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1.
4种海洋贝类对水体中Pb的富集规律   总被引:1,自引:0,他引:1  
为了研究泥蚶、菲律宾蛤、缢蛏和单齿螺等海洋贝类对海水中Pb的富集规律,本文在设置Pb质量浓度分别为0.001 0,0.003 5,0.006 0,0.011 0,0.026 0和0.051 0 mg/L 6个试验组中,采用半静水法进行泥蚶、菲律宾蛤、缢蛏和单齿螺对海水中Pb的富集试验,分别在0,1,3,5,10,15,20,25和30 d时取出部分贝类用微波消解原子吸收光谱法测定Pb含量,并探讨了贝类对Pb的富集机制,比较了不同贝类对Pb的富集能力。实验结果表明:4种贝类均表现出了对Pb有一定的富集效应。水体中Pb质量浓度达到0.003 5 mg/L时,泥蚶对Pb富集明显;水体中Pb质量浓度达到0.006 0 mg/L时,菲律宾蛤对Pb富集明显。水体中Pb质量浓度达到0.011 0 mg/L时,缢蛏和单齿螺对Pb富集明显。总体上,贝类体内重金属含量随着水体中Pb质量浓度和富集时间的增加而增加。在Pb质量浓度低于0.051 mg/L的所有试验组中,时间越长,贝类体内富集的Pb含量越高,但在3 d左右时,贝类体内富集的Pb含量却出现低值。  相似文献   

2.
深圳福田白骨壤红树林Cu,Pb,Zn,Cd的累积及分布   总被引:17,自引:0,他引:17  
郑文教  林鹏 《海洋与湖沼》1996,27(4):386-393
于1994年3月,采用样方法分析、探讨深圳福田自然保护区车公庙林区白骨壤红树林重金属Cu,Ph,Zn,Cd元素的累积及分布。结果表明:该林地表层土壤(0—3cm深),Cu,Ph,Zn,Cd的含量分别为383.28.7,1140,0136×10-6,储量分别为5285.40,3960.60,15732.00,18.77mg/m2、植物体各部位Cu,Pb,Zn,Cd含量范围分别为1.81-13.8,0.402-3.51,3.42-69.5,0.013-0295×10-6对表层土壤加权平均富集系数为Cd>Zn>Cu>Pb.该群落Cu,Pb,Zn,Cd现存累积量分别为53.70,19.27,187.89,0.72mg/m2;年净存留累积量分别为4063.91,1318.14,16358.62,60.21μg/m2;林地残留物相应元素的储量分别为2091.18,1958.66,5046.60,19.30μg/m2。该林区不同群落叶层Cu,Pb,Zn,Cd现存累积量为白骨壤林>桐花树林>秋茄林。  相似文献   

3.
深圳湾福田潮滩重金属含量及对大型底栖动物的影响   总被引:9,自引:0,他引:9  
杨丽  蔡立哲  童玉贵  高阳 《台湾海峡》2005,24(2):157-164
根据2002年1月和10月在深圳湾福田潮滩同时获得的大型底栖动物和重金属数据进行分析表明,深圳湾福田潮滩Cu、Pb、Zn、Cd含量明显超标.2002年10月Pb、Cd、Cu、Zn含量的平均值比2002年1月高.与历史资料对比,近几年Cu含量有增加趋势.2002年1月,深圳湾福田潮滩奇异稚齿虫密度与沉积物中Pb、Cd、Cu、Zn含量均有显著负相关关系.尖刺缨虫密度与Pb、Cd、Zn含量均有显著负相关关系,与Cu的相关系数也接近显著相关临界值.2002年10月,只有小头虫密度与Cd有显著正相关关系.文中分析了影响重金属与大型底栖动物数量关系的环境因素.  相似文献   

4.
广东惠州海域是粤港澳大湾区生态安全屏障的关键节点。本文分析了2018年夏季惠州20种海洋鱼类体内Cu、Pb、Cd含量,利用单因子污染指数(SFI)进行了重金属污染水平评价,探讨了栖息水层、食性对鱼类体内重金属富集的影响。结果显示,(1)2018年夏季惠州海域鱼类体内重金属含量大小顺序与春季相同,皆为CuPbCd;夏季鱼类体内Cd含量显著高于春季,其与海水、沉积物重金属的季节变化无明显响应关系。(2)栖息水层方面,中上层鱼类体内Cu、Cd含量平均值高于中下层及底层鱼类,Pb含量反之;鱼类体内Cu含量差异显著,说明生境中重金属生物可利用性和鱼种类对鱼体内重金属富集有重要影响。(3)杂食性鱼类体内Cu和Pb较高,底栖动物食性鱼类容易富集Cd,反映了鱼类选择性吸收重金属元素;方差分析结果显示,摄食行为并未导致鱼类体内Cu、Pb、Cd元素富集。(4)鱼类体内Cu与Pb的Pearson相关分析结果为显著正相关,反映其具有同源性。(5)SFI平均值显示,夏季惠州海洋鱼类体内重金属污染程度高于春季;夏季鱼类体内Cu含量为正常水平,Pb整体为轻度污染,Cd为重度污染。(6)参照《无公害食品水产品中有毒有害物质限量》(NY 5073-2006)和WHO/FAO标准,2018年夏季鱼类体内Cd含量分别超标70%和20%,需引起关注。  相似文献   

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季节变化和个体大小对河蚬积累重金属的影响   总被引:12,自引:0,他引:12  
孙平跃  王斌 《海洋通报》2004,23(2):19-24
以长江河口湿地生态系统一种习见的大型底栖动物河蚬Corbicula fluminea为研究对象,分析了季节变化和个体大小对河蚬积累Zn,Cu,Pb,Cd和Cr的影响。结果表明。季节变化对河蚬积累重金属没柯显著的影响,春季和秋季河蚬体内的重金属含量较为接近。河蚬体内Cu的积累量在不同大小个体间存在着显著的差异,大个体体内的Cu含量明显高于小个体,但Zn,Cd,Cr和Pb的含量在不同大小个体间的差异不显著。总体上看,季节变化和个体大小对河蚬积累重金属的影响均不是很显著。  相似文献   

6.
产于烟台的5种海产经济动物对Cr的富集存在明显差异。底栖的滤食性贝类的富集量远远超自游泳的种类。紫贻贝为理想的海洋重金属Cr污染的指示动物。烟台海域各海区紫贻贝体风Cr含量最高,向国远海区逐渐降低。5种海产动物体内Cr的含量均在食品允许范围之内。  相似文献   

7.
热致死小球藻生物富集Cr3+的研究   总被引:5,自引:0,他引:5       下载免费PDF全文
研究了热致死小球藻对微量Cr^3 的生物吸附富集和机理。结果表明,培养72h左右的热致死小球藻吸附富集Cr^3 的能力最强;当pH为4.5—5.0,藻浓度为1—2g/L时,死体藻对Cr^3 有较好的生物吸附作用;随着Cr^3 浓度增加,单位质量藻的Cr^3 吸附量呈上升趋势,但其Cr^3 吸附率却急剧下降。热致死小球藻对Cr^3 的吸附可以用Freundlich模型描述,拟合方程为:q=5.3369C11/2.6295,R^2=0.9974;在生物吸附的起始阶段,藻体对Cr^3 的吸附较快,40min左右时藻体达到最大吸附量。  相似文献   

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泥螺自2001因养殖目的引入黄河三角洲以来,随着分布范围的扩大和种群数量的增长,已成为当地潮间带的关键种。泥螺给当地民众带来较高收入,但其对底栖生态系统的潜在影响还不清楚。为了明确该种群的生物扰动对底栖微藻和微生物的初级生产,以及对水体-沉积物界面营养盐交换的影响,开展了该项实验。结果表明,在光照条件下,泥螺能显著影响沉积物-水体界面的溶解氧DO通量;在黑暗及无生物处理组的恢复期,泥螺能显著增加两界面间氨氮的通量。底栖微藻和小型生物在黑暗条件下也能增加氨氮的通量;但在有光照条件下,上述微藻和小型底栖动物对沉积物-水体界面间溶解氧和氨氮通量的影响不明显。实验结果为更深入理解泥螺对生态系统的影响提供重要理论支持。  相似文献   

9.
产于烟台的5种海产经济动物对Cr的富集存在明显差异。底栖的滤食性贝类(紫贻贝M.edulis、栉孔扇贝Chlamysfarreri、菲律宾蛤仔Ruditapesphilippinensis)的富集量远远超过自游泳的种类(中华马鲛Scomberomorussinensis,长额七腕虾Heptacarpuspandaloides)。紫贻贝为理想的海洋重金属Cr污染的指示动物.烟台海域各海区紫贻贝体内Cr含量最高,向边远海区逐渐降低。5种海产动物体内Cr的含量均在食品允许范围之内。  相似文献   

10.
羟基自由基对细胞的三大基本分子核酸、蛋白质、葡萄糖有着强烈破坏作用。压载水中羟基的比值浓度达到0.63mg/L时,含有微生物液体中的总蛋白质含量从1.49g/100mL降到0.993g/100mL,减少了33.4%;核酸中RNA、DNA的含量分别从2.43μg/mg、0.96μg/mg分别减少到1.29μg/mg、0.19μg/mg,分别减少46.9%、80.2%;葡萄糖含量从0.246mg/100mL增加到0.492mg/100mL,增加了1倍。试验数据表明,羟基自由基氧化、分解、破坏了微生物细胞三大基本分子核酸、蛋白质、葡萄糖,这是微生物致死的主要生化原因之一。  相似文献   

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鳚亚目 4 科 33 属 95 种,鰕虎鱼亚目 5 科 98 属 259 种,刺尾鱼亚目 5 科 11 属 65 种,鲈形目 19亚目 104 科 535 属 1799 种。  相似文献   

12.
Soil-sized particulates have been collected on board ship by a mesh technique from the lower troposphere of the North, Equatorial and South Atlantic Ocean, northern and southern Indian Ocean, South and East China Sea and various coastal localities.Spectrographic analysis reveals that, on average, the particulates have concentrations of Mn, Ni, Co, Ga, Cr, V, Ba, and Sr which are of the same order of magnitude as those in average crustal material. In contrast, the average concentrations of Pb, Sn, and Zn are one order of magnitude higher than those in average crustal material.Within this “world-wide” average there are significant geographical variations in the distributions of Pb, Sn, and Zn which may be related to anthropogenic sources.On the basis of trace-element distributions lower tropospheric soil-sized marine particulates have been divided into four genetic components; local, zonal, inter-zonal, and global. The proportions of these components vary geographically, and each component may have both a natural and an anthropogenic fraction.  相似文献   

13.
Tautog, Tautoga onitis, is an abundant species of fish in estuaries of the northeastern United States. Planktonic tautog larvae are abundant in summer in these estuaries, but there is little information on rates of growth of tautog larvae feeding on natural assemblages of food in the plankton. We examined abundance and growth of larval tautog and environmental factors during weekly sampling at three sites along a nearshore‐to‐offshore transect in Buzzards Bay, Massachusetts, USA during summer 1994. This is the first study of a robust sample size (336 larvae) to estimate growth rates of field‐caught planktonic tautog larvae feeding on natural diets, using the otolith daily‐growth‐increment method. The study was over the entire summer period when tautog larvae were in the plankton. The sampling sites contrasted in several environmental variables including temperature, dissolved oxygen (DO), and chlorophyll a concentration. There was a temporal progression in the abundance of tautog larvae over the summer, in relation to location and temperature. Tautog larvae were first present nearshore, with a pronounced peak in abundance occurring at the nearshore sites during the last 2 weeks in June. Larvae were absent at this time further offshore. From late June through August, larval abundance progressively decreased nearshore, but increased offshore although never approaching the abundance levels observed at the nearshore sites. The distribution and abundance of tautog larvae appeared to be related to a nearshore‐to‐offshore seasonal warming trend and a nearshore decrease in DO. Otoliths from 336 larvae ranging from 2.3 to 7.7 mm standard length had otolith increment counts ranging from 0 to 19 increments. Growth of larval tautog was estimated at 0.23 mm·day?1, and length of larvae prior to first increment formation was estimated at 2.8 mm indicating that first increment formation occurs 3–4 days after hatching at 2.2 mm. Despite spatial and temporal differences in environmental factors, there were no significant differences in growth rates at any of three given sites over time, or between sites. Because larval presence only occurred at a narrow range of temperature (17–23.5 °C) and DO (6.5–9.3 mg·l?1), in situ differences in growth did not appear to be because of differences in larval distribution and abundance patterns relative to these parameters.  相似文献   

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Concentrations of dissolved nutrients (NO3, PO4, Si), germanium species, arsenic species, tin, barium, dimethylsulfide and related parameters were measured along the salinity gradient in Charlotte Harbor. Phosphate enrichment from the phosphate industry on the Peace River promotes a productive diatom bloom near the river mouth where NO3 and Si are completely consumed. Inorganic germanium is completely depleted in this bloom by uptake into biogenic opal. The GeSi ratio taken up by diatoms is about 0·7 × 10?6, the same as that provided by the river flux, confirming that siliceous organisms incorporate germanium as an accidental trace replacement for silica. Monomethylgermanium and dimethylgermanium concentrations are undetectable in the Peace River, and increase linearly with increasing salinity to the seawater end of the bay, suggesting that these organogermanium species behave conservatively in estuaries, and are neither produced nor consumed during estuarine biogenic opal formation or dissolution. Inorganic arsenic displays slight removal in the bloom. Monomethylarsenic is produced both in the bloom and in mid-estuary, while dimethylarsenic is conservative in the bloom but produced in mid-estuary. The total production of methylarsenicals within the bay approximately balances the removal of inorganic arsenic, suggesting that most biological arsenic uptake in the estuary is biomethylated and released to the water column. Dimethylsulfide increases with increasing salinity in the estuary and shows evidence of removal, probably both by degassing and by microbial consumption. An input of DMS is observed in the central estuary. The behavior of total dissolvable tin shows no biological activity in the bloom or in mid-estuary, but does display a low-salinity input signal that parallels dissolved organic material, perhaps suggesting an association between tin and DOM. Barium displays dramatic input behavior at mid-salinities, probably due to slow release from clays deposited in the harbor after catastrophic phosphate slime spills into the Peace River.  相似文献   

18.
Three years of temperature data along two transects extending to 90 m depth, at Palau, Micronesia, show twice-a-day thermocline vertical displacements of commonly 50–100 m, and on one occasion 270 m. The internal wave occurred at a number of frequencies. There were a number of spectral peaks at diurnal and semi-diurnal frequencies, as well as intermediate and sub-inertial frequencies, less so at the inertial frequency. At Palau the waves generally did not travel around the island because there was no coherence between internal waves on either side of the island. The internal waves at a site 30 km offshore were out-of-phase with those on the island slopes, suggesting that the waves were generated on the island slope and then radiated away. Palau Island was thus a source of internal wave energy for the surrounding ocean. A numerical model suggests that the tidal and low-frequency currents flowing around the island form internal waves with maximum wave amplitude on the island slope and that these waves radiate away from the island. The model also suggests that the headland at the southern tip of Palau prevents the internal waves to rotate around the island. The large temperature fluctuations (commonly daily fluctuations ≈10 °C, peaking at 20 °C) appear responsible for generating a thermal stress responsible for a biologically depauperate biological community on the island slopes at depths between 60 and 120 m depth.  相似文献   

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In June 1981, dissolved Zn, Cd, Cu, Ni, Co, Fe, and Mn were determined from two detailed profiles in anoxic Baltic waters (with extra data for Fe and Mn from August 1979). Dramatic changes across the O2H2S interface occur in the abundances of Cu, Co, Fe, and Mn (by factors of ?100). The concentrations of Zn, Cd, and Ni at the redox front decrease by factors between 3 to 5.Equilibrium calculations are presented for varying concentrations of hydrogen sulfide and compared with the field data. The study strongly supports the assumption that the solubility of Zn, Cd, Cu, and Ni is greatly enhanced and controlled by the formation of bisulfide and(or) polysulfide complexes. Differences between predicted and measured concentrations of these elements are mainly evident at lower ΣH2S concentrations.Cobalt proved to be very mobile in anoxic regions, and the results indicate that the concentrations are limited by CoS precipitation. The iron (Fe2+) and manganese (Mn2+) distribution in sulfide-containing waters is controlled by total flux from sediment-water interfaces rather than by equilibrium concentrations of their solid phases (FeS and MnCO3). The concentrations of these metals are therefore expected to increase with prolonged stagnation periods in the basin.  相似文献   

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