首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 988 毫秒
1.
A systematic investigation of fluxes and compositions of lipids through the water column and into sediments was conducted along the U.S. JGOFS EgPac transect from l2°N to l5°S at 140°W. Fluxes of lipids out of the euphotic zone varied spatially and temporally, ranging from ≈0.20 – 0.6 mmol lipid-C m−2 day−1. Lipid fluxes were greatly attenuated with increasing water column depth, dropping to 0.002-0.06 mmol lipid-C m−2 day−1 in deep-water sediment traps. Sediment accumulation rates for lipids were ≈ 0.0002 – 0.00003 mmol lipid-C m−2 day−1. Lipids comprised ≈ 11–23% of Corg in net-plankton, 10–30% in particles exiting the euphotic zone, 2–4% particles in the deep EgPac, and 0.1-1 % in sediments. Lipids were, in general, selectively lost due to their greater reactivity relative to bulk organic matter toward biogeochemical degradation in the water column and sediment. Qualitative changes in lipid compositions through the water column and into sediments are consistent with the reactive nature of lipids. Fatty acids were the most labile compounds, with polyunsaturated fatty acids (PUFAs) being quickly lost from particles. Branchedchain C15 and C17 fatty acids increased in relative abundance as particulate matter sank and was incorporated into the sediment, indicating inputs of organic matter from bacteria. Long-chain C39 alkenones of marine origin and long-chain C20-C30 fatty acids, alcohols and hydrocarbons derived from land plants were selectively preserved in sediments. Compositional changes over time and space demonstrate the dynamic range of reactivities among individual biomarker compounds, and hence of organic matter as a whole. A thorough understanding of biogeochemical reprocessing of organic matter in the oceanic water column and sediments is, thus, essential for using the sediment record for reconstructing past oceanic environments.  相似文献   

2.
To investigate organic matter source and reactivity in the Zhujiang River (Pearl River)Estuary and its adjacent areas, particulate organic carbon (POC), particulate hydrolysable amino acids (PHAA), and Chl a during two cruises in July 1999 and July 2000 were measured. The highest POC and PHAA concentration was observed in the waters with maximum Chl a. The spectra distribution,relative content (dry weight in milligram per gram), PHAA-C% POC and other indicators such as the ratios of amino acids vs. amino sugars (AA/AS) and glucosamine vs. galactosamine (Glum/Gal) suggested that particulate amino acids in the water column and sediments in the Zhujiang River Estuary were mainly derived from biogenic processes rather than transported from terrestrial erosion. In inner estuary where high turbidity was often observable, organic matter was mainly contributed by re-suspension of bottom sediments with revealed zooplankton, microbial reworked characteristics, which suggest that these organic matters were relatively “old“. In the estuarine brackish region, organic matter in water column is mainly contributed by relatively fresh, easily degradable phytoplankton derived organic matter.During physical - biological processes within the eastuary, organic matter derived from phytoplankton was subjected to alteration by zooplankton grazing and bacterial reworking.  相似文献   

3.
Suspended particulate matter samples were collected from the water column, the bottom nepheloid layer and the ‘ fluffy layer ’ from four stations along a coastal-basin transect in the Pomeranian Bight, western Baltic Sea. Sampling was performed nine times between October 1996 and December 1998 for various analyses, including electron probe x-ray micro analysis for detailed mineralogical investigations.Specific vertical patterns of clay mineral distributions were found. Suspended particulate matter (SPM) in the bottom nepheloid layer and the ‘ fluffy layer ’ overlying sediments was enriched in organic carbon and hydrated three layer clay minerals, whereas the non-aggregated SPM was dominated by quartz and biogenic opal. It appears that separation effects operate during aggregation of mineral particles and organic matter in repeated cycles of resuspension and settling. No clear seasonal variations in the composition of the SPM were found, in spite of high spatial and temporal variability of biological and physical variables. The results suggest that preferential incorporation, possibly aided by microbiological colonization, of hydrated three layer silicates into the organic flocs is a process that occurs under a wide range of conditions. Because aggregates sink faster than individual particles, aggregate formation led to a relative enrichment of illite and smectite in the near-bottom layers. Considering the affinity of organic contaminants and heavy metals to organic matter, the selective removal of aggregated organic matter and hydrated three-layer clay minerals from the water column and enhanced transport in the near-bottom fluffy layer may be a natural cleansing mechanism operating in the shallow waters of the bight.  相似文献   

4.
The Atacama trench, the deepest ecosystem of the southern Pacific Ocean (ca. 8000 m depth) was investigated during the Atacama Trench International Expedition. Sediments, collected at three bathyal stations (1040–1355 m depth) and at a hadal site (7800 m) were analyzed for organic matter quantity and biochemical composition (in terms of phytopigments, proteins, carbohydrates and lipids), bacterial abundance, biomass and carbon production and extracellular enzymatic activities. Functional chlorophyll-a (18.0±0.10 mg m−2), phytodetritus (322.2 mg m−2) and labile organic carbon (16.9±4.3 g C m−2) deposited on surface sediments at hadal depth (7800 m) reached concentrations similar to those encountered in highly productive shallow coastal areas. High values of bacterial C production and aminopeptidase activity were also measured (at in situ temperature and 1 atm). The chemical analyses of the Atacama hadal sediments indicate that this trench behaves as a deep oceanic trap for organic material. We hypothesize that, despite the extreme physical conditions, benthic microbial processes might be accelerated as a result of the organic enrichment.  相似文献   

5.
Cylindrical sediment traps were deployed at various depths in the anoxic water of Framvaren for two periods of one year (1981–1982 and 1983–1984). The traps were emptied three times during 1981–1982 and five times during 1983–1984. The vertical fluxes of total suspended material, organic carbon and nitrogen were calculated on a daily and annual basis. The average annual sediment flux 20 m above the bottom was approximately 60 g m−2 y−1 and the flux of organic carbon was 20 g m−2 y−1. On the basis of an average C/N ratio of 8 and a constant carbon flux below a depth of 20 m, it is concluded that little mineralization of the organic matter takes place in the anoxic water column. Assuming a primary production of the order to 50–100 g m−2 y−1, 22–24% of that reaches the anoxic water masses. Further breakdown of organic matter takes place in the surface sediments.  相似文献   

6.
Molecular organic biomarkers together with trace element composition were investigated in sediments east of Barrow Canyon in the western Arctic Ocean to determine sources and recycling of organic carbon in a continuum from the shelf to the basin. Algal biomarkers (polyunsaturated and short-chain saturated fatty acids, 24-methylcholesta-5,24(28)-dien-3β-ol, dinosterol) highlight the substantial contribution of organic matter from water column and sea-ice primary productivity in shelf environments, while redox markers such as acid volatile sulfide (AVS), Mn, and Re indicate intense metabolism of this material leading to sediment anoxia. Shelf sediments also receive considerable inputs from terrestrial organic carbon, with biomarker composition suggesting the presence of multiple pools of terrestrial organic matter segregated by age/lability or hydrodynamic sorting. Sedimentary metabolism was not as intense in slope sediments as on the shelf; however, sufficient labile organic matter is present to create suboxic and anoxic conditions, at least intermittently, as organic matter is focused towards the slope. Basin sediments also showed evidence for episodic delivery of labile organic carbon inputs despite the strong physical controls of water depth and sea-ice cover. Principal components analysis of the lipid biomarker data was used to estimate fractions of preserved recalcitrant (of terrestrial origin) and labile (of marine origin) organic matter in the sediments, with ranges of 12–79%, 14–45%, and 37–66% found for the shelf, slope, and basin cores, respectively. On average, the relative preserved terrestrial organic matter in basin sediments was 56%, suggesting exchange of organic carbon between nearshore and basin environments in the western Arctic.  相似文献   

7.
The principal regularities were ascertained for the spatiotemporal distribution of organic carbon in the water and bottom sediments of the Russian part of the Sea of Azov. The relationships between allo- and autochthonous organic matter in water and bottom sediments from different parts of the sea aquatic area were found. The behavior of organic carbon in the water-bottom sediments system was characterized as the effect of the variability of hydrochemical, biological, and hydrological factors ad processes.  相似文献   

8.
Data are presented on the content of aliphatic and polycyclic aromatic hydrocarbons (AHC and PAH, respectively) in the interstitial waters and bottom sediments of the Kara Sea compared to the distribution of the particulate matter and organic carbon. It was found that the AHC concentrations within the water mass (16 μg/l on average) are mainly formed by natural processes. The AHC distribution represents the variability of the hydrological and sedimentation processes in different regions of the sea. The widest ranges of the concentrations were registered in the Ob Bay-Kara Sea section: in the water (10–310 μg/l for the AHC and 0.4–7.2 ng/l for the PAH) and in the surface layer of the bottom sediments (8–42 μg/l for the AHC and 9–94 ng/g for the PAH). The differentiation of the hydrocarbons (HC) in the different media follows the marginal filter’s regularities; therefore, no oil and pyrogenic compounds are supplied to the open parts of the sea. In the sediment mass, the HC content is determined by the variations in the oxidative conditions in the sediment and its material’s composition.  相似文献   

9.
We studied the behavior of chemical substances in the upper 300 m of the water column across the continental shelf–slope interface in the East China Sea off the Okinawa Trough. The behaviors of iron, inorganic nutrients, and humic-like fluorescent dissolved organic matter were strongly influenced by the extensive water exchange between the East China Sea and the Kuroshio Current across the shelf break and slope via upwelling and frontal processes. We attributed the high humic-like fluorescent intensity at the subsurface of the shelf break and slope regions to the lateral supply of humic-like fluorescent dissolved organic matter from the shelf sediments to the outer shelf region due to the intrusion of shelf water into Kuroshio subsurface water. We found that the behavior of iron at the continental shelf–slope was remarkably different from the conservative mixing of inorganic nutrients and humic-like fluorescent dissolved organic matter. In deep and bottom waters at the shelf–slope, high total iron concentrations, which were closely related to water transmittance, possibly resulted from the swept transport of iron-rich resuspended sediments over the shelf floor from the slope by the invading Kuroshio Intermediate Water close to the bottom.  相似文献   

10.
A sequential leaching technique has been used to characterize the solid state speciation of total copper (∑Cu) among a number of operationally defined host fractions in surface seawater particulates from the Atlantic Ocean, a diagenetically active hemipelagic sediment core from the eastern Mediterranean, a turbidite - rich sediment core from the Madeira Abyssal Plain and a series of 79 Atlantic Ocean surface or near surface sediments. Around 50% of the ∑Cu in the surface water particulates is held in organic associations. When the material is deposited at the sediment surface, following its entry into the down-column carbon flux, the ∑Cu undergoes phase transformations as the organic carriers are destroyed. However, some of the organically associated copper (Cu5) is preserved in the sediments, the amount depending on the diagenetic environment of deposition. The relationship between ∑Cu and organic carbon in an oceanic sediment may be masked, but the partitioning speciation data has shown that good correlations can be found between organic carbon and Cu5. The concentration of Cu5 in Atlantic Ocean surface sediments is highest in hemipelagic (diagenetically active) sediments deposited in the marginal regions, and lowest in open-ocean (less diagenetically active) sediments of the Mid-Atlantic Ridge and ridge flanks. The marginal sediments contain an average of 20% of their total Cu in an organic association, with the result that these sediments can act as traps for seawater-derived Cu that would normally be regarded as being ‘reactive’ in the marine environment. To a first approximation, the preservation of Cu5 in the sediments mimics that of primary production in the overlying waters, and so ‘fingerprints’ the operation of the global ocean carbon flux in oceanic deposits. However, the relationship can be perturbed by the off-shelf transport of organic-rich, Cu5-containing, turbidites which can result in the transfer and burial of organic copper host fractions in open-ocean oxic environments.  相似文献   

11.
1. (1) The nature of sediment—sea interactions depends on the time scale considered. At a time scale commensurate with human life, one can define a water—sediment interface, and the main exchanges are solutes exchanges through this interface by concentration diffusion. This condition will be termed as “Short time-scale equilibrium interaction”.
On the other hand, at a geological time scale, there is a continuous accretion to the “sediment” of suspended particulate matter, bottom-current borne materials and sometimes precipitates of previously dissolved salts; to this sediment build-up corresponds a flux of water of reverse sense, from the sediment to the water column, due to the compaction of muds and oozes which reduce their porosity (their water content) under their own load. The concept of interface is then of limited utility, since physically it is constantly changing, and since the material balance of the exchanges does not depend on its characteristics at a first order of approximation. This condition will be termed “long time-scale geological interaction”.
These situations are extreme ones. In areas of present important detrital sedimentation, even for short time spans it is doubtful if the definition of an interface has some utility: we are in a situation close to “geological time scale”. On the contrary, in abyssal zones remote from continents, the rate of sedimentation is so low that even for eons an interface separating two environments in physico-chemical equilibrium exists.
2. (2) If there were no internal sources of dissolved species in the sediment, the only concentration changes to occur would be due to the decrease in porosity (in water content) following gravitational compaction of sediments. But this phenomenon is the same as sedimentation, thus transfer of matter would be unappreciable within short time spans. The fact that this transfer can be measured at human time scale shows therefore that dissolved species are actually produced in the sediment. Some of these can originate from possible inorganic chemical reactions, but all the organic molecules, and an important part of the inorganic (such as phosphates, nitrates, NH4+, S2-) require processing of organic matter for their production. Whether or not this reworking is of biological origin remains controversial. On the whole, the quantities of matter thus transferred are very minute compared to the quantities present in oceanic waters. They cannot be considered in general as a significant input. But they may be important locally (nearshore restricted water bodies, or manganese nodules formation).
3. (3) At geological time scale, sedimentation, which adds solid material to the preexisting sediment, results also in the compaction of this sediment. At every depth in the sediment there exists an equilibrium value of the porosity, i.e. the fluids content, of the sediment; it tends to this value by expelling the corresponding quantity of fluids, with a rate determined by its permeability. This input may be important, but it is mainly water, and water formerly oceanic: therefore it is not a true input, but simply a delayed return. The transfer of other fluids (mainly oil and gas) is unsignificant generally speaking. Once more, it may be locally important (submarine seepages).
4. (4) On the whole, the processes of water—sediment interaction appear not to add any new matter into the oceanic pool, but rather to regulate the restitution by the sediment to the water of substances which were already present in ocean, in particulate or dissolved form, either free or combined. One can trace out two main processes, which differ in their rates and yields:
4.1. (a) the short time scale diffusion—high rate low yield restitution of organics and inorganics in dissolved state:
4.2. (b) the long time scale compaction: low rate high yield restitution of entrapped fluids, essentially water (devoid of dissolved species).
Not only do these processes not bring any new matter to the ocean, but even the absolute quantities involved are modest compared either to the quantities present in the ocean or to the quantities generated by the photosynthetic primary production or brought by the rivers.In contrast to the insignificance of the water—sediment interaction in the oceanic material balance, this same interaction is one of the main sources for the material sedimented and especially the organic one, and therefore it is a fundamental key for all the subsequent sedimentary history.The significant inputs at the limit “bottom”-water come from the regions of deep tectonic activity, volcanism, creation of new oceanic crust etc… There tremendous amounts of substances can be brought into solution, changing at least locally the concentration equilibrium values of seawater. They are of course inorganic ions, but they can have important biological consequences. The buffering capacity of the world ocean is so high that only cosmic events can influence its composition.  相似文献   

12.
To understand the role that physical processes play on the biogeochemical cycles of estuaries, we conducted intense field studies of the turbidity maximum region within a partially mixed estuary (Winyah Bay, SC, USA) under contrasting conditions of river discharge, tides and wind. Water samples and hydrographic data were collected at different depths and locations along the main channel over several tidal cycles during several cruises to Winyah Bay. Tidal variations in current speed, salinity, total suspended solid concentrations were measured within each cruise and were consistent with estuarine circulation processes. Salinity and total suspended solid concentrations ranged from 0 to 32 and from 20 to over 500 mg L−1, respectively, with the highest salinity and total suspended solid values measured during periods of low river discharge. In fact, comparison of tidally averaged salinity and total suspended solid concentrations revealed marked differences among cruises that were negatively correlated to river discharge and SW wind speed. Moreover, significant contrasts in the chemical compositions of suspended particles were evident among periods of contrasting river discharge and wind regime. For example, the weight percent organic carbon content of suspended particles ranged from 1 to over 6% and displayed a positive correlation with river discharge. Similarly, both the molar carbon to nitrogen ratios (10 to 20 mol:mol) and stable carbon isotopic compositions (−25 to −29%) of the suspended organic matter varied significantly as a function of discharge and wind. Such trends indicate that in Winyah Bay low river discharge and steady SW winds promote resuspension of bed sediments from shallow regions of the estuary. These materials contain highly altered organic matter and their incorporation into the water column leads to the observed trends in suspended particle concentrations and compositions. Furthermore, these conditions result in net landward fluxes of salt, sediment and particulate organic matter throughout most of the water column, promoting efficient trapping of materials within the estuary. Our results illustrate the fundamental connection between physical forcings, such as discharge and wind, sediment transport processes and the cycling of biogeochemical materials in estuarine environments.  相似文献   

13.
Measurement of the vertical distribution of total suspended matter (TSM) was carried out during summer throughout the Seto Inland Sea. TSM concentration near the bottom is influenced significantly by water movement and turbid bottom water is observed in all areas where median grain size (Md) of the bottom sediment is more than 47gf. The high concentration of TSM near the bottom may be due to resuspension of the surface layer of bottom sediments. Comparison of the organic content of the resuspended matter with that of the bottom sediment shows that the resuspended matter contains more organic matter with a lower C : N ratio than the bottom sediment. The C : N ratio of the resuspended matter is similar to that of TSM in the surface layer of the water column. It is thought that TSM in surface waters sinks and settles on the surface of the bottom sediment. This deposited material is then easily resuspended in the water column by tidal currents before becoming permanently incorporated into the bottom sediment.  相似文献   

14.
Results of organic carbon, total nitrogen, amino acid and hexosamine analyses of samples collected during time-series sediment trap investigations in the Arabian Sea are presented. Samples were taken over a period of years at two depths at each of three locations in the western, central and eastern part of the basin. Seasonal changes in amino acid contents and their spectral distributions show that degradation of organic matter in the water column is reduced during the monsoons, which are the high-flux periods in the western and central Arabian Sea. At the eastern site more degraded material of possibly recycled marine or terrestrial origin reaches the traps during the late summer peak fluxes. The results of hexosamine analyses suggest that bacterial biomass is relatively enriched on particles sinking in the water column and, to a larger extent, at the sediment-water interface. Decomposition between intermediate and deep water results in a loss of 30–40% of total organic carbon and more than 40% of amino acids. Comparison of the measured accumulation rates of organic carbon in sediment traps with those of organic carbon preserved in sediments show that more than 85% is lost before final burial in the sediments. Organic matter preservation in the Arabian Sea is higher than the average for the open ocean; this maybe due to the abundance of refractory organic matter of recycled marine or terrestrial origin.  相似文献   

15.
The speciation of sedimentary sulfur (pyrite, acid volatile sulfides (AVS), S0, H2S, and sulfate) was analyzed in surface sediments recovered at different water depths from the northwestern margin of the Black Sea. Additionally, dissolved and dithionite-extractable iron were quantified, and the sulfur isotope ratios in pyrite were measured. Sulfur and iron cycling in surface sediments of the northwestern part of the Black Sea is largely influenced by (1) organic matter supply to the sediment, (2) availability of reactive iron compounds and (3) oxygen concentrations in the bottom waters. Biologically active, accumulating sediments just in front of the river deltas were characterized by high AVS contents and a fast depletion of sulfate concentration with depth, most likely due to high sulfate reduction rates (SRR). The δ34S values of pyrite in these sediments were relatively heavy (−8‰ to −21‰ vs. V-CDT). On the central shelf, where benthic mineralization rates are lower, re-oxidation processes may become more important and result in pyrite extremely depleted in δ34S (−39‰ to −46‰ vs. V-CDT). A high variability in δ34S values of pyrite in sediments from the shelf-edge (−6‰ to −46‰ vs. V-CDT) reflects characteristic fluctuations in the oxygen concentrations of bottom waters or varying sediment accumulation rates. During periods of oxic conditions or low sediment accumulation rates, re-oxidation processes became important resulting in low AVS concentrations and light δ34S values. Anoxic conditions in the bottom waters overlying shelf-edge sediments or periods of high accumulation rates are reflected in enhanced AVS contents and heavier sulfur isotope values. The sulfur and iron contents and the light and uniform pyrite isotopic composition (−37‰ to −39‰ vs. V-CDT) of sediments in the permanently anoxic deep sea (1494 m water depth) reflect the formation of pyrite in the upper part of the sulfidic water column and the anoxic surface sediment. The present study demonstrates that pyrite, which is extremely depleted in 34S, can be found in the Black Sea surface sediments that are positioned both above and below the chemocline, despite differences in biogeochemical and microbial controlling factors.  相似文献   

16.
Extracellular enzyme activities were compared among surface water, bottom water, and sediments of the Delaware Estuary using six fluorescently labeled, structurally distinct polysaccharides to determine the effects of suspended sediment transport on water column hydrolytic activities. Potential hydrolysis rates in surface waters were also measured for the nearby shelf. Samples were taken in December 2006, 6 months after a major flood event in the Delaware Basin that was followed by high freshwater run-off throughout the fall of 2006. All substrates were hydrolyzed in sediments and in the water column, including two (pullulan and fucoidan) that previously were not hydrolyzed in surface waters of the Delaware estuary. At the time of sampling, total particulate matter (TPM) in surface waters at the lower bay, bay mouth, and shelf ranged between 31 mg l−1 and 48 mg l−1 and were 2 to 20 times higher than previously reported. The presence of easily resuspended sediments at the lower bay and bay mouth indicated enhanced suspended sediment transport in the estuary prior to our sampling. Bottom water hydrolysis rates at the two sites affected by sediment resuspension were generally higher than those in surface waters from the same site. Most notably, fucoidan and pullulan hydrolysis rates in bay mouth bottom waters were 22.6 and 6.2 nM monomer h−1, respectively, and thus three and five times higher than surface water rates. Our data suggest that enhanced mixing processes between the sediment and the overlying water broadened the spectrum of water column hydrolases activity, improving the efficiency of enzymatic degradation of high molecular weight organic matter in the water with consequences for organic matter cycling in the Delaware estuary.  相似文献   

17.
The reaction pathways of nitrogen and carbon in the Framvaren Fjord (Norway) were studied through stable isotope analysis (δ15N and δ13C) of dissolved inorganic and particulate organic matter (POM). The variations in the isotopic compositions of the various C and N pools within the water column were use to evaluate the historical deposition of material to the sediments. The high δ15N-NH4+ at the O2/H2S interface, as a consequence of microbial uptake between 19 and 25 m, results in extremely depleted δ15N-particulate nitrogen (PN) of approximately 1‰ within the particulate maximum at approximately 19 m. The carbon isotopic distribution of dissolved inorganic carbon (DIC) and particulate organic carbon (POC) within the interface suggests that the distinct microbial flora (Chromatium sp. and Chlorobium sp.) fractionate inorganic carbon to different degrees. The extremely light δ13C-POC within the interface (−31‰) appears to be a result of carbon uptake by Chromatium sp. while δ13C-POC of −12‰ is more indicative of Chlorobium sp. Nitrogen isotopic mass balance calculations suggested that approximately 75% of the material sinking to the sediments was derived from the dense particulate maximum between 19 and 25 m. The sediment distribution of nitrogen isotopes varied from 2‰ at the surface to approximately 6‰ at 30 cm. The nitrogen isotopic variations with depth may be an indicator of the depth or position of the O2/H2S interface in the fjord. Low sediment δ15N indicated that the interface was within the photic zone of the water column, while more enriched values suggested that the interface was lower in the water column potentially allowing for less fractionation during biological incorporation of dissolved inorganic nitrogen. Results indicate that the dense layers of photo-autotrophic bacteria in the upper water column impart unique carbon and nitrogen isotopic signals that help follow processes within the water column and deposition to the sediments.  相似文献   

18.
Research has been conducted in Nha Trang Bay (Southern Vietnam, the South China Sea) at the section from the estuary of the Cai River to the marine part of the bay, as well as in the area of coral reefs. The objects of the studies are the river and sea waters, the suspended matter, and the bottom sediments. Data on the dissolved organic carbon and the total nitrogen in the water are obtained. The organic carbon content is estimated in the suspended matter; the organic carbon and the molecular and group composition of the n-alkanes are determined in the bottom sediments. The molecular and group composition of the n-alkanes in the bottom sediments of the landfill have made it possible to identify three types of organic matter (OM): marine, mixed, and of mainly terrigenous origin. All the types of OM are closely related to the specificity of the sedimentation and the hydrodynamics of the waters in this water area.  相似文献   

19.
The rate of benthic denitrification in slope and rise sediments of a transect across the N.W. European Continental Margin (Goban Spur) was evaluated from 31 pore water nitrate profiles obtained during six cruises between May and October. All profiles had well separated zones of nitrification and denitrification. High near-surface nitrate concentrations prevented the influx of nitrate from the bottom water. The denitrification rates obtained from steady-state-modelling ranged from 0.13 to 2.56 μmol N cm−2 y−1 and showed an exponential increase both with decreasing water depth and with increasing rate of organic carbon degradation. Denitrification rates in a nearby canyon, which did not follow these relationships, were estimated to be much higher as a result of erosion and redistribution of organic matter. Denitrification at the Goban Spur slope and rise is much lower than previously reported for similar environments in the Pacific resulting predominantly from the different oxygen and nitrate concentrations in the bottom water. A weighted average for the whole slope and rise sediment system shows that 17% of the particulate organic nitrogen input (8.93 μmol N cm−2 y−1) is denitrified and only 1% is buried, the rest being released as nitrate. Although being ten times higher compared with basin sediments, denitrification on the slope and rise is several times lower than on the adjacent shelf.  相似文献   

20.
Investigations in the water column and bottom sediments including entrapped water were carried out on expeditions of the P.P. Shirshov Institute of Oceanology in the Dvina Bay, the White Sea. We studied the transformation of particulate organic matter at the biogeochemical barrier between the water and bottom and in the underlying Holocene sediments. Low rates of the early diagenesis of sediments caused by low values of primary production in the conditions of high fluxes of terrigenous organic matter were established. The low temperatures of microorganisms habitat play the secondary role.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号