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1.
The annual subduction rate of the North Pacific was calculated based on isopycnally averaged hydrographic climatology (HydroBase), high-resolution winter mixed-layer climatology (NWMLC), and various wind stress climatologies from ship reports, numerical weather prediction products, and satellite products. The calculation was performed using Lagrangian coordinates in the same manner as in previous works, except a less smoothed oceanic climatology (HydroBase and NWMLC) was used instead of a World Ocean Atlas. Differences in the wind stress climatologies have very little effect on subduction rate estimates. The subduction rate census for density classes showed peaks corresponding to subtropical mode water (STMW), central mode water (CMW), and eastern subtropical mode water (ESTMW). The deeper mixed layer and the associated sharper mixed-layer fronts in the present climatology resulted in a larger lateral induction, which boosted the subduction rate, especially for the potential density anomaly (σθ) range of the lighter STMW (25.0 < σθ < 25.2 kg m−3) and lighter CMW (26.0 < σθ < 26.2 kg m−3), compared to previous estimates. The renewal time of permanent pycnocline water was estimated as the volume of water divided by the subduction rate for each σθ class: 2–4 years for ESTMW (24.5 < σθ < 25.2 kg m−3), 2 years for the lighter STMW (25.0 < σθ < 25.3 kg m−3), 5–9 years for the denser STMW (25.3 < σθ < 25.6 kg m−3), 10–20 years for the lighter CMW (26.0 < σθ < 26.2 kg m−3), 20–30 years for the middle CMW (26.2 < σθ < 26.3 kg m−3), and 60 years or longer for the denser CMW (26.3 < σθ < 26.6 kg m−3). A comparison of the water volume and subduction rate in potential temperature–salinity (θ–S) space indicated that the upper permanent pycnocline water (25.0 < σθ < 26.2 kg m−3) was directly maintained by nondiffusive subduction of winter surface water, including STMW and lighter CMW. The lower permanent pycnocline water (26.2 < σθ < 26.6 kg m−3) may be maintained through the subduction of fresher and colder water from the subarctic–subtropical transition region and subsequent mixing with saltier and warmer water. Diagnosis of the potential vorticity (PV) of the subducted water demonstrated that the low PV of STMW was mainly due to the large subduction rate, whereas that of both ESTMW and CMW was due mainly to the small density advection rate (cross-isopycnal flow). Additionally, a relatively large subduction rate probably contributes to the low PV of part of the lighter CMW (ESTMW) formed in the region around 38°N and 170°W (28°N and 145°W), which is characterized by a relatively thick winter mixed layer and an associated mixed-layer front, causing a large lateral induction rate.  相似文献   

2.
Monte Carlo simulation of wave spectra was carried out to provide an assessment of JONSWAP spectral model and parameters. The simulation method is found to be satisfactory because (a) it excludes the spectral variability due to geophysical factors from the sampling errors in the spectral estimates and the statistical uncertainty in determining the model parameters; and (b) the simulated spectra can represent ideal spectral estimates where the sampling errors have been minimized by increasing the degrees of freedom of the spectra. The latter (b) allows both the magnitude of sampling errors to be evaluated and errors due to statistical uncertainty to be isolated. Thus, the stimulation study provides a useful error analysis to assess the JONSWAP spectral model and parameters. For instance, it is found from the results that the sampling errors could be as high as 20% while errors due to uncertainty in determining the model parameter could be as high as 17%. However, the overall errors may be reduced to the minimum of approx. 15% if the simulated spectra have 80 degrees of freedom and constant values of σa and σb i.e. σa = 0.07 and σb = 0.09. This implies that the maximum accuracy of 85% may be achieved in JONSWAP spectral model even though the α parameter has been underestimated by about 1.5%. The overestimated values of γ might come from the underestimated α and the biased φm estimator caused by the statistical uncertainty in the presence of a sharp spectral peak. Although the scale parameters (α and φm) exhibit smaller errors and variability than the shape parameters (ψ, σa and σb), they are more sensitive to the degrees of freedom of the spectra and their estimators are not better than the estimators of shape parameters. The simulation experiments have also shown that simulated spectra at 20–40 degrees of freedom contain a substantial amount of sampling errors. Therefore, the measured wave spectra at the same degrees of freedom (20–40) are not suitable and should not be used for evaluating the accuracy of any wave spectral model.  相似文献   

3.
A procedure is described for the analysis of the stable carbon isotopic composition of dissolved organic carbon (DOC) in natural waters from marine and higher-salinity environments. Rapid (less than 5 min) and complete oxidation of DOC is achieved using a modification of previous photochemical oxidation techniques. The CO2 evolved from DOC oxidation can be collected in less than 10 min for isotopic analysis. The procedure is at present suitable for oxidation and collection of 1–5 μmol of carbon and has an associated blank of 0.1–0.2 μmol of carbon.Complete photochemical oxidation of DOC standards was demonstrated by quantitative recovery of CO2 as measured manometrically. Isotopic analyses of standards by photochemical and high-temperature sealed-tube combustion methods agreed to within 0.3.. Photochemical oxidation of DOC in a representative sediment pore-water sample was also quantitative, as shown by the excellent agreement between the photochemical and sealed-tube methods. The δ13C values obtained for pore-water DOC using the two methods of oxidation were identical, suggesting that the modified photochemical method is adequate for the isotopically non-fractionated oxidation of pore-water DOC.The procedure was evaluated through an analysis of DOC in pond and pore waters from a hypersaline microbial mat environment. Concentrations of DOC in the water column over the mat displayed a diel pattern, but the isotopic composition of this DOC remained relatively constant (average δ13C = −12.4.). Pore-water DOC exhibited a distinct concentration maximum in the mat surface layer, and δ13C of pore-water DOC was nearly 8. lighter at 1.5–2.0-cm depth than in the mat surface layer (0–0.5-cm depth). These results demonstrate the effectiveness of the method in elucidating differences in DOC concentration and δ13C over biogeochemically relevant spatial and temporal scales. Carbon isotopic analysis of DOC in natural waters, especially pore waters, should be a useful probe of biogeochemical processes in recent environments.  相似文献   

4.
The salinity minimum frequently occurring in the Mixed Water Region between the Oyashio and Kuroshio Fronts seems to originate from the salinity minimum at the density of 26.8σθ called the North Pacific Intermediate Water. We examined water exchange of this region with the Oyashio and the Kuroshio Extension using mixing ratio RK defined as (θ - θOY)/(θK - θOY) × 100, where θOY, θK, and θ represent potential temperature of the Oyashio and Kuroshio Waters and their mixture on the isopycnal surfaces, respectively. CTD data were obtained by repeated observation from January 1990 to May 1991. RK increases southward from the Oyashio Front to the Kuroshio Front with the range of −20 to 120%. The gradient of RK on the isopycnal surfaces is large around the Oyashio Front above the 26.8σθ surface, while it is large around the Kuroshio Front below it. This agrees with the average RK in the Mixed Water Region decreasing greatly with the increase of density at densities less dense than 26.8σθ. We calculated thickness and volume transport of the Oyashio between the isopycnal surfaces near the coast of Hokkaido. They increase largely with density at densities less dense than 26.8σθ. It is supposed that the salinity minimum in the Mixed Water Region is the upper limit of the water largely influenced by the Oyashio Water. Its density could depend only on the density structure of the Oyashio.  相似文献   

5.
Microstructure measurements in natural waters: Methodology and applications   总被引：2，自引：0，他引：2  
Modern approaches to microstructure data processing, including wavelet denoising, are discussed. The wavelet procedure is applied to small-scale shear signals before estimating the dissipation rate ε and to the temperature/density profiles used to calculate Thorpe scales. Microstructure data obtained on the Mediterranean shelf of Catalonia are used to illustrate various approaches to the Thorpe displacement calculations. It is suggested that the Weibull probability function is an appropriate model for the Thorpe scale distribution. Microstructure measurements from the upper layer of the Boadella reservoir (Catalonia, Spain) support this finding.A new analytical approximation for the 1D Panchev–Kesich spectrum is deduced and the results of ε computation are compared with spectral fitting by the widely used Nasmyth spectrum. Applying the Kraichnan spectral model to compute ε from temperature spectra in the convective-viscous sub-range is examined as an alternative to the Batchelor spectrum. Microstructure measurements taken in Lake Banyoles (Catalonia, Spain) and in the North Atlantic were used for spectral calculations.Statistical analysis of eddy Kb and thermal Kθ diffusivities measured on a shallow shelf of the Black Sea shows the importance of process-orientated domain averaging of the diffusivities in obtaining good correspondence between Kb and Kθ in active turbulent regions. In weakly turbulent, stratified interior layers, the averaged Kb and Kθ differ significantly, which may point to the inapplicability of isotropic formulae used for ε and temperature dissipation χθ estimates, as well as to a dependence of the mixing efficiency γ on the Richardson number or in some cases on regions of fossil turbulence.  相似文献   

6.
This paper is concerned with the hydroelastic analysis of a pontoon-type, circular, very large floating structure (VLFS) with a horizontal submerged annular plate attached around its perimeter. The coupled fluid–structure interaction problem may be solved by using the modal expansion method in the frequency domain. It involves, firstly, the decomposition of the deflection of a circular Mindlin plate with free edges into vibration modes that are obtained analytically. Then the hydrodynamic diffraction and radiation forces are evaluated by using the eigenfunction expansion matching method which can also be done in an exact manner. The hydroelastic equation of motion is solved by the Rayleigh–Ritz method for the modal amplitudes, and then the modal responses are summed up to obtain the total response. The effectiveness of the attached submerged annular plate in reducing the motion of VLFS has been confirmed by the analysis.  相似文献   

7.
An accurate numerical prediction of the oceanic upper layer velocity is a demanding requirement for many applications at sea and is a function of several near-surface processes that need to be incorporated in a numerical model. Among them, we assess the effects of vertical resolution, different vertical mixing parameterization (the so-called Generic Length Scale –GLS– set of k–ε, k–ω, gen, and the Mellor–Yamada), and surface roughness values on turbulent kinetic energy (k) injection from breaking waves.First, we modified the GLS turbulence closure formulation in the Regional Ocean Modeling System (ROMS) to incorporate the surface flux of turbulent kinetic energy due to wave breaking. Then, we applied the model to idealized test cases, exploring the sensitivity to the above mentioned factors. Last, the model was applied to a realistic situation in the Adriatic Sea driven by numerical meteorological forcings and river discharges. In this case, numerical drifters were released during an intense episode of Bora winds that occurred in mid-February 2003, and their trajectories compared to the displacement of satellite-tracked drifters deployed during the ADRIA02-03 sea-truth campaign.Results indicted that the inclusion of the wave breaking process helps improve the accuracy of the numerical simulations, subject to an increase in the typical value of the surface roughness z0. Specifically, the best performance was obtained using αCH = 56,000 in the Charnok formula, the wave breaking parameterization activated, k–ε as the turbulence closure model. With these options, the relative error with respect to the average distance of the drifter was about 25% (5.5 km/day). The most sensitive factors in the model were found to be the value of αCH enhanced with respect to a standard value, followed by the adoption of wave breaking parameterization and the particular turbulence closure model selected.  相似文献   

8.
Henry's law constants were determined for α- and γ-hexachlorocyclohexane (HCH) as a function of temperature (0.5–45°C) in artificial seawater (SW; 30‰) and distilled water (DW) using the gas stripping method. Water samples (1–5 ml) were withdrawn from the stripping vessel during the stripping process (30–360 h), solvent extracted and analyzed by gas chromatography—electron-capture detection. The effect of bubbling depth was checked to ensure that bubbles leaving the system were at equilibrium with HCHs in the aqueous phase. Henry's law constants determined at 35 and 45°C in SW were significantly higher (P≤ 0.05) than in DW for both α- and γ-HCH, but not at lower temperatures. The slopes (m) and intercepts (b) of log H vs. 1 / T plots were: α-HCH (DW, 0.5–45°C); m = −2810 ± 110, B = 9.31 ± 0.38; α-HCH (SW, 0.5–23°C); M = −2969 ± 218, B = 9.88 ± 0.76; γ-HCH (DW, 0.5–45°C); M = −2382 ± 160, B = 7.54 ± 0.54; γ-HCH (SW, 0.5–23°C); M = −2703 ± 276, B = 8.68 ± 0.96. Henry's law constants determined in this study compared well with those calculated from reported vapor pressure and solubility data.  相似文献   

9.
This study examined the relationship between carbon isotopic composition of sinking organic matter (OM) and the biological, physical and chemical properties of the surface ocean in the Cariaco Basin. The 13C/12C ratio of OM (δ13Corg) in sinking particles was determined on sediment trap samples from four depths collected from 1996 to 1999 as part of the CArbon Retention In A Colored Ocean time series. Water column properties, including temperature, productivity, chlorophyll and concentration of dissolved CO2, were concurrently measured on monthly cruises. The δ13Corg varied from a high of –17.7‰ to a low of –22.6‰ during the study period. The variation of the δ13Corg throughout seasonal cycles was directly proportional to the strength of upwelling and was negatively correlated with temperature (r2=0.64). During the 1996–1997 upwelling event, the strongest during the study period, the δ13Corg increased by 4.4‰ whereas during the 1998–1999 upwelling event, the weakest during the study period, the δ13Corg only increased by 3.3‰. Contrary to most previous studies, we observed a negative relationship (r2=0.53) between [CO2 aq] and the estimated isotopic fractionation factor (εp). However, there was no correlation between εp and the calculated growth rates indicating that there was non-diffusive uptake of carbon into phytoplankton cells. It thus appears that [CO2 aq] does not control the δ13Corg in the water column of the study site. The best explanation for the isotopic enrichment observed is a carbon concentrating mechanism (CCM) in phytoplankton. The existence of a CCM in phytoplankton has major implications for the interpretation of the δ13Corg in the Cariaco Basin.  相似文献   

10.
Western boundary currents flow poleward from low latitudes until they ultimately separate from the coast and turn eastward into the ocean interior. The separation is mainly due to either: (i) the variation of the Coriolis parameter with latitude (β) which causes vanishing of the near-wall depth; (ii) vanishing wind stress curl over the ocean interior which forces zero meridional transport; or (iii) opposing currents that flow toward the equator and force the northward flowing currents to turn offshore (Agra and Nof, Deep Sea Research I, 40, 2259–2282). Here, we focus on the third kind of separated currents and show that, due to β, such separated currents migrate along the wall. A nonlinear “reduced gravity” one-and-a-half layer model is used to compute the desired migration speed. Solutions of the primitive equations are constructed analytically assuming that the translation rate is steady. It is found that the migration rate along the wall is given by βRd2 cosα/2 sinγ, where Rd is the Rossby radius, α an angle that measures the inclination of the joint offshore currents relative to the north, and γ is the angle between the axis of the joint offshore currents and the wall. The migration meridional component can be either northward or southward (depending on the inclination of the wall) but the zonal component is always westward. When the separated joint offshore flow is in the east-west direction (i.e. α = π/2 or 3π/2 so that the separated flow is zonal) no migration is taking place. It turns out that the above migration formula is so robust that it is also describes the migration rate in a two-and-a-half layer model where one current is allowed to, at least partially, dive under the other. For most separated currents the computed migration rate is a few centimeters per second.Possible application of this theory to the Confluence zone in the South Atlantic (where significant seasonal movement of the separation latitude has been observed) is discussed.  相似文献   

11.
The title problem is solved in the case where uniform applied loading is present at the plate outer boundary. Two independent solutions are obtained: the optimized Rayleigh–Ritz method and the finite element algorithmic procedure. Good engineering agreement is shown to exist. The proposed analytical procedure is convenient from a designer's viewpoint. Admittedly exact analytical solutions can be found in terms of Bessel functions, the procedure being rather complex from an engineering viewpoint.  相似文献   

12.
Two models, a spectral refraction model (Longuet-Higgins) and a parabolic equation method (PEM) refraction-diffraction model (Kirby), are used to simulate the propagation of surface gravity waves across the Southern California Bight. The Bight contains numerous offshore islands and shoals and is significantly larger (≈ 300 km by 300 km) than regions typically studied with these models. The effects of complex bathymetry on the transformation of incident wave directional spectra, S0(f,θ0), which are very narrow in both frequency and direction are difficult to model accurately. As S0(f,θ0) becomes broader in both dimensions, agreement between the models improves and the spectra predicted at coastal sites become less sensitive to errors in the bathymetry grid, to tidal changes in the mean water depth, and to uncertainty in S0(f,θ0) itself. The smoothing associated with even relatively narrow (0.01 Hz-5° bandwidth) S0(f,θ0) is usually sufficient to bring the model predictions of shallow water energy into at least qualitative agreement. However, neither model is accurate at highly sheltered sites. The importance of diffraction degrades the predictions of the refraction model, and a positive bias [O (10%) of the deep ocean energy] in the refraction-diffraction model estimates, believed to stem from numerical “noise” (Kirby), may be comparable to the low wave energy. The best agreement between the predicted spectra generally occurs at moderately exposed locations in deeper waters within the Bight, away from shallow water diffractive effects and in the far-field of the islands. In these cases, the differences between the models are small, comparable to the errors caused by tidal fluctuations in water depth as waves propagate across the Bight. The accuracy of predicted energies at these sites is likely to be limited by the uncertainty in specifying S0(f,θ0).  相似文献   

13.
Atlantic–Mediterranean anchovies were genetically characterized at two polymorphic nuclear loci (intron 6 of two creatine-kinase genes) and compared to reference Engraulis albidus and E. encrasicolus samples from the northern Western Mediterranean to provide new insights into their geographic structure. Northeastern Atlantic anchovy, represented by one sample from the Canary archipelago and one sample from the Alboran Sea, were genetically distinct from Mediterranean E. encrasicolus (Weir and Cockerham's ^θ = 0.027–0.311), indicating geographic isolation from either side of the Almería–Oran oceanographic front. Generally smaller genetic differences were evident among anchovy populations from different sub-basins in the Mediterranean (^θ = − 0.019–0.116), the genetic differences between Black Sea and Ionian Sea/Aegean Sea anchovies being the strongest (^θ = 0.002–0.116). There was no evidence of the presence of E. albidus in our samples outside Camargue (northern shore of the Western Mediterranean). However, a sample from the southern Western Mediterranean appeared to be genetically intermediate between E. albidus and Mediterranean E. encrasicolus, indicating possible hybridization. Anchovy from the Benguela current system off southern Africa possessed allele frequencies characteristic of E. albidus at one locus and Northeastern Atlantic anchovy at the other locus, suggesting past introgression.  相似文献   

14.
A simple k–ε turbulence closure is introduced which has no stability functions but instead a Richardson number-dependent turbulent Prandtl number. Its free parameters are determined in a comparison with microstructure observations from a stratified and sheared tidal estuary and laboratory measurements. The closure is able to simulate observed turbulent dissipation rates (ε) and turbulent length scales (lth) in regions of strong mean shear and small gradient Richardson number (Rg) to within factors of 2–3. It fails in regions of small shear and large Rg, presumably because of the dominance of internal wave-driven mixing. Additional simulations with a k–ε closure with stability functions taken from Canuto et al. [Canuto, V.M., Howard, A., Cheng, Y., Dubovikov, M.S., 2001. Ocean turbulence I: one-point closure model. Momentum and heat vertical diffusivities. J. Phys. Oceanogr. 31, 1413–1426] and with the closure of Baumert and Peters [Baumert, H., Peters, H., 2004. Turbulence closure, steady state, and collapse into waves. J. Phys. Oceanogr. 34, 505–512] show poor performance. Establishing a valid 1:1 comparison of simulated and observed ε and lth requires nudging the model velocity and density toward observed values because free model integrations quickly diverge from the observations. Steady state gradient Richardson numbers are constrained to a range of 0.18–0.25, while flux Richardson numbers are constrained to the range of 0.1–0.22. The closure output is rather insensitive to such parameter variations. The simulations are sensitive, however, to the treatment of the observed velocity and density used to nudge the model. Good closure performance requires averaging the measured tidal flow over about an hour, a time scale for which conventional numerical models of estuarine circulations should be able to match observed shears. In the closure simulations the TKE balance stays close to a production–dissipation balance. The time rate of change and vertical diffusion of TKE are small, of the same order of magnitude, and vary in magnitude relative to each other systematically across the water column.  相似文献   

15.
New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H2S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H2S. In order to assess the origin of fatal H2S as well as the cause of petroleum alteration, H2S concentrations and the isotopes, δ34S and δ13C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ34S values have been measured for comparison. The high concentrations of H2S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H2S concentrations are greater than 10% its δ34S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ34S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H2S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ13C values become significantly heavier as TSR proceeded. Methane δ13C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H2S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.  相似文献   

16.
The Faroe Bank Channel (FBC) is the deepest passage across the Greenland–Scotland Ridge and there is continuous overflow of dense water through the channel, which provides a substantial contribution to the global thermohaline circulation. Since November 1995, Acoustic Doppler Current Profilers (ADCPs) have been moored at the sill of the channel continuously, except for short annual servicing periods. In addition to this, CTD sections have regularly been occupied across the channel and instruments, recording temperature and salinity, have been moored for short periods. These observations demonstrate that the channel, due to its small width, can be monitored fairly well with only one ADCP mooring and they allow the generation of a time-series of overflow volume flux for the 1995–2005 period. The kinematic overflow flux, defined solely from the velocity field, was found to have an average value of 2.1 ± 0.2 Sv with a seasonal and with inter-annual variations of approximately 10% amplitude, but with no discernible trend for the whole period. The average flux of water with potential density exceeding 27.8 kg m−3 was found to be 1.9 ± 0.3 Sv with average properties: θ = 0.25 °C, S = 34.93, γθ = 28.01 kg m−3 for this period. No evidence was found for a weakening overflow flux, but the salinity of the FBC-overflow, especially the warmer parts, has increased substantially during the period, which implies an increased average density on the order of 0.01 kg m−3. Previous observations of a helical cross-channel circulation are confirmed and may explain the thin pycnocline layer, but shear-instability induces intensive mixing that puts a lower limit on the layer thickness. Critical control at one point of the sill cross-section, rather than friction, seems to govern the overflow dynamics and simple layered models can explain much of the observed features as well as the seasonal variation, but potential vorticity, as defined for a single overflow layer, is not conserved. A previously suggested 1950–2000 weakening of the FBC-overflow, which was partly based on a subset of the data presented here, is not supported by the full dataset.  相似文献   

17.
A sediment disk reactor was tested in once flow-through mode to retrieve kinetic parameters for the Monod rate law that describes sulfate reduction. The experimental method was compared with a previously described procedure by the authors where a sediment plug-flow reactor was operated in a recirculation mode. In recirculation mode, accumulation of metabolic byproducts in certain cases may result in negative feedback, thus preventing accurate determination of kinetic information. The method described in this article provides an alternative to the recirculation sediment plug-flow-through reactor technique for retrieving kinetic parameters of microbially mediated reactions in aquatic sediments.For sulfate reduction in a saltmarsh site, a maximum estimate of the half-saturation concentration, Ks, of 204±26 μM and a maximum reaction rate, Rm, of 2846±129 nmol cm(wetsediment)3 d−1 was determined. The Ks value obtained was consistent with the one estimated previously (Ks=240±20 μM) from a different site within the same saltmarsh mud flat using a recirculating reactor. From the Rm value and reduction rates determined using 35SO42− incubation experiments, we infer that sulfate reduction is limited in the field. Substrate availability is not the main contributor for the limitation, however. Competition from other microbes, such as iron reducers affects the activity of sulfate reducers in the suboxic to anoxic zones, whereas aerobes compete in the oxic zone. High sulfide concentration in the pore water may also have acted as a toxin to the sulfate reducers in the field.  相似文献   

18.
Sand transport rates were measured via bedload traps that were inserted into the sediment surface on the continental shelf southwest of England. Analysis of the trapped mobile sediment shows this to be finer and better sorted than nearby Shipek grab samples. The transport rates are combined with simultaneous, near-bed flow measurements to assess a Bagnold type predictive equation,j = k 1(u 2 100 -u 2 100cr)u 100. The measured transport rates vary between 0.41 × 10–3 and 1.67 × 10–3 gm/cm s. The data yield a mean calibration coefficient (k 1) of 0.4 × 10–6 which is slightly lower than values computed from flume and shallow water data.  相似文献   

19.
In order to evaluate the respiration–photosynthesis dynamics in two contrasting North Sea estuaries, pH, temperature, alkalinity, chlorophyll-a (chl-a), and isotopic ratios of dissolved inorganic carbon (δ13CDIC) and dissolved oxygen (δ18ODO) were measured in the Tyne (July 2003) and Tweed (July 2003 and December 2003) estuaries. Using a concentration-dependent isotope mixing line, δ13CDIC values in the Tweed (July 2003) demonstrated mostly conservative behaviour across the estuary, reflecting mixing between riverine and marine sources, although some samples were slightly more 13C-enriched than predicted δ13CDIC values. Low pCO2 (less than 2 times atmospheric pressure) and 18O-depleted δ18ODO signatures below equilibrium with the atmosphere provided further evidence for net autotrophy in the Tweed estuary in summer 2003. Conversely, in the Tyne during the summer and in the Tweed during the winter higher pCO2 (up to 6.5 and 14.4 times atmospheric partial pressure in the Tweed and Tyne, respectively), slightly 13C-depleted δ13CDIC and 18O-enriched δ18ODO values indicated heterotrophy as the dominant process. The relatively large releases of CO2 observed during these two estuarine surveys can be attributed to significant oxidation of terrigenous organic matter (OM). This study therefore demonstrates the usefulness of combined δ18ODO and δ13CDIC isotopes in examining the relationship between respiration–photosynthesis dynamics and the fate of terrestrially derived OM during estuarine mixing.  相似文献   

20.
Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.  相似文献   

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