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1.
The compositions, distribution and its interaction with rocks of the evolving pore fluids controls the distribution of carbonate cements and reservoir storage spaces. The reservoir quality of the red-bed sandstone reservoirs in the Dongying Depression was investigated by an integrated and systematic analysis including carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and fluid inclusions. The investigation was also facilitated by probing the mineral origins, precipitation mechanisms, pore fluid evolution and distribution, and water-rock interaction of carbonate cements and their influences on reservoir quality. Diagenetic-evolving fluids in the interbedded mudstones are the main source for the precipitation of calcite cements that completely fill the intergranular volume (CFIV calcite) with heavier oxygen and carbon isotopes. The ferro-carbonate cements in the reservoir sandstone are enriched in lighter carbon and oxygen isotopes. In addition to the cations released by the conversion of clay minerals in reservoirs, products of organic acid decarboxylation and the associated feldspar dissolution process provide important sources for such carbonate cementation. The carbon isotopes of CO2 and the oxygen isotopic composition of fluids equilibrated with the CFIV calcite, ferro-calcite, dolomite and ankerite cements indicate that the pore in the red-bed reservoirs experienced high salinity fluids, which evolved from the early-formed interbedded mudstones, through organic acid input and to organic acid decarboxylation. Pore fluids from nearby mudstones migrated from the edge to the centre of sandbodies, causing strong calcite cementation along the sandbody boundaries and forming tight cementation zones. Pore fluids associated with organic CO2 and acids and organic acid decarboxylation are mainly distributed in the internal portion of sandbodies, causing feldspar dissolution and precipitation of ferro-carbonate cements. The distribution of pore fluids caused the zonal distribution of carbonate cements in sandbodies during different periods. This may be advantageous to preserve the porosity of reservoirs as exemplified by the distribution of high-quality reservoirs in the red-bed sandbodies. 相似文献
2.
Peiwu Shen Dingjian Wang Yibing Ning Yongquan Zhang Xuexue Su 《Marine Georesources & Geotechnology》2020,38(7):818-829
AbstractFluctuant marine and reservoir water levels are the main failure-inducing factors for embankment slopes. The soft embankment rocks, e.g., red-bed mudstone, eroded by the reservoir water level in the Three Gorges Reservoir area greatly influence the stability of the embankment slopes. In this study, unified strength theory was innovatively applied for damage evaluation and combined with the Weibull distribution to obtain the strength statistics of micro units. Additionally, one damage constitutive model and one damage evolution model considering the initial damage, strain softening and damage weakening were proposed. Then, a series of tests, e.g., modified cyclic wetting and drying test, triaxial compression test and modified numerical simulation test for reservoir embankment red-bed mudstone, were conducted to verify the feasibility of the proposed models. In addition, grey system theory was originally used to evaluate the effects of the Weibull distribution parameters (m and w) and the confining stress on the peak stress. Finally, the proposed model was tentatively applied to the modification of the limit failure height model of the bedded rock slopes. The verification implies that the proposed model results are consistent with the testing results, especially in the simulation of compaction, elastic deformation and strain softening and in the prediction of peak strength. The results from grey system theory analysis indicate that the micro unit strength parameter (w) has the most obvious effect on the strength. Moreover, the modified method based on the damage evolution model for calculating the limit failure height of the bedded rock slopes is conservative. 相似文献
3.
Oedometric mechanical compaction tests were performed on brine-saturated synthetic samples consisting of silt-clay mixtures to study changes in microfabric and rock properties as a function of effective stress. The silt consisted of crushed quartz (∼100%) with grain size range between 4 and 40 μm, whereas the clay consisted of 81% kaolinite, 14% mica/illite and 5% microcline of grain size between 0.4 and 30 μm. Five sample pairs ranging in composition from pure silt to pure clay were compacted to 5 and 50 MPa effective stress respectively. SEM studies were carried out to investigate microfabric changes in the mechanically compacted silt-clay mixtures. The degree of alignment of the different minerals present (quartz, mica/illite and kaolinite) were computed by using an image analysis software. Experimental compaction have measured the changes in the rock properties such as porosity and velocity as a function of effective stress for different mixtures of clay and silt. Clay-rich samples showed a higher degree of mineral orientation and lower porosity compared to silt-dominated samples as a function of effective stress. Pure clay sample had 11% porosity at 50 MPa effective stress whereas the pure silt sample retained about 29% porosity at the same effective stress. The experiments showed that low porosity down to 11% is possible by mechanical compaction only. A systematic increase in strain was observed in the silt-clay mixtures with increasing clay content but the porosity values found for the 50:50 silt-clay mixture were lower than that of 25:75 silt-clay mixture. No preferential mineral orientation is expected before compaction owing to the high initial porosity suggesting that the final fabric is a direct result of the effective stress. Both P- and S-wave velocities increased in all silt-clay mixtures with increasing effective stress. The maximum P- and S-wave velocities were observed in the 25:75 silt-clay mixture whereas the minimum Vp and Vs were recorded in the pure silt mixture. At 50 MPa effective stress P- wave velocities as high as 3 km/s resulted from experimental mechanical compaction alone. The results show that fine-grained sediment porosity and velocity are dependent on microfabric, which in turn is a function of grain size distribution, particle shape, sediment composition and stress. At 5 MPa effective stress, quartz orientation increased as a function of the amount of clay indicating that clay facilitate rotation of angular quartz grains. Adding clay from 25% to 75% in the silt-clay mixtures at 50 MPa effective stress decreased the quartz alignment. The clay mineral orientation increased by increasing both the amount of clay and the effective stress, the mica/illite fabric alignment being systematically higher than that of kaolinite. Even small amount of silt (25%) added to pure clay reduced the degree of clay alignment significantly. This study demonstrates that experimental compaction of well characterized synthetic mudstones can be a useful tool to understand microfabric and rock properties of shallow natural mudstones where mechanical compaction is the dominant process. 相似文献
4.
A suite of selected Tertiary mudstones was studied to improve the knowledge about microstructure and related transport processes in mudstones. Samples were investigated by mercury- and Wood's metal injection, SEM, XRD, and grain size analysis. Wood's metal injection has the advantage of visualising the ‘frozen’ injection process. The smallest pore casts observed were down to 40 nm in diameter, while the largest, bottle-shaped pores were up to 5 μm in diameter. Bottle-shaped pores occurred in all the samples, usually around silt or sand grains. One sample, which had a porosity of 28.5% according to mercury injection data, had not been impregnated by the molten alloy. We suggest this to reflect a strong deformation of the clay fabric by the high pressure without intrusion into the matrix. This raises questions about the reliability of mercury injection data for very fine-grained, highly porous sediments.After excluding these very fine-grained samples and one very calcareous sample regressions were found which relate porosity (φ), clay content (C), and sand content (S) to capillary displacement pressure (Pd(Hg)): Pd(Hg)=−25.05+0.63 C+0.29S (R2=0.92), and Pd(Hg)=−10.24+0.47 C−0.15φ (R2=0.88). 相似文献
5.
ABSTRACT Marine manganese nodules and crusts, when processed, yield tailings which may be utilized for environmental and economic benefit. The key to the reasonable and effective utilization of these tailings lies in making a systematic appraisal of their composition and properties. This article gives an introduction to the investigation of manganese tailings properties. The tailings have a high iron and/or manganese content, high surface area, high porosity, and fine grain size. Some tailings have a high rare earth element content which is valuable. They may also have high SO3, arsenic, and uranium contents which are harmful. Depending on the process used to produce the tailings, there will likely be some differences in chemical composition, mineral assemblages, surface area and adsorption capability, pore diameter and volume, density and pH. In assigning potentially beneficial applications for these tailings, these differences should be taken into account to optimize utilization. 相似文献
6.
The Late Triassic mudstones are considered to be the most significant hydrocarbon source rocks (TOC: 0.54%–3.29%) in the North Qiangtang Depression, eastern Tethys. Here, we present geochemical data from the Woruo Mountain Carnian mudstones, in order to investigate their paleoclimate, paleoenvironment, and provenance and to analyze the mechanism of organic material accumulation. The paleoclimate condition was warm and humid during the Carnian mudstones deposition, as indicated by moderate chemical index of alteration (CIA; 73–76), which may be connected with the Late Triassic Carnian stage global climate event in the Tethys. The low U/Th (0.17–0.25) and Corg/Ptot (7–33) ratio values and moderate manganese contents, reflect the oxidizing conditions during the Carnian mudstones deposition. The relatively high primary productivity in this study is supported by the relatively high P concentrations. The Al2O3–(CaO* + Na2O)–K2O ternary plot and Th/Sc–Zr/Sc crossplot reflect that the source areas have undergone a medium chemical weathering with weak sedimentary recycling. The TiO2–Zr, Co/Th–La/Sc, La/Th–Hf, and La/Yb–∑REE bivariate diagrams indicate that the provenance of Carnian mudstones was primarily from felsic igneous rocks. The collision setting has been identified based on the multi-major elements discriminate plots in the present study. The Riwanchaka and Mayigangri masses to the southwest and south of the study area consisting mainly of Middle-Triassic granodiorite and Late-Triassic granite are likely responsible for supplying provenance to the Woruo Mountain Carnian mudstones, which have similar REE patterns. The relatively high TOC contents of Carnian mudstones are related to high paleoproductivity and fast sedimentation rates, which will lead to preservation of some organic matter even when bottom waters are completely oxidizing. The detrital input during the Carnian mudstones deposition would result in dilution of organic matter. 相似文献
7.
天然砾石海滩作为一种高能环境下的海岸堆积体,因其粒径粗、孔隙度大等特征,是良好的海岸防护屏障。了解砾石海滩形成过程离不开砾石形貌这一重要参数,但要快速、准确获得大量砾石的定量参数比较困难。本文对山东北长山岛3个砾石海滩(九丈崖、月牙湾、长滩)、南长山岛的4个砾石海滩(仙境源、林海、长山尾和明珠广场)进行现场剖面测量并采集砾石样品及砾石图像,应用ImageJ软件对砾石进行原位无干扰数字图像测算,可以快速大量分析砾石粒径、磨圆度等形貌参数。结果显示:砾石的粒径范围为4～79 mm,主要集中在中砾,各海滩分选较好;其中,北长山岛海滩的砾石平均粒径略小于南长山岛,北长山岛九丈崖海滩的砾石平均粒径最大,南长山岛的仙境源海滩砾石平均粒径最小。向海方向从滩肩到高潮线平均粒径逐渐减小,但在水边线处增大。砾石磨圆度介于0.59～0.75之间,等级均为圆状,砾石海滩均已达到较成熟阶段;其中北长山岛的月牙湾海滩砾石磨圆最好,长滩海滩砾石的磨圆最差,由陆向海磨圆度值呈增大的趋势。形状比率范围介于1.36～1.77之间,与磨圆度呈明显负相关(R2=0.98),砾石由陆向海从长条状渐变为椭圆状。南、北长山岛的砾石海滩的砾石形貌受到物源、动力条件和人为活动的影响。研究区砾石海滩坡度范围为16%～35%,海滩坡度与沉积物粒径呈正相关。 相似文献
8.
AbstractThe electrokinetic treatments on high natural moisture content, large compressibility, and low strength dredged marine soil are regarded as an innovative method, but it has not been widely applied due to the difference between theory predictions and realities. To minimize the difference which is resulted from the electric permeability coefficient variations due to pore water drainage and the degree of saturation drops during the electrokinetic treatment of soils, several one-dimensional indoor experiments were conducted with single kaolin clay and natural soft clay. The test results indicate that the electric permeability values conform to the predicted value of Helmholtz–Smoluchowski (H-S) theory under saturated conditions. The permeability for unsaturated soils can be described with relative electric permeability, that is, ke,rel=a(Sr)b. The ranges of fitting parameters are 0.8–1.2 for a and 3–9 for b. The fitting parameters are dependent on the soil type, electric potential gradient, and pore size distribution and so on. The smaller the soil pore size is the more sensitive the permeability coefficient is to the degree of saturation. 相似文献
9.
Abstract The granulometry of 21 box core sediments from five selected sites in the Central Indian Basin (CIB) have been studied to understand the sediment size characteristics in the Pioneer area before the benthic disturbance experiment. The sediments are predominantly clayey silt. Statistical parameters were determined to understand the control and variations in the grain size. The mean grain size (Mzφ) ranged from 7.0 to 8.6 for the surface and from 6.6 to 8.6 for the subsurface sediments, indicating deposition of very fine fractions during the Neogene period. The sediments were poorly sorted as revealed from the higher ρ1 values (2.7 to 2.9). Higher and negative values of skewness (SK1) indicated a winnowing action of prevailing currents in the area. Average kurtosis (KG) values for the surface (0.4 to 0.8) and subsurface (0.5 to 1.2) showed that sediments were very platykurtic and leptokurtic. Clay mineralogical studies showed that smectite had a wider range (from 6% to 55%) and decreased southward because of its terrigenous origin. The terrigenous influence of the sediments could be documented as far as 12°S. Smectite and kaolinite increased eastward and chlorite decreased southward. This observation positively correlated with the mean current direction in the area. However, the influence of Antarctic Bottom Water (AABW) in the area could be predicted from the southward increase in chlorite content. 相似文献
10.
Chaoyu Wu 《Marine Georesources & Geotechnology》2013,31(2):99-122
Abstract Three sets of bottom sediment samples, totalling 563, were collected in the Atchafalaya Bay, Louisiana. Cluster analysis was applied to each set of data based on grain‐size distribution. Comparison between resulting clusters and depositional environments indicates that the results of cluster analysis are sedimentologically meaningful and environmentally significant. A follow‐up discriminant analysis shows the stability of the classification system. The system then, in turn, can be used to classify sediments from unknown sources in the study area. 相似文献
11.
基于Chirp数据和Biot-Stoll模型反演南海北部陆坡海底表层沉积物物理性质 总被引：1，自引：1，他引：0
浅地层剖面是基于声学信号(频率在几百至几千赫兹)在沉积物中的传播得到可反映沉积地层结构的数据，海底反射系数与沉积物物理性质密切相关。Biot-Stoll声波传播理论模型可以预测海底沉积物的物理性质，构建反射系数等声学参数与物理参数之间的关系，但在不同的海域采用不同的参数所获得的效果不同。为此，本文基于南海北部陆坡海底表层沉积物的实测物理参数，利用Biot-Stoll模型建立研究区海底反射系数和沉积物物理性质之间的关系，结果表明模型计算值与样品实测值吻合度总体较好，偏差在0.1%～4.9%之间，并建立了频率3.5 kHz时海底反射系数与沉积物孔隙度、密度、平均粒径之间的关系方程，且方程拟合度较高，可决系数R2均大于0.99。在对典型Chirp剖面数据计算其海底反射系数的基础上，反演了海底表层沉积物的孔隙度、密度、颗粒平均粒径等物理性质，其中反演孔隙度、密度、平均粒径与实测孔隙度、密度、平均粒径相对误差均小于5%，结果与实测值基本相符，表明该反演方法在南海北部陆坡区的应用是可行的。 相似文献
12.
While clastic mudstones and shale were traditionally interpreted to have been deposited in quiet water settings, recent flume experiments and studies have shown that mud can be transported in and deposited by traction currents as migrating ripples of mud aggregates. Despite these recent advances, mud aggregates have rarely been adequately described in the rock record.These mud aggregates and the sedimentary structures they form in mudstone successions are difficult to observe in the rock record due to compaction, which often obliterates the aggregates and flattens bedforms. This paper documents unambiguously identifiable sand sized mudstone aggregates in thin sections and SEM, transported in traction, and deposited in a series of prograding clinothems. These aggregates were sufficiently indurated to locally preserve shelter porosity, significantly improving the hydrocarbon reservoir properties.Grain size analysis of the aggregates was performed on thin sections, as well as disaggregated samples measured by a laser diffraction grain size analyzer for comparison. These analyses showed that sand sized aggregates often comprise more than half of the sediment volume. While the clay-rich composition of the Carlile Formation would suggest that it is a mudstone, statistical analysis of these grain size measurements show that it could alternatively be described as a silty sandstone. These findings potentially change how we think about mudstone classification, fine-grained sedimentation, and mudstone dominated petroleum reservoirs. 相似文献
13.
AbstractVarious modified direct shear tests on the interface between calcareous sand and steel with different degrees of roughness were conducted in this article, and the different interface property results between calcareous sand-steel and siliceous sand-steel were compared. It was found that: (1) Under various normal stresses, the limit shear stress at the interface reaches the peak value when the groove depth is at the critical value Rcr. Further, when the flat width is at a critical value Gcr, the limit interface shear stress reaches to that of a grooved surface with a flat width of zero. (2) The magnitudes of Rcr and Gcr are related to the gradation and grain size of sand. For the calcareous sand tested, Rcr and Gcr are three times and seven times the mean grain size, respectively. (3) When the intersection angle between the symmetrical V-shaped grooves and the direct shear direction equals to 45°, the limit interface shear stress reaches the peak value and no significant increase is observed at the larger intersection angle. (4) Under the same interface testing conditions with siliceous and calcareous sands, the interface friction angle of the calcareous sand is ～5°–6° greater than that of siliceous sand. 相似文献
14.
东海盆地某油气田A井钻遇古近系平湖组P层为一套灰绿色含砾细砂岩.对此层中的微量元素、古生物资料、粒度特征以及测井资料的分析表明：沉积物中的硼元素含量较低,Sr/Ba比值小于1,Fe/Mn比值远大于5,这些指标反映沉积水体为淡水;同时,Ni/Co比值大多数介于2.5～5之间,而V/Ni比值大于1,指示研究层位沉积于还原环境中.该层沉积物中,蕨类孢子含量极高,花粉组合以阔叶类木本为主,且含较多喜暖湿针叶类花粉,说明当时盆地周边区域气候大致相当于现代亚热带气候,较温暖且偏湿润.A井P层中,砾石具近源快速堆积特征,泥岩属较深水沉积,岩层粒度具浊积岩特征;结合空间岩性展布状况可以判断,P层沉积相属于温暖湿润气候下的淡水近岸水下扇相. 相似文献
15.
E.R. McGreer 《Marine environmental research》1982,7(2):131-149
An investigation of the factors responsible for the distribution of Macoma balthica (L.) on a mudflat receiving sewage effluent was carried out in the Fraser River estuary, British Columbia. The factors examined included reduced salinity, low levels of dissolved oxygen, effluent toxicity, chlorination, substrate grain size and the effects of metal contaminated sediments. Results showed that salinity, dissolved oxygen and sediment grain size did not satisfactorily explain the distribution of M. balthica. Unchlorinated and chlorinated sewage effluent were shown to be non-toxic in laboratory tests, and these results were confirmed by 7-day in situ bioassays. The factor which appeared to determine the distribution of M. balthica was the degree of contamination of the substrate which affected the settling and survival of larval and juvenile clams. Heavy metals occurred in high concentrations in the contaminated sediments and were considered to be the most probable controlling factor. 相似文献
16.
《Marine and Petroleum Geology》2012,36(1):154-165
This study aims at investigating hydrocarbon generation potential and biological organic source for the Tertiary coal-bearing source rocks of Pinghu Formation (middle-upper Eocene) in Xihu depression, East China Sea shelf basin. Another goal is to differentiate coal and mudstone with respect to their geochemical properties. The coal-bearing sequence has a variable organofacies and is mainly gas-prone. The coals and carbonaceous mudstones, in comparison with mudstones, have a higher liquid hydrocarbon generation potential, as reflected by evidently higher HI values (averaging 286 mg HC/g C) and H/C atomic ratios (round 0.9). The molecular composition in the coal-bearing sequence is commonly characterized by unusually abundant diterpenoid alkanes, dominant C29 sterane over C27 and C28 homologues and high amount of terrigenous-related aromatic biomarkers such as retene, cadalene and 1, 7-dimethylphenanthrene, indicating a predominantly terrigenous organic source. The source rocks show high Pr/Ph ratios ranging mostly from 3.5 to 8.5 and low MDBTs/MDBFs ratios (<1.0), indicating deposition in an oxic swamp-lacustrine environment. The coals and carbonaceous mudstones could be differentiated from the grey mudstones by facies-dependent biomarker parameters such as relative sterane concentration and gammacerane index and carbon isotope composition. Isotope and biomarker analysis indicate the genetic correlation between the Pinghu source rocks and the oils found in Xihu depression. Moreover, most oils seem to be derived from the coal as well as carbonaceous mudstone. 相似文献
17.
Experimental data are described on the threshold of transport of quartz, ilmenite, and cassiterite grains under oscillatory flow in a flume and the results are compared to those of other investigators. The results show that for a given particle size, critical shear stress (τcrit) increases with increasing wave period and that τcrit increases with both grain size and grain density. These data are compared with prediction equations. 相似文献
18.
Different sperm allocation strategies in two populations of the semiterrestrial crab Neohelice granulata (Brachyura,Grapsoidea, Varunidae) 
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下载免费PDF全文 Sperm reserves are costly to produce and so the development of different sperm allocation strategies may be advantageous. Knowledge of sperm allocation strategies is important from an evolutionary perspective because they contribute to characterize mating systems. However, population differences in sperm allocation strategies of the same species have rarely been assessed. Here, we studied the male sperm allocation strategies in two different populations of Neohelice granulata in Mar Chiquita Lagoon (MCL) and San Antonio Oeste (SAO), Argentina. We found that the quantity of ejaculate transferred by N. granulata males depended on different factors such as male size and female receptivity duration, while it was independent of female size, at both study areas. Regarding the operational sex ratio factor, the amount of ejaculate transferred depended on it in MCL but not in SAO. Thus, N. granulata males may have the capacity to regulate the quantity of ejaculate transferred based on individual factors such as their own size and female receptivity duration, and population factors such as operational sex ratio, which varies in the two populations studied. 相似文献
19.
Isabel López Luis Aragonés Yolanda Villacampa 《Marine Georesources & Geotechnology》2013,31(6):683-694
AbstractArtificial neural networks (ANN) have been widely used successfully to solve coastal engineering problems. In this article, they are used to model the cross-shore profile of sandy beaches taking into account the possible effect of marine vegetation (Posidonia oceanica). Sixty ANNs were generated by modifying both the inputs and the number of neurons in the hidden layer. The best results were obtained with the following inputs: wave height perpendicular to the coast and the associated period and probability of occurrence, median sediment size, profile slope, and energy reduction factor due to P. oceanica. With these inputs and 10 neurons in the hidden layer, a mean absolute error of 0.22?m during training and 0.21?m during the test was obtained, which represents an improvement of 81.2% and 55.5% compared to models without and with P. oceanica. 相似文献
20.
Hoi-Soo Jung Kap-Sik Jeong Yong-Shik Chu Sung-Hyun Park Ki-Hyune Kim 《Marine Georesources & Geotechnology》2013,31(3):181-195
Abstract Grain size and water content in box-core sediments from the Clarion-Clipperton fracture zone (C-C zone) in the northeast equatorial Pacific were analyzed in detail to understand the downcore variations across a hiatus between Quaternary and Tertiary layers. Grain-size distributions in the topmost core sediments show two modes: a coarse mode (peaked at 50 μm) and a fine mode (at 2–25 μm). The coarse mode disappears gradually with depth accompanied by the dissolution of siliceous fossil tests, whereas the fine mode coarsens due to the formation of authigenic minerals. Water content increases abruptly across a color boundary between an upper pale brown layer and a lower dark brown layer that is the hiatus between Quaternary and Tertiary layers. Abundant smectites and microvoid molds, which are created by the prolonged fossil dissolution in the underlying sediment, are attributed for the abrupt downcore variation of water content. Overall variations in grain size and water content in the topmost core sediments in the western C-C zone are possibly constrained by the dissolution of biogenic siliceous fossils. Variations in geotechnical properties related to these changes must be considered in the design of nodule collectors. 相似文献