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1.
The Fula Sub-basin of the Muglad Basin of southern Sudan is an active-fault bounded basin with an area of approximately 3300 km2. The Lower Cretaceous Abu Gabra Formation formed during the first of three rifting cycles. It can be subdivided into five 3rd-order sequences named SQA∼SQE from bottom to top, indicating five stages of tectonostratigraphy and tectonosedimentary evolution. The spatial distribution and temporal evolution of clastic depositional systems are described in this paper based on integrated analysis of seismic, core and well logging data. In the Abu Gabra Formation of the Fula Sub-basin, a variety of depositional systems are recognized, namely, fan delta, braided delta, delta, sublacustrine fan and lacustrine system. The Fula Sub-basin has undergone a complex and phased rifting evolution, and a high abundance of transfer zones developed, causing the resulting distribution and architecture of both the sequence and depositional system to be controlled by various types of transfer zones. The following three types of sequence architectures from northern to southern part of the Fula Sub-basin have been identified: simple dustpan-shaped sequence architecture in the north, transfer-zone sequence stratigraphic architecture in the middle and graben-shaped sequence architecture in the south. The sequence architecture is under the control of the large-scale central transfer zone, and nine models are built to study the effect of at least three categories of small-scale transfer zones on the depositional systems in the Fula Sub-basin. The small-scale transfer zones play significant roles in basin fill, primarily in controlling of the positions of deposit-input points. This study provides valuable insights into tectonic control of depositional systems and sequence architectures in a continental rift basin such as the Fula Sub-basin. 相似文献
2.
Cretaceous sedimentary rocks of the Mukalla, Harshiyat and Qishn formations from three wells in the Jiza sub-basin were studied to describe source rock characteristics, providing information on organic matter type, paleoenvironment of deposition and hydrocarbon generation potential. This study is based on organic geochemical and petrographic analyses performed on cuttings samples. The results were then incorporated into basin models in order to understand the burial and thermal histories and timing of hydrocarbon generation and expulsion.The bulk geochemical results show that the Cretaceous rocks are highly variable with respect to their genetic petroleum generation potential. The total organic carbon (TOC) contents and petroleum potential yield (S1 + S2) of the Cretaceous source rocks range from 0.43 to 6.11% and 0.58–31.14 mg HC/g rock, respectively indicating non-source to very good source rock potential. Hydrogen index values for the Early to Late Cretaceous Harshiyat and Qishn formations vary between 77 and 695 mg HC/g TOC, consistent with Type I/II, II-III and III kerogens, indicating oil and gas generation potential. In contrast, the Late Cretaceous Mukalla Formation is dominated by Type III kerogen (HI < 200 mg HC/g TOC), and is thus considered to be gas-prone. The analysed Cretaceous source rock samples have vitrinite reflectance values in the range of 0.37–0.95 Ro% (immature to peak-maturity for oil generation).A variety of biomarkers including n-alkanes, regular isoprenoids, terpanes and steranes suggest that the Cretaceous source rocks were deposited in marine to deltaic environments. The biomarkers also indicate that the Cretaceous source rocks contain a mixture of aquatic organic matter (planktonic/bacterial) and terrigenous organic matter, with increasing terrigenous influence in the Late Cretaceous (Mukalla Formation).The burial and thermal history models indicate that the Mukalla and Harshiyat formations are immature to early mature. The models also indicate that the onset of oil-generation in the Qishn source rock began during the Late Cretaceous at 83 Ma and peak-oil generation was reached during the Late Cretaceous to Miocene (65–21 Ma). The modeled hydrocarbon expulsion evolution suggests that the timing of oil expulsion from the Qishn source rock began during the Miocene (>21 Ma) and persisted to present-day. Therefore, the Qishn Formation can act as an effective oil-source but only limited quantities of oil can be expected to have been generated and expelled in the Jiza sub-basin. 相似文献
3.
Digital outcrop models help to constrain the interactions of stratigraphic and structural heterogeneity on ancient depositional systems. This study uses a stochastic approach that incorporates stratigraphic and structural modeling to interrogate the three-dimensional morphology of deep-water channel strata outcropping on Sierra del Toro in the Magallanes Basin of Chile. This approach considers the relative contributions, and associated uncertainty, of erosional downcutting versus post-depositional structural folding and small-offset faulting on the present-day configuration of the submarine channel complexes. Paleodepositional channel-belt gradients were modeled using a combination of three-dimensional visualization, stochastic surface modeling, palinspastic restoration, and decompaction modeling that are bound with errors constrained by stratigraphic and structural uncertainty. Modeling results indicate that at least 100 m of downcutting occurs over 6 km, and the resultant thalweg gradient of 64–125 m/km (decompacted) suggests that the Cerro Toro axial channel belt is an out-of-grade depositional system. Furthermore, the presence of steeper segments (100–175 m/km decompacted) suggests the preservation of one or more knickpoints that are similar in magnitude to tectonically-induced knickpoints on the modern seafloor. The interpreted knickpoints are correlated with a decreasing channel width-depth ratio and an increase of channel depth. These results indicate that stochastic surface modeling using digital outcrop models can constrain stratigraphic interpretations and post-depositional structural heterogeneity. 相似文献
4.
Asphaltites, long known to strand along the coastline of southern Australia and as distantly as New Zealand and Macquarie Island, are widely regarded as artefacts of submarine oil seepage. Their remarkably uniform composition suggests a common source: marine shale containing sulphur-rich Type II kerogen, probably deposited during an Early Cretaceous oceanic anoxic event (OAE). Suitable hydrocarbon kitchens may exist in the offshore Bight and Otway basins. The physical character of the asphaltites, including laminations and flow structures, and their degree of alteration, which is not the result of biodegradation or extensive water washing, suggest an origin from subsurface tar mats subsequently exposed by the incision of submarine canyons, with the possible formation of asphaltic volcanoes. API gravities of 4–18° impart quasi-neutral buoyancy, implying many asphaltites were submerged drifters prior to stranding, their degree of weathering reflecting, at least in part, the residence time in the marine environment. For any individual asphaltite specimen, this will depend on the proximity of the seafloor seep to the stranding site, an important consideration when attempting to locate their point of origin.This study investigates the hydrocarbon biomarker signatures and n-alkane δ13C profiles of asphaltite specimens from stranding sites on the Eyre Peninsula (n = 2), Kangaroo Island (n = 4) and the Limestone Coast (n = 3), South Australia, and the south island of New Zealand (n = 2). Sub-samples of the interior and weathered surface of each specimen were analysed. No distinction could be made between strandings based on their source-dependent molecular and isotopic signatures, confirming their common origin. Comparison of the interior and exterior sub-samples revealed subtle although consistent differences. Given their degree of degradation and isotopic variance, these Australasian asphaltites seem to be products of low intensity seeps in the Ceduna Sub-basin of the Bight Basin and/or Morum Sub-basin of the Otway Basin. 相似文献
5.
Structural analysis of the Indian Merge 3D seismic survey identified three populations of normal faults within the Exmouth Sub-basin of the North West Shelf volcanic margin of Australia. They comprise (1) latest-Triassic to Middle Jurassic N-NNE-trending normal faults (Fault Population I); (2) Late Jurassic to Early Cretaceous NE-trending normal faults (Fault Population II); and (3) latest-Triassic to Early Cretaceous N-NNE faults (Fault Population III). Quantitative evaluation of >100 faults demonstrates that fault displacement occurred during two time periods (210–163 and 145–138 Ma) separated by ∼20 Myr of tectonic quiescence. Latest Jurassic to Early Cretaceous (145–138 Ma) evolution comprises magmatic addition and contemporaneous domal uplift ∼70 km wide characterised by ≥ 900 m of denudation. The areally restricted subcircular uplift centred on the southern edge of the extended continental promontory of the southern Exmouth Sub-basin supports latest Jurassic mantle plume upwelling that initiated progradation of the Barrow Delta. This polyphase and bimodal structural evolution impacts current hydrocarbon exploration rationale by defining the nature of latest Jurassic to Early Cretaceous fault nucleation and reactivation within the southern Exmouth Sub-basin. 相似文献
6.
The southern Makran fold-thrust belt, Pakistan, displays unique outcrop examples of well-exposed, kilometre-scale, listric growth faults that displace Miocene-age deltaic growth strata by several hundreds of metres to kilometers. The largest growth faults are counter-regional (landward-dipping), bounding major clastic depocentres exposed over areas > 1000 km2. Stratal offset along these faults can exceed 1.5 km. Fault-zone thicknesses range between ca. 100 and 400 m, and average fault thickness-displacement ratios are around 1:10. High-resolution satellite data show in unprecedented detail the faults and the stratigraphic architecture of associated growth sequences, which comprise kilometre-scale progradational clinoforms, thick mudstone units and basinwards wedging sandstone-shale deposits. The true vertical thickness of the syn-kinematic record is, in places, up to 8 km, making the outcrop examples equivalent to major growth faulted successions known from seismic data of large deltas, and at least an order of magnitude larger than other outcrop examples. A comparison of the Makran outcrops with seismic-reflection examples offshore NW Borneo reveals distinct similarities in the gross depocentre geometries and internal architecture. The key control for growth faulting is interpreted to result from sedimentary loading, with rapid sedimentary progradation causing the development of rollover synclines by differential compaction and fluid expulsion, and counter-regional growth faults preferentially forming on the basinward side of these synclines. The data and interpretations presented can be used to assess the key parameters that contribute to the development of growth faults and growth successions above shale, reinforcing structural and stratigraphic observations from seismic interpretation and modelling studies in demonstrating their occurrence in exposure. 相似文献
7.
Chun-Feng Li Zuyi Zhou Jiabiao Li Bing Chen Jianhua Geng 《Marine Geophysical Researches》2008,29(4):223-238
We made a systematic investigation on major structures and tectonic units in the South China Sea basin based on a large magnetic
and seismic data set. For enhanced magnetic data interpretation, we carried out various data reduction procedures, including
upward continuation, reduction to the pole, 3D analytic signal and power spectrum analyses, and magnetic depth estimation.
Magnetic data suggest that the South China Sea basin can be divided into five magnetic zones, each with a unique magnetic
pattern. Zone A corresponds roughly to the area between Taiwan Island and a relict transform fault, zone B is roughly a circular
feature between the relict transform fault and the northwest sub-basin, and zones C, D, and E are the northwest sub-basin,
the east sub-basin, and the southwest sub-basin, respectively. This complexity in basement magnetization suggests that the
South China Sea evolved from multiple stages of opening under different tectonic settings. Magnetic reduction also fosters
improved interpretation on continental margin structures, such as Mesozoic and Cenozoic sedimentary basins and the offshore
south China magnetic anomaly. We also present, for the first time, interpretations of three new 2D reflection seismic traverses,
which are of ~2,000 km in total length and across all five magnetic zones. Integration of magnetic and seismic data enables
us to gain a better 3D mapping on the basin structures. It is shown that the transition from the southwest sub-basin to the
east sub-basin is characterized by a major ridge formed probably along a pre-existing fracture zone, and by a group of primarily
west-dipping faults forming an exact magnetic boundary between zones D and E. The northwest sub-basin has the deepest basement
among the three main sub-basins (i.e., the northwest sub-basin, the southwest sub-basin, and the east sub-basin). Our seismic
data also reveal a strongly faulted continent–ocean transition zone of about 100 km wide, which may become wider and dominated
with magmatism or transit to an oceanic crust further to the northeast. 相似文献
8.
Sedimentary heterogeneities are ubiquitous in nature and occur over a range of scales from core, reservoir to basin scales. They may thus exert significant influences on hydrocarbon generation, migration and accumulation. The sedimentary heterogeneities of the Permian Shanxi Formation in the Ordos Basin, China were modelled using Sedsim, a stratigraphic forward modelling program. The simulation results were then used to construct a 3D petroleum system model using PetroMod. The effects of sedimentary heterogeneities on hydrocarbon accumulations were evaluated by comparing the integrated Sedsim-PetroMod model with the classic 3D basin model. The Sedsim simulation shows that considerable sedimentary heterogeneities are present within the Shanxi Formation, as a result of the interplay of the initial topography, tectonic subsidence, base level change and sediment inputs. A variety of lithologies were developed both laterally and vertically within the Shanxi Formation at kilometre and metre scales, respectively, with mudstones mainly developed in the depositional centre, while sandstones developed in the southern and northern margin areas. A typical source-ward retrogradation is well developed within the Lower Shanxi Formation.A base-case classic 3D basin model was constructed to quantify the Permian petroleum system in the Ordos Basin. The geological and thermal models were calibrated using Vr and borehole temperature data. The source rocks of the Upper Paleozoic became mature (Ro > 0.5%) and high mature (Ro > 1.2%) in the late Triassic and late Jurassic, respectively, in the central and southern areas. During the Early Cretaceous, a tectonically induced geothermal event occurred in the southern Ordos Basin. This caused the source rocks to reach over maturity (Ro > 2.0%) quite rapidly in the early Late Cretaceous in the central and southern areas. All the source rock transformation ratios (TR) at present are greater than 70% in the P1 coal and P1 mudstone layers with TR values approaching 100% in the central and southern areas. The transformation ratios of the P1 limestone are close to 100% over the entire interval.In the base-case model, a large amount of hydrocarbons appear to have been expelled and migrated into the Shanxi Formation, but only a minor amount was accumulated to form reservoirs. In the model, the Shanxi Formation sandstone layer was set to be homogeneous vertically and there was no regional seal rocks present at the top of the Shanxi Formation. Therefore hydrocarbons could not be trapped effectively with only minor accumulations in some local structural highs where hydrocarbons are trapped both at the top and in the up-dip direction by the adjacent mudstone facies. In contrast, the integrated Sedsim-PetroMod model takes into account of the internal lithological and sedimentary facies heterogeneities within the Shanxi Formation, forming complex contiguous sandstone-mudstone stacking patterns. Hydrocarbons were found to have accumulated in multiple intervals of lithological traps within the Shanxi Formation. The results indicate that lithological distinctions, controlled by sedimentary heterogeneities in three dimensions can provide effective sealing in both the top and up-dip directions for hydrocarbon accumulations, with gas being mainly accumulated near the depocentre where lithological traps usually formed due to frequent oscillations of the lake level. 相似文献
9.
Mechanisms of petroleum accumulation in the Bozhong sub-basin, Bohai Bay Basin, China. Part 1: Origin and occurrence of crude oils 总被引：1，自引：0，他引：1
Fang Hao Xinhuai Zhou Yangming Zhu Huayao Zou Xiaohuan Bao Qingying Kong 《Marine and Petroleum Geology》2009,26(8):1528-1542
The origin of the fourteen major oil fields in the Bozhong sub-basin, Bohai Bay basin was studied based on the results of Rock-Eval pyrolysis on more than 700 samples and biomarker analysis on 61 source rock samples and 87 oil samples. The three possible source rock intervals have different biomarker assemblages and were deposited in different environments. The third member of the Oligocene Dongying Formation (E3d3, 32.8–30.3 Ma in age) is characterized mainly by high C19/C23 tricyclic terpane (>0.75), high C24 tetracyclic terpane/C26 tricyclic terpane (>2.5), low gammacerane/αβ C30 hopane (<0.15) and low 4-methyl steranes/ΣC29 steranes (<0.15) ratios, and was deposited in sub-oxic to anoxic environments with significant terrigenous organic matter input. The first (E2s1, 35.8–32.8 Ma) and third (E2s3, 43.0–38.0 Ma) members of the Eocene Shahejie Formation have low C19/C23 tricyclic terpane and low C24 tetracyclic terpane/C26 tricyclic terpane ratios and were deposited in anoxic environments with minor terrestrial organic matter input, but have different abundances of 4-methyl steranes and gammacerane. The hydrocarbon-generating potential and biomarker associations of these three source rock intervals were controlled by tectonic evolution of the sub-basin and climate changes. Three oil families derived from E2s3, E2s1 and E3d, respectively, and three types of mixed oils have been identified. All large oil fields in the Bozhong sub-basin display considerable heterogeneities in biomarker compositions and originated from more than one source rock interval, which suggests that mixing of oils derived from multiple source rock intervals or multiple generative kitchens, and/or focusing of oils originated from a large area of a generative kitchen, is essential for the formation of large oil fields in the Bozhong sub-basin. E2s3- and E2s1-derived oils experienced relatively long-distance lateral migration and accumulated in traps away from the generative kitchen. E3d3-derived oils had migrated short distances and accumulated in traps closer to the generative kitchen. Such a petroleum distribution pattern has important implications for future exploration. There is considerable exploration potential for Dongying-derived oils in the Bozhong sub-basin, and traps close to or within the generative kitchens have better chance to contain oils generated from the Dongying Formation. 相似文献
10.
Two petroleum source rock intervals of the Lower Cretaceous Abu Gabra Formation at six locations within the Fula Sub-basin, Muglad Basin, Sudan, were selected for comprehensive modelling of burial history, petroleum maturation and expulsion of the generated hydrocarbons throughout the Fula Sub-basin. Locations (of wells) selected include three in the deepest parts of the area (Keyi oilfield); and three at relatively shallow locations (Moga oilfield). The chosen wells were drilled to depths that penetrated a significant part of the geological section of interest, where samples were available for geochemical and source rock analysis. Vitrinite reflectances (Ro %) were measured to aid in calibrating the developed maturation models.The Abu Gabra Formation of the Muglad Basin is stratigraphically subdivided into three units (Abu Gabra-lower, Abu Gabra-middle and Abu Gabra-upper, from the oldest to youngest). The lower and upper Abu Gabra are believed to be the major source rocks in the province and generally contain more than 2.0 wt% TOC; thus indicating a very good to excellent hydrocarbon generative potential. They mainly contain Type I kerogen. Vitrinite reflectance values range from 0.59 to 0.76% Ro, indicating the oil window has just been reached. In general, the thermal maturity of the Abu Gabra source rocks is highest in the Abu Gabra-lower (deep western part) of the Keyi area and decreases to the east toward the Moga oilfied at the Fula Sub-basin.Maturity and hydrocarbon generation modelling indicates that, in the Abu Gabra-Lower, early oil generation began from the Middle- Late Cretaceous to late Paleocene time (82.0–58Ma). Main oil generation started about 58 Ma ago and continues until the present day. In the Abu Gabra-upper, oil generation began from the end of the Cretaceous to early Eocene time (66.0–52Ma). Only in one location (Keyi-N1 well) did the Abu Gabra-upper reach the main oil stage. Oil expulsion has occurred only from the Abu Gabra-lower unit at Keyi-N1 during the early Miocene (>50% transformation ratio TR) continuing to present-day (20.0–0.0 Ma). Neither unit has generated gas. Oil generation and expulsion from the Abu Gabra source rocks occurred after the deposition of seal rocks of the Aradeiba Formation. 相似文献
11.
Sufyan Sub-basin is an East-West trending Sub-basin located in the northwestern part of the Muglad Basin (Sudan), in the eastern extension of the West and Central Africa Rift System (WCARS). The trend of the Sufyan Sub-basin (E-W) is different from the general trend of Muglad Basin (NW-SE) and similar to Baggara basin in the west of Sudan and other basins in east Chad. The unique E-W trend, suggests that this Sub-basin originated by a mechanism different from Muglad Basin that is considered more extensional in origin. Five regional seismic lines are included to illustrate the structural and stratigraphic variation across the Sub-basin. Fault polygons maps for six horizons, four isopach maps, five cross-sections, and two associated kinematic models are presented in this study. Sufyan Sub-basin is characterized by rhombic geometry with three boundary faults; two of those faults exhibit dextral strike slip movement, with two depocenters at the western and eastern segments of the southern fault. Structural interpretation of Sufyan Sub-basin based on 2D seismic data highlights the style of strike-slip related structure. Negative flower structures, en-echelon faults, and rhombic geometry all suggest a significant component of a pull-apart transtensional movement in Sufyan Sub-basin. Other alternative scenarios for evolutionary history and the forming mechanism were introduced such as the oblique extension model. The Sufyan Sub-basin is believed to be highly affected by the Central African Shear Zone (CASZ). In this study, several transtension and oblique rift related features interpreted from Bouguer gravity map and seismic data are briefly described and illustrated. Based on this study, the favorable areas for hydrocarbon accumulation are the areas of flower structure and the areas that near to the two depocenters that controlled by the southern boundary fault. 相似文献
12.
Quantifying the geometries of evaporite deposits at a <1 km scale is critical in our understanding of similar ancient depositional systems, but is challenging given evaporite mineral dissolution at surface conditions. A high-resolution stratigraphic study of the basal Purbeck Beds in Brightling Mine, UK, provides insight into the three-dimensional architecture, lateral continuity and vertical heterogeneity within an evaporite seal. We conducted a field mapping study, combined with X-ray diffraction, petrographic microscopy, and δ13C and δ18O isotope analysis. The stratigraphic interval contains five facies. In stratigraphic order, these include supratidal porphyritic nodular evaporite, shallow subtidal peloidal packstone with evaporite and two overlying rhythmic sequences of intertidal microbial laminite, subtidal shale, and subtidal laminar marl, capped by nodular anhydrite. The interpreted environment of deposition is a supratidal sabkha subject to periodic flooding in which intertidal (tidal flat) facies and subtidal (shallow marine) facies laterally passed into the evaporative sabkha. The cycles are interpreted as meter-scale shoaling-upward sequences, likely controlled by localized high-frequency changes in relative sea level and/or sabkha hydrology. Spatial patterns in the geometries of key stratigraphic surfaces reveal a subtle depression towards the central western region of the mine seam. The variation in stratal geometries is interpreted as paleotopography and is a function of individual or composite processes related to dissolution, eolian processes, and coastal erosion. These observations indicate a similar mode of deposition to the modern-day sabkha of the Persian Gulf. We conclude that the dynamic process of evaporite deposition led to subtle stratigraphic heterogeneities and changes in bed thicknesses, but largely continuous lateral bedding at an interwell-scale. 相似文献
13.
B.W. Romans A. FildaniS.M. Hubbard J.A. CovaultJ.C. Fosdick S.A. Graham 《Marine and Petroleum Geology》2011,28(3):612-628
The ˜4000 m thick and ∼20 Myr deep-water sedimentary fill of the Upper Cretaceous Magallanes Basin was deposited in three major phases, each with contrasting stratigraphic architecture: (1) the oldest deep-water formation (Punta Barrosa Formation) comprises tabular to slightly lenticular packages of interbedded sandy turbidites, slurry-flow deposits, and siltstone that are interpreted to record lobe deposition in an unconfined to weakly ponded setting; (2) the overlying, 2500 m thick and shale-dominated Cerro Toro Formation includes a succession of stacked conglomeratic and sandstone channel-fill deposits with associated finer-grained overbank deposits interpreted to record deposition in a foredeep-axial channel-levee system; (3) the final phase of deep-water sedimentation is characterized by sandstone-rich successions of highly variable thickness and cross-sectional geometry and mudstone-rich mass transport deposits (MTDs) that are interpreted to record deposition at the base-of-slope and lower slope segments of a prograding delta-fed slope system. The deep-water formations are capped by shallow-marine and deltaic deposits of the Dorotea Formation.These architectural changes are associated with the combined influences of tectonically driven changes and intrinsic evolution, including: (1) the variability of amount and type of source material, (2) variations in basin shape through time, and (3) evolution of the fill as a function of prograding systems filling the deep-water accommodation. While the expression of these controls in the stratigraphic architecture of other deep-water successions might differ in detail, the controls themselves are common to all deep-water basins. Information about source material and basin shape is contained within the detrital record and, when integrated and analyzed within the context of stratigraphic patterns, attains a more robust linkage of processes to products than stratigraphic characterization alone. 相似文献
14.
June-Soo Park Olga Ioanna Kalantzi Dianne Kopec Myrto Petreas 《Marine environmental research》2009,67(3):129-135
Bioaccumulation of endocrine disruptors in marine mammals positioned at the top of the food chain is of toxicological concern. Livers from four pups and ten adult harbor seals (Phoca vitulina) stranded in San Francisco Bay (SFB) and the Gulf of Maine (GOM) were analyzed for polychlorinated biphenyls (PCBs) and their hydroxylated metabolites (OH-PCBs). We used GC–ECD and GC–NCI/MS to investigate the presence of 28 PCBs and 8 OH-PCB metabolites, respectively. Σ28PCB concentrations (di- to octa-CBs) ranged from 1.81 to 35.9 μg/g lipid with a median of 6.53 for the seal pups and 2.31 to 249 μg/g lipid with a median of 28.9 for the adult seals. Σ8OH-PCB concentrations (penta- to hepta-OH-PCBs) ranged from 0.02 to 0.69 μg/g lipid with a median of 0.04 for the adult seals, i.e., at much lower concentrations than those for PCBs. Ratios of OH-PCBs to PCBs (0.24% on average) were comparable to those in beluga whale, but were lower than ratios in human livers. The OH-PCB profiles were slightly different between SFB and GOM seal livers, although similar PCB congener patterns were observed. Generally, 4-OH-CB107 was found predominantly in seal livers and was the only OH-PCB detectable in most of seal pup livers. This study provides information on OH-PCBs in seals, adding to the scarce exposure data for these chemicals. 相似文献
15.
Central Luconia is a geological province of the Sarawak Basin, offshore NW Borneo, characterised by extensive development of Miocene to Recent carbonate build-ups. In the subsurface, many of these build-ups are reservoirs for hydrocarbons. This study focuses on shelf-wide stratigraphic architecture, from which implications are drawn for the stratigraphic-sealing potential of the deltaic clastics. A stratigraphic model is proposed whereby clastic sediments surrounding the carbonate build-ups are interpreted as stacked low-relief deltas deposited in response to high-frequency oscillation of the sea level. The deltas are shown to have frequently prograded beyond carbonate build-ups. As a result of interaction between eustacy and deposition, deltaic topsets are juxtaposed against carbonate build-ups, providing migration routes for hydrocarbons. Most of the carbonate reservoirs are consequently underfilled, with hydrocarbon columns limited to the youngest onlapping stratigraphic sequence. 相似文献
16.
Late Jurassic organic-rich shales from Shabwah sub-basin of western Yemen were analysed based on a combined investigations of organic geochemistry and petrology to define the origin, type of organic matter and the paleoenvironment conditions during deposition. The organic-rich shales have high total sulphur content values in the range of 1.49–4.92 wt. %, and excellent source rock potential is expected based on the high values of TOC (>7%), high extractable organic matter content and hydrocarbon yield exceeding 7000 ppm. The high total sulphur content and its relation with high organic carbon content indicate that the Late Jurassic organic-rich shales of the Shabwah sub-basin were deposited in a marine environment under suboxic-anoxic conditions. This has been evidenced from kerogen microscopy and their biomarker distributions. The kerogen microscopy investigation indicated that the Late Jurassic organic-rich shales contain an abundant liptinitic organic matter (i.e., alginite, structureless (amorphous organic matters)). The presence of alginite with morphology similar to the lamalginite alga and amorphous organic matter in these shale samples, further suggests a marine origin. The biomarker distributions also provide evidence for a major contribution by aquatic algae and microorganisms with a minor terrigenous organic matter input. The biomarkers are characterized by unimodal distribution of n-alkanes, low acyclic isoprenoids compared to normal alkanes, relatively high tricyclic terpanes compared to tetracyclic terpanes, and high proportion of C27 and C29 regular steranes compared to C28 regular sterane. Moreover, the suboxic to anoxic bottom water conditions as evidenced in these Late Jurassic shales is also supported based on relatively low pristane/phytane (Pr/Ph) ratios in the range of 0.80–1.14. Therefore, it is envisaged here that the high content of organic matter (TOC > 7 wt.%) in the analysed Late Jurassic shales is attributed to good organic matter (OM) preservation under suboxic to anoxic bottom water conditions during deposition. 相似文献
17.
Multiple stages of large-scale shelf sand ridges, including the shoreface-attached and the offshore types, have developed in the Miocene successions on the mid-shelf region of the Pear River Mouth Basin, northern South China Sea. Utilizing a high-quality 3D seismic data set, accompanying 2D seismic profiles and well logs, the morphology, architecture and genesis of these shelf sand ridges have been systematically investigated in this study. The ridges are of very large scale, with the largest one having a maximum height of 64 m, a width of more than 20 km and a length of 37 km within the 3D survey area. Being mound-shaped, they also display obvious asymmetry character, with the ridge crest preferentially located on the SE side. Three main internal components, including the ridge front, central ridge and the ridge tail, have been recognized through careful anatomy analysis of the two most well-imaged ridges, each displaying distinct expressions on seismic amplitudes and geometries. In the plan view, most of the shelf sand ridges are generally NE–SW oriented and widening to the SW direction. Scouring features can also be clearly observed along the SW direction, including scour depressions and linear sandy remnants. On well logs, the shelf sand ridges are represented by an overall coarsening-upward pattern. Intervals with blocky sandstones are preferentially present on higher locations due to a differential winnowing process controlled by shelf topography.Plenty of evidence indicates that these ridges were primarily formed by the reworking of forced regressive or lowstand deltaic deposits under a persistent southwesterly flowing current during the subsequent transgression. This very current is a composite one, which is speculated to consist of winter oceanic current, SCSBK (South China Sea Branch of Kuroshio) intrusion onto the shelf and internal waves propagating from the Luzon Strait. Tidal currents might have contributed to the SE growth of the ridge. In response to the reglaciation of Antarctic ice-sheet and the closure of Pacific-Indian ocean seaway in the middle Miocene, the intensification of the North Pacific western boundary current was considered to have potential links to the initiation of the shelf sand ridges at ∼12 Ma. The development of shelf ridges was terminated and replaced by rapid deltaic progradation at ∼5.5 Ma. 相似文献
18.
Patrick Ollivier Christelle Claude Olivier Radakovitch Bruno Hamelin 《Marine Chemistry》2008,109(3-4):337
Submarine groundwater discharge (SGD) is now recognized as an important pathway for water and chemical species fluxes to the coastal ocean. In order to determinate SGD to the Gulf of Lion (France), we measured the activities of 226Ra and 228Ra by thermal ionization mass spectrometry (TIMS) in coastal waters and in the deep aquifer waters of the Rhone deltaic plain after pre-concentration of radium by MnO2. Compared to conventional counting techniques, TIMS requires lower quantities of water for the analyses, and leads to higher analytical precision. Radium isotopes were thus measured on 0.25–2 L water samples containing as little as 20 fg of 226Ra and 0.2–0.4 fg of 228Ra with precision equal to 2%. We demonstrate that coastal surface waters samples are enriched in 226Ra and 228Ra compared to the samples further offshore. The high precision radium measurements display a small but significant 226Ra and 228Ra enrichment within a strip of circa 30 km from the coast. Radium activities decrease beyond this region, entrained in the northern current along the shelf break or controlled by eddy diffusion. The radium excess in the first 30 km cannot be accounted for by the river nor by the early diagenesis. The primary source of the radium enrichment must therefore be ascribed to the discharge of submarine groundwater. Using a mass-balance model, we estimated the advective fluxes of 226Ra and 228Ra through SGD to be 5.2 × 1010 and 21 × 1010 dpm/d respectively. The 226Ra activities measured in the groundwater from the Rhone deltaic plain aquifer are comparable to those from other coastal groundwater studies throughout the world. By contrast, 228Ra activities are higher by up to one order of magnitude. Taking those groundwater radium activities as typical of the submarine groundwater end-member, a minimum volume of 0.24–4.5 × 1010 l/d is required to support the excess radium isotopes on the inner shelf. This has to be compared with the average rivers water runoff of 15.4 × 1010 l/d during the study period (1.6 to 29% of the river flow). 相似文献
19.
This study integrates newly acquired stratigraphic data, geologic mapping, and paleocurrent data to constrain the stratigraphic evolution of the oldest channel-lobe complex in the Upper Cretaceous Cerro Toro Formation in the Silla Syncline area of the Magallanes Basin, termed the Pehoe member. The Pehoe member ranges in thickness from 60 m in the north to at least 410 m farther down system and comprises three separate divisions (A, B, and C). A lower conglomerate unit and an upper one, termed Pehoe A and C divisions respectively, represent the fill of major incised submarine channels or channel complexes. These are separated by stratified sandstone of the Pehoe B division, representing a weakly confined lobe complex, either transient or terminal.The integration of new data with observations from previous studies reveal that the three main coarse-grained conglomerate and sandstone members in the Cerro Toro Formation in the Silla Syncline include at least seven distinct submarine channels or channel complexes and two major lobe complexes. The thinning and disappearance of these units along the eastern limb of the syncline reflect confinement of the flows to a narrow trough or mini-basin bounded to the east by a topographic high. This confinement resulted in unidirectional paleocurrents to the south and southeast in all deposits. Changes in depositional geometries are interpreted as reflecting changes in sediment supply and relative confinement. Submarine channels were from 700 m to 3.5 km wide and occupied a fairway that was 4-5 km wide. Flows moving south and southeast in this mini-basin probably crossed the eastern topographic high south of the present exposures and joined those moving southward along the axis of the foreland basin at least 16 km to the east. 相似文献
20.
Exceptionally high shelf-subsidence rates (0.8–6.0+ mm/yr), a marked basinward stepping (to east and northeast) of the paleo-Orinoco shelf prism and post-Pliocene uplift of Trinidad all allow the sedimentary facies, process regime and the evolution of the Late Miocene Orinoco Delta to be evaluated from extensive outcrops along the southwest, and south coasts of Trinidad. The ca. 200 km easterly growth (late Miocene to present) of the Orinoco shelf-margin was generated by repeated cross-shelf, regressive–transgressive transits of the Orinoco Delta system. The studied Late Pliocene segment of this shelf-margin prism allows insight to how this margin was built. The Morne L'Enfer Formation (Late Pliocene) along Cedros Bay and Erin Bay in SW Trinidad, provides a window into the facies and process regime of the ca. 850 m-thick deltaic succession at an inner-shelf location some 100 km landward of the coeval shelf edge. Regressive facies associations include tide-influenced delta-front to prodelta deposits (FA1) within upward coarsening units, shoreface to offshore deposits, possibly with prograding mud cape deposits (FA2), and fluvial distributary channel infills (FA3), as well as muddy sediments of floodbasins and coastal embayments between the distributary channels (FA4), and tide-influenced bay-head delta deposits (FA5). Transgressive facies associations show an overall upward fining of grain size and include inner estuary distributary channels with minimal brackish-water or tidal influence (FA6), transition zone fluvial-tidal distributary channels (FA7), tide-dominated mid-outer estuary channel-bars (FA8), and intertidal to supratidal flat units (FA9). The tidal signals in both deltaic and estuarine units include bi-directional paleocurrents (channels), frequent mud drapes within stacked sets of cross-strata (delta-front), fluid mud layers, flaser, wavy and lenticular bedding, and ubiquitous spring-neap stratal bundling. The tide dominated nature of the paleo-delta in SW Trinidad was likely due to its location within an embayed proto-Columbus Channel, though by analogy with the modern Orinoco Delta, it is predicted that the same succession becomes wave dominated to the east as the delta emerged to the open ocean and approached the outer shelf and shelf-edge region. It is difficult to estimate how much of the abundant mud in the Pliocene deltaic sequences was derived from inner-shelf littoral currents with suspended Amazon River mud. The studied Late Pliocene Morne L'Enfer succession contains some 17 high-frequency transgressive–regressive sequences, each ca. 40–60 m thick, estimated to have an average time duration of 90–120 Ky. By analogy, the last glacial cycle on the Orinoco shelf saw the delta prograding across the 200 km-wide shelf to the shelf edge in ca. 100 Ky, then transgressing back to its present position in 20 Ky. A predicted model of the linkage between the study succession on SW Trinidad and its eastward continuation offshore towards the outer shelf and shelf edge in the Columbus Basin is suggested. 相似文献