2.9 × 109 cm-3 at 15km altitude to about 2.4 × 108 cm-3 at 21 km. Corresponding mass mixing ratios are 2.5 and 0.6 ppbm, respectively. Calculated sulfuric acid mixing ratios from aerosol volumes inferred from aerosol size distribution measurements on the same balloon agree well with the IMRMS data using standard assumption aerosol composition.  相似文献   

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