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1.
本文研究了甲醛、戊二醛、甲醇作交联剂对海带藻粉进行化学交联后,不同交联方式对Cu^2 、Cd^2 的吸附率的影响,并与未交联的藻粉吸附Cu^2 、Cd^2 的效果进行了比较.同时分析了藻粉对Cu^2 、Cd^2 金属离子吸附动力学方程,探讨了pH值、温度、藻粉颗粒粒径等因素对吸附率的影响.  相似文献   

2.
固定化海藻对金属离子吸附效果的研究   总被引:4,自引:0,他引:4  
研究了固定化海带吸附含铜、镉溶液的过程,结果表明:非活性海带吸附水溶液中铜、镉离子的动力学过程可以用班厄姆吸附速率方程描述,铜和镉的吸附速率常数分别为0.1078和0.03028min-1;生物吸附过程符合Langmuir模型,根据Langmuir吸附等温模型的计算结果,得到固定化海带对铜和镉离子的最大吸附量分别为83.3和112.4mg/g,海带对铜离子的亲和性比对镉离子强.  相似文献   

3.
采用室内培养实验方法,研究了褐藻海黍子(Sargassum muticum)和红藻脆江蓠(Gracilaria chouae)在不同质量浓度的锌和镉溶液里15 d,藻体的生长和体内金属离子含量的变化。结果表明:两种藻的生长速率与暴露溶液金属质量浓度呈负相关,藻体内积累金属离子的量和溶液的金属质量浓度呈正相关,藻体内金属离子的含量均在培养3 d后显著增加,且随着培养时间的延长而持续增加。海黍子和脆江蓠对重金属Zn~(2+)的富集能力明显高于对Cd~(2+)的富集能力,在相同条件下,海黍子对重金属Zn~(2+),Cd~(2+)的积累量明显高于脆江蓠。以上研究结果对利用藻类修复重金属污染的海洋水体能起到一定的指导和参考作用。  相似文献   

4.
利用合成的非晶态磷酸锡作为吸附剂, 研究了多种因素(pH、吸附时间、初始浓度、温度、离子强度)对吸附剂吸附水溶液中Pb2+的影响。结果表明, 非晶态磷酸锡对Pb2+的吸附量随着pH(3~6)以及吸附时间的增大而增加。用Freundlich、Langmuir 模型对等温吸附数据进行处理, Langmuir 方程拟合效果最...  相似文献   

5.
黄河水中镉(Ⅱ)与悬浮粒子液—固界面交换反应的研究   总被引:4,自引:1,他引:4  
本文研究了黄河悬浮粒子与镉(Ⅱ)相互作用的离子交换率(%)—pH曲线,以及河水中赖氨酸存在下对该曲线的影响。主要结果有;(1)镉以Cd(OH)+形式在悬浮粒子上进行阳离子交换,在天然pH下(8.0×8.5),镉离子交换率接近最大值;(2)镉离子浓度由8.9×10-6mol·L-1增加到2×8.9×10-6mol.L-1时,离子交换率降低;(3)浓度为6.8×10-6mol·L-1的赖氨酸对提高离子交换率起促进作用;(4)交换剂为转化沙的镉离子交换率比未转化沙小;(5)海水、金沙江水中悬浮粒子对镉的吸附弱于黄河水。  相似文献   

6.
褐藻多酚含量的季节变化   总被引:1,自引:1,他引:1  
褐藻多酚的季节变化研究具有重要的理论意义,对海黍子和鼠尾藻褐藻多酚的含量测定结果表明,褐藻多酚含量的季节变化范围分别在1.5 ̄3.1%之间以及0.8 ̄1.8%之间。另外,PVP吸附率也有相应的变化,分别在51 ̄69%之间以及41 ̄63%之间。  相似文献   

7.
选取胶州湾海域2个站点的沉积物进行了表面酸碱电位滴定实验,并考察了人工海水介质中对铜离子的吸附性能,比较了介质的盐度和温度等对吸附动力学曲线和吸附等温线的影响.结果发现:2个站点的沉积物随pH值由3增大到10表面质子电荷密度的值由正转负,零净质子电荷点pHPZNPC均在4.0~4.5之间,表面位浓度Hs在1.34×104~1.90×10-4 mol·L-1之间;沉积物对铜离子的动力学吸附曲线可用伪一级动力学方程、伪二级动力学方程、Elovich方程、双常数速率方程拟合,其中伪二级动力学方程符合较好,吸附在2h左右达到平衡;吸附等温线可用Langmuir等温式拟合.零净质子电荷点低、表面位浓度大的沉积物对铜离子的吸附能力较强.蒸馏水介质中,沉积物对铜离子的饱和吸附量小于在稀释人工海水中和人工海水中的结果;较高的温度使饱和吸附量增大.  相似文献   

8.
镉对中华绒螯蟹(Eriocheir sinensis)抗氧化酶活性的影响   总被引:6,自引:0,他引:6  
将中华绒螯蟹(河蟹Eriocheir sinensis)浸泡在2.Omg/L氯化镉(CdCl2)溶液中,分别于第0、6、12、24、48、72、96小时提取河蟹的肝胰腺,测定抗氧化酶:超氧化物歧化酶(Superoxicle dismutase,SOD)、过氧化氢酶(Catalase,CAT)、谷胱甘肽过氧化物酶(Glutathione Peroxiclase.GPx)的活性,探讨了镉(Cd^2 )对河蟹肝胰腺抗氧化酶活性的影响。结果显示,在低浓度Cd^2 环境下,河蟹肝胰腺的抗氧化酶活性随时间发生规律性变化。暴露于Cd^2 后,河蟹肝胰脏SOD活性降低,随时间的延长,在暴露72h后,SOD活性恢复并超过未染毒时22.3%。表明Cd^2 中毒导致细胞内氧自由基大量积累从而诱导酶活性升高;CAT活性先下降后增高,随后减少,最后以低于对照的水平趋于平衡;肝胰腺中GPx酶活性的变化规律与SOD相似,在解除氧自由基毒性方面有一定的协调性。实验表明河蟹抗氧化系统酶对Cd^2 很敏感。而酶活性在短时间内的变化规律可以为镉对河蟹早期的毒性研究提供参考。  相似文献   

9.
选取胶州湾海域2个站点的沉积物进行了表面酸碱电位滴定实验,并考察了人工海水介质中对铜离子的吸附性能,比较了介质的盐度和温度等对吸附动力学曲线和吸附等温线的影响。结果发现:2个站点的沉积物随pH值由3增大到10表面质子电荷密度的值由正转负,零净质子电荷点pHPZNPC均在4.0~4.5之间,表面位浓度HS在1.34×10-4~1.90×10-4mol.L-1之间;沉积物对铜离子的动力学吸附曲线可用伪一级动力学方程、伪二级动力学方程、Elovich方程、双常数速率方程拟合,其中伪二级动力学方程符合较好,吸附在2 h左右达到平衡;吸附等温线可用Langmuir等温式拟合。零净质子电荷点低、表面位浓度大的沉积物对铜离子的吸附能力较强。蒸馏水介质中,沉积物对铜离子的饱和吸附量小于在稀释人工海水中和人工海水中的结果;较高的温度使饱和吸附量增大。  相似文献   

10.
几种大型海藻对赤潮异弯藻生长抑制效应的初步研究   总被引:6,自引:1,他引:6  
利用共存培养系统研究了大型海藻缘管浒苔、刚毛藻、石花菜、鸭毛藻、扇形拟伊藻、蜈蚣藻、海黍子、脆江蓠对赤潮异弯藻(Heterosigma akashiwo)生长的抑制效应并和孔石莼的作用进行比较。实验指出:孔石莼和缘管浒苔对赤潮异弯藻的抑制效应最强,石花菜次之;扇形拟伊藻、蜈蚣藻、刚毛藻、脆江蓠、海黍子虽表现出抑制作用但较差;鸭毛藻的抑制效应最弱。  相似文献   

11.
Coastal inundation associated with extreme sea levels is the main factor which leads to the loss of life and property whenever a severe tropical cyclonic storm hits the Indian coasts. The Andhra and Orissa coasts are most vulnerable for coastal inundation due to extreme rise in sea levels associated with tropical cyclones. Loss of life may be minimized if extreme sea levels and associated coastal flooding is predicted well in advance. Keeping this in view, location specific coastal inundation models are developed and applied for the Andhra and Orissa coasts of India. Several numerical experiments are carried out using the data of past severe cyclones that struck these regions. The simulated inland inundation distances are found to be in general agreement with the reported flooding.  相似文献   

12.
Grain size and water content in box-core sediments from the Clarion-Clipperton fracture zone (C-C zone) in the northeast equatorial Pacific were analyzed in detail to understand the downcore variations across a hiatus between Quaternary and Tertiary layers. Grain-size distributions in the topmost core sediments show two modes: a coarse mode (peaked at 50 μm) and a fine mode (at 2-25 μm). The coarse mode disappears gradually with depth accompanied by the dissolution of siliceous fossil tests, whereas the fine mode coarsens due to the formation of authigenic minerals. Water content increases abruptly across a color boundary between an upper pale brown layer and a lower dark brown layer that is the hiatus between Quaternary and Tertiary layers. Abundant smectites and microvoid molds, which are created by the prolonged fossil dissolution in the underlying sediment, are attributed for the abrupt downcore variation of water content. Overall variations in grain size and water content in the topmost core sediments in the western C-C zone are possibly constrained by the dissolution of biogenic siliceous fossils. Variations in geotechnical properties related to these changes must be considered in the design of nodule collectors.  相似文献   

13.
This article concerns an interrelation between the sea levels and the western boundary flow near a tectonic boundary in a local zone in the Northwestern Pacific. In this zone, sea level variations at stations located on the coast facing the Pacific are studied to find the interrelation between variations of the Kurosio flow as an index of the distance of the flow axis off a specific coast. The result is discussed after data processing of the monthly means of the sea levels, and a notice is taken of variations caused by active crustal upheavals during a seismic event, a local earthquake.  相似文献   

14.
This study tests the hypothesis that the in situ void ratio of surficial marine sediments may be predicted from shear wave velocity-depth data with a reliability equal to that of other methods currently available. Shear wave velocity is fundamentally controlled by the number of grain-to-grain contacts per unit volume of material and by the effective stress across those contacts. In this study, three previously established empirical formulae are used to predict void ratio from velocity-depth data. Field data were acquired along a transect off the northern Californian coast across which water depth increased from 35 to 70 m and seafloor sediment type varied from sand to silty-sand, respectively. A towed seafloor sled device was used to collect shear wave refraction data, and a marked, systematic decrease in velocity was observed along the line, ranging from 35-70 m/s for the coarse, near-shore material to 25-40 m/s for the finer, offshore deposits. Void ratios predicted from these velocities were compared with data measured directly from box-core samples. Of the formulae used for prediction, two agree remarkably well with the control data. Both predicted and control values increase from 0.6-0.8 for the sandy material to 1.1-1.5 for the silty-sand. Thus, this study does not disprove the hypothesis set and demonstrates the potential of field shear wave velocity-depth data as a means of delineating spatial variation in void ratio for surficial marine sediments in a remote, nondestructive manner.  相似文献   

15.
Particulate samples were collected from the Changjiang river system during a flood period, in May 1997, and POC, stable isotope and lipids associated with particles were examined. Results showed the decrease (0.84% ~ 1.88%) of organic carbon content from the upper reaches to the estuary.δ13C values of particulate organic carbon was in the range of -24.9×10-3 to -26.6×10-3, which were close to the isotopic signature of continental C3 vegetation. Total particulate n-alkanes concentrations varied from 1.4 to 10.1μg/dm3,or from 23.7 to 107μg/g of total suspended matter. Fatty acids were present in all the samples, from 1.4 to 5.4μg/dm3, with saturated and unsaturated straight-chain and branched compounds in the carbon number range from C12 to C30. Both δ13C and the ratio of carbon content to nitrogen content indicate the predominance of terrestrial inputs (soil organic matter) among the particles. The biomarker approach has been used to identify the relative portion of terrigenous and autochthonous fraction in the particulate samples. The distribution of fatty acids suggests a striking phytoplanktonic and microbial signal in most particle samples. The terrestrial alkanes are used to estimate the contribution of terrestrial inputs along the mainstream.  相似文献   

16.
Current trends of development of satellite derived bathymetry (SDB) models rely on applying calibration techniques including analytical approaches, neuro-fuzzy systems, regression optimization and others. In most of the cases, the SDB models are calibrated and verified for test sites, that provide favorable conditions for the remote derivation of bathymetry such as high water clarity, homogenous bottom type, low amount of sediment in the water and other factors. In this paper, a novel 3-dimensional geographical weighted regression (3GWR) SDB technique is presented, it binds together methods already presented in other studies, the geographically weighted local regression (GWR) model, with depth dependent inverse optimization. The proposed SDB model was calibrated and verified on a relatively difficult test site of the South Baltic near-shore areas with the use of multispectral observations acquired by a recently launched Sentinel-2 satellite observation system. By conducted experiments, it was shown that the proposed SDB model is capable of obtaining satisfactory results of RMSE ranging from 0.88 to 1.23[m] depending on the observation and can derive bathymetry for depths up to 12m. It was also shown, that the proposed approach may be used operationally, for instance, in the continuous assessment of temporal bathymetry changes, for areas important in the context of ensuring local maritime safety.  相似文献   

17.
As a part of the environmental impact assessment studies, geotechnical properties of sediments were determined in the Central Indian Basin. The undrained shear strength and index properties of the siliceous sediments were determined on 20 box cores of uniform dimension collected from various locations in five preselected sites. The maximum core length encountered was 41 cm and most of the sediments were siliceous oozes consisting of radiolarian or diatomaceous tests. The shear strength measurements revealed that surface sediments deposited in recent times (0-10 cm) have a shear strength of 0-1 kPa; this value increases with depth, reaching 10 kPa at 40 cm deep. Older sediments have greater strength because of compaction. Water content varies in the wide range of 312-577% and decreases with depth. The clay minerals such as smectite and illite are dominant and show some control over water content. Wet density, specific gravity, and porosity do not indicate any notable variation with depth, thereby indicating a uniform, slow rate of sedimentation. The average porosity of sediments is 90.2%, specific gravity 2.18, and wet bulk density 1.12 g/cm 3 . Sediments exhibit medium to high plasticity characteristics, with the average plasticity index varying between 105% and 136%. Preliminary studies on postdisturbance samples showed an increase in natural water content and a decrease in undrained shear strength of sediments in the top 10- to 15-cm layer.  相似文献   

18.
Extreme sea levels associated with severe cyclonic storms are common occurrences along the east coast of India. The coastal districts of Orissa have experienced major surges in the past. The recent Paradip super cyclone is one of the most severe cyclones, causing extensive damage to property and loss of lives. Extreme sea levels are major causes for coastal flooding in this region. Damages can be minimized if the extreme sea levels are forecast well in advance. In the present study, we develop a location specific, fine resolution model for the Orissa coast on the lines similar to that of IIT-D storm surge model (Dube et al. 1994). The model runs on a personal computer. The bathymetry for the model is extracted from very fine resolution naval hydrographic charts for the region extending from the south of Orissa to south of West Bengal. A simple drying scheme has also been included in the model in order to avoid the exposure of land near the coast due to strong negative sea surface elevations. An attempt was made in this study to simulate extreme sea levels along the Orissa coast using the data of past severe cyclones. The model results reported in the present study are in good agreement with available observations or estimates.  相似文献   

19.
Several major improvements to an existing method for calibrating satellite altimeters using tide gauge data are described. The calibration is in the sense of monitoring and correcting temporal drift in the altimetric time series, which is essential in efforts to use the altimetric data for especially demanding applications. Examples include the determination of the rate of change of global mean sea level and the study of the relatively subtle, but climatically important, decadal variations in basin scale sea levels. The improvements are to the method described by Mitchum (1998a), and the modifications are of two basic types. First, since the method depends on the cancellation of true ocean signals by differencing the altimetric data from the tide gauge sea level time series, improvements are made that produce a more complete removal of the ocean signals that comprise the noise for the altimetric drift estimation problem. Second, a major error source in the tide gauge data, namely land motion, is explicitly addressed and corrections are developed that incorporate space-based geodetic data (continuous GPS and DORIS measurements). The long-term solution, having such geodetic measurements available at all the tide gauges, is not yet a reality, so an interim solution is developed. The improved method is applied to the TOPEX altimetric data. The Side A data (August 1992?February 1999) are found to have a linear drift component of 0.55 + / 0.39 mm/yr, but there is also a significant quadratic component to the drift that is presently unexplained. The TOPEX Side B altimeter is estimated to be biased by 7.0 + / 0.7 mm relative to the Side A altimeter based on an analysis of the first 350 days of Side B data.  相似文献   

20.
The rare earth element (REE) distribution in nine deep-sea ferromanganese nodules and their associated siliceous sediments from the Central Indian Ocean Basin (CIOB) have been studied to elucidate the REE relationship among them. Total REE concentration varies from 398-928 ppm in the nodules and 137-235 ppm in the associated sediments, suggesting two- to four-fold enrichment in the nodules compared to associated sediments. REE of nodules and their associated sediments show a positive correlation, suggesting REE are supplied from a common source such as seawater. The positive correlation between REE of nodules and sediments from the CIOB is contrary to the competitive scavenging of REE between nodules and sediment in the equatorial Pacific Ocean. REEs in the nodules are carried by Fe, P, and Ti, whereas in the sediment they are carried by P and Mn phases. A similar REE fractionation pattern with middle REE enrichment over heavy and light REE in both the nodules and their associated sediment suggest fractionation is independent of REE abundance and their carrier phases.  相似文献   

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