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1.
Abstract. A number of recent studies based on hydrographic observations and modelling simulations have dealt with the major climatic shift that occurred in the deep circulation of the Eastern Mediterranean. This work presents hydrographic observations and current measurements conducted from 1997 to 1999, which reveal strong modifications in the dynamics of the upper, intermediate and deep layers, as well as an evolution of the thermohaline characteristics of the deep Aegean outflow since 1995. The reversal of the circulation in the upper layer of the north/central Ionian is worthy of note. The observations indicate a reduction of Atlantic Water in the northern Ionian with an increase on the eastern side of the basin. In the intermediate layer, the dispersal path of the Levantine Intermediate Water (LIW) is altered. Highly saline (>39.0) and well-oxygenated intermediate waters were found near the Western Cretan Arc Straits. They flow out from the Aegean, thus interrupting the traditional path of the LIW, and spread prevalently northwards into the Adriatic Sea. In the deep layer, dense waters, exiting from the Adriatic (σø−29.18 kg · m−3), flow against the western continental margin in the Ionian Sea at a depth of between 1000–1500 m. Dense waters of Aegean origin (> 29.20 kg · m−3), discharged into the central region of the Eastern Mediterranean during the early stages of the transient, propagate prevalently to the east in the Levantine basin and to the west in the northern Ionian Sea. Near-bottom current measurements conducted in the Ionian Sea reveal unforeseen aspects of deep dynamics, suggesting a new configuration of the internal thermohaline conveyor belt of the Eastern Mediterranean.  相似文献   

2.
Dissolved organic carbon (DOC), dissolved organic nitrogen (DON) and dissolved organic phosphorus (DOP) measured in deep profiles in the N-E Atlantic and in the N-W Mediterranean in the period 1984–2002 are described. After accurate validation, they show close agreement with those previously published.Classic profiles were obtained, with concentrations decreasing in deep waters. In the Mediterranean and in the Atlantic comparable concentrations were found in the 1500–2000 m waters, 44–46 μmol l−1 DOC, 2.6–2.8 μmol l−1 DON and 0.02–0.03 μmol l−1 DOP. In the surface layers, DOC concentrations were higher, but DON and DOP concentrations lower, in the Mediterranean than in the Atlantic, leading to higher element ratios in the Mediterranean. In autumn, values were, respectively, DOC:DON 17 vs. 14, DOC:DOP 950 vs. 500 and DON:DOP 55 vs. 35. The data suggest an increase in DOC and DON in the North Atlantic Central Water over 15 years, which may be linked to the North Atlantic climatic oscillations.Refractory DOM found in the 1500–2000 m layer exhibited C:N:P ratios of 1570:100:1. The labile+semi-labile (=non-refractory) DOM (nrDOM) pool was computed as DOM in excess of the refractory pool. Its contribution to total DOM above the thermocline in the open sea amounted to 25–35% of DOC, 30–35% of DON, and 60–80% of DOP. Element ratios of the nrDOM varied among stations and were lower than those of refractory DOM, except for C:N in the Mediterranean: nrDOC:nrDON 10–19, nrDOC:nrDOP 160–530 and nrDON:nrDOP 15–38. The specific stoichiometry of DOM in the Mediterranean led us to postulate that overconsumption of carbon is probably a main process in that oligotrophic sea.By coupling non-refractory DOM stoichiometry and relationships between the main DOM elements in the water column, the relative mineralization of C, N and P from DOM was studied. Below the thermocline, the preferential removal of phosphorus with regard to carbon from the semi-labile DOM can be confirmed, but not the preferential removal of nitrogen. In the ocean surface layers, processes depend on the oceanic area and can differ from deep waters, so preferential carbon removal seems more frequent. Bacterial growth efficiency data indicate that bacteria are directly responsible for mineralization of a high proportion of DON and DOP in the deep water.  相似文献   

3.
In the current study, low-background γ-spectrometry was employed to determine the 228Ra/226Ra activity ratio and 137Cs activity of 84 coastal water samples collected at six sites along the main island of Japan (Honshu Island) within the Sea of Japan, including the Tsushima Strait, and two other representative sites on Honshu Island (a Pacific shore and the Tsugaru Strait) at 1-month intervals in 2006.The 228Ra/226Ra ratio of coastal waters in the Sea of Japan exhibited similar patterns of seasonal variation, with minimum values during early summer (228Ra/226Ra = 0.6–0.8), maximum values during autumn (228Ra/226Ra = 1.5–3), and a time lag in their temporal changes ( 2.5 months and over  1300 km distance). However, the 2 other sites represented no clear periodic variation.In contrast to the positive correlation between 137Cs activity (0.6–1.7 mBq/L) and salinity (15–35), the 228Ra/226Ra ratio of coastal water samples from the Sea of Japan was not observed to correlate with salinity, and the increase in the 228Ra/226Ra ratio was not as marked (0.5–1; May–June 2004 and 2005) during the migration along Honshu Island. The input of land-derived water and/or the diffusion of radium from coastal sediments is unlikely to have affected the wide seasonal variation in the 228Ra/226Ra ratio observed in these water samples.The seasonal variation in the 228Ra/226Ra ratio recorded for the coastal waters of the Sea of Japan is considered to be mainly controlled by the remarkable changes in the mixing ratio of the 228Ra-poor Kuroshio and the 228Ra-rich continental shelf waters within the East China Sea (ECS). After passing through the Tsushima Strait, this water mass moves northeast along the coastline of the Sea of Japan as the Tsushima Coastal Branch Current (TCBC).  相似文献   

4.
The Wadden Sea (North Sea, Europe) is a shallow coastal sea with high benthic and pelagic primary production rates. To date, no studies have been carried out in the Wadden Sea that were specifically designed to study the relation between pelagic respiration and production by comparable methods. Because previous studies have suggested that the import of primary-produced pelagic organic matter is important for benthic Wadden Sea carbon budgets, we hypothesised that on an annual average the northern Wadden Sea water column is autotrophic. To test this hypothesis, we studied annual dynamics of primary production and respiration at a pelagic station in a shallow tidal basin (List Tidal Basin, northern Wadden Sea). Since water depth strongly influences production estimates, we calculated primary production rates per unit area in two ways: on the basis of the mean water depth (2.7 m) and on the basis of 1 m depth intervals and their respective spatial extent in the List Tidal Basin. The latter more precise estimate yielded an annual primary production of 146 g C m− 2 y− 1. Estimates based on the mean water depth resulted in a 40% higher annual rate of 204 g C m− 2 y− 1. The total annual pelagic respiration was 50 g C m− 2 y− 1. The P/R ratio varied between seasons: from February to October the water column was autotrophic, with the highest P/R ratio of 4–5 during the diatom spring bloom in April/May. In autumn and winter the water column was heterotrophic. On an annual average, the water column of the List Tidal Basin was autotrophic (P/R 3). We suggest that a large fraction of the pelagic produced organic matter was respired locally in the sediment.  相似文献   

5.
Quasi-synoptic observations of the horizontal and vertical structure of a cold-core cyclonic mesoscale eddy feature (Cyclone Noah) were conducted in the lee of Hawai’i from November 4–22, 2004 as part of the E-Flux interdisciplinary collaborative research program. Cyclone Noah appears to have spun up to the southwest of the ‘Alenuihaha Channel (between Maui and Hawai’i) as a result of strong and persistent northeasterly trade winds through the channel. Shipboard hydrographic surveys 2.5 months later suggest that Noah weakened and was in a hypothesized spin-down phase of its life cycle. Although the initial surface expression of Noah was limited in scale to 40 km in diameter and, as evidenced by surface temperatures, 2–3 °C cooler than the surrounding waters, depth profiles revealed a fully developed semi-elliptical shallow feature (200 m), 144 km long and 90 km wide (based on sigma-t=23 kg m−3) with tangential speeds of 40–80 cm s−1, and substantial isopycnal doming. Potential vorticity distribution of Noah suggests that radial horizontal flow of the core water was inhibited from the surface to depths of 75 m, with high vorticity confined above the sigma-t=23.5 kg m−3 isopycnal surface. Upward displacements of isopycnal surfaces in the eddy's center (50 m) were congruent with enhanced pigment concentrations (0.50 mg m−3). Comparisons of the results obtained for E-Flux I (Noah) and E-Flux III (Opal) suggest that translation characteristics of cyclonic Hawaiian lee eddies may be important in establishing the biogeochemical and biological responses of the oligotrophic ocean to cyclonic eddies.  相似文献   

6.
The biogeochemistry of the following elements Al, Fe, Sibio, POC, PNtot, Cabio, Sorg, P and Mn has been studied within waters of the Cretan Sea in March and September 1994, as part of the PELAGOS project. Particulate aluminosilicate concentrations, exemplified by Al, are very low (<1 μgl−1) especially in the upper waters. Higher concentrations occur below 200 m, especially at depths of 200 m and 500–700 m in the central and eastern areas, and are thought to result from sediment injections from the shelf edge and slope. The results for Sibio, Cabio, P and Sorg show much higher concentrations within the photic waters. Temporal and spatial high concentrations in these waters closely relate to the existence of cyclonic eddies on the east and west sides of the sea, while low concentrations are associated with an intervening anticyclonic eddy. However in September, discharge of Black Sea Water in the west sufficiently suppresses the thermocline to prevent upwelled water from reaching the surface and hence these substances are prevented from forming.Particulate Fe (expressed as Feexcess) concentrations show much higher concentrations relative to Al in September, and are thought to result from additional atmospheric inputs. The low particulate Mn concentrations in the upper water compared with deeper waters are considered to be a product of photoinhibition of MnOx precipitation from Mn(II).An attempt has been made to assess input/output budgets of Al, Ca, Fe and Mn through the Antikithira and Kassos Straits. Much of the outflows leave through the Kassos Strait and, except for Ca, net outflows through the Antikithira Straits are negligible.  相似文献   

7.
Benthic foraminiferal biomass, density, and species composition were determined at 10 sites in the Gulf of Mexico. During June 2001 and 2002, sediment samples were collected with a GoMex box corer. A 7.5-cm diameter subcore was taken from a box core collected at each site and sliced into 1-cm or 2-cm sections to a depth of 2 or 3 cm; the >63-μm fraction was examined shipboard for benthic foraminifera. Individual foraminifers were extracted for adenosine triphosphate (ATP) using a luciferin–luciferase assay, which indicated the total ATP content per specimen; that data was converted to organic carbon. Foraminiferal biomass and density varied substantially (2–53 mg C m−2; 3600–44,500 individuals m−2, respectively) and inconsistently with water depth: although two 1000-m deep sites were geographically separated by only 75 km, the foraminiferal biomass at one site was relatively low (9 mg C m−2) while the other site had the highest foraminiferal biomass (53 mg C m−2). Although most samples from Sigsbee Plain (>3000 m) had low biomass, one Sigsbee site had >20 mg foraminiferal C m−2. The foraminiferal community from all sites (i.e. bathyal and abyssal locales) was dominated by agglutinated, rather than calcareous or tectinous, species. Foraminiferal density never exceeded that of metazoan meiofauna at any site. Foraminiferal biomass, however, exceeded metazoan meiofaunal biomass at 5 of the 10 sites, indicating that foraminifera constitute a major component of the Gulf's deep-water meiofaunal biomass.  相似文献   

8.
Sources and discharges of dissolved organic carbon (DOC) from the central Sumatran river Siak were studied. DOC concentrations in the Siak ranged between 560 and 2594 μmol l−1 and peak out after its confluence with the river Mandau. The Mandau drains part of the central Sumatran peatlands and can be characterized as a typical blackwater river due to its high DOC concentration, its dark brown-coloured, acidic water (pH 4.4–4.7) and its low concentration of total suspended matter (12–41 mg l−1). The Mandau supplies about half of the DOC that enters the Siak Estuary where it mixes conservatively with ocean water. The DOC input from the Siak into the ocean was estimated to be 0.3 Tg C yr−1. Extrapolated to entire Indonesia the data suggest a total Indonesian DOC export of 21 Tg yr−1 representing 10% of the global riverine DOC input into the ocean.  相似文献   

9.
The dynamics of dissolved inorganic carbon (DIC) and processes controlling net community production (NCP) were investigated within a mature cyclonic eddy, Cyclone Opal, which formed in the lee of the main Hawaiian Islands in the subtropical North Pacific Gyre. Within the eddy core, physical and biogeochemical properties suggested that nutrient- and DIC-rich deep waters were uplifted by 80 m relative to surrounding waters, enhancing biological production. A salt budget indicates that the eddy core was a mixture of deep water (68%) and surface water (32%). NCP was estimated from mass balances of DIC, nitrate+nitrite, total organic carbon, and dissolved organic nitrogen, making rational inferences about the unobserved initial conditions at the time of eddy formation. Results consistently suggest that NCP in the center of the eddy was substantially enhanced relative to the surrounding waters, ranging from 14.1±10.6 (0–110 m: within the euphotic zone) to 14.2±9.2 (0–50 m: within the mixed layer) to 18.5±10.7 (0–75 m: within the deep chlorophyll-maximum layer) mmol C m−2 d−1 depending on the depth of integration. NCP in the ambient waters outside the eddy averaged about 2.37±4.24 mmol C m−2 d−1 in the mixed layer (0–95 m). Most of the enhanced NCP inside the eddy appears to have accumulated as dissolved organic carbon (DOC) rather than exported as particulate organic carbon (POC) to the mesopelagic. Our results also suggest that the upper euphotic zone (0–75 m) above the deep chlorophyll maximum is characterized by positive NCP, while NCP in the lower layer (>75 m) is close to zero or negative.  相似文献   

10.
Two strings of moored current meters deployed between March 1993 and May 1994, together with monthly CTD surveys, provide the first comprehensive set of observations over the seasonal cycle in the Clyde Sea. In the summer, a strong thermal stratification maintained a partial isolation of the deep waters. In winter, the stratification was weaker, and a 1 °C temperature inversion was persistent from November to the end of March. Rapid inflow of dense water from the North Channel of the Irish Sea served to re-establish the strong stratification in the spring. The mean rate of exchange was estimated from the salinity (practical salinity scale) and mass budgets to be 1·1×104 m3 s−1, indicating an average flushing time for the Clyde Sea of 3–4 months.Episodic increases in deep water salinity indicated that bottom water renewal occurred throughout the winter. Intense renewal events were observed in March 1993 and February 1994, when the North Channel density was near its seasonal maximum, and were coincident with periods of high wind stress. In the month prior to these rapid spring inflows, the basin bottom salinity reached its seasonal minimum, indicating that the effects of mixing dominated over renewal at this time. A marked inflow in the summer was inferred from the salinity budget, and observed as a salinity increase at a depth of 90 m. A 2-layer flow was observed in the Arran Deep basin throughout the year, the surface flow forming part of a clockwise circulation about Arran, with an opposing bottom layer circulation. This surface circulation prevents freshwater from entering the Kilbrannan Sound, leaving this area relatively susceptible to deep water mixing by the wind.At a station in the north of the basin, the internal tidal current was observed to have an amplitude of 2–3 cm s−1, which is half the amplitude of the barotropic tide. The energy available to mix the water column mixing associated with the internal tide at this position is estimated to be 0·01 mWm−2, which is 2 orders of magnitude less than wind mixing. The kinetic energy density in the Clyde Sea was found to be predominantly in low frequency oscillations (<1·0 cycles per day), the seasonal variation exhibiting some correlation with the wind.  相似文献   

11.
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12.
We report measurements of dissolved iron (dFe, <0.4 μm) in seawater collected from the upper 300 m of the water column along the CLIVAR SR3 section south of Tasmania in March 1998 (between 42°S and 54°S) and November–December 2001 (between 47°S and 66°S). Results from both cruises indicate a general north-to-south decrease in mixed-layer dFe concentrations, from values as high as 0.76 nM in the Subtropical Front to uniformly low concentrations (<0.1 nM) between the Polar Front and the Antarctic continental shelf. Samples collected from the seasonal sea-ice zone in November–December 2001 provide no evidence of significant dFe inputs from the melting pack ice, which may explain the absence of pronounced ice-edge algal blooms in this sector of the Southern Ocean, as implied by satellite ocean-color images. Our data also allow us to infer changes in the dFe concentration of surface waters during the growing season. South of the Polar Front, a comparison of near-surface with subsurface (150 m depth) dFe concentrations in November–December 2001 suggests a net seasonal biological uptake of at least 0.14–0.18 nM dFe, of which 0.05–0.12 nM is depleted early in the growing season (before mid December). A comparison of our spring 2001 and fall 1998 data indicates a barely discernible seasonal depletion of dFe (0.03 nM) within the Polar Frontal Zone. Further north, most of our iron profiles do not exhibit near-surface depletions, and mixed-layer dFe concentrations are sometimes higher in samples from fall 1998 compared to spring 2001; here, the near-surface dFe distributions appear to be dominated by time-varying inputs of aerosol iron or advection of iron-rich subtropical waters from the north.  相似文献   

13.
Lagrangian time series of dimethylsulfide (DMS) concentrations from a cyclonic and an anticyclonic eddy in the Sargasso Sea were used in conjunction with measured DMS loss rates and a model of vertical mixing to estimate gross DMS production in the upper 60 m during summer 2004. Loss terms included biological consumption, photolysis, and ventilation to the atmosphere. The time- and depth (0–60 m)-averaged gross DMS production was estimated to be 0.73±0.09 nM d−1 in the cyclonic eddy and 0.90±0.15 nM d−1 in the anticyclonic eddy, with respective DMS replacement times of 5±1 and 6±1 d. The higher estimated rate of gross production and lower measured loss rate constants in the anticyclonic eddy were equally responsible for this eddy's 50% higher DMS inventory (0–60 m). When normalized to chlorophyll and total dimethylsulfoniopropionate (DMSP), estimated gross production in the anticyclonic eddy was about twice that in the cyclonic eddy, consistent with the greater fraction of phytoplankton that were DMSP producers in the anticyclonic eddy. Higher rates of gross production were estimated below the mixed layer, contributing to the subsurface DMS maximum found in both eddies. In both eddies, gas exchange, microbial consumption, and photolysis were roughly equal DMS loss terms in the surface mixed layer (0.2–0.4 nM d−1). Vertical mixing was a substantial source of DMS to the surface mixed layer in both eddies (0.2–0.3 nM d−1) owing to the relatively high DMS concentrations below the mixed layer. Estimated net biological DMS production rates (gross production minus microbial consumption) in the mixed layer were substantially lower (by almost a factor of 3) than those estimated in a previous study of the Sargasso Sea, which may explain the relatively low mixed-layer DMS concentrations found here during July 2004 (3 nM) compared to previous summers (4–6 nM).  相似文献   

14.
The recent changes in the thermohaline circulation of the Eastern Mediteranean caused by a transition from a system with a single source of deep water in the Adriatic to one with an additional source in the Aegean are described and assessed in detail. The name Cretan Sea Overflow Water (CSOW) is proposed for the new deep water mass. CSOW is warmer (θ>13.6°C) and more saline (S>38.80) than the previously dominating Eastern Mediterranean Deep Water (EMDW), causing temperatures and salinities to rise towards the bottom. All major water masses of the Eastern Mediterranean, including the Levantine Intermediate Water (LIW), have been strongly affected by the change. The stronger inflow into the bottom layer caused by the discharge of CSOW into the Ionian and Levantine Basins induced compensatory flows further up in the water column, affecting the circulation at intermediate depth. In the northeastern Ionian Sea the saline intermediate layer consisting of Levantine Intermediate Water and Cretan Intermediate Water (CIW) is found to be less pronounced. The layer thickness has been reduced by factor of about two, concurrently with a reduction of the maximum salinity, reducing advection of saline waters into the Adriatic. As a consequence, a salinity decrease is observed in the Adriatic Deep Water. Outside the Aegean the upwelling of mid-depth waters reaches depths shallow enough so that these waters are advected into the Aegean and form a mid-depth salinity-minimum layer. Notable changes have been found in the nutrient distributions. On the basin-scale the nutrient levels in the upper water column have been elevated by the uplifting of nutrient-rich deeper waters. Nutrient-rich water is now found closer to the euphotic zone than previously, which might induce enhanced biological activity. The observed salinity redistribution, i.e. decreasing values in the upper 500–1400 m and increasing values in the bottom layer, suggests that at least part of the transition is due to an internal redistribution of salt. An initiation of the event by a local enhancement of salinity in the Aegean through a strong change in the fresh water flux is conceivable and is supported by observations.  相似文献   

15.
Nutrient and oxygen data collected in the southern Aegean Sea (Cretan Sea) and the straits of the Cretan Arc, during the four seasonal PELAGOS cruises in 1994–1995, are investigated and compared with data collected from 1987 to 1992 within the same area. During the cruises of the PELAGOS Project, nutrient enrichment of the intermediate layers of the Cretan Sea was observed, as a result of intrusion of ‘nutrient-rich, oxygen-poor’ Transition Mediterranean Water (TMW) compensating the Cretan Deep Water (CDW) outflow. TMW occupied the intermediate layers of the entire Cretan Sea. The concentrations of nutrients within this layer were often two times higher than those observed in the same area during previous studies undertaken before 1992 (increase 2.5 μmol/l of nitrate, 0.05 μmol/l of phosphate and 2.5μmol/l of silicate). The decrease of oxygen in this layer is about 0.8ml/l (35 μmol/l). Outflow of CDW occurs principally through the Antikithira and Kassos Straits (the two deeper straits of the Cretan Arc); it results in an increase of oxygen content but a decrease in the nutrient content of water in the deep and bottom layers outside the Cretan Sea. The major mesoscale features in the area have a major influence of the distributions and exchanges of nutrients and oxygen through the straits of the Cretan Arc. The surface and the intermediate layers were richer in nutrients and poorer in oxygen in spring (March 1994), than in autumn (September 1994).  相似文献   

16.
In order to better understand the relationship between the natural radionuclide 234Th and particulate organic carbon (POC), marine particles were collected in the northwestern Mediterranean Sea (spring/summer, 2003 and 2005) by sediment traps that separated them according to their in situ settling velocities. Particles also were collected in time-series sediment traps. Particles settling at rates of >100 m d−1 carried 50% and 60% of the POC and 234Th fluxes, respectively, in both sampling years. The POC flux decreased with depth for all particle settling velocity intervals, with the greatest decrease (factor of 2.3) in the slowly settling intervals (0.68–49 m d−1) over trap depths of 524–1918 m, likely due to dissolution and decomposition of material. In contrast the flux of 234Th associated with the slowly settling particles remained constant with depth, while 234Th fluxes on the rapidly settling particles increased. Taking into account decay of 234Th on the settling particles, the patterns of 234Th flux with depth suggest that either both slow and fast settling particles scavenge additional 234Th during their descent or there is significant exchange between the particle classes. The observed changes in POC and 234Th flux produce a general decrease in POC/234Th of the settling particles with depth. There is no consistent trend in POC/234Th with settling velocity, such as might be expected from surface area and volume considerations. Good correlations are observed between 234Th and POC, lithogenic material and CaCO3 for all settling velocity intervals. Pseudo-Kds calculated for 234Th in the shallow traps (2005) are ranked as lithogenic material opal <calcium carbonate <organic carbon. Organic carbon contributes 33% to the bulk Kd, and for lithogenic material, opal and CaCO3, the fraction is 22% each. Decreases in POC/234Th with depth are accompanied by increases in the ratio of 234Th to lithogenic material and opal. No change in the relationship between 234Th and CaCO3 was evident with depth. These patterns are consistent with loss of POC through decomposition, opal through dissolution and additional scavenging of 234Th onto lithogenic material as the particles sink.  相似文献   

17.
Geochemical estimates of N2 fixation in the North Atlantic often serve as a foundation for estimating global marine diazotrophy. Yet despite being well-studied, estimations of nitrogen fixation rates in this basin vary widely. Here we investigate the variability in published estimates of excess nitrogen accumulation rates in the main thermocline of the subtropical North Atlantic, testing the assumptions and choices made in the analyses. Employing one of these previously described methods, modified here with improved estimates of excess N spatial gradients and ventilation rates of the main thermocline, we determine a total excess N accumulation rate of 7.8 ± 1.7 × 1011 mol N yr− 1. Contributions to excess N development include atmospheric deposition of high N:P nutrients (adding excess N at a rate of 3.0 ± 0.9 × 1011 mol N yr− 1 for  38% of the total), high N:P dissolved organic matter advected into and mineralized in the main thermocline (adding excess N at 2.2 ± 1.1 × 1011 mol N yr− 1 for  28% of the total), and, calculated by mass balance of the excess N field, N2 fixation (adding excess N at 2.6 ± 2.2 × 1011 mol N yr− 1 for  33% of the total). Assuming an N:P of 40 and this rate of excess N accumulation due to the process, N2 fixation in the North Atlantic subtropical gyre is estimated at  4 × 1011 mol N yr− 1. This relatively low rate of N2 fixation suggests that i) the rate of N2 fixation in the North Atlantic is greatly overestimated in some previous analyses, ii) the main thermocline is not the primary repository of N fixed by diazotrophs, and/or iii) the N:P ratio of exported diazotrophic organic matter is much lower than generally assumed. It is this last possibility, and our uncertainty in the N:P ratios of exported material supporting excess N development, that greatly lessens our confidence in geochemical measures of N2 fixation.  相似文献   

18.
New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σt16.2) and anoxic layers (σt16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σt16.2±0.2 kg m−3. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σt16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate.  相似文献   

19.
Biweekly composite averages of the standing stock of sea-surface chlorophyll (SSC) were derived from SeaWiFS satellite ocean-color data at 44 benthic sampling stations occupied along the continental slope and rise by the Deep Gulf of Mexico Benthos (DGoMB) program. At the 22 DGoMB sites north of 26°N and west of 91°W in the NW Gulf of Mexico, annual average SSC was 0.19 mg m−3, ranging at most locations from annual highs of about 0.3 mg m−3 in November–February to lows of about 0.1 mg m−3 in May–August. Comparison of three years of SeaWiFS data (January 1998–December 2000) showed little inter-annual variation at these NW Gulf stations. In contrast, at the 22 NE Gulf sites north of 26°N and east of 91°W, SSC averaged 2.8 times higher than in the NW Gulf, showing also strong inter-annual variation. Maxima in the NE region occurred in November–February and also during summers. The summer maxima were associated with Mississippi River water transported offshore to the east and southward by anticyclonic eddies in the NE Gulf. The apparent increases in SSC in June–August at NE Gulf stations reached average monthly concentrations >50% greater than in November–February. Based on a primary productivity model and a vertical flux model, the calculated export of particulate organic carbon (POC flux reaching the seafloor) was estimated as 18 mg C m−2 day−1 at the 22 NE Gulf stations, and 9 mg C m−2 day−1 at the 22 NW Gulf stations. These estimates are comparable to fluxes measured by benthic lander by others in the DGoMB program, which may drive the differences in west versus east bathymetric zonation and community structure of macrobenthos that were sampled with large box corers by others in the DGoMB program.  相似文献   

20.
Delayed coincidence counters (RaDeCC), used for measuring 223Ra and 224Ra preconcentrated from water onto MnO2-impregnated acrylic fiber (“Mn-fiber”), require a standard Mn-fiber column that has a precisely known activity of 224Ra for calibration. This may be done by adding an aged 228Th standard solution to adsorb both 228Th and its daughter 224Ra quantitatively onto a Mn fiber. We used both seawater and deionized water (DIW) for testing the adsorption efficiency of Th and Ra onto Mn fibers. Our experimental results show that more than 50% of thorium (232Th and 228Th) breaks through the Mn-fiber column when DIW is used as a medium. However, near quantitative recoveries are obtained if filtered (0.45 μm) seawater is used to prepare the standard. In the case of pure DIW, the pH (initial pH  5.3) rises to > 10 after passing through the column while seawater (initial pH  7.8) changes to  7.2. Thus, the lack of thorium adsorption in DIW may be attributed to this huge increase of pH and the consequent formation of Th(OH)4 and polyhydroxyl colloids. Based on these observations, we recommend that one should use either artificial seawater or natural seawater (which has negligible 224Ra and 228Th) as a loading solution after 0.45 μm filtration. In addition, the thorium adsorption efficiency should be confirmed either by thorium analysis of the effluent solution or long-term monitoring of the supported 224Ra on the Mn fiber using the RaDeCC. Similar cautions are likely necessary for making 223Ra standards by adsorption of 227Ac onto Mn fibers.  相似文献   

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