首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到10条相似文献,搜索用时 109 毫秒
1.
In order to test the hypothesis that the ambient iron concentrations could regulate sulfate reducing activity (SRA) in mangrove areas, 10 cm cores were examined from test and reference sites. The test site at Diwar mangrove ecosystem is highly influenced by iron released by the movement of barges carrying iron ore during the non-monsoon seasons and the reference site at Tuvem is relatively pristine. The average iron concentrations were 17.9% (±8.06) at Diwar and 6.3% (±1.5) at Tuvem. Sulfate reducing rates (SRR) ranged from 50.21 to 698.66 nM cm−3 d−1 at Tuvem, and from 23.32 to 294.49 nM cm−3d−1 in Diwar. Pearson’s correlation coefficients between SRR and environmental parameters showed that at Tuvem, the SRR was controlled by SO4−2 (r = 0.498, p < 0.001, n = 60) more than organic carbon (r = 0.316 p < 0.05, n = 60). At Diwar, the SRR was governed by the iron concentrations at an r-value of −0.761 (p < 0.001, n = 60), suggesting that ca.58% of the variation in SRR was influenced negatively by variations in ambient iron concentrations. This influence was more than the positive influence of TOC (r = 0.615, p < 0.001, n = 60). Laboratory experiments to check the influence of iron on SRR also supported our field observations. At an experimental manipulation of 50 ppm Fe3+ there was an increase in SRR but at 100 ppm an inhibitory effect was observed. At 1000 ppm Fe3+ there was a decrease in the SRR up to 93% of the control. Thus, our study showed that ambient iron concentrations influence SRR negatively at Diwar and counters the positive influence of organic carbon. Consequently, the influence could cascade to other biogeochemical processes in these mangrove swamps, especially the mineralization of organic matter to carbon dioxide by sulfate respiration.  相似文献   

2.
Nine surface sediments collected from Daya Bay have been Soxhlet-extracted with 2:1 (v/v) dichloromethane-methanol. The non-aromatic hydrocarbon (NAH) fraction of solvent extractable organic matter (EOM) and some bulk geochemical parameters have been analyzed to determine petroleum pollution of the bay. The NAH content varies from 32 to 276 μg g−1 (average 104 μg g−1) dry sediment and accounts for 5.8–64.1% (average 41.6%) of the EOM. n-Alkanes with carbon number ranging from 15 to 35 are identified to be derived from both biogenic and petrogenic sources in varying proportions. The contribution of marine authigenic input to the sedimentary n-alkanes is lower than the allochthonous input based on the average n-C31/n-C19 alkane ratio. 25.6–46.5% of the n-alkanes, with a mean of 35.6%, are contributed by vascular plant wax. Results of unresolved complex mixture, isoprenoid hydrocarbons, hopanes and steranes also suggest possible petroleum contamination. There is strong evidence of a common petroleum contamination source in the bay.  相似文献   

3.
GC and GC/MS/MS analysis on rock extracts has shown that the bitumen in the peralkaline Ilímaussaq intrusion, previously assumed to be abiogenic, is biotic in origin. A biotic origin is in accordance with previously published stable carbon isotopic data on bituminous matter in the rocks. The biomarker distribution in the bitumen, including the less common bicadinanes, resembles that of oil seeps on the central West Greenland coast 2200 km farther north, whose source rocks and migration history are relatively well established. We use a recent re-construction of the subsidence and later exhumation of the West Greenland coastal region during the Mesozoic-Cenozoic (Japsen et al., 2006a, b) to anticipate that hydrocarbons migrated from deeper parts of the basin offshore west of Greenland. The rocks of Ilímaussaq were probably more deeply invaded than the surrounding granites due to their higher proportion of corroded minerals, which may explain why bitumen has not been observed elsewhere in the area.Hydrocarbon gases (C1-C5) present in fluid inclusions were also analysed, after having been released by treatment with hydrochloric acid that resulted in an almost complete disintegration of the Ilímaussaq intrusion rocks. The acid extraction method proved generally more efficient than the crushing procedure applied by others, but gave similar results for the chemical composition of the gas (CH4: 88-97%) and isotopic ratios (δ13C4CH: −1.6 to −5.0‰; δ13CC2H6: −9.2 to −12.5‰), with the exception of hydrocarbons hosted in quartz, which showed significantly lower isotopic values for methane (Graser et al., 2008). Previous researchers have suggested an abiotic origin for these hydrocarbon gases, but we suggest a biotic origin for the majority of them, not just those in quartz, assuming that the isotopic ratio of the constituents have changed due to loss of gas by diffusion. The assumption of gas loss via diffusion is supported by published studies on micro-fissures in minerals typical of the Ilímaussaq and field investigations showing diffusive loss of gas from the peralkaline Khibina and Lovozero massifs on the Kola Peninsula, Russia, which are, in many respects of mineralogy and hydrocarbon content, similar to the Ilímaussaq intrusion.Both the hydrocarbon gases and bitumen in the Khibina and Lovozero massifs have been cited as prime examples of a deep mantle source, although the carbon isotopic ratio of the bitumen clearly pointed to an organic origin. The trends in carbon isotopic ratio of methane released with time from freshly exposed rocks also supports our hypothesis of 13C enrichment of the methane remaining within the rock. Thus, there is good evidence that the hydrocarbons in the Kola alkaline massifs are mostly biotic in origin, in which case the probability of finding economic hydrocarbon accumulations from a deep mantle source seems exceedingly small.  相似文献   

4.
Nutrient inputs associated with coastal population growth threaten the integrity of coastal ecosystems around the globe. In order to assess the threat posed by rapid growth in tourism, we analyzed the nutrient concentrations as well as the δ15N of NO3 and macrophytes to detect wastewater nitrogen (N) at 6 locations along a groundwater-dominated coastal seagrass bed on the Caribbean coast of Mexico. We predicted that locations with greater coastal development would have higher concentrations of dissolved inorganic nitrogen (DIN) and phosphorus (P), as well as δ15N of NO3, reflecting wastewater sources of N. However, concentrations of NO3 were not significantly different between developed (3.3 ± 5.3 μM NO3) and undeveloped (1.1 ± 0.7 μM) marine embayments. The most important control on DIN concentration appeared to be mixing of fresh and salt water, with DIN concentrations negatively correlated with salinity. The δ15N of NO3 was elevated at an inland pond (7.0 ± 0.42‰) and a hydrologically-connected tide pool (7.6 ± 0.57‰) approximately 1 km downstream of the pond. The elevated δ15N of NO3 at the pond was paralleled by high δ15N values of Cladophora sp., a ubiquitous green alga (10 ± 1‰). We hypothesize that inputs of nitrogen rich (NO3 > 30 μM) groundwater, characterized by 15N enriched signatures, flow through localized submarine groundwater discharges (SGD) and contribute to the elevated δ15N signatures observed in many benthic macrophytes. However, changes in nitrogen concentrations and isotope values over the salinity gradient suggest that other processes (e.g. denitrification) could also be contributing to the 15N enrichments observed in primary producers. More measurements are needed to determine the relative importance of nitrogen transformation processes as a source of 15N to groundwaters; however, it is clear that continued inputs of anthropogenic N via SGD have the potential to severely impact ecologically and economically valuable seagrass meadows and coral reefs along the Caribbean coast of Mexico.  相似文献   

5.
In order to estimate submarine groundwater discharge (SGD) and SGD-driven nutrient fluxes, we measured the concentrations of nutrients, 224Ra, and 226Ra in seawater, river water, and coastal groundwater of Yeongil Bay (in the southeastern coast of Korea) in August 2004 and February 2005. The bottom sediments over the shallow areas of this bay are composed mainly of coarse sands. Large excess concentrations of 224Ra, 226Ra, and Si supplied from SGD were observed in August 2004, while these excess concentrations were not apparent in February 2005. Based on the mass balance for 224Ra, 226Ra, and Si, which showed conservative mixing behavior in seawater, SGD was estimated to be approximately 6 × 106 m3 day− 1 (seepage rate = 0.2 m day− 1) in shallow areas (< 9 m water depth) in August 2004, which is much higher than the SGD level typically found in other coastal regions worldwide. During the summer period, SGD-driven nutrients in this bay contributed approximately 98%, 12%, and 76% of the total inputs for dissolved inorganic nitrogen (DIN), phosphorus (DIP), and silicate (DSi), respectively. Our study implies that the ecosystem in this highly permeable bed coastal zone is influenced strongly by SGD during summer, while such influences are negligible in winter.  相似文献   

6.
The coast of Jiangsu Province in China – where Ulva prolifera has always been firstly spotted before developing into green tides – is uniquely characterized by a huge intertidal radial mudflat. Results showed that: (1) propagules of U. prolifera have been consistently present in seawater and sediments of this mudflat and varied with locations and seasons; (2) over 50,000 tons of fermented chicken manure have been applied annually from March to May in coastal animal aquaculture ponds and thereafter the waste water has been discharged into the radial mudflat intensifying eutrophication; and (3) free-floating U. prolifera could be stranded in any floating infrastructures in coastal waters including large scale Porphyra farming rafts. For a truly integrated management of the coastal zone, reduction in nutrient inputs, and control of the effluents of the coastal pond systems, are needed to control eutrophication and prevent green tides in the future.  相似文献   

7.
The Arcachon lagoon is a 156 km2 temperate mesotidal lagoon dominated by tidal flats (66% of the surface area). The methane (CH4) sources, sinks and fluxes were estimated from water and pore water concentrations, from chamber flux measurements at the sediment–air (low tide), sediment–water and water–air (high tide) interfaces, and from potential oxidation and production rate measurements in sediments. CH4 concentrations in waters were maximal (500–1000 nmol l−1) in river waters and in tidal creeks at low tide, and minimal in the lagoon at high tide (<50 nmol l−1). The major CH4 sources are continental waters and the tidal pumping of sediment pore waters at low tide. Methanogenesis occurred in the tidal flat sediments, in which pore water concentrations were relatively high (2.5–8.0 μmol l−1). Nevertheless, the sediment was a minor CH4 source for the water column and the atmosphere because of a high degree of anaerobic and aerobic CH4 oxidation in sediments. Atmospheric CH4 fluxes at high and low tide were low compared to freshwater wetlands. Temperate tidal lagoons appear to be very minor contributor of CH4 to global atmosphere and to open ocean.  相似文献   

8.
Measurements were made of chlorophyll-a and phaeophytin-a in calcareous sediments along transects off the east coast of Florida (75–190 m) and the west coast of Grand Bahama Island (170–300 m). Solvent partitioning showed that chlorophyll-a concentrations never exceeded 0·1 mg m?2 at either location, most as degradation products. Total pigment concentrations (chlorophyll and phaeopigments) ranged from 0·18–1·83 mg m?2 in sediments off Grand Bahama Island and 2·50 to 20·65 mg m?2 off West Palm Beach. Pigments, expressed per gram dry weight of sediments, increased with depth across the Florida Continental Shelf. This is probably due to differences in sediment character between near-shore and off-shore sediments.  相似文献   

9.
The Upper Cretaceous Mukalla coals and other organic-rich sediments which are widely exposed in the Jiza-Qamar Basin and believed to be a major source rocks, were analysed using organic geochemistry and petrology. The total organic carbon (TOC) contents of the Mukalla source rocks range from 0.72 to 79.90% with an average TOC value of 21.50%. The coals and coaly shale sediments are relatively higher in organic richness, consistent with source rocks generative potential. The samples analysed have vitrinite reflectance in the range of 0.84–1.10 %Ro and pyrolysis Tmax in the range of 432–454 °C indicate that the Mukalla source rocks contain mature to late mature organic matter. Good oil-generating potential is anticipated from the coals and coaly shale sediments with high hydrogen indices (250–449 mg HC/g TOC). This is supported by their significant amounts of oil-liptinite macerals are present in these coals and coaly shale sediments and Py-GC (S2) pyrograms with n-alkane/alkene doublets extending beyond nC30. The shales are dominated by Type III kerogen (HI < 200 mg HC/g TOC), and are thus considered to be gas-prone.One-dimensional basin modelling was performed to analysis the hydrocarbon generation and expulsion history of the Mukalla source rocks in the Jiza-Qamar Basin based on the reconstruction of the burial/thermal maturity histories in order to improve our understanding of the of hydrocarbon generation potential of the Mukalla source rocks. Calibration of the model with measured vitrinite reflectance (Ro) and borehole temperature data indicates that the present-day heat flow in the Jiza-Qamar Basin varies from 45.0 mW/m2 to 70.0 mW/m2 and the paleo-heat flow increased from 80 Ma to 25 Ma, reached a peak heat-flow values of approximately 70.0 mW/m2 at 25 Ma and then decreased exponentially from 25 Ma to present-day. The peak paleo-heat flow is explained by the Gulf of Aden and Red Sea Tertiary rifting during Oligocene-Middle Miocene, which has a considerable influence on the thermal maturity of the Mukalla source rocks. The source rocks of the Mukalla Formation are presently in a stage of oil and condensate generation with maturity from 0.50% to 1.10% Ro. Oil generation (0.5% Ro) in the Mukalla source rocks began from about 61 Ma to 54 Ma and the peak hydrocarbon generation (1.0% Ro) occurred approximately from 25 Ma to 20 Ma. The modelled hydrocarbon expulsion evolution suggested that the timing of hydrocarbon expulsion from the Mukalla source rocks began from 15 Ma to present-day.  相似文献   

10.
Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L−1), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L−1, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m−2 d−1 in the hypoxic western LSLE to 100 μmol m−2 d−1 in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m−2 d−1, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 106 t N, yielding an almost balanced N budget for the SL marine system.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号