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1.
In the Mediterranean Sea the carbon chemistry is poorly known. However, the impact of the regional and large-scale anthropogenic pressures on this fragile environment rapidly modifies the distribution of the carbonate system key properties like CT (total dissolved inorganic carbon), AT (total alkalinity), CANT (anthropogenic CO2), and pH. This leads inexorably to the acidification of its waters. In order to improve our knowledge, we first develop interpolation procedures to estimate CT and AT from oxygen, salinity, and temperature data using all available data from the EU/MEDAR/MEDATLAS II database. The acceptable levels of precision obtained for these estimates (6.11 ??mol-kg−1 for CT and 6.08 ??mol kg−1 for AT) allow us to draw the distribution of CANT (with an uncertainty of 6.75 ??mol kg−1) using the Tracer combining Oxygen, inorganic Carbon, and total Alkalinity (TrOCA) approach. The results indicate that: 1) all Mediterranean water bodies are contaminated by anthropogenic carbon; 2) the lowest concentration of CANT is 37.5 ??mol kg−1; and 3) the western basin is more contaminated than the Eastern basin. After reconstructing the distribution of key properties (CT, AT, CANT) for four periods of time (between 1986 and 2001) along a west-east section throughout the whole Mediterranean Sea, we analyze the impact of the Eastern Mediterranean Transient (EMT). Not only has the concentration of CANT increased (especially in the intermediate and the bottom layers of the eastern basin, during and after the EMT), but also the distribution of all properties has been considerably perturbed. This is discussed in detail. For the first time, the level of acidification is estimated for the Mediterranean Sea. Our results indicate that for the year 2001 all waters (even the deepest) have been acidified by values ranging from −0.14 to −0.05 pH unit since the beginning of the industrial era, which is clearly higher than elsewhere in the open ocean. Given that the pH of seawater may affect a very large number of chemical and biological processes, our results stress the necessity to develop new programs of research to understand and then predict the evolution of the carbonate system properties in the Mediterranean Sea.  相似文献   

2.
The Mediterranean Sea transforms surface Atlantic Water (AW) into a set of cooler and saltier typical Mediterranean Waters (tMWs) that are formed in different subbasins within the sea and thus have distinct hydrological characteristics. Depending on the mixing conditions along their route and on their relative amounts, the tMWs are more or less differentiated at any given place, and some mix together up to forming new water masses. We emphasise the fact that any of these Mediterranean Waters (MWs) must outflow from the sea, even if more or less identifiable and/or in a more or less continuous way. Historical data from the 1960s–1980s showed that the densest MW outflowing through the Strait of Gibraltar at Camarinal Sill South (CSS) was a relatively cool and fresh tMW formed in the western basin, namely the Western Mediterranean Deep Water (WMDW). At these times, the sole other tMW identified in the strait was the Levantine Intermediate Water (LIW); no mention was made there of, in particular, the two densest tMWs formed in the eastern basin (in the Aegean and the Adriatic) that are now named Eastern Overflow Water (EOW) when they reach the Channel of Sicily (where they cannot be differentiated). A fortiori, no mention was made of the Tyrrhenian Dense Water (TDW) that results from the mixing of EOW with waters resident in the western basin (in particular WMDW) when it cascades down to ∼2000 m from the channel of Sicily. New measurements (essentially temperature and salinity time series) collected at CSS since the mid-1990s indicate that the densest MWs outflowing through the strait have been continuously changing; temperature and salinity there have been increasing, being actually (early 2000s) much warmer (∼0.3 °C) and saltier (0.06) than ∼20 years ago. These changes are one order of magnitude larger than the decadal trends shown for WMDW in particular. We thus demonstrate that, in the early 2000s, (i) the densest MW outflowing at Gibraltar is TDW and (ii) TDW is mainly composed of EOW (the percentage of MWs from the western basin, in particular WMDW, is lower): the densest part of the outflow is thus “more eastern than western”. This Mediterranean Sea Transient (a shift from the western basin to the eastern one) could be linked to the Eastern Mediterranean Transient (a shift from the Adriatic subbasin to the Aegean one). Whatever the case, we demonstrate that the proper functioning of the Mediterranean Sea leads to a variability in its outflow's composition that can have consequences for the mid-depth water characteristics in the North-Atlantic much more dramatic than previously thought.  相似文献   

3.
Monthly observations accumulated over more than a decade at the DYFAMED time-series station allow us to estimate the temporal evolution of anthropogenic CO2 in the western Mediterranean Sea. This objective is reached by using recognized interpolation procedures to reconstruct the incomplete distributions of measured total dissolved inorganic carbon and total alkalinity. These reconstructed fields, associated with those available for dissolved oxygen and temperature, are used to estimate the distribution of anthropogenic CO2. This is done with the recently developed Tracer combining Oxygen, inorganic Carbon, and total alkalinity (TrOCA) approach. The main results indicate that (1) the concentrations of anthropogenic CO2 are much higher than those found in the Atlantic Ocean (the minimum concentration at the DYFAMED site is 50 μmol kg−1), and (2) the temporal trend for anthropogenic CO2 is decreasing, especially in the intermediate and the deep layers of the water column at the DYFAMED site. This decrease in anthropogenic CO2 is significantly correlated with a decrease in the dissolved oxygen and with an increase in both salinity and temperature. These trends are discussed in the light of recent published works that propose explanations for the observed increases in salinity and temperature that occurred in the western basin since the 1950s. We conclude that the decrease in anthropogenic CO2 probably resulted from an invasion of old water masses. Different hypotheses on the origin of these water masses are considered and several arguments indicate that the eastern Mediterranean transient (EMT) could have played an important role in the observed decrease in anthropogenic CO2 concentrations at the DYFAMED site.  相似文献   

4.
Abstract. A number of recent studies based on hydrographic observations and modelling simulations have dealt with the major climatic shift that occurred in the deep circulation of the Eastern Mediterranean. This work presents hydrographic observations and current measurements conducted from 1997 to 1999, which reveal strong modifications in the dynamics of the upper, intermediate and deep layers, as well as an evolution of the thermohaline characteristics of the deep Aegean outflow since 1995. The reversal of the circulation in the upper layer of the north/central Ionian is worthy of note. The observations indicate a reduction of Atlantic Water in the northern Ionian with an increase on the eastern side of the basin. In the intermediate layer, the dispersal path of the Levantine Intermediate Water (LIW) is altered. Highly saline (>39.0) and well-oxygenated intermediate waters were found near the Western Cretan Arc Straits. They flow out from the Aegean, thus interrupting the traditional path of the LIW, and spread prevalently northwards into the Adriatic Sea. In the deep layer, dense waters, exiting from the Adriatic (σø−29.18 kg · m−3), flow against the western continental margin in the Ionian Sea at a depth of between 1000–1500 m. Dense waters of Aegean origin (> 29.20 kg · m−3), discharged into the central region of the Eastern Mediterranean during the early stages of the transient, propagate prevalently to the east in the Levantine basin and to the west in the northern Ionian Sea. Near-bottom current measurements conducted in the Ionian Sea reveal unforeseen aspects of deep dynamics, suggesting a new configuration of the internal thermohaline conveyor belt of the Eastern Mediterranean.  相似文献   

5.
Four seasonal oceanographic cruises were carried out in the Eastern Mediterranean Sea, within the framework of the CEC/MAST-MTP Project PELAGOS, during 1994–1995. The surveys covered the South Aegean Sea and the adjacent open sea regions (southeastern Ionian, northwestern Levantine). Analysis of CTD data revealed that a multiscaled circulation pattern prevails in the area. It differs from the circulations detected during the 1986–87, thus indicating interannual variability. Cyclonic and anticyclonic gyres and eddies are interconnected by currents and jets variable in space and time. Most of the features are persistent, others seem transitional or recurrent. The hydrological structure is also complex and apart from the upper layer does not present basinwide any significant seasonality. Dynamical and hydrological regimes are variable in the upper and intermediate layers at the Straits of the Cretan Arc, while the deep regime seems rather constant. Topographic control is evident on the flows through the straits. The new very dense deep water mass, namely the Cretan Deep Water (CDW) and a well-defined intermediate layer of minimum temperature and salinity, the so-called Transition Mediterranean Water (TMW), consists the new important structural elements of the South Aegean Sea. The CDW outflows towards the deep and bottom layers of the Eastern Mediterranean, thus considerably contributing to the formation of the new, denser Deep and Bottom Water of the Eastern Mediterranean, which sinks and displaces the Eastern Mediterranean Deep Water of Adriatic origin in the adjacent sea regions outside the Aegean Sea.  相似文献   

6.
This paper evaluates whether a thermodynamic ocean-carbon model can be used to predict the monthly mean global fields of the surface-water partial pressure of CO2 (pCO2SEA) from sea surface salinity (SSS), temperature (SST), and/or nitrate (NO3) concentration using previously published regional total inorganic carbon (CT) and total alkalinity (AT) algorithms. The obtained pCO2SEA values and their amplitudes of seasonal variability are in good agreement with multi-year observations undertaken at the sites of the Bermuda Atlantic Timeseries Study (BATS) (31°50’N, 60°10’W) and the Hawaiian Ocean Time-series (HOT) (22°45’N, 158°00’W). By contrast, the empirical models predicted CT less accurately at the Kyodo western North Pacific Ocean Time-series (KNOT) site (44°N, 155°E) than at the BATS and HOT sites, resulting in greater uncertainties in pCO2SEA predictions. Our analysis indicates that the previously published empirical CT and AT models provide reasonable predictions of seasonal variations in surface-water pCO2SEA within the (sub) tropical oceans based on changes in SSS and SST; however, in high-latitude oceans where ocean biology affects CT to a significant degree, improved CT algorithms are required to capture the full biological effect on CT with greater accuracy and in turn improve the accuracy of predictions of pCO2SEA.  相似文献   

7.
The recent changes in the thermohaline circulation of the Eastern Mediteranean caused by a transition from a system with a single source of deep water in the Adriatic to one with an additional source in the Aegean are described and assessed in detail. The name Cretan Sea Overflow Water (CSOW) is proposed for the new deep water mass. CSOW is warmer (θ>13.6°C) and more saline (S>38.80) than the previously dominating Eastern Mediterranean Deep Water (EMDW), causing temperatures and salinities to rise towards the bottom. All major water masses of the Eastern Mediterranean, including the Levantine Intermediate Water (LIW), have been strongly affected by the change. The stronger inflow into the bottom layer caused by the discharge of CSOW into the Ionian and Levantine Basins induced compensatory flows further up in the water column, affecting the circulation at intermediate depth. In the northeastern Ionian Sea the saline intermediate layer consisting of Levantine Intermediate Water and Cretan Intermediate Water (CIW) is found to be less pronounced. The layer thickness has been reduced by factor of about two, concurrently with a reduction of the maximum salinity, reducing advection of saline waters into the Adriatic. As a consequence, a salinity decrease is observed in the Adriatic Deep Water. Outside the Aegean the upwelling of mid-depth waters reaches depths shallow enough so that these waters are advected into the Aegean and form a mid-depth salinity-minimum layer. Notable changes have been found in the nutrient distributions. On the basin-scale the nutrient levels in the upper water column have been elevated by the uplifting of nutrient-rich deeper waters. Nutrient-rich water is now found closer to the euphotic zone than previously, which might induce enhanced biological activity. The observed salinity redistribution, i.e. decreasing values in the upper 500–1400 m and increasing values in the bottom layer, suggests that at least part of the transition is due to an internal redistribution of salt. An initiation of the event by a local enhancement of salinity in the Aegean through a strong change in the fresh water flux is conceivable and is supported by observations.  相似文献   

8.
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9.
The intermediate and deep waters of the Labrador Sea are dominated by recently ventilated water masses (ventilation ages <20 yr). Atmospheric gases such as CO2 and chlorofluorocarbons are incorporated into these water masses at the time of formation and subsequently transported via boundary currents into the North Atlantic interior. Recent measurements of total carbonate were used in tandem with total alkalinity and oxygen to estimate the levels of anthropogenic carbon dioxide in the Labrador Sea region. Upper water column anthropogenic CO2 estimated in this manner showed good agreement with levels calculated from CO2 increase in the atmosphere. In spring 1997, anthropogenic contributions to total carbonate (CTant) were 40±3 μmol/kg in water penetrated by deep convection the previous winter and slightly lower (37±2 μmol/kg) in the deeper convective layer formed in the winters of 1992–1994. Consistent with the concurrent profiles of CFC-11, levels decrease into the older NEADW (North East Atlantic Deep Water) with levels of 30±3 μmol/kg and then increase near bottom within the layer of DSOW (Denmark Strait Overflow Water). The distribution of CTant shows the flow of new LSW southwards with the western boundary current and also eastwards into the Irminger Sea. We estimate that 0.15–0.35 Gt carbon of anthropogenic origin flow through the Labrador Sea within the Western Boundary Undercurrent per year.  相似文献   

10.
The Arctic Ocean is connected to the Pacific by the Bering Sea and the Bering Strait. During the 4th Chinese National Arctic Research Expedition, measurements of carbon tetrachloride (CCl4) were used to estimate ventilation time-scales and anthropogenic CO2 (Cant) concentrations in the Arctic Ocean and Bering Sea based on the transit time distribution method. The profile distribution showed that there was a high-CCl4 tongue entering through the Canada Basin in the intermediate layer (27.6?<?σθ?<?28), at latitudes between 78 and 85°N, which may be related to the inflow of Atlantic water. Between stations B09 and B10, upwelling appeared to occur near the continental slope in the Bering Sea. The ventilation time scales (mean ages) for deep and bottom water in the Arctic Ocean (~?230–380 years) were shorter than in the Bering Sea (~?430–970 years). Higher mean ages show that ventilation processes are weaker in the intermediate water of the Bering Sea than in the Arctic Ocean. The mean Cant column inventory in the upper 4000 m was higher (60–82 mol m?2) in the Arctic Ocean compared to the Bering Sea (35–48 mol m?2).  相似文献   

11.
Historical data of total dissolved inorganic carbon (CT), together with nitrate and phosphate, have been used to model the evolution of these constituents over the year in the Atlantic water of the Norwegian Sea. Changes in nutrient concentration in the upper layer of the ocean are largely related to biological activity, but vertical mixing with the underlying water will also have an impact. A mixing factor is estimated and used to compute the entrainment of these constituents into the surface water from below. After taking the mixing contribution into account, the resulting nutrient concentration changes are attributed to biological production or decay. The results of the model show that the change in CT by vertical mixing and by biological activity based on nutrient equivalents needs another sink to balance the carbon budget. It cannot be the atmosphere as the surface water is undersaturated with respect to carbon dioxide and is, thus, a source of CT in this region. Inasmuch as the peak deficit of carbon is more than a month later than for the nutrients, the most plausible explanation is that other nitrogen and phosphate sources than the inorganic salts are used together with dissolved inorganic carbon during this period. As nitrate and phosphate show a similar trend, it is unlikely that the explanation is the use of ammonia or nitrogen fixation but rather dissolved organic nitrogen and phosphate, while dissolved organic carbon is accumulating in the water.  相似文献   

12.
The saturation of calcite and aragonite in the Arctic Ocean   总被引：1，自引：0，他引：1  
We report on the chemical saturation of CaCO3 in the waters of the Arctic Ocean calculated from total alkalinity (AT) and total dissolved inorganic carbon (CT). Data based on four different expeditions are presented: International Arctic Ocean Expedition (IAOE-91), Arctic Ocean Section 94 (AOS94), Polarstern Arctic '96 expedition (ACSYS 96), and Joint Ocean Ice Study 97 (JOIS 97). The results show a lysocline at around 3500 m for aragonite and that most of the Arctic Ocean sea floor lies above the lysocline for calcite. The only anomaly is the low degree of saturation at the shelf break depth in the Canadian Basin seen in the sections of the AOS94 and JOIS 97 cruises, correlated with nutrient maxima and very low O2 concentration, suggesting decomposition of organic matter. The insignificant variability in degree of saturation between the deep waters of the different basins in the Arctic Ocean indicates a very low sedimentation/remineralisation of organic soft matter.  相似文献   

13.
A preliminary study of carbon system in the East China Sea   总被引：1，自引：0，他引：1  
In the central part of the East China Sea, the activity of CO2 in the surface water and total carbonate, pH and alkalinity in the water column were determined in winter and autumn of 1993. The activity of CO2 in the continental shelf water was about 50 ppm lower than that of surface air. This decrease corresponds to the absorption of about 40 gC/m2/yr of atmospheric CO2 in the coastal zone or 1 GtC/yr in the global continental shelf, if this rate is applicable to entire coastal seas. The normalized total carbonate contents were higher in the water near the coast and near the bottom. This increase toward the bottom may be due to the organic matter deposited on the bottom. This conclusion is supported by the distribution of pH. The normalized alkalinity distribution also showed higher values in the near-coast water, but in the surface water, indicating the supply of bicarbonate from river water. The residence time of the East China Sea water, including the Yellow Sea water, has been calculated to be about 0.8 yr from the excess alkalinity and the alkalinity input. Using this residence time and the excess carbonate, we can estimate that the amount of dissolved carbonate transported from the coastal zone to the oceanic basin is about 70 gC/m2/yr or 2 GtC/yr/area-of-global-continental-shelf. This also means that the rivers transport carbon to the oceans at a rate of 30 gC/m2/yr of the coastal sea or 0.8 GtC/yr/ area-of-global shelf, the carbon consisting of dissolved inorganic carbonate and terrestrial organic carbon decomposed on the continental shelf.  相似文献   

14.
Several methods to compute the anthropogenic component of total dissolved inorganic carbon () in the ocean have been reported, all in some way deducing (a) the effect by the natural processes, and (b) the background concentration in the pre-industrial scenario. In this work we present a method of calculating using nutrient and CFC data, which takes advantage of the linear relationships found between nitrate (N), phosphate (P) and CFC-11 in the Nordic Seas sub-surface waters. The basis of the method is that older water has lower CFC-11 concentration and also has been exposed to more sinking organic matter that has decayed, resulting in the slopes of P versus CFC-11 and N versus CFC-11 being close to the classic Redfield ratio of 1:16. Combining this with the slope in total alkalinity (AT) versus CFC-11 to correct for the dissolution of metal carbonates gives us the possibility to deduce the concentration of anthropogenic CT in the Nordic Seas. This further allowed us to compute the inventory of anthropogenic CT below 250 m in the Nordic Seas in spring 2002, to ∼1.2 Gt C.  相似文献   

15.
Data on the carbonate system of the Northwestern Indian Ocean obtained on a cruise of F.S. Meteor during SW monsoon in July/August 1995 were compared with those of George et al. [George, M.D., Kumar, M.D., Naqvi, S.W.A., Banerjee, S., Narvekar, P.V., de Sousa, S.N., Jayakumar, D.A., 1994. A study of the carbon dioxide system in the northern Indian Ocean during premonsoon. Mar. Chem. 47, 243–254] collected during intermonsoon. In general, deep water values agreed well between the two expeditions. Surface waters, however, showed a substantial increase in dissolved inorganic carbon (CT) in the coastal regions due to strong upwelling in the SW monsoon. This was also accompanied by very high CO2 partial pressures in surface waters. The north–south gradients in vertical profiles of the measured parameters in the Arabian Sea are discussed by comparing profiles from the oligotrophic equatorial region with those from the highly productive central Arabian Sea. The effect of denitrification on regenerated CT and AT is minor, with contributions of <9 and <8 μmol kg−1, respectively, to the total amount regenerated also utilizing oxygen. The dissolution of biogenic carbonates is discussed; different approaches to define the depth, where the dissolution starts (lysocline(s), carbonate critical depth (CCrD)), are compared together with the calculation of saturation depth from carbonate concentrations. It is shown, that small differences in measured CT and AT (found between our data and those measured during GEOSECS) and different calculation approaches to the CO2 system (different dissociation constants for species involved and taking into account phosphate and silicate concentrations) can produce pronounced differences in the calculated saturation depths. However, CT and AT data suggest substantial dissolution of biogenic carbonate in the water column even above the calcite lysocline, irrespective of the procedures followed to calculate this horizon.  相似文献   

16.
基于海洋环流模式POP和生物地球化学模型OCMIP-2,建立了全球海洋碳循环模式,并用于对全球海洋碳循环的模拟研究。该模式在大气CO2为283×10-6条件下,积分3 100 a,达到工业革命前的平衡态。在此基础上,用历史时期观测的大气CO2浓度进行强迫,模拟了历史时期的海洋碳循环。模拟的无机碳浓度、总碱度与基于观测得到的结果基本一致,模式能够较好地模拟全球碳循环过程。模拟结果表明,在北半球中高纬度和南半球的中纬度,海洋是大气CO2的主要汇区;在赤道南北纬20°之间和南大洋50°S以南,海洋表现为大气CO2的源区。在1980s海洋吸收CO2速率(以C计)为1.38 Pg/a,1990s为1.55 Pg/a。海洋中人为碳在北大西洋含量最大,向下到达海底并向南输运到30°N附近;在南极附近,浓度较小,深度达到3 000 m;在中纬度,人为碳被限制在温跃层以上。  相似文献   

17.
白令海BR断面海-气CO2通量及其参数特征   总被引：1，自引：0，他引：1  
通过对2008年夏季白令海大气和海水pCO2连续观测资料,结合BR断面上站位水体垂直采样测量,对白令海不同海区pCO2的分布特征及其与理化参数的关系进行了初步研究,结果表明,将白令海划分为4个具有不同CO2吸收能力的海区,其中陆坡流区碳通量高达-18.72 mmol/(m2·d),是海盆北区的近2倍,比海盆南区高一个量...  相似文献   

18.
To study the dissolved carbonate system in the South China Sea (SCS) and to understand the water mass exchange between the SCS and the West Philippine Sea (WPS), pH, total alkalinity and total CO2 were measured aboard the R/V Ocean Researcher 1. Because of the sill that separates these two seas in the Luzon Strait with a maximum depth of 2200 m, the SCS Deep Water has characteristics similar to those of water at about 2200 m in the WPS. The minimum pH and the maxima of normalized alkalinity and total CO2 commonly found in the open oceans at mid-depth also prevail in the WPS but are, however, very weak in the SCS. Rivers and inflows from Kuroshio Surface and Deep Waters through the Luzon Strait as well as those through the Mindoro Strait transport carbon to the SCS year-round. Meanwhile, the outflowing Taiwan Strait water as well as the SCS Surface and Intermediate Waters of the Luzon Strait transports carbon out of the SCS year-round. The Sunda Shelf is also a channel for carbon transport into the SCS in the wet season and out of the SCS in the dry season.fCO2 data and mass balance calculations indicate that the SCS is a weak CO2 source in the wet season but an even weaker CO2 sink in the dry season. With these facts taken together, the SCS is likely a very weak CO2 source. Anthropogenic CO2 penetrates to about 1500 m in depth in the SCS, and the entire SCS contains 0.60 ± 0.15 × 1015 g of excess carbon. Typical profiles of pH as well as the degree of saturation of each of calcite and aragonite in 1850 and 1997 are presented, and those for 2050 AD are projected. The maximum decrease in pH is estimated to be 0.16 pH units in the surface layer when the amount of CO2 is doubled. It is anticipated that aragonite in the upper continental slope will likely start to dissolve, thereby neutralizing excess CO2 by around 2050 AD. This paper is unique in that it presents the results of the first attempt ever to estimate the past, present and future physico-chemical properties of the world's largest marginal sea.  相似文献   

19.
The total organic carbon (TOC) and total inorganic carbon (CT) exchange between the Atlantic Ocean and the Mediterranean Sea was studied in the Strait of Gibraltar in September 1997. Samples were taken at eight stations from western and eastern entrances of the Strait and at the middle of the Strait (Tarifa Narrows). TOC was analyzed by a high-temperature catalytic oxidation method, and CT was calculated from alkalinity–pHT pairs and appropriate thermodynamic relationships. The results are used in a two-layer model of water mass exchange through the Strait, which includes the Atlantic inflow, the Mediterranean outflow and the interface layer in between. Our observations show a decrease of TOC and an increase of CT concentrations from the surface to the bottom: 71–132 μM C and 2068–2150 μmol kg−1 in the Surface Atlantic Water, 74–95 μM C and 2119–2148 μmol kg−1 in the North Atlantic Central Water, 63–116 μM C and 2123–2312 μmol kg−1 in the interface layer, and 61–78 μM C and 2307–2325 μmol kg−1 in the Mediterranean waters. However, within the Mediterranean outflow, we found that the concentrations of carbon were higher at the western side of the Strait (75–78 μM C, 2068–2318 μmol kg−1) than at the eastern side (61–69 μM C, 2082–2324 μmol kg−1). This difference is due to the mixing between the Atlantic inflow and the Mediterranean outflow on the west of the Strait, which results in a flux of organic carbon from the inflow to the outflow and an opposite flux of inorganic carbon. We estimate that the TOC input from the Atlantic Ocean to the Mediterranean Sea through the Strait of Gibraltar varies from (0.97±0.8)104 to (1.81±0.90)104 mol C s−1 (0.3×1012 to 0.56×1012 mol C yr−1), while outflow of inorganic carbon ranges from (12.5±0.4)104 to (15.6±0.4)104 mol C s−1 (3.99–4.90×1012 mol C yr−1). The high variability of carbon exchange within the Strait is due to the variability of vertical mixing between inflow and outflow along the Strait. The prevalence of organic carbon inflow and inorganic carbon outflow shows the Mediterranean Sea to be a basin of active remineralization of organic material.  相似文献   

20.
Month-to-month fluctuations in the abundance of bacteria and heterotrophic nanoflagellates (HNF) and bacterial production, as well as various chemical (nutrients, oxygen) and physical (salinity, temperature) parameters were analysed at a station located in the open middle Adriatic Sea during one decade (1997-2006). Being influenced by both coastal waters and open Adriatic circulation in the surface layer, and by the deep Adriatic water masses in the deep layers (100 m), this station is quite suitable for detecting the environmental changes occurring in the open Adriatic Sea with respect to the circulation of its water masses and their long-term changes and anomalies. Multivariate methods were used to identify seasonal and inter-annual changes of the investigated parameters, associating observed changes to the changes in Adriatic water masses and circulation regimes. The analyses showed that bacterial abundance and production were controlled by different water mass dynamics during 1997-2001 compared to 2002-2006 period, particularly noticeable in different seasonal patterns of biological parameters. The interplay between North Adriatic Dense Water (NAdDW) and Levantine Intermediate Water (LIW) resulted in a change in the available nutrients (NAdDW is poor in orthophosphates), and as a consequence different bacterial abundance and production. A few periods were examined in detail, such as 2004, when LIW inflow was particularly strong and was accompanied by an increase of bacterial and HNF abundances, as well as of bacterial production.  相似文献   

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