共查询到19条相似文献，搜索用时 109 毫秒
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东太平洋多金属结核中稀土元素的测试及其地球化学特征 总被引：1，自引：0，他引：1
本文研究了大洋多金属结核中稀土元素的测试方法.多金属结核这种特殊地质样品,含铁、锰一般在20%～40%左右,而铁、锰属富线光谱元素,对稀土元素谱线均有干扰.本文根据样品特性,仅取250mg多金属结核样品,碱熔后,通过小型阳离子树脂交换柱,采用不同类型酸和不同酸度,洗脱交换柱上的杂质和稀土元素,使稀土元素与杂质元素分离.采用此方法测试国家一级多金属结核标准物质GBW07249中的稀土元素,取得了满意结果.同时利用本法测试了东太平洋多金属结核中稀土元素,并对其地球化学特征进行了初步研究. 相似文献
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在莱恩海山链MP2海山的一块富钴结壳样品新壳层中,发育有"褐红色碎屑物质",这种物质粒度细小,呈浸染状分布,以Fc-Mn壳层柱状结构间的填隙物的形式产出.基于对该海区结壳样品手标本和光片的观察,认为这种"褐红色碎屑物质"可作为新壳层的一个标志物.利用电子探针技术,对这块富钴结壳样品进行了分析,获得了该结壳新壳层中"褐红... 相似文献
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微波消解仪在海洋沉积物重金属环境有效态及全量分析形态分析中的应用 总被引：4，自引：0，他引：4
通过研究微波消解酸量及酸系、消解温度、消解时间、是否赶酸、是否加入 HF 等条件,得出了在加入12.5mL的4 1的NO3 -HCl时,微波消解温度175℃、消解时间20 min的情况下,近海海洋沉积物成份分析标准物质(GBW 07314)样品消解液不经赶酸(或经120℃赶酸后)直接以原子吸收分光光度计测定,其中Cu,Pb,Cd,Cr的溶出值在环境有效态标准范围内;Zn介于环境有效态与全量分析形态标准之间.基于上述条件,再加入2.5mL的HF后样品消解液经赶酸后测定,其中Cu,Pb,Zn,Cd,Cr的溶出值均在全量分析形态标准范围内. 相似文献
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《中国海洋大学学报(自然科学版)》2015,(5)
本文采用防腐高效溶样法,实验消解了国家标准物质GBW08517(海带)、GBW08571(贻贝)、GBW08573(黄鱼)、GBW010016(茶叶)、GBW07602(灌木枝叶)及GBW07603(灌木枝叶),标准模式测试了As、Cd、Cr、Cu、Hg、Mn、Pb、Se与Zn元素,测试结果大致与标准值相符合。该方法具有操作简单、扣合速度快(一秒扣合)、试剂用量少、密封效果好、安全可靠、消解完全(有效消解有机质)、批量处理(一次完成200个样品)等优点,可在生物及环境样品分析中广泛应用。 相似文献
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南海东部海盆海山磁性对比 总被引：1，自引：0，他引：1
根据 1 980年～ 1 987年在南海海盆进行地球物理调查获取的海山地形和地磁异常资料 ,运用虚源法 ,对南海东部海盆区域的 9座海山作了磁性计算及对比。结果表明 :(1 )每座海山非均匀磁性反演的磁异常形态比均匀磁性反演的磁异常形态更接近观测异常 ,海山为非均匀磁化。 (2 )每座海山的非均匀磁化计算的拟合度参数值 (GFR值 )大于均匀磁化计算的拟合度参数值 (GFR0 值 ) ,平均每座海山增加 3 .7。 (3 )海山形成后均向北运移 ,位于东部海盆北侧的5座海山沿纬向位移的平均距离为 9.2 1°,南侧 4座海山沿纬向位移的平均距离为 3 .6 7°;海山均呈逆时针旋转 ,但旋转的角度存在区域性差异 ;东部海盆的运移方式与东邻的吕宋岛、西菲律宾海盆和台湾岛相一致。 (4)海山的磁化强度呈明显的分区性 ,北侧 5座海山的磁化强度大于南侧 4座海山的磁化强度 ,推测东部海盆形成过程中整体向北运动 相似文献
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南海海盆15°N附近呈东西向展布的珍贝-黄岩海山被认为是32~17Ma前南海海盆的残留扩张中心.对采自黄岩海山的两个火山岩样品(9DG,9DG-2)进行了岩石学、地球化学和年代学研究.两个样品的SiO2含量分别为60.3%和63.6%,Al2O3含量分别为17.56%和17.55%,TiO2含量分别为0.48%和0.31%,碱度率分别为3.88和3.62.根据岩石学和岩石化学分类,样品属碱性系列的粗面岩.对稀土元素和微量元素分析表明岩石具有洋岛玄武岩(OIB)型配分型式,轻重稀土总量比(∑c(LREE)/∑c(HREE))和球粒陨石标准化镧镱比((La/Yb)N)分别高达17.22和27.23,并具有铕负异常和锶、磷、钛亏损的特点.样品9DG的锶-钕-铅同位素分析结果为锶-87的含量与锶-86的含量之比值为0.704183,钕-143的含量与钕-144的含量之比值为0.512827,铅-206的含量与铅-207的含量之比值为18.68668,铅-207的含量与铅-204的含量之值为15.67962,铅-208的含量与铅-204的含量之比值为39.00261,表明初始岩浆来自软流圈地幔,具有与珍贝海山玄武岩相似的同位素组成.经钾-氩法测年,粗面岩的年龄为(7.77±0.49)Ma,略晚于珍贝海山玄武岩的年龄[(9.1±1.29)~10.0±1.80Ma],属于南海扩张期后晚中新世火山活动的产物.对比珍贝海山玄武岩的地球化学和同位素特征,认为两者有相同的岩浆源区,但是它们经历了不同程度的结晶分异过程,在晚中新世期间珍贝-黄岩海山可能有地幔柱活动. 相似文献
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海山铁锰结壳基岩岩石学特征及其生长关系 总被引：2，自引：0，他引：2
为了研究海山铁锰结壳基岩类型与结壳壳层生长的关系。对麦哲伦海山及中太平洋海山区取得的铁锰结壳及其基岩样品在电子显微镜下进行了观察和研究。结果表明，上述2个区域基岩岩石类型主要有玄武岩，火山熔岩，火山碎屑岩，硅质岩和碳酸盐岩，其中麦哲伦海山玄武岩为块状构造，中太平洋海山玄武岩则主要为气孔-杏仁状构造，多发生蚀变或完全蚀变，硅质岩颗粒物质主要是硅藻，碳酸盐岩则以晶质灰岩为主，结壳壳层厚度在各类基岩类型上都有变化，以在玄武岩和碳酸盐岩上变化最大。 相似文献
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中国系列标准海水制备与质量评价 总被引：1，自引：1，他引：1
中国系列标准海水是国家二级标准物质 [GBW (E) 130 0 11],在盐度或电导率传感器的现场检定 ,实验室盐度计的检定和校准中应用广泛。主要介绍中国系列标准海水的制备和不确定度分析。 相似文献
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能量色散X射线荧光光谱法测定海洋碎屑沉积物中28种元素 总被引：1，自引：0，他引：1
采用粉末样品压片制样,利用Epsilon3能量色散X射线荧光光谱仪(EDXRF)对我国边缘海碎屑沉积物中28种主量元素和微量元素进行测定。使用33个海洋沉积物、深海沉积物、水系沉积物、三角洲沉积物和岩石标样等国内外标准物质建立标准曲线,采用仪器软件的数学模式校正基体效应和元素间的谱线重叠效应。经国家标准物质检验,分析结果与标样值吻合;元素的检出限为0.02~124.14μg·g-1;精密度(RSD)均小于9%。对我国边缘海碎屑沉积物样品进行分析,其测定值与重量法、电感耦合等离子体光谱法和电感耦合等离子体质谱法的测定值基本一致。鉴于Epsilon3 EDXRF具有体积小、多元素同时快速分析、准确度高和精密度好的优点,可考虑作为船载仪器,在科考现场测定海洋沉积物的元素含量,对于及时指导海上工作、撰写航次报告具有重要作用。 相似文献
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V. Balaram 《Marine Georesources & Geotechnology》1999,17(1):17-26
A polymetallic nodule reference sample (No. 2388)collected from the Indian Ocean, and seven other samples, two from the United States Geological Survey, USA (Nod-A-1 and Nod-P-1), three from Russia (OOPE 601, OOPE 602, and OOPE 603), and two from China (GSPN-2 and GSPN-3), collected from different loca tions, are available for calibration purposes and as control samples in the analytical programs for polymetallic nodules and associated sediments to ensure accurate measurements. They are not certified for precious metal concentrations, however, and the data available are very scanty. An attempt has been made to provide working values for platinum, palladium, gold, and silver and indicative values for osmium, iridium, and ruthenium in these eight ferromanganese nodule reference samples, using inductively coupled plasma mass spectrometry (ICP-MS). To assess the accuracy of the method, certified reference materials, WPR-1, WMS-1, WMG-1, and WGB-1 Canadian Certified Materials Project (CCRMP, Canada) were analyzed, and the data obtained were compared with the certified values. The estimate of analytical reproducibility was found to be better than 15 % RSD for most elements with comparable accuracy. The data presented for this set of manganese nodule reference samples may be useful in geochemical studies of manganese nodules and associated sediments. 相似文献
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In this article, sampling locations, sample types, sample processing methods, and certified values of ocean manganese nodule and sediment reference materials available throughout the world are briefly described. Recommended or information values of major, minor, and trace constituents in those samples have also been collected, and a review of the main characteristics of their property values is presented. 相似文献
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高压密闭消解-电感耦合等离子体光谱和质谱联合测定海洋地质样品中52种元素 总被引：4，自引：0，他引：4
An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples. 相似文献
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单道扫描电感耦合等离子发射光谱的内标元素选择的灰色关联分析再研究(英文) 总被引：1，自引：0，他引：1
应用动态灰色模型（ＧＭ）的灰色关联分析（ＧＩＡ）为单道扫描（ＳＣＳ）电感偶合等离子发射光谱（ＩＣＰＯＥＳ）选择内标（ＩＳＴＤ）。经发射强度序列的ＧＩＡ计算和关联度序列优化后,Ｇｅ ２１９．８７ 被指定为内标。应用内标法和无内标法对中华人民共和国标样ＧＢ０７２３２ 的各元素的分析结果的相对百分误差范围分别为：０．８％ ～７．５％ 和２．５％ ～１７．５％ 。变更系数（ＣＶ）范围分别为：０．７％ ～２．９％ 和２．０％ ～５．８％ 。对内标选择与平均关联度的关系,Ｇｅ ２１９．８７ 特征的某些具体问题及统计相关分析与灰色关联分析在内标选择计算中的不可替代性问题,亦进行讨论 相似文献
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Final dissolved organic carbon broad community intercalibration and preliminary use of DOC reference materials 总被引：1，自引：0，他引：1
Jonathan H. Sharp Craig A. Carlson Edward T. Peltzer Dawn M. Castle-Ward Karen B. Savidge Katherine R. Rinker 《Marine Chemistry》2002,77(4):1819
A broad community intercalibration exercise for accurate measurement of dissolved organic carbon (DOC) in seawater has been carried out over a period of 5 years. A set of 10 natural samples with DOC content from 40 to 200 μM C were accompanied by two glucose standards and a “zero C” blank; all sealed in glass ampoules. Samples were sent to all interested analysts for “blind” analysis; 62 laboratories in 17 countries participated. A total of 59 separate analyses were determined to be acceptable by screening criteria based on standards and blank; another nine sets of analyses did not pass the screening. The majority of the analyses, both those passing and those that did not, were performed with high temperature combustion (HTC) methods, six sets of analyses were done using wet chemical oxidation methods.From the 53 sets of acceptable HTC analyses, the coefficient of variation (%CV) for analytical comparability of the samples was 10% (“community precision”). It is estimated that the individual replicate injection precision for most instruments was approximately 2% and that no additional variability was caused by differences within the ampoules of individual samples. The additional variability over 2% was likely a result of both random and systematic differences in analytical capabilities from instrument to instrument and from day to day for individual instruments. With an arbitrary selection after the fact, smaller subsets of analysts can show comparability better than 10% and duplicate or triplicate runs on different days of the full sets of samples in several laboratories showed comparability in the 2–6.5% range. Experienced oceanic analysts, with internal or shared reference materials, can now show reproducibility and comparability at a level closer to 2%.Preliminary use of DOC reference materials by 14 participants showed day-to-day reproducibilities for their laboratories in the 2–6% range in most cases; several with poorer reproducibility do not normally perform DOC analyses on samples with concentrations as low as the deep ocean reference used here. Use of these reference materials can also give a demonstration of comparability between laboratories. For credibility of DOC analyses, it is necessary for analysts to use community reference materials and report results of their analytical performance with these references.This paper does not identify individual data nor should it be considered an evaluation of individual laboratories or analysts. The purpose is to show the summary picture of the international community of DOC analysts as it existed in the mid- to late 1990s. 相似文献
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本文介绍了低盐度海水中5种重金属元素混合溶液标准物质的研究和制备过程。以稀释的大洋海水为基体,用容量法以加标方式制备了低盐度海水中重金属标准物质。各元素统计结果表明样品的均匀性和稳定性良好。经9家具有中国计量认定(CMA)资质的实验室分别采用原子吸收分光光度法、电感耦合等离子体质谱法和阳极溶出伏安法对标准溶液进行分析定值,并用国家标准物质作量值溯源,以分析结果的总平均值作为标准值,标准值及不确定度的结果分别为铜15.2±0.7 μg/L、铅15.3±0.7 μg/L、锌98.9±4.7 μg/L、镉2.02±0.10 μg/L以及铬15.3±0.6 μg/L。该标准物质可用于近岸、河口区低盐度海水重金属分析过程的量值传递和质量控制。 相似文献
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Patrick Louchouarn Rainer M.W. Amon Shuiwang Duan Christina Pondell Shaya M. Seward Noah White 《Marine Chemistry》2010,118(1-2):85-97
A series of reference materials are proposed for intercomparison and quality control purposes during the quantification of lignin oxidation products (LOP) from diverse environmental matrices. These materials are all easily accessible and certified for diverse organic constituents (NIST and IHSS). They represent a suite of natural environmental matrices (from solids to aqueous) and are characterized by a wide range of organic carbon and lignin concentrations with abundant proportions of all major LOP. The variability of LOP concentrations and signatures for all these materials averages 3–5% and does not exceed 10%. Using these standards, a new quantification method was developed and validated for the determination of low-level CuO oxidation products using capillary gas chromatography–tandem mass spectrometry (GC/MS–MS). Tandem mass spectrometry provides both the high sensitivity and selectivity required for the identification and quantification of trace levels of dissolved lignin. The method is particularly useful for removing interference from co-eluting isotopes generated from the DOM matrix and during glucose amendment procedures of low-carbon samples. Such glucose amendment is not necessary, however, when the CuO to organic carbon weight-to-weight ratio can be kept at a value < 200–300. 相似文献
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The published global ocean tide models show good agreement in deep oceans and exhibit differences in complex coastal areas, along with subsequent Ocean Tide Loading Displacement (OTLD) modeling differences. Meanwhile, OTLD parameters (amplitudes and phase lags) derived by Global Positioning System (GPS) Precise Point Positioning (PPP) approach need long time to converge to a stable state and show poor precision of S2, K1, and K2 constituents. Based on the fact that no constraint is imposed in the current kinematic solution, a new method is put forward, in which global ocean tide model predictions are taken as the priori information constraints to speed up the convergence rate and improve the accuracy of the GPS-derived OTLD parameters. First, the data of tide gauge from 01 January 2014 to 31 December 2016 are used to generate the harmonic parameters to evaluate the accuracy of six global ocean tide models and a regional ocean tide model (osu.chinesea.2010). Osu.chinesea.2010 model shows good agreement with the tide gauge results, while NAO99b model presents relatively large difference. The predictions from osu.chinesea.2010 and NAO99b model are employed as reference and the prior information, respectively. Second, continuous observations of 12 GPS sites during 2006–2013 in Hong Kong are collected to generate three dimensional OTLD amplitudes and phase lags of eight constituents using PPP with prior information constraints approach and harmonic analysis. Third, comparing the convergence time of eight constituents from PPP without and with priori information constraints approaches, the results show that the new method can significantly improve the convergence rate of OTLD amplitude estimates which obtain a certain level of stability seven years earlier than that derived by the PPP without priori information constraints. Precision of OTLD parameters derived by the new method is about 1 mm. By comparing with the precision of single PPP approach, the accuracy of eight constituents has been improved, especially for S2, K1, and K2 constituents. Finally, through comparing the different correction effects of OTLD estimates on the coordinates and their time series of the ground GPS stations, the results show that OTLD estimates derived by the new approach have similar influence as the osu.chinasea.2010 ocean tide model. The new method provides an effective means to improve the convergence and precision of the GPS-derived OTLD parameters, and achieve a similar correction as the high precision ocean tide model. 相似文献