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《海洋地质前沿》2017,(11)
利用常规测井资料评价致密储层的含油气性往往具有多解性。根据储层定量荧光分析(QGF和QGF-E)的技术特点,将其应用于渤海海域黄河口凹陷BZ-A构造沙河街组储层中,结合测井解释和试油结果,探究该技术在致密储层流体识别中的应用效果。研究表明,通过QGF-E强度得出的BZ-A构造现今油水界面与测井解释的界面深度相近。研究区油水层的判别基准线约为70pc,含油饱和度与QGF-E强度正相关,测井解释为油层段的样品QGF-E强度值绝大多数70pc,含油水层和水层段均小于该值。利用储层定量荧光技术建立了该区含油性判别标准并利用试油结论进行验证,有效识别出了沙一段上部干层段和测井资料遗漏的沙一段下部的致密油层,该技术可以为判别致密储层的流体性质提供新的方法支持。 相似文献
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基于2010年10月国家自然科学基金委东海调查公共航次所获得的数据和悬浮体样品,使用ICP-AES、ICP-MS仪器对悬浮体中的主、微量元素含量进行了测定,对悬浮体中元素组成、空间分布及其影响因素进行了研究,结果表明:长江口及邻近海域悬浮体中主量元素铝、镁、铁、钙等含量为1%~30%,含量以铝为主;微量元素镉、铬、钴、铜、锰、镍、铅、钒等含量为n×10-6~n×10-9,以锰最高;铝与铁、锰以及大部分的微量元素都有良好的相关性,指示这些主量元素以陆源输入为主和微量元素被细颗粒物质吸附为主的特征。水团对长江口及邻近海域颗粒态地球化学组分的空间分布具有重要的影响,其中铝、铁及铬、钴、铜、锰、镍、钒等元素受水团的制约更加显著。 相似文献
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多金属结核微层中元素的富集系数特征及其成因 总被引：4，自引：0，他引：4
作者定义元素富集系数（Ｋ）为结核样品中元素的含量与太平洋多金属结核的平均值的比值，并按Ｋ值大小将元素的富集程度分成六级。本文研究表明：多金属结核壳层中元素的富集系数是波动的；Ｋ＿（Ｍｎ）与Ｋ＿（Ｆｅ）呈负相关性，而与Ｋ＿（Ｎｉ）、Ｋ＿（ｃｕ）呈正相关性；按Ｍｎ／Ｆｅ和生长速率，多金属结核ＣＣＡ３３、ＣＣＢ２９、ＣＣＣ５０、ＣＣＣ１４的壳层，分别划分为８、７、１４、２４个微层；微层中元素富集程度与成因相关，结核生长间断面中，锰呈弱亏损至极亏损，铁弱亏损至较富集，铜弱亏损至较亏损，镍较亏损至极亏损，而由强缺氧性成岩作用为主所形成的微层中，锰、镍呈较富集至极富集，铜极富集，而铁极亏损。 相似文献
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通过对东北太平洋海域中国多金属结核开辟区沉积物间隙水中铜、锰、镍等微量元素的详细研究表明,锰主要受沉积环境的影响,其含量的变化范围在0.16～8.61μg/dm3之间;铜和镍则主要与表层海水的初级生产力有关,研究区内间隙水中铜和镍含量的变化范围分别为0.16～20.8和0.80～3.12μg/dm3,且这些元素在沉积物—水界面处均存在最大浓度梯度.利用“Fick扩散定律”计算表明,锰在研究区主要是从上覆海水向沉积物扩散,是沉积物中锰的主要来源之一;而铜和镍则是从沉积物向上覆海水扩散,是底层海水中铜和镍的主要来源。与表层海水中铜和镍向底层海水的输送通量计算结果相比,底层海水中铜和镍的含量主要受沉积物的控制. 相似文献
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涠洲11-1油田角尾组二段油层普遍具有低电阻率特征,在复杂的地质条件下使得低阻油层与水层的识别难度增大,为此,利用岩心分析化验、录井、测井、构造及试油等资料,从宏观和微观地质因素入手,对该区低阻油层成因机制进行了系统深入的剖析。结果表明,角尾组低阻油层的主要宏观地质成因是构造和沉积特征,它们共同为涠洲11-1地区低阻油层的形成和分布创造了条件;微观低阻成因是在水动力条件较弱的滨海沉积环境下发育的岩性粒度细、泥质含量高、黏土矿物附加导电性以及低幅度构造背景下的高束缚水饱和度所致。在此基础上,结合成因提出了改进后的自然伽马相对值与视地层水电阻率的交会图、改进后的自然电位相对值与深感应电阻率的交会图以及束缚水饱和度—视地层水电阻率的交会图来综合识别低阻油层,结果表明,该方法显著提高了低阻油层的识别能力,展示出良好的应用前景。 相似文献
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海洋富有机碳岩石通常赋存对公众生命、人类健康和环境有潜在危害的痕量元素。与世界页岩平均值（ＷＳＡ）相比,中新世蒙特里建造（加利福尼亚最广泛的油源岩）富集多种痕量元素。早期研究表明,在这些岩石中,与有机碳呈高度正相关（γ２＞０．７５）的元素有铬（Ｃｒ）、铜（Ｃｕ）、镍（Ｎｉ）、锑（Ｓｂ）、硒（Ｓｅ）、铀（Ｕ）、钒（Ｖ）、锌（Ｚｎ）等,呈明显正相关（γ２＝０．４～０．７５）的元素有砷（Ａｓ）、钡（Ｂａ）、镉（Ｇｄ）、和钼（Ｍｏ）。在这１２种元素中Ｓｅ对环境最为有害,Ａｓ、Ｇｄ、Ｃｕ、Ｍｏ、Ｎｉ、Ｓｂ… 相似文献
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富钴结壳中成矿元素的微区分布特征及其地质意义 总被引：2，自引：0，他引：2
采用X射线荧光光谱仪,对CCLLD27站位富钴结壳中8个主要成矿元素(Mn、Fe、Co、Cu、Si、Al、Ca和Ti元素)含量的分布特征进行了微区扫描和人工分层样品方法的分析,结果表明:(1) 成矿元素Mn、Fe、Co和Cu的微区变化很大:Mn与Co元素的微区分布特征相似,而Fe和Cu元素的微区分布特征则相反.主要造岩元素Si和Al的微区分布特征基本类似;Ca元素的微区变化较大,在近底部的基岩层其含量达到最高峰值.Ti元素的微区分布特征与Mn、Co元素微区分布特征接近.(2) 微区扫描与人工分层样品两种不同测试方法所得的结果基本一致,说明微区扫描方法具有一定的可靠性,能反映富钴结壳在不同生长时代各成矿元素含量的变化特征.(3) 富钴结壳微区元素分布特征的研究,有助于对结壳不同成矿阶段各种不同成矿作用的定性评估. 相似文献
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以镍铝水滑石为前体（主体），以蒸馏水为分散介质，用离子交换法组装丁二酸根（客体）插层水滑石，同时用一步合成法合成丁二酸根插层水滑石，并用XRD，IR，TG-DTA和元素分析等手段对样品进行了表征。结果表明，离子交换法制得的产品中丁二酸根阴离子取代了镍铝水滑石前体层间的碳酸根离子，组装得到晶体结构良好的丁二酸根插层水滑石，层间距为1．23nm。 相似文献
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光释光测年作为一种沉积物绝对测年方法已在第四纪地质研究中得到了广泛应用,提高光释光测年精度和准确度一直是学术界关注的热点,长期以来人们对等效剂量测量程序和计算方法的研究十分丰富,而对环境剂量率的研究则相对较少。本文以琼西南海域ZBW钻孔岩心样品为例,利用电感耦合等离子质谱/发射光谱法（ICP-MS/OES）、中子活化分析（NAA）、γ谱仪法对海洋沉积物环境剂量率进行了对比测量。结果表明,在部分层段3种方法测量的结果存在差异,其原因为：（1）ICPMS/OES前处理过程中重矿物中的U不完全溶解;（2）ICP-MS/OES测量结果为U、Th、K元素含量,包含了部分非放射性核素含量;（3）NAA测量用的样品量小,存在偶然性误差,样品中非放射性物质的稀释作用影响测量结果;（4）样品中存在铀系不平衡现象,结合研究区沉积环境和高纯锗γ谱仪测量结果进行对比分析表明,铀系不平衡主要来源于自生铀吸收,对环境剂量率的影响约为11%。 相似文献
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《中国海洋大学学报(自然科学版)》2015,(6)
基于高分辨率层序地层学及储层沉积学理论,利用岩心、测井曲线、分析化验等资料,研究松辽盆地大安油田葡萄花油层沉积特征及演化。通过对泥岩颜色、生物化石、沉积构造、储层岩石学特征、特殊矿物及沉积背景等分析,确定研究区葡萄花油层发育浅水三角洲前缘沉积、前浅水三角洲沉积和浅湖—半深湖沉积。其中,浅水三角洲前缘亚相可进一步细分为水下分支河道、水下天然堤、水下分支河道间湾、河口坝和远砂坝5种微相。并对研究区沉积相进行了单井岩心相分析、测井相分析、连井相对比和平面沉积微相研究。大安油田葡萄花油层沉积时期,三角洲为先进积后退积:葡萄花8—4小层(P8—P4)时期,为湖盆萎缩、三角洲进积的阶段;葡萄花4—0小层(P4—P0)时期,则为湖盆扩张、三角洲退积的过程。物源来自北西方向的白城水系。 相似文献
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Zhengxin Yin Zhourong Cai Cheng Zhang Xiaofeng Huang Qianru Huang Liang Chen 《海洋学报(英文版)》2021,40(9):33-42
Identifying distinct tectonic units is key to understanding the geotectonic framework and distribution law of oil and gas resources. The South China Sea and its adjacent areas have undergone complex tectonic evolution processes, and the division of tectonic units is controversial. Guided by block tectonics theory, this study divide the South China Sea and its adjacent areas into several distinguished tectonic units relying on known boundary markers such as sutures(ophiolite belts), subduction-collision zones, orogenic belts, and deep faults. This work suggests that the study area is occupied by nine stable blocks(West Burma Block, Sibumasu Block, LanpingSimao Block, Indochina Block, Yangtze Block, Cathaysian Block, Qiongnan Block, Nansha Block, and Northwest Sulu Block), two suture zones(Majiang suture zone and Southeast Yangtze suture zone), two accretionary zones(Sarawak-Sulu accretionary zone and East Sulawesi accretionary zone), one subduction-collision zone(RakhineJava-Timor subduction-collision zone), one ramp zone(Philippine islands ramp zone), and six small oceanic marginal sea basins(South China Sea Basin, Sulu Sea Basin, Sulawesi Sea Basin, Banda Sea Basin, Makassar Basin, and Andaman Sea Basin). This division reflects the tectonic activities, crustal structural properties, and evolutionary records of each evaluated tectonic unit. It is of great theoretical and practical importance to understand the tectonic framework to support the exploration of oil and gas resources in the South China Sea and its adjacent areas. 相似文献
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The geochemical and petrographic characteristics of saline lacustrine shales from the Qianjiang Formation, Jianghan Basin were investigated by organic geochemical analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and low pressure nitrogen adsorption analysis. The results indicate that: the saline lacustrine shales of Eq3 member with high oil content are characterized by type I and type II oil-prone kerogen, variable TOC contents (1.0–10.0 wt%) and an early-maturity stage (Ro ranges between 0.41 and 0.76%). The mineral compositions of Eq3 saline shale show strong heterogeneity: brittle intervals with high contents of quartz and carbonate are frequently alternated with ductile intervals with high glauberite and clay contents. This combination might be beneficial for oil accumulation, but may cause significant challenges for the hydraulic stimulation strategy and long-term production of shale oil. The interparticle pores and intraparticle pores dominate the pore system of Eq3 shale, and organic matter hosted pores are absent. Widely distributed fractures, especially tectonic fractures, might play a key role in hydrocarbon migration and accumulation. The pore network is contributed to by both large size inorganic pores and abundant micro-factures, leading to a relatively high porosity (2.8–30.6%) and permeability (0.045–6.27 md) within the saline shale reservoir, which could enhance the flow ability and storage capacity of oil. The oil content (S1 × 100/TOC, mg HC/g TOC and S1, mg HC/g rock) and brittleness data demonstrate that the Eq33x section has both great potential for being a producible oil resource and hydraulic fracturing. Considering the hydrocarbon generation efficiency and properties of oil, the mature shale of Eq3 in the subsidence center of the Qianjiang Depression would be the most favorable zone for shale oil exploitation. 相似文献
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The Songliao Basin is a large-scale petroliferous basin in China. With a gradual decline in conventional oil production, the exploration and development of replacement resources in the basin is becoming increasingly important. Previous studies have shown that the Cretaceous Qingshankou Formation (K2qn) has favorable geological conditions for the formation of shale oil. Thus, shale oil in the Qingshankou Formation represents a promising and practical replacement resource for conventional oil. In this study, geological field surveys, core observation, sample tests, and the analysis of well logs were applied to study the geochemical and reservoir characteristics of shales, identify shale oil beds, build shale oil enrichment models, and classify favorable exploration areas of shale oil from the Cretaceous Qingshankou Formation. The organic matter content is high in shales from the first member of the Cretaceous Qingshankou Formation (K2qn1), with average total organic carbon (TOC) content exceeding 2%. The organic matter is mainly derived from lower aquatic organisms in a reducing brackish to fresh water environment, resulting in mostly type I kerogen. The vitrinite reflectance (Ro) and the temperature at which the maximum is release of hydrocarbons from cracking of kerogen occurred during pyrolysis (Tmax) respectively range from 0.5% to 1.1% and from 430 °C to 450 °C, indicating that the K2qn1 shales are in the low-mature to mature stage (Ro ranges from 0.5% to 1.2%) and currently generating a large amount of oil. The favorable depth for oil generation and expulsion is 1800–2200 m and 1900–2500 m, respectively as determined by basin modeling. The reserving space of the K2qn1 shale oil includes micropores and mircofractures. The micropore reservoirs are developed in shales interbedded with siltstones exhibiting high gamma ray (GR), high resistivity (Rt), low density (DEN), and slightly abnormal spontaneous potential (SP) in the well-logging curves. The microfracture reservoirs are mainly thick shales with high Rt, high AC (acoustic transit time), high GR, low DEN, and abnormal SP. Based on the shale distribution, geochemical characteristics, reservoir types, fracture development, and the process of shale oil generation and enrichment, the southern Taikang and northern Da'an are classified as two favorable shale oil exploration areas in the Songliao Basin. 相似文献
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在深入调研南海深水盆地油气地质条件的基础上,系统分析了油气分布规律和成藏主控因素,明确了油气资源潜力和有利勘探方向,旨在为南海深水油气勘探决策提供科学依据。研究结果表明:南海深水盆地发育在非典型边缘海大陆边缘,其石油地质条件具有特殊性,油气分布特征存在显著的南北差异。其中,南海北部深水的珠江口盆地和琼东南盆地,以构造圈闭型油气藏为主;南海中南部深水的曾母盆地南部和文莱-沙巴盆地,主要为构造圈闭型油气藏,曾母盆地北部以岩性油气藏(生物礁滩型油气藏)为主,万安盆地主要为构造圈闭型和基岩潜山型油气藏。南海北部深水盆地和中南部深水盆地的烃源岩、储盖和圈闭等油气地质特征表明,南海深水盆地具有巨大的油气勘探潜力。南海深水的有利勘探方向为:①琼东南盆地乐东-陵水凹陷的中央峡谷、陵南斜坡带,松南-宝岛凹陷的反转构造带,宝岛凹陷北坡海底扇,长昌凹陷的环A洼圈闭带(海底扇);珠江口盆地白云凹陷的主洼深水扇、主洼两翼、西南断阶带,荔湾凹陷的深水扇。②南海中南部深水盆地的文莱-沙巴、曾母和万安盆地。 相似文献
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The identification of reservoir oil–gas–water layers is a fundamental task in petroleum exploration and exploitation, but is difficult, especially in cases of complex hydrocarbon migration and accumulation. In such cases, hydrocarbon remigration and dysmigration take place very commonly, leading to the presence of residual or paleo-oil accumulations and layers, which cannot be easily identified or misinterpreted as oil layers by conventional logging and geophysical data. In this paper, based on a case study in the Luxi area of the central Junggar Basin, NW China, we seek to characterize such layers in terms of organic geochemistry. We suggest specific indicator parameters of organic geochemistry such as the chloroform bitumen content of reservoir extracts, which is usually >1.0% in oil layers. We explore the application of grains containing oil inclusions (GOI) (the ratio of mineral grains containing oil inclusions to the total number of mineral grains) for the identification of oil–gas–water layers in the Junggar Basin for the first time; this method has been used elsewhere. The maximum GOI values for the oil layers, oil–water layers, water layers and dry layers are >11%, 7%–11%, 6%–7% and <6%, respectively. In addition, gas layers and heavy-oil layers that are difficult to identify by conventional organic geochemical parameters were identified using biomarkers. The typical characteristics of the soluble reservoir bitumen in the gas layers include a much greater abundance of tricyclic terpanes (two times in general) relative to pentacyclic terpanes and a tricyclic terpane distribution of C20 > C21 > C23. In contrast, the typical characteristic of the heavy-oil layers is the presence of 25-norhopanes in reservoir bitumen extracts. These specific indicators can be applied in the Junggar Basin and in similar settings elsewhere. 相似文献
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在对南黄海盆地海相中、古生界烃源条件和后期保存条件研究的基础上,运用盆地模拟手段并结合前人研究成果,对海相地层烃源岩的排烃史进行了模拟,计算了海相地层油气资源量,从而进行了海相油气资源潜力的分析;同时通过对海相上构造层和下构造层两套含油气系统成藏条件的研究,预测了盆地内海相油气资源的有利运聚区,进而指出南黄海盆地海相油气勘探的有利区,为下一步南黄海盆地的勘探部署提供了依据。研究表明,南黄海盆地海相下构造层和海相上构造层栖霞组、龙潭组—大隆组烃源岩推测为好的烃源岩,海相上构造层青龙组烃源岩推测为中等—好的烃源岩;盆地海相地层具有一定的油气资源潜力,油气资源总量为35.37×10^8t,且在纵向上,油气资源主要来自海相下构造层烃源岩系,在平面上主要分布于南部坳陷;盆地海相地层存在两类油气资源勘探有利区,其中,最有利区位于中部隆起区南部、南部坳陷区和勿南沙隆起区北部。 相似文献
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古巴三区块是2005年中国石化获得的风险勘探开发合同区块，位于墨西哥湾西南部，是古巴西部的前陆盆地之一。结合该盆地勘探现状，对相关的钻井、物探以及地球化学等资料进行石油地质综合分析，评价了该盆地的油气成藏条件及其勘探潜力，预测了有利区带。三区块主要发育上侏罗统一下白垩统的泥灰岩、泥质灰岩和中-下侏罗统泥页岩两套主要烃源岩，储层以泥晶灰岩、灰岩和砂砾岩为主，区内早期形成的圈闭在造山期基本遭到破坏，有效的圈闭主要形成于晚古近纪，圈闭类型有背斜、断鼻、断块和地层圈闭等，推测可能发育多套储盖组合。据区域对比和钻井资料分析，区内的前陆冲断带是本区最有利勘探区带，南盆地北缘发育较厚的第三系，推测是本区有利远景区。 相似文献