共查询到17条相似文献，搜索用时 109 毫秒
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荧光猝灭法溶解氧传感器实验室校准方法研究 总被引：1，自引：0，他引：1
针对我国目前缺乏荧光猝灭法光学溶解氧传感器校准方法的现状,以AADI 4330F溶解氧传感器为实验对象,提出了一种适用于所有荧光猝灭法光学溶解氧传感器的实验室校准方法.该方法使用一个能够精确控制水体温度的自制校准装置,通过改变通入容器的氧气和氮气比例来控制容器内的溶解氧含量,在4个温度下分别测定至少10组水体温度值、传感器相位值和Winkler碘量法测定值数据,使用回归分析进行多项式拟合获取传感器校准系数.经过实验室验证,在校准试验温度范围内随机温度和溶解氧浓度下,使用该方法校准后传感器测定值与标准值偏差在±5 μmol/L以内,达到了仪器自身的准确度水平.本方法在校准结果准确度和温度适用范围等方面都明显优于两点校正法,表明该方法具有良好的校准效果和推广应用价值. 相似文献
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溶解氧是海洋水质监测的常规关键参数,基于荧光猝灭原理研制的溶解氧传感器具有准确度高、稳定性好和可长期在线测量等优点,已经被广泛用于海水溶解氧浓度监测。针对传感器可能发生的数据漂移和显著偏差可能造成的准确度问题,本文设计了一套专门的校准装置和校准方法。通过严格控制校准水体的温度和溶解氧浓度,测量待校准传感器和参比传感器的相移、温度和溶解氧浓度数据,拟合获取传感器校准系数,实现对光学溶解氧传感器的单个多点校准。传感器校准值与参比值偏差在±8μmol·L–1以内。实验室和海水现场比测结果显示,校准结果达到传感器性能指标要求。此校准装置及方法并不局限于光学溶解氧传感器,具有良好的推广价值。 相似文献
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用自制的海水有色可溶性有机物(CDOM)干粉配制不同质量浓度的水溶液,研究其对三维荧光光谱(EEMS)和同步荧光光谱(SFS)的影响。结果表明:当CDOM质量浓度ρ≥62.5 mg/L时,其EEMS均为单一峰,随着质量浓度降低,激发和发射波长向短波长方向移动,这种波长移动变化与质量浓度的变化呈良好的线性相关关系;当ρ≤52.5 mg/L时,其三维荧光光谱显示3个峰。质量浓度在此范围内变化时,EEMS谱形基本不变。不同质量浓度CDOM水溶液的SFS显示,当质量浓度ρ≥150 mg/L时,随着质量浓度降低,激发和发射波长也向短波长方向移动,其谱形也发生变化;当ρ<150 mg/L时,激发和发射波长不发生漂移,谱形不变,荧光强度随质量浓度降低而降低。一定范围内CDOM质量浓度的变化会影响EEMS和SFS的谱形,从而影响EEMS和SFS法定性判定水体CDOM质量浓度的准确性。用EEMS和SFS法定性不同水体中的CDOM要考虑质量浓度的影响。 相似文献
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介绍一种测量溶解氧的微型光纤传感器 总被引：2，自引：0，他引：2
本文介绍了一种根据动态荧光猝灭原理而设计的微型光纤溶解氧传感器（氧微光极）,讨论了氧微光极的结构设计、工作原理、技术特点及试验应用情况。该系统具有良好的测量特性,是适合于水环境应用的理想工具 相似文献
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叶绿素荧光遥感算法为探测近岸海域二类水体叶绿素浓度开辟了新途径．基于大连湾及邻近海域的实测数据,本文研究了海水叶绿素浓度的荧光遥感算法．结果表明：随着海水叶绿素质量浓度的增高,荧光峰出现显著的红移现象,叶绿素质量浓度与荧光峰波长存在着正相关关系．此外,基于MODIS、MERIS及GLI传感器荧光波段建立的荧光基线高度算法较差,不适用于该研究海域．选择680、685、690、695、700、705nm作为荧光峰波长建立的荧光基线高度算法,随着选定波长的增大,该算法拟合的相关性逐渐增高,最大相关系数（R2）可达0．91;而以实测荧光峰波长建立的荧光基线高度算法最佳,乘幂函数拟合优于线性拟合,拟合方程为P（chl）=3．167×10^5 FLH^1.45（R2=0．93）．本研究为新一代海洋水色卫星传感器的开发、建造提供了科学依据,并为已有高光谱传感器在叶绿素荧光遥感反演方面的应用打下了基础． 相似文献
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水中荧光计在高混浊水域中的混合扩散实验 总被引：1，自引：0，他引：1
为了研究长江水域污染物质的输运和扩散规律，作者利用研制成功的水中荧光计在该水流域事扩散实验。该仪器在高混浊水中对罗丹明Ｂ的浓度检测范围为１×１０＾－９－－５×１０＾－５ｇ／ｃｍ＾３，精确度≤±１０％。。本文着重论述使用水中荧光计和荧光示踪染料在流速大、混浊度高的长江九江江段和镇江段进行水体混合扩散测量实验的情况，结果令人满意，为我国的高混浊水体混合扩散实验研究提供了新的手段和方法。 相似文献
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基于神经网络和TM图像的大连湾海域悬浮物质量浓度的反演 总被引：3，自引：1，他引：2
水体中的悬浮物是评价海洋水质的重要指标之一。采用卫星遥感方法可以获得大范围连续的悬浮物质量浓度。以1999年5月10日大连湾海上现场-卫星同步实验数据为基础,采用神经网络模型技术模拟了陆地卫星TM传感器中心波长分别为485,560和660nm3个波段的辐射亮度值与在该海域现场获取的悬浮物质量浓度之间的传递机理。以TM图像的3个可见光波段作为输入的神经网络模型的相关系数达0．79,在反演海水表层悬浮物质量浓度方面比传统的统计分析方法表现要好。这说明神经网络方法在模拟非线性关系进行遥感反演方面更具应用前景。 相似文献
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A. N. Solov’ev 《Oceanology》2006,46(3):440-445
A submersible eight-channel filter-fluorometer was constructed for the estimation of the variability of the ratio between the integral intensities of several bands of the fluorescence spectrum of dissolved organic agents in natural water excited in specified wavelength intervals. The filter-fluorometer was used to obtain three vertical profiles of the fluorescence intensity at 18 points in Kaliningrad Bay of the Baltic Sea in the spectral bands at 415, 458, and 510 nm emitted simultaneously from the water column excited by the ultraviolet radiation in the interval from 320 to 380 nm. It was shown that a pronounced (tens of times as much) relative (between the spectral bands) variability of the fluorescence allows a number of water conditions to be recognized. The correlations of the multiband fluorometric information with the biohydrochemical and ecological characteristics of the water still require clarification. 相似文献
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Hiroshi Hasumoto Tsuneo Imazu Toshiaki Miura Kazuhiro Kogure 《Journal of Oceanography》2006,62(1):99-103
The use of an optical oxygen sensor to measure dissolved oxygen in seawater was investigated. The sensor is based on the dynamic
quenching of an oxygen-sensitive fluorochrome embedded in the tip. Dissolved oxygen in seawater samples collected from eight
stations at depths ranging from 3000 to 6000 m was analyzed both with the optical sensor and by the Winkler titration method.
The two sets of data did not differ significantly. The stability and simplicity of the method and the good agreement of the
results with those of the titration method indicate that the sensor would be useful for fieldwork. 相似文献
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为克服温度对溶解氧传感器的影响，对极谱型溶解氧检测系统的溶解氧电极激励源、高精度信号采样、软件标定和温度补偿等方面进行研究。通过对极谱型溶解氧传感器工作原理进行分析，设计了极谱型溶解氧传感器检测电路；根据溶解氧电极的温度特性，设计了基于NTC（负温度系数）热敏电阻的硬件温度补偿电路，并利用最小二乘法及RBF神经网络构建了软件温度补偿模型。利用饱和蒸馏水进行温度补偿实验，结果表明：经温度补偿后，该溶解氧检测系统的相对误差及采样波动均在1%以内，大大减小了传感器的非线性误差，测量精度和稳定性均可满足应用要求。 相似文献
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介绍一种SWQ-1型多功能水质测定仪,以数字显示温度,盐度,溶解氧,pH和氧化还原电势。仪器用干电池供电,其结构是以一个带有多路模数转换器和液晶显示器的低功耗单片微计算机为基础而构成。通过微计算机按照存贮器中的物理化学公式和定标常数进行数据处理,并把结果送给显示器。温度和pH传感器用的是定型的商品—热敏电阻和玻璃电极。盐度和溶解氧分别采用由作者自行设计的铂电极电导池和薄膜原电池型传感器进行现场测量。溶解氧的测量采用了自动定标程序,减少了电位漂移对测量的影响,提高了测量的可靠性,并且便于操作。这种水质测定仪是一种尺寸小,重量轻,效率高的便携式仪器。 相似文献
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Wayne S. Gardner 《Marine Chemistry》1978,6(1):15-26
Improved methodology for amino acid analysis coupled with semi-micro isolation techniques make feasible the measurement of individual amino acids from marine waters where sample volumes are limited (e.g., sediment pore water or culture filtrates). If a water sample contains more than 20 nmole 1?1 of the respective compounds, dissolved free amino acids (DFAA) can be isolated from 5 ml of filtrate by cation exchange and measured on a sensitive amino-acid analyzer equipped with a fluorometric detector. Two ml generally provides sufficient sample to determine total dissolved amino acids. Lower concentrations of amino acids can be measured after concentration from larger samples (250 ml) by ligand exchange. 相似文献
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RESEARCH ON DETERMINATION OF DISSOLVED OXYGEN IN SEAWATER 总被引：1，自引：0，他引：1
Based on the principle of laminar flow-constant potential-chronocoulometry, this article presents a new method of determining the dissolved oxygen in seawater with considerable success. A new model of electrochemical sensor has been designed for this purpose.The sensor has the advantage of overcoming hysteresis and "outskirts effect", thus increasing its stability and prolonging its use to 1-2 years.In connection with this new method a new model SY-1 integrating microcoulorneter with digital display is designed.It is a fast (a sample/2 min) and accurate (±1 - 1.5%) method, suitable for use in the laboratory on board a ship. 相似文献
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Onega Bay waters are characterized by a high content of chromophoric dissolved organic matter (CDOM). The absorbance spectra and fluorescence intensity (excitation wavelength 455 nm, emission wavelength >680 nm) were used to assess the distribution of CDOM content in water filtered through a GF/F filter. The CDOM content at different points in Onega Bay showed more than a fourfold difference, as inferred from the measured values. The CDOM content in surface waters was, as a rule, higher than in the deeper horizons. A higher CDOM content was measured near the Onega River, near the middle part of the Onega shore, and near the Pomor shore opposite the town of Belomorsk. River runoff is the major source of CDOM in Onega Bay water. The CDOM chemical composition in Onega Bay waters was heterogeneous. The ratio of the fluorescence intensity to the absorbance value was higher near the mouths of rivers and in intensive mixing zones than in water characterized by high salinity. A highly significant linear correlation (R2 = 0.7825) between water salinity and CDOM fluorescence intensity was demonstrated. The contribution of fluorescent compounds to river runoff CDOM is substantially higher than the contribution to the composition marine CDOM. 相似文献