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1.
海洋浮游植物对2-甲基萘的生物富集研究 总被引：1，自引：0，他引：1
该文改进并完善适合现场实验条件的生物富集动力学参数测定的静态动力学实验方法 ,同时提出比较完善的生物富集动力学模型。应用该模型实验测定 6种浮游植物对 2 -甲基萘的吸收速率常数 k1,释放速率常数 k2 和生物富集因子 BCF。实验表明 ,6种浮游植物对 2 -甲基萘的 BCF与浮游植物细胞比表面积之间有较好的 log- log相关性 ,进一步验证了浮游植物对有机污染物的生物富集与浮游植物的比表面积之间存在定量关系。 相似文献
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研究了大型底栖海藻对海水中元素的富集系数（ＣＦ） 和元素在海水中平均逗留时间（ＭＯＲＴ） 、海水中的浓度（Ｃ） 、在深海粘土／ 海水中分配系数（Ｋ） 之间的关系,给出了ｌｇＣＦ～ｌｇ（ＭＯＲＴ） 、ｌｇＣＦ～ｌｇＣ及ｌｇＣＦ～ｌｇＫ等的线性回归方程。指出元素在大型底栖藻中的富集主要地是一种服从吸着———配位作用规律的化学作用,并采用Ф（ Ｚ／ｒ,Ｘ） 函数来估算富集系数。 相似文献
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本文应用海洋围隔生态实验研究了浮游植物对石油烃污染物生物富集动力学过程 ,提出了“水相差法”测定海洋浮游植物体内石油烃浓度 ,以及包括石油烃挥发和生物生长等影响因素的石油烃生物富集动力学模型 ,并利用非线性拟合技术得到了海洋浮游植物对 0 #柴油 WAF中正构烷烃的生物富集动力学参数 kup,kel和 BCFPOC,结果与 Kováts色谱保留指数具有很好的相关性 ,与利用生物分析平衡法测定的文献数据基本一致。本模型及实验方法简便可靠 ,可在现场实验中广泛应用 ,得到的动力学参数应用于多介质环境模型和生态动力学模型 ,用以研究石油烃污染物中正构烷烃在海洋环境中的迁移变化规律 相似文献
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台湾海峡西部海域水体中的二氧化碳体系 总被引：7，自引：0，他引：7
据１９８４年５月至１９８５年２月的调查资料，计算了该水体中二氧化碳体系各要素的统计值，着重研究了它们的季节变化及其与水文，化学和生物因子的关系。结果表明该水体中ＰＣＯ２，ＣＯ２（Ｔ），ＣＯ＾２＾－３，ＨＣＯ３，∑ＣＯ２，ＣＯ＾２＾－３／∑ＣＯ２，ＨＣＯ３／∑ＣＯ２，ＨＣＯ２，ＣＯ２（Ｔ），ＣＯ＾２＾－３，∑ＣＯ２／Ｃｌ，Ωｃ，Ωａ和Ｃ：Ｎ：Ｐ平均值依次分别为２５１ｄＰａ，８．４３μｍｏｌ／ｄｍ×３ 相似文献
6.
浮游生物对某些化学物质在海洋微表层中富集所起的作用 总被引：3，自引：0，他引：3
本文综合分析了浮游生物对有机物、痕量金属、氮磷营养盐在海洋微表层中富集所起的作用。浮游植物和部分浮游细菌释放的溶解有机物大部分具有表面活性且能与痕量金属络合,它们能靠Gibbs吸附富集于微表层,并促成与络合的痕量金属的富集。浮游细菌对微表层中富集的含氮和含磷有机物的分解可能是促成氮磷营养盐在微表层中富集的重要原因。 相似文献
7.
九龙江口生物可利用磷的行为与人海通量 总被引：1，自引：1，他引：0
于１９９５年３、５月在九江口进行两个航次的现场调查，研究不同形态磷的河口行为，并估算生物可利用磷的入海通量。结果表明，在Ｓ〈２０区域内，溶解活性磷（ＤＲＰ）的行为受控于“缓冲机制”，其含量在８－１０μｇ／ｄｍ＾３水平上下波动。颗粒磷中ＭｇＣｌ２可提取磷（ＭｇＣｌ２－Ｐ）含量随盐度增大而增大，并与叶绿素ａ以及悬浮物Ｆｅ、Ｍｎ、Ａｌ含量呈正相关关系。ＮａＯＨ／ＮａＣｌ可提取磷（ＮａＯＨ／ＮａＣｌ－Ｐ） 相似文献
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厦门海域二氧化碳及其生物生产力的估算 总被引：3，自引：0，他引：3
根据１９９５年４月在厦门海域对ＣＯ２系统作定点连续观测的资料,讨论了海－气ＣＯ２交换以及生物活动对海水总ＣＯ２变化的影响。结果表明：海水ＣＯ垢变化主要受生物活动所控制,生物过程引起的ＣＯ２变化远大于海－气ＣＯ２交换的影响。得胜平衡法估算出厦门海域的生物生产力为６２．４ｍｍｏｌ／）ｍ＾２．ｄ）。 相似文献
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大亚湾海水微表层生物—化学研究：Ⅱ.（二）生物—化学特性的周日变化 … 总被引：1，自引：0，他引：1
１９９８年１１月对大亚湾大鹏澳东山港网箱养殖区进行定点２６h连续观测。结果表明： 海水微表层对Ｃｈｌ－ａ,ＰＯ４－Ｐ无富集作用,对浊度,ＢＯＤ,ＣＯＤ和ＳｉＯ３－Ｓｉ富集,营养盐中氮富集因数的复杂性反映了微表层在调节该养殖区内氮分布上的重要作用;海水微、次表层中部分要素分布和周日变化的差异受生物活动的影响较大。 相似文献
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南麂列岛附近海域的浮游植物和赤潮生物 总被引：3，自引：0，他引：3
１９９０年４月和１０月在南麂列岛附近海域进行了两个航次的浮游植物采样调查，共检出浮游植物９７种，隶属于３６属。春季同样浮游植物的平均丰度为２９．７×１０４个／ｍ３，水样浮游植物平均丰度达５２７６０×１０４个／ｍ３。优势种有三鳍原角藻Ｐｒｏｒｏｃｅｎｔｒｕｍｔｒｉｅｓｔｉｎｉｕｍ、夜光藻Ｎｏｃｔｉｌｕｃａｓｃｉｎｔｉｌｌａｎｓ和威氏圆筛藻Ｃｏｓｃｉｎｏｄｉｓｃｕｓｗａｉｌｅｓｉｉ。秋季浮游植物同样的平均丰度为３２．５×１０４个／ｍ３；水样浮游植物平均丰度为９２８×１０４个／ｍ３。优势类群有角刺藻Ｃｈａｅｔｏｃｅｒｏｓｓｐｐ、圆筛藻Ｃｏｓｃｉｎｏｄｉｓｃｕｓｓｐｐ、角藻Ｃｅｒａｔｉｕｍｓｐｐ、海毛藻Ｔｈａｌａｓｓｉｏｔｈｒｉｘｓｐｐ、根管藻Ｒｈｉｚｏｓｏｌｅｎｉａｓｐｐ、骨条藻Ｓｋｅｌｅｔｏｎｅｍａｃｏｓｔａｔｕｍ等。该海区春秋两季均存在多种赤潮生物。 相似文献
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Dissolved organic matter (DOM) is comprised of a myriad of macromolecules with specific physical and chemical properties that may influence the bioavailability of hydrophobic pesticides to animals. This study was conducted to assess the role of various forms of DOM on the uptake and bioconcentration of the organophosphate insecticide chlorpyrifos (CHPY) to the bivalve Mercenaria mercenaria. Bivalves were exposed to DOM-free seawater (30 per thousand) or to seawater containing a single form of DOM. DOM forms included two filtrate fractions of natural salt-marsh sediment DOM (DOM-(<0.45 mum) and DOM-(<3 kDa)); natural purified humic (HA) and fulvic (FA) acids; and water soluble cyclic oligosaccharides alpha and beta cyclodextrins (CD-alpha and CD-beta). In (14)C-CHPY uptake and elimination experiments, juvenile bivalves were exposed to uniformly-labeled (14)C-CHPY and collected at time intervals during 48 h. The remaining bivalves were transferred to (14)C-CHPY-free elimination chambers with bivalve collection at time intervals over 144 h. Total uptake of (14)C-CHPY by bivalves in DOM-free seawater was >40% greater than in bivalves exposed to (14)C-CHPY in the presence of most DOM forms. These results are consistent with much faster (14)C-CHPY uptake rates estimated using a simple two parameter model. After the elimination period, bivalves exposed to DOM-free seawater had (14)C-CHPY body residue concentrations between 25% and 86% greater than bivalves in the presence of DOM forms. Experiments with larger bivalves showed that pulse-chase exposures with a 1.5 h exposure period to (14)C-CHPY was not long enough to detect differences in (14)C-CHPY tissue accumulation efficiencies across treatments. Our findings suggest that natural forms of DOM, at environmentally realistic organic carbon concentrations, reduced pesticide uptake and bioconcentration, consistent with much lower uptake rates relative to bivalves exposed to (14)C-CHPY in the absence of DOM. Interestingly, at the tested organic carbon concentrations CD-alpha and CD-beta did not reduce (14)C-CHPY bioconcentration in M. mercenaria. 相似文献
12.
Shi Xiaoyong Wang Xiulin Han Xiurong Jiang Yu Zhu Mingyuan Chen Shang Koshikawa Hiroshi 《海洋学报(英文版)》2001,20(2):231-240
~IOXWith economic development and consumer demand, oil pollutants have been one of themain marine pollutants in the coastal regal Of China. The oil-contaminated area incrsharply to 69% in 1995 and its average criterion index reached up to 2. 17 in the ChangjiangEstuary (NBEP, 1996). TO assess the influences Of the oil POllutants on the marine ~tern, it is neceSSary to develOP a mathematical kinetic model of the tranSport, distribution andfate in the marine ~teln, espeCially to esthate … 相似文献
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The sorptive behaviour of natural estuarine colloids was investigated with benzene, naphthalene and anthracene. The equilibrium sorption isotherms were linear. Freundlich partition coefficients normalized to the organic content of the colloids for benzene, naphthalene, and anthracene were 920, 4060 and 510000, respectively. These values are at least an order of magnitude higher than those reported for corresponding soil/sediment systems. This suggests that hydrophobic compounds are more strongly bound to estuarine colloidal organic material.The effect of pH on sorption waas also studied. A significant decrease in sorption was observed when the ambient pH (8·01) of natural water was decreased by a factor of 2. The experimentally determined Koc values were regressed against the water solubilities of PAHs and compared with a corresponding predictine relationship developed for a soil/sediment system. Such information greatly facilitates prediction of PAH phase partitioning in natural waters. 相似文献
14.
Hydrophobic organic contaminants (HOCs) may be used as tracers of particle dynamics in aquatic systems. Internal cycling of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were studied in the mesohaline Chesapeake Bay to assess the role of resuspension in maintaining particle and contaminant inventories in the water column, and to compare settling and suspended particle characteristics. Direct measurements of sediment resuspension and settling conducted in conjunction with one of the sediment trap deployments indicate reasonable agreement between measurements of particle flux using the two different methods. Organic carbon and PCB concentrations in settling solids collected in near-surface sediment traps were remarkably lower than concentrations in suspended particles collected by filtration during the trap deployments, but higher PAH concentrations were found in the settling particles. The different behaviors of PAHs and PCBs in the settling particles are due to their different source types and association to different types of particles. Sediment trap collections in near bottom waters were dominated by resuspension. Resuspension fluxes of HOCs measured 2 m above the bay bottom were as high as 2.5 μg/m2 day for total PCBs and 15 μg/m2 day for fluoranthene, and were 25 and 10 times higher than their settling fluxes from surface waters, respectively. HOC concentrations in the near bottom traps varied much less between trap deployments than HOC concentrations in the surface traps, indicating that the chemical composition of the resuspended particles collected in the near bottom traps was more time-averaged by repeated resuspension than the surface particles. 相似文献
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V. I. Mankovskii 《Izvestiya Atmospheric and Oceanic Physics》2016,52(3):328-333
A semiempirical model is constructed for the relationship between the coefficient of asymmetry of Light Scattering phase function in water K and the scattering coefficient σ, which shows a mechanism of an increase in the asymmetry coefficient as the scattering coefficient grows as a result of an increase in the concentration of organic particles. The mechanism of this relationship lies in the presence in all natural waters of molecular scattering and scattering by mineral particles that create background scattering in water medium, which is overlaid by scattering by organic particles. This relationship has a regional character caused by the regional features of background scattering and the average size of organic particles in those regions. The model relationships K = f(σ) are plotted properly to the experimental ones in the various regions. 相似文献
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Polychlorinated biphenyls(PCBs) were measured in atmospheric samples collected from the North Pacific to the Arctic Ocean between July and September 2012 to study the atmospheric concentration characteristics of PCBs and their gas/particle partitioning. The mean concentration of 26 ∑PCBs(vapor plus particulate phase)(∑PCBs) was 19.116 pg/m3 with a standard deviation of 13.833 pg/m3. Three most abundant congeners were CB-28,-52 and-77, accounting for 43.0% to ∑PCBs. The predominance of vapor PCBs(79.0% to ∑PCBs) in the atmosphere was observed. PCBs were negative correlated with the latitudes and inverse of the absolute temperature(1/T). The significant correlation for most congeners was also observed between the logarithm of gas/particle partition coefficient(log KP) and 1/T. Shallower slopes(from-0.15 to-0.46, average-0.27) were measured from the regression of the logarithm of sub-cooled liquid vapor pressures(logpo L) and log KP for all samples. The difference of the slopes and intercepts among samples was insignificant(p0.1), implying adsorption and/or absorption processes and the aerosol composition did not differ significantly among different samples. By comparing three models, the J-P adsorption model, the octanol/air partition coefficient(KOA) based model and the soot-air model, the gas/particle partitioning of PCBs in the Arctic atmosphere was simulated more precisely by the soot-air model, and the adsorption onto elemental carbon is more sensitive than the absorption into organic matters of aerosols, especially for lowchlorinated PCB congeners. 相似文献
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Melisa Daiana Fernández Severini Sandra Elizabeth BottéMónica Susana Hoffmeyer Jorge Eduardo Marcovecchio 《Estuarine, Coastal and Shelf Science》2009
Cadmium and copper in the dissolved and particulate phase and in zooplankton were determined in the Bahía Blanca estuary during six surveys from March to December 2005. Temperature, pH, salinity, dissolved oxygen, suspended particulate matter, particulate organic matter and chlorophyll-a were also considered. Dissolved Cd was below the detection limit (0.2 μg L−1) for almost the entire study period whereas Cu concentrations (0.5–2.4 μg L−1) indicated a continuous dissolved Cu input. Particulate Cd concentrations ranged from below the detection limit (<0.01) to 28.6 μg g−1 d.w. while particulate Cu ranged from below the detection limit (<0.04) to 53.5 μg g−1 d.w. Cd in mesozooplankton ranged from below the detection limit (<0.01) to 37.4 μg g−1 d.w. Some of the Cd levels were higher than those reported for other aquatic ecosystems. Cu in the mesozooplankton ranged from 1.3 to 89.3 μg g−1 d.w., values which were within the reported values or higher than other studies. The log of the partition coefficients (log (Kd)) of Cd was 0.04, while log (Kd) for Cu ranged from −0.39 to 2.79. These values were lower than both those calculated for other estuaries and the typical coefficients for marine environments. The log of the bioconcentration factor (log BCF) of Cd was 1.78, indicating that Cd concentration was higher in the zooplankton than in the dissolved phase. Log BCF of Cu ranged from 1.15 to 3. The logs of the biomagnification factors (log BMF) of Cd were low, with a range between −3.45 and 2.21 and those for Cu ranged from −0.1 to 3.35. Positive values indicate biomagnification while negative values indicate biodiminution. In general, no significant dissolved Cd concentration appeared to be present in the Bahía Blanca estuary and Cu values did not indicate a critical environmental status. The particulate phase seemed to be the major carrier for Cd and Cu and TPCu values were within the normal values for an anthropogenically stressed estuary but not for a strongly polluted system. This fraction was the most important metal source for the mesozooplankton. Moreover, the highest metal concentrations were in the mesozooplankton since most of the bioconcentration and biomagnification factors were positive, especially for Cu. 相似文献
18.
应用半静态的双箱式生物富集动力学模型,在室内研究了柄海鞘对重金属 Pb2+ 的生物富集作用,通过非线性拟合得到了相应的生物富集动力学参数.结果表明:柄海鞘对金属 Pb2+ 具有一定的富集作用,对 Pb2+ 的富集吸收速率常数 k1 和富集系数 BCF均随外部水体中 Pb2+ 浓度的增大而减小.富集平衡时,海鞘体内的铅含? Camax)与外部水体中 Pb2+ 的浓度基本呈正相关.柄海鞘不同器官中的 Pb 浓度不同,依次为:生殖腺>消化腺≈其他部分>外背囊.排出阶段 Pb 在柄海鞘体内的生物学半衰期(B1/2)为 10.05～36.76d. 相似文献
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应用半静态双箱动力学模型室内模拟了沉积物暴露条件下文蛤Meretrix meretrix 对Cu、Pb的生物富集,通过对富集与排出过程中文蛤体内重金属污染物的动态监测和对富集与排出过程监测结果的非线性拟合,得到了文蛤富集重金属的吸收速率常数K1、排出速率常数K2、生物富集因子BCF(bioconcentration factors)、生物学半衰期B1/2等动力学参数。拟合结果得到的Cu、Pb各动力学参数分别为,K1为4.633372.3754;K2为0.05120.0798;BCF为60.76461414.9634;B1/2为8.6913.55。对模型的拟合优度检验结果显示,沉积物暴露条件下文蛤对重金属Cu、Pb的生物富集数据符合双箱模型,模型的拟合优度良好。比较结果得出,吸收速率常数K1及生物富集因子BCF均随着外部水体金属暴露浓度的增大而减小;文蛤对Cu富集能力大于Pb;Cu在文蛤体内的生物学半衰期B1/2大于Pb;理论平衡状态下生物体内Cu、Pb的含量CAmax随着外部水体中金属暴露浓度的增大而增大,且呈显著正相关,实验结果表明沉积物暴露条件下双箱动力学模型在一定条件下是可以应用于文蛤的富集动力学研究的,仍需要进一步开展不同条件下实验研究分析。 相似文献