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1.
The formation of Subantarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW) significantly contributes to the total uptake and storage of anthropogenic gases, such as CO2 and chlorofluorocarbons (CFCs), within the world's oceans. SAMW and AAIW formation rates in the South Pacific are quantified based on CFC-12 inventories using hydrographic data from WOCE, CLIVAR, and data collected in the austral winter of 2005. This study documents the first wintertime observations of CFC-11 and CFC-12 saturations with respect to the 2005 atmosphere in the formation region of the southeast Pacific for SAMW and AAIW. SAMW is 94% and 95% saturated for CFC-11 and CFC-12, respectively, and AAIW is 60% saturated for both CFC-11 and CFC-12. SAMW is defined from the Subantarctic Front to the equator between potential densities 26.80-27.06 kg m−3, and AAIW is defined from the Polar Front to 20°N between potential densities 27.06-27.40 kg m−3. CFC-12 inventories are 16.0×106 moles for SAMW and 8.7×106 moles for AAIW, corresponding to formation rates of 7.3±2.1 Sv for SAMW and 5.8±1.7 Sv for AAIW circulating within the South Pacific. Inter-ocean transports of SAMW from the South Pacific to the South Atlantic are estimated to be 4.4±0.6 Sv. Thus, the total formation of SAMW in the South Pacific is approximately 11.7±2.2 Sv. These formation rates represent the average formation rates over the major period of CFC input, from 1970 to 2005. The CFC-12 inventory maps provide direct evidence for two areas of formation of SAMW, one in the southeast Pacific and one in the central Pacific. Furthermore, eddies in the central Pacific containing high CFC concentrations may contribute to SAMW and to a lesser extent AAIW formation. These CFC-derived rates provide a baseline with which to compare past and future formation rates of SAMW and AAIW.  相似文献   

2.
Within the Central waters of the North Atlantic Ocean there is a significant east–west difference in salinity, similar to that caused by Mediterranean Water at deeper levels. In this paper we hypothesize that the salinity of the Central Water is influenced by the saline Mediterranean Outflow Water, despite physical separation of the two water masses by a salinity minimum over most of the ocean basin. It is suggested that there occurs a cross-isopycnal flux of salinity from the Mediterranean Outflow Water towards the low-density Central Water (detrainment) in the eastern Gulf of Cadiz, not far from the Strait of Gibraltar, where the two water masses are in physical contact. Laboratory experiments, inverse modeling and direct current observations are applied to support the hypothesis.  相似文献   

3.
Recent multibeam bathymetry and acoustic imagery data provide a new understanding of the morphology of the western part of the Gulf of Cadiz. The gulf is under the influence of a strong current, the Mediterranean Outflow Water (MOW). This current is at the origin of the construction of the giant Contourite Depositional System. Canyons and valleys with erosive flanks are observed. Only the Portimao Canyon is presently connected to the continental shelf. Channels occur on the continental shelf but are presently disconnected from the deeper network of channels and valleys. Slumps are localized in steep slope areas. They are caused by oversteepening and overloading, sometimes probably associated with earthquake activity. Slumps transform sharply into turbidity currents, depositing turbidites on the floor of deep valleys. Interaction of the MOW and gravity currents is suggested by the filling of the incisions located on the drifts below the present seafloor, the shifting of valleys and canyons in the direction of the MOW flow inducing an unusual phenomenon of capture of submarine valleys.  相似文献   

4.
A large set of new data concerning dissolved metal concentrations has been acquired in the Gulf of Cadiz and in the Strait of Gibraltar from 1996 to 1999. These data, associated with models (hydrodynamic, tracer advection–dispersion and mixing), have been used to assess the influence of rivers draining the South Iberian Pyrite Belt on the Gulf of Cadiz and on the Atlantic inflow in the Strait of Gibraltar.Metal concentrations in surface waters from the Gulf of Cadiz are maximal near the mouth of the Tinto/Odiel rivers with values exceeding 50 nmol/kg (Mn), 5 nmol/kg (Ni), 30 nmol/kg (Cu), 100 nmol/kg (Zn), 0.9 nmol/kg (Cd) and 45 nmol/kg (As). From the Tinto/Odiel river, a plume of contamination follows the coast in the direction of the Strait of Gibraltar. The computation of a tracer advection–dispersion model confirms that the coastal currents carry the metals discharged from the Tinto and Odiel to the Strait of Gibraltar.From temperature–salinity and metal–salinity plots, four water masses can be recognised in the Gulf of Cadiz and in the Strait of Gibraltar: North Atlantic Surface Water (NASW), North Atlantic Central Water (NACW) and metal-enriched Spanish Shelf Waters from the Gulf of Cadiz (SSW). The Mediterranean Outflow Water (MOW) is also clearly seen at depths greater than 300 m.The chemical characteristics of these various water masses have been used in a mixing model to evaluate their relative contribution to the Atlantic inflow through the Strait of Gibraltar. These contributions are seasonally variable. In June 1997, the contribution was: 80±20%, 5±5% and 15±10% for NASW, NACW and SSW, respectively. In September, the SSW contribution was apparently negligible.Finally, these relative contributions allow the evaluation of the metal fluxes in the Strait of Gibraltar. The presence of SSW in the Strait increases the metal flux to the Mediterranean Sea by a factor of 2.3 (Cu), 2.4 (Cd), 3 (Zn) and 7 (Mn). It does not modify significantly As and Ni fluxes.  相似文献   

5.
In OMEX-II-II, 9 cruises gathered optical data, principally by transmissometer. The distribution of optical turbidity caused by concentration of particulate matter (PMC) in the water column over the northern Iberian margin shows several features related to hydrography. It is concluded that a signal of PMC seen in Mediterranean Water (MW) found north of 42°N is not carried from its source at the Gibraltar Sill and Gulf of Cadiz because it is shown, using intermediate stations, that this turbid plume decays, mainly by fall out but also partly by mixing, to very low levels around southern Portugal. PMC maxima sometimes seen in MW on the northern Iberian margin are thus most likely to result from intermittent local resuspension by MW interacting with slope sediments. The highest turbidity is found over the upper slope and is the result of (i) shelf edge resuspension and off-shelf flow of turbid plumes, mainly between 100 and 300 m depth, and (ii) resuspension under the slope current aided by internal waves, in the depth range 500–800 m where the density gradient between ENACW and MW is maximal. Below the MW, flows are generally slow, and turbidity is low. The bottom nepheloid layer in deep water is also weak with PMC values <100 mg m-3. The focus of resuspension activity on the upper slope means that the region is an efficient exporter to the ocean of sediment that either escapes from the shelf or sinks to the bed from surface production. This accounts for upper slope sediments recorded in other studies as sandy or in places as rocky bottom.  相似文献   

6.
Heat flow anomalies provide critical information in active tectonic environments. The Gulf of Cadiz and adjacent areas are affected by the plate convergence between Africa and Europe, causing widespread deformation and faulting. Active thrust faults cause lateral movement and advection of heat that produces systematic variations in surface heat flow. In December 2003 new heat flow data were collected during the research vessel Sonne cruise SO175 in the Gulf of Cadiz over two sites of recent focused research activity: (i) the Gulf of Cadiz sedimentary prism and (ii) the Marques de Pombal escarpment. Both features have also been discussed as potential source areas of the Great Lisbon earthquake and tsunami of 1755. Background heat flow at the eastern terminus of the Horseshoe abyssal plain is about 52–59 mW/m2. Over the Gulf of Cadiz prism, heat flow decreases from ∼57 mW/m2 to unusually low values of 45 mW/m2 roughly 120 km eastward. Such low values and the heat flow trend are typical for active thrusting, supporting the idea of an east-dipping thrust fault. Slip rates are 10 ± 5 mm per year, assuming that the fault dips at 2°. A fault dipping at 5°, however, would result into slip rates of 1.5–5 mm per year, suggesting that subduction has largely ceased. Based on seismic data, the Marques de Pombal fault is interpreted as part of an active fault system located ∼100 km westward of Cape San Vincente. Heat flow over the fault is affected by refraction of heat caused by the 1 km high escarpment. Thermal models suggest that the slip rate along the fault must either be small or shear stresses acting on the fault are rather high. With respect to other fault zones, however, it is reasonable to assume that the fault's slip rate is small.  相似文献   

7.
Temperature, salinity and chlorofluorocarbons (CFCs) 11, 12 and 113 were measured on a line of stations along the front of the Ross Ice Shelf in the austral summers of 1984, 1994 and 2000. Water mass distributions were similar each year but with high variability in the cross-sectional areas. CFC concentrations increased and salinity decreased with time throughout the water column. CFC saturation levels in the shelf and surface waters also increased with time and ranged from 43% to 90%. The undersaturation was due to inflow of low-CFC modified Circumpolar Deep Water, gas exchange limited by sea ice cover and isolation of water from the atmosphere beneath the ice shelf. The residence time of dense shelf waters resulting from sea ice formation is less well constrained by the chemical data than is the strong flow into the Ross Ice Shelf cavity. Shelf waters are transformed over about 3.5 years, by net basal melting of the ice shelf, into fresher Ice Shelf Water (ISW), which emerges as a large plume near the central ice front at temperatures below the sea surface freezing point. We estimate an average ISW production rate of 0.86 Sv and an average net basal melt rate of 60 km3/year for the Ross Ice Shelf exceeding a 300 m draft (75% of the ice cavity) during recent decades from box and stream tube models fit to all of the CFC and salinity data. Model fits to the individual data sets suggest ISW production and net basal melt rate variability due to interannual changes on a shorter time scale than our observations. ISW production based on the CFC budget is better constrained than net basal melting based on thermohaline data, with a heat budget yielding a rate of only 20 km3/yr. Reconciling differences between apparent freshwater and temperature changes under the ice shelf involves considerations of mixing, freezing and the flow of meltwater across the ice shelf grounding line.  相似文献   

8.
On the basis of the salinity distribution of isopycnal(σ_0=27.2 kg/m~3) surface and in salinity minimum, the Antarctic Intermediate Water(AAIW) around South Australia can be classified into five types corresponding to five regions by using in situ CTD observations. Type 1 is the Tasman AAIW, which has consistent hydrographic properties in the South Coral Sea and the North Tasman Sea. Type 2 is the Southern Ocean(SO) AAIW, parallel to and extending from the Subantarctic Front with the freshest and coldest AAIW in the study area. Type 3 is a transition between Type 1 and Type 2. The AAIW transforms from fresh to saline with the latitude declining(equatorward). Type 4, the South Australia AAIW, has relatively uniform AAIW properties due to the semienclosed South Australia Basin. Type 5, the Southeast Indian AAIW, progressively becomes more saline through mixing with the subtropical Indian intermediate water from south to north. In addition to the above hydrographic analysis of AAIW, the newest trajectories of Argo(Array for real-time Geostrophic Oceanography) floats were used to constructed the intermediate(1 000 m water depth) current field, which show the major interocean circulation of AAIW in the study area. Finally, a refined schematic of intermediate circulation shows that several currents get together to complete the connection between the Pacific Ocean and the Indian Ocean. They include the South Equatorial Current and the East Australia Current in the Southwest Pacific Ocean, the Tasman Leakage and the Flinders Current in the South Australia Basin, and the extension of Flinders Current in the southeast Indian Ocean.  相似文献   

9.
Dense water formation and circulation in the Barents Sea   总被引：1，自引：0，他引：1  
Dense water masses from Arctic shelf seas are an important part of the Arctic thermohaline system. We present previously unpublished observations from shallow banks in the Barents Sea, which reveal large interannual variability in dense water temperature and salinity. To examine the formation and circulation of dense water, and the processes governing interannual variability, a regional coupled ice-ocean model is applied to the Barents Sea for the period 1948-2007. Volume and characteristics of dense water are investigated with respect to the initial autumn surface salinity, atmospheric cooling, and sea-ice growth (salt flux). In the southern Barents Sea (Spitsbergen Bank and Central Bank) dense water formation is associated with advection of Atlantic Water into the Barents Sea and corresponding variations in initial salinities and heat loss at the air-sea interface. The characteristics of the dense water on the Spitsbergen Bank and Central Bank are thus determined by the regional climate of the Barents Sea. Preconditioning is also important to dense water variability on the northern banks, and can be related to local ice melt (Great Bank) and properties of the Novaya Zemlya Coastal Current (Novaya Zemlya Bank). The dense water mainly exits the Barents Sea between Frans Josef Land and Novaya Zemlya, where it constitutes 63% (1.2 Sv) of the net outflow and has an average density of 1028.07 kg m−3. An amount of 0.4 Sv enters the Arctic Ocean between Svalbard and Frans Josef Land. Covering 9% of the ocean area, the banks contribute with approximately 1/3 of the exported dense water. Formation on the banks is more important when the Barents Sea is in a cold state (less Atlantic Water inflow, more sea-ice). During warm periods with high throughflow more dense water is produced broadly over the shelf by general cooling of the northward flowing Atlantic Water. However, our results indicate that during extremely warm periods (1950s and late 2000s) the total export of dense water to the Arctic Ocean becomes strongly reduced.  相似文献   

10.
Although the circulation of intermediate water masses in the eastern North Atlantic remains poorly defined, the presence of fresher intermediate waters, the Sub-Artic (SAIW) and the Antarctic Intermediate Water (AAIW), as well the saline intermediate Mediterranean Water (MW), has been tracked using biogeochemical properties. Here we assess the hydrographic and chemical structures of intermediate waters along the western Portuguese margin by examining the vertical distributions and property-property plots of chemical tracers (oxygen and nutrients). AAIW was traced by low oxygen and high nutrients, while SAIW was recognized by low nutrients. The Mediterranean Water (MW) undercurrent is shown to spread towards the eastern flank of Gorringe bank. Concurrently, the fresher waters gained salt by direct incorporation of MW, while this water was enriched in nutrients on its way northward and westward owing, to a great extent, to the entrainment of an AAIW branch. The distributions of nutrients and apparent oxygen utilization are discussed in terms of regional ocean circulation. Our analysis suggests a circulation pattern of the various intermediate waters along the western Portuguese margin: MW extends all over the area, but its presence is more pronounced around cape St. Vincent; SAIW apparently moves southward, reaching the Gorringe bank region, and AAIW flows northward along the coast and around the bank.  相似文献   

11.
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12.
High resolution seafloor images in the Gulf of Cadiz, Iberian margin   总被引：1，自引：0，他引：1  
In the Gulf of Cadiz, the hydrodynamic process acting on particle transport and deposition is a strong density-driven bottom current caused by the outflow of the saline deep Mediterranean water at the Strait of Gibraltar: the Mediterranean Outflow Water (MOW). New high resolution acoustic data including EM300 multibeam echo-sounder, deep-towed acoustic system SAR and very high resolution seismic, completed by piston cores collected during the CADISAR cruise allow to improve the understanding of the hydrodynamics of the MOW in the eastern part of the Gulf of Cadiz. Interpretation of data corrects the previous model established in this area and allows, for the first time, the accurate characterization of various bedforms and erosive structures along the MOW pathway and the precise identification of numerous gravity instabilities. The interaction between the MOW, the seafloor morphology and the Coriolis force is presently the driving force of the sedimentary distribution pattern observed on the Gulf of Cadiz continental slope.  相似文献   

13.
The winter water mass distributions in the western Gulf of Mexico, affected by the collision of a Loop Current anticyclonic ring, during January 1984 are analyzed. Two principal modes of Gulf Common Water (GCW) formation, arising from the dilution of the Caribbean Subtropical Underwater (SUW), are identified. Within the western gulf continental slope to the east of Tamiahua, the GCW is formed by the collision of anticyclonic rings. During these collision events, the SUW, entrapped at the core (200 m depth) of these features, is diluted by low salinity (36.1S36.3) water from the uppermost layer of the main thermocline. The end product of this mixture is GCW, which is further diluted by low salinity coastal water within the western gulf continental shelf. The second GCW formation mode is associated to the northerly wind stress which propagates over the western gulf during winter. During January, 1984, this wind stress gave rise to a 175 m mixed layer. This convective mixing destroyed the static stability of the summer thermocline and allowed for the partial dilution of the SUW with low salinity (S36.3) water from the western gulf continental shelf. Within the western gulf's upper 2000 m, the following water masses were identified to be present: GCW, SUW, Tropical Atlantic Central Water and associated dissolved oxygen minimum stratum, Antarctic Intermediate Water remnant, a mixture of the Caribbean Intermediate Water and the upper portion of North Atlantic Deep Water (NADW), and the NADW itself. The topographic distribution of these water masses' strata was dictated by the cyclonic-anticyclonic baroclinic circulation that evolved from the anticyclone's collision to the east of Tamiahua. Between the cyclonic and anticyclonic domains, the maximum pressure differential of these water masses' core occurrences was 150 to 280 dbar. The topographic transition zone defined by these strata occurred between the cyclonic and anticyclonic domains and coincided unambiguously with the anticyclone's collision zone. Within the continental shelf, we identified low temperature (12°C) and low salinity (31) coastal waters contributed by river runoff. Driven by the northerly wind stress, these coastal waters were advected toward the south hugging the coastline. The coastal and continental shelf waters demarcated a sea surface temperature, salinity, and dissolved oxygen discontinuity region that coincided with the horizontal baroclinic flow transition zone associated to the anticyclone's collision.  相似文献   

14.
Recently obtained World Ocean Circulation Experiment (WOCE) sections combined with a specially prepared pre-WOCE South Atlantic data set are used to study the dianeutral (across neutral surface) mixing and transport achieving Antarctic Intermediate Water (AAIW) being transformed to be part of the North Atlantic Deep Water (NADW) return cell. Five neutral surfaces are mapped, encompassing the AAIW from 700 to 1100 db at the subtropical latitudes.Coherent and significant dianeutral upwelling is found in the western boundary near the Brazil coast north of the separation point (about 25°S) between the anticyclonic subtropical and cyclonic south equatorial gyres. The magnitude of dianeutral upwelling transport is 10-3 Sv (1 Sv=106 m3 s-1) for 1°×1° square area. It is found that the AAIW sources from the southwestern South Atlantic and southwestern Indian Ocean do not rise significantly into the Benguela Current. Instead, they contribute to the NADW return formation by dianeutral upwelling into the South Equatorial Current. In other words, the AAIW sources cannot obtain enough heat/buoyancy to rise until they return to the western boundary region but north of the separation point. The basin-wide integration of dianeutral transport shows net upward transports, ranging from 0.25 to 0.6 Sv, across the lower and upper boundary of AAIW north of 40°S. This suggests that the equatorward AAIW is a slow rising water on a basin average. Given one order of uncertainty in evaluating the along-neutral-surface and dianeutral diffusivities from the assumed values, K=103 m2 s-1 and D=10-5 m2 s-1, the integrated dianeutral transport has an error band of about 10–20%. The relatively weak integrated dianeutral upwelling transport compared with AAIW in other oceans implies much stronger lateral advection of AAIW in the South Atlantic.Mapped Turner Angle in diagnosing the double-diffusion processes shows that the salty Central Water can flux salt down to the upper half of AAIW layer through salt-fingering. Therefore, the northward transition of AAIW can gain salt either through along-neutral-surface advection and diffusion or through salt fingering from the Central Water and heat through either along-neutral-surface advection and diffusion or dianeutral upwelling. Cabbeling and thermobaricity are found significant in the Antarctic frontal zone and contribute to dianeutral downwelling with velocity as high as −1.5×10-7 m s-1. A schematic AAIW circulation in the South Atlantic suggests that dianeutral mixing plays an essential role in transforming AAIW into NADW return formation.  相似文献   

15.
Transient tracer data (tritium, CFC11 and CFC12) from the southern, central and northwestern Weddell Sea collected during Polarstern cruises ANT III-3, ANT V-2/3/4 and during Andenes cruise NARE 85 are presented and discussed in the context of hydrographic observations. A kinematic, time-dependent, multi-box model is used to estimate mean residence times and formation rates of several water masses observed in the Weddell Sea.Ice Shelf Water is marked by higher tritium and lower CFC concentrations compared to surface waters. The tracer signature of Ice Shelf Water can only be explained by assuming that its source water mass, Western Shelf Water, has characteristics different from those of surface waters. Using the transient nature of tritium and the CFCs, the mean residence time of Western Shelf Water on the shelf is estimated to be approximately 5 years. Ice Shelf Water is renewed on a time scale of about 14 years from Western Shelf Water by interaction of this water mass with glacial ice underneath the Filchner-Ronne Ice shelf. The Ice Shelf Water signature can be traced across the sill of the Filchner Depression and down the continental slope of the southern Weddell Sea. On the continental slope, new Weddell Sea Bottom Water is formed by entrainment of Weddell Deep Water and Weddell Sea Deep Water into the Ice Shelf Water plume. In the northwestern Weddell Sea, new Weddell Sea Bottom Water is observed in two narrow, deep boundary currents flowing along the base of the continental slope. Classically defined Weddell Sea Bottom Water (θ ≤ −0.7°C) and Weddell Sea Deep Water (−0.7°C ≤ θ ≤ 0°C) are ventilated from the deeper of these boundary currents by lateral spreading and mixing. Model-based estimates yield a total formation rate of 3.5Sv for new Weddell Sea Bottom Water (θ = −1.0°C) and a formation rate of at least 11Sv for Antarctic Bottom Water (θ = −0.5°C).  相似文献   

16.
Processes relating to the formation of dense shelf water and intermediate water in the Okhotsk Sea were studied by examining oxygen isotope ratios (δ18O), salinity, and temperature. The salinity and δ18O of the cold dense shelf water on the northern continental shelf showed peculiar relationship. The relationship indicates that 3% of the mixed-layer water, having salinity of 32.6, froze and the remaining 97% became dense shelf water of salinities of more than 33.2 (σθ>26.7) during the sea ice formation. The salinity–δ18O relationship also shows that 20% of the Okhotsk Sea Intermediate Water at the σθ=26.8 level was derived from the dense shelf water. The remaining 80% came from the Western Subarctic Pacific water modified by diapycnal mixing of water affected by the surface cooling and freshening within the Okhotsk Sea. The mixing with dense shelf water contributes to only 26% of the temperature difference or 8% of the salinity difference between the original Pacific water and the Okhotsk Sea Intermediate Water at σθ=26.8. This result suggests that the cold and less saline properties of the Okhotsk Sea Intermediate Water are produced mainly by diapycnal mixing, rather than by mixing of the Pacific water with the dense shelf water.  相似文献   

17.
Dissolved Fe, Mn and Al concentrations (dFe, dMn and dAl hereafter) in surface waters and the water column of the Northeast Atlantic and the European continental shelf are reported. Following an episode of enhanced Saharan dust inputs over the Northeast Atlantic Ocean prior and during the cruise in March 1998, surface concentrations were enhanced up to 4 nmol L− 1 dFe, 3 nmol L− 1 dMn and 40 nmol L− 1 dAl and returned to 0.6 nmol L− 1 dFe, 0.5 nmol L− 1 dMn and 10 nmol L− 1 dAl towards the end of the cruise three weeks later. A simple steady state model (MADCOW, [Measures, C.I., Brown, E.T., 1996. Estimating dust input to the Atlantic Ocean using surface water aluminium concentrations. In: Guerzoni. S. and Chester. R. (Eds.), The impact of desert dust across the Mediterranean, Kluwer Academic Publishers, The Netherlands, pp. 301–311.]) was used which relies on surface ocean dAl as a proxy for atmospheric deposition of mineral dust. We estimated dust input at 1.8 g m− 2 yr− 1 (range 1.0–2.9 g m− 2 yr− 1) and fluxes of dFe, dMn and dAl were inferred. Mixed layer steady state residence times for dissolved metals were estimated at 1.3 yr for dFe (range 0.3–2.9 yr) and 1.9 yr for dMn (range 1.0–3.8 yr). The dFe residence time may have been overestimated and it is shown that 0.2–0.4 yr is probably more realistic. Using vertical dFe versus Apparent Oxygen Utilization (AOU) relationships as well as a biogeochemical two end member mixing model, regenerative Fe:C ratios were estimated respectively to be 20 ± 6 and 22 ± 5 μmol Fe:mol C. Combining the atmospheric flux of dFe to the upper water column with the latter Fe:C ratio, a ‘new iron’ supported primary productivity of only 15% (range 7%–56%) was deduced. This would imply that 85% (range 44–93%) of primary productivity could be supported by regenerated dFe. The open ocean surface data suggest that the continental shelf is probably not a major source of dissolved metals to the surface of the adjacent open ocean. Continental shelf concentrations of dMn, dFe, and to a lesser extent dAl, were well correlated with salinity and express mixing of a fresher continental end member with Atlantic Ocean water flowing onto the shelf. This means probably that diffusive benthic fluxes did not play a major role at the time of the cruise.  相似文献   

18.
In order to identify the major sources of trace metals (TM) in the Portuguese coastal waters, 58 surface water samples were collected during September 1988. The area sampled extended from the Tagus Estuary (down to a salinity of 25) to cape Ste Marie on the southern coast of Portugal. Dissolved metal concentrations in the fully marine waters ranged from 30 to 250 pM for Cd, 0.7–15 nM for Cu, 0.9–20 nM for Zn and 1.8–4.5 nM for Ni. Within the Tagus Estuary (salinity 25), concentrations increased to 3400 pM for Cd, 26 nM for Cu, 14 nM for Ni and 230 nM for Zn.The large-scale distribution of these metals is dominated by two strong continental sources, both probably linked to the exploitation of pyrite ores. In the Tagus Estuary, TM enrichments can be mostly attributed to a pyrite roasting plant located on the shore in front of Lisbon. Concerning the south Portuguese shelf waters, several hypotheses are proposed to explain their elevated metal concentrations. We particularly discussed the likely influence of the Tinto/Odiel rivers located 100 km eastward, an influence well known in the shelf waters of the Gulf of Cadiz. These rivers are extremely metal-rich because of acid mine tailings originating from their catchment. Between these two regions, upwelling of relatively metal-poor water largely contributes to the dilution of the continental inputs. Indeed, water exchanges on the shelf linked to the upwelling involve water fluxes 500 times higher than the Tagus River flow, and renew the coastal waters that are thus cleaned from terrestrial contamination. Contrary to many other upwelling systems in non-contaminated areas, the Portuguese upwelling does not act as a source of trace-metal enrichment of the continental margin waters.  相似文献   

19.
The intermediate water masses in the eastern Atlantic Ocean between 31°N and 53°N were studied by analysis of the distributions of potential temperature, salinity, dissolved nutrients and oxygen. Sub-surface salinity minima are encountered everywhere in the area. At the northern and southern boundary they are connected with the presence of Sub-Arctic Intermediate Water and Antarctic Intermediate Water, respectively, but towards the European ocean margin the sub-surface salinity minima shift to shallower density levels. The sub-surface salinity minima observed west of the Iberian Peninsula represent a water mass formed by winter convection in the Porcupine Sea Bight and the northern Bay of Biscay. These minima gain salt by diapycnal mixing with the underlying Mediterranean Sea Outflow water and with the overlying permanent thermocline. The core of Antarctic Intermediate Water appears to contribute to the formation of Mediterranean Sea Outflow Water since it becomes entrained into the overflow near Gibraltar. This entrainment gives rise to an enhanced concentration of the nutrients in the Mediterranean water in the North Atlantic. The deep salinity minimum, due to the presence of Labrador Sea Water, is restricted mainly to the Porcupine Abyssal Plain. In the Bay of Biscay this water type is strongly modified by enhanced diapycnal mixing near the continental slope. At all intermediate levels the continental slope in the Bay of Biscay seems to be a focal point for water mass modification by diapycnal mixing. Below the core of the Mediterranean Sea Outflow Water the Labrador Sea Water is also strongly modified. Its salinity is strongly enhanced by diapycnal mixing with the overlying core of Mediterranean Sea Outflow Water. An analysis of the oxygen and nutrient data indicates that the large spatial concentration differences at the level of the Labrador Sea Water are caused mainly by ageing of the water. The youngest water is observed at 52°N, and, especially in the Bay of Biscay and off south-west Portugal, the water at levels of about 1700 dbar are strongly enriched in nutrients and depleted in oxygen.  相似文献   

20.
利用Argo资料和《世界海洋数据集2001版》(WOD01)温盐历史资料,通过对代表性等位势面上盐度分布的分析,探讨了次表层和中层等不同层次上印尼贯通流(ITF)的起源与路径问题.分析结果表明,ITF的次表层水源主要来自北太平洋,中层水源地既包括北太平洋、南太平洋,同时也不能排除有印度洋的可能性.在印度尼西亚海域西部,ITF的次表层和中层水源分别为北太平洋热带水(NPTW)和中层水(NPIW),经苏拉威西海、望加锡海峡到达弗洛勒斯海,层次越深特征越明显.在印度尼西亚海域东部,发现哈马黑拉-新几内亚水道附近存在次表层强盐度锋面,阻隔了南太平洋热带水(SPTW)由此进入ITF海域;中层水具有高于NPIW和来自南太平洋的南极中层水(AAIW)的盐度值,既可能是AAIW和SPTW在当地发生剧烈垂直混合而形成,也可能是来自印度洋的AAIW向北延伸进入ITF的结果.  相似文献   

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