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混凝土在海洋暴露过程中的氯离子渗透研究 总被引：2，自引：0，他引：2
将矿粉掺量0%~65%、粉煤灰掺量0%~30%混凝土置于海洋大气区、潮汐区2年,研究海洋不同区域、矿粉掺量、粉煤灰掺量对混凝土中氯离子渗透规律的影响。结果表明:混凝土在海洋环境下暴露2年,氯离子质量分数随着渗透深度的增加而减小,最后趋于稳定;海洋潮汐区腐蚀混凝土氯离子传输受扩散机制控制,而大气区腐蚀混凝土受到扩散和毛细吸附双重机制控制。随着腐蚀龄期的增加,混凝土中氯离子侵蚀深度增加,表面层氯离子浓度线性增加。潮汐区腐蚀混凝土的氯离子浓度高于大气区腐蚀混凝土,但其表观氯离子扩散系数小于大气区腐蚀混凝土。粉煤灰和矿粉掺量对于混凝土的抗氯离子渗透能力而言,其最优值分别为15%、30%。 相似文献
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表面氯离子含量(C_s)是研究海洋环境条件下混凝土结构耐久性和服役寿命的氯离子扩散方程的边界条件,是海洋混凝土结构耐久性分析和定量设计的重要参数。依据国内外大量自然暴露试验与工程实测数据,通过采用Excel、Origin等数据分析软件进行数据统计和回归分析,确定了海洋混凝土结构表面自由氯离子含量(C_(sf))与表面总氯离子含量(C_(st))之间的相互关系,探讨了海洋混凝土结构的C_(sf)时变规律,建立了C_(sf)与暴露时间之间的关系表达式及其取值范围,并运用可靠度理论和修正氯离子扩散理论分析了C_(sf)时变性对海洋混凝土结构寿命的影响。结果表明:C_(sf)与C_(st)线性相关,且C_(sf)随着暴露时间的延长呈指数或者幂函数的增长关系;采用不同的C_(sf)时变性规律,对海洋混凝土结构寿命具有重大的影响。 相似文献
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对服役12年的华南某跨海大桥典型构件开展碳化性能、氯离子扩散性能等指标的耐久性检测,评估了海水环境下掺粉煤灰的高性能混凝土长期耐久性。研究表明:随高程的增加混凝土碳化深度逐渐增大,其中大气区浪溅区水位变动区,碳化作用对粉煤灰混凝土结构耐久性的影响较小;粉煤灰可显著提升实体结构混凝土抗氯离子侵蚀性能,粉煤灰高性能混凝土的氯离子扩散系数不大于0.40×10-12m2/s,比普通混凝土氯离子扩散系数降低了约6倍;利用规范计算了引桥承台混凝土中氯离子含量计算值,其计算值与实测值吻合较好,可用于实体工程混凝土结构的耐久性评估,评估结果显示采用粉煤灰高性能的桥梁典型构件满足100年设计使用寿命的要求。 相似文献
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海洋环境中混凝土结构服役寿命预测 总被引：2，自引：1，他引：1
通过参数定义对Fick定律的不合理假定进行修正,推导氯离子在混凝土中扩散的多因素修正模型,综合考虑氯离子扩散系数的时随效应、混凝土的氯离子结合能力和混凝土自身缺陷的影响.根据对大量数据的分析试算,给出模型中参数的取值.利用该扩散模型,进一步推导海洋环境下基于概率性能的混凝土结构服役寿命计算方法,有效解决混凝土结构服役寿命预测中氯离子扩散系数及混凝土保护层厚度的随机特性.最后给出实际工程算例,说明该预测方法的有效性. 相似文献
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通过室内干湿循环条件下混凝土中氯离子扩散试验,实测得到6种不同粗骨料体积分数的混凝土试件在不同时刻、不同深度处的氯离子浓度。经回归分析得到了不同粗骨料体积分数下混凝土的氯离子整体扩散系数,其值随粗骨料体积分数的增加而减小。同时,探讨了粗骨料的稀释、曲折和界面过渡区效应对混凝土中氯离子扩散的影响。在此基础上,同时考虑粗骨料体积分数Vf和界面过渡区厚度h的影响系数α(Vf,h),建立混凝土界面过渡区氯离子扩散系数模型,界面过渡区氯离子扩散系数随粗骨料体积分数的增大呈近乎线性地减小,随界面过渡区厚度的增大先显著减小而后逐渐趋于平稳。最后,将建立的界面过渡区氯离子扩散系数模型应用于混凝土中氯离子扩散的三维细观数模中。结果表明:细观数模计算结果与物理试验实测数据在变化趋势和数值大小上均能够吻合,可验证界面过渡区氯离子扩散系数模型的正确性与合理性。 相似文献
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根据人工模拟的流动海水环境(流速约为0.15m/s)下的混凝土侵蚀试验测得的混凝土中氯离子质量分数,分别测定了腐蚀350,380,400d后混凝土的氯离子扩散系数,并计算和预测了混凝土人工鱼礁的耐久性寿命。研究结果表明:氯离子在混凝土人工鱼礁中的扩散规律基本上遵循Fick第二定律;钢筋混凝土人工鱼礁的耐久性寿命与保护层厚度的平方成正比;海水盐度对混凝土人工鱼礁的耐久性寿命影响较大。 相似文献
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有氯盐侵蚀的钢筋腐蚀,是钢筋混凝土结构性能劣化的主要原因之一,混凝土构件使用寿命的关键是氯离子的传输速率和使钢筋产生锈蚀的时间。本文以人工鱼礁混凝土构件为研究对象,分析海水氯离子在C30、C35和钢渣复合材料人工鱼礁混凝土中的扩散系数,以混凝土中钢筋锈蚀的临界氯离子浓度为寿命预测的边界条件,利用氯离子扩散模型预测C30、C35和钢渣复合材料人工鱼礁在海水中的腐蚀寿命。研究结果表明,氯离子在混凝土人工鱼礁中的扩散规律基本满足Fick第二定律。通过模型计算得出C30、C35和钢渣复合材料混凝土人工鱼礁的腐蚀寿命分别为51.6,54.8和56.8年。 相似文献
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本文专门研究时变环境下的自适应时间延迟估计问题，首先明确时变环境的含义，再分析时变环境所提出的新问题，然后介绍几种适用于时变环境的自适应时延估计方法，最后给出计算机模拟的结果。 相似文献
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Influence ofwaterlogging time on the growth ofKandeliacandel(L.) Druce seedlings grown for 70 d in the artificial-tidal tanks' simulated semidiumal tide under greenhouse is studied. Sand and soil act as the substrate and artificial sea-water with salinity of 15 is used in cultivation. Shorter waterlogging time (inundated for about 2 ～ 4 h) promotes thegrowth of K. candel seedlings, while longer time(inundated more than 8 h) or no waterlogging(0 h) inhibits theirgrowth. The number and length of aerating roots increase with the increase ofwaterlogging time. Under existing condi-tions, the optimalwaterlogging time for the growth of K. canoel seedlings is about 2 ～ 4 h in every tide cycle. Com-pared with other treatments, the 2 h sanded treatments obtain the highest biomass of seedlings, have the lowest massloss ofhypocotyl and broaden the photosynthetic area by increasing the area per leaf after 70-d cultivation. And the soiltreatments have the similar tendeney. However, waterlogging for 8 h in every tide cycle is critieal for normal develop-ment of seedlings. K. candel seedlings are highly tolerant to waterlogging and a proper waterlogging is beneficial to thegrowth ofK. candel seedlings. 相似文献
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Generally the waters of the Ria Formosa Lagoon, Portugal have a short residence time, in the order of 0.5 days (Tett, P., Gilpin, L., Svendsen, H., Erlandsson, C.P., Larsson, U., Kratzer, S., Fouilland, E., Janzen, C., Lee, J., Grenz, C., Newton, A., Ferreira, J.G., Fernandes, T., Scory, S., 2003. Eutrophication and some European waters of restricted exchange. Continental Shelf Research 23, 1635–1671). This estimation is based on the measurements of currents and the modelling of water exchange at the outlets to the ocean. However, observations of the temperature and salinity in the inner channels imply that residence time is greater in these regions of the lagoon. To resolve this apparent contradiction, spatial measurements of the temperature and salinity were made with a meter for conductivity, temperature and depth along the principal channels of the western portion of the lagoon, with a sampling frequency of two per second. Evaporation rates of 5.4 mm day−1 were measured in a salt extraction pond adjacent to the lagoon and used to determine the residence time through salinity differences with the incoming seawater. In June 2004, the water flooding in from the ocean had an average salinity of 36.07 which contrasted with a maximum of 37.82 at mid ebb on a spring tide, corresponding to a residence time of >7 days; the mean residence time was 2.4 days. As the tide flooded into the channels, the existing water was advected back into the lagoon. Although there was a small amount of mixing with water from another inlet, the water body from the inner lagoon essentially remained distinct with respect to temperature and salinity characteristics. The residence time of the water was further prolonged at the junction between the main channels, where distinct boundaries were observed between the different water masses. As the water ebbed out, the shallow Western Channel was essentially isolated from the rest of the outer lagoon, and the water from this channel was forced down the Ramalhete Channel, from where it was unable to exit the lagoon in one tidal cycle due to the extensive path length of ∼14 km to the sea. 相似文献
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Transport timescales for identifying seasonal variation in Bass Strait, south-eastern Australia 总被引：1，自引：0，他引：1
A three-dimensional σ-coordinate ocean model with realistic forcing is used to derive and compare flushing time, residence time and water age distributions in Bass Strait, a broad shallow shelf sea in south-eastern Australia which exhibits seasonal variation in water mass properties and circulation. Results illustrate flushing out of most old water occurs each winter–spring period and the circulation in summer increases age of remnant older water in the Strait. A correlation between water age and salinity is found in winter which is the result of advective “erosion” of the interior water mass. The presence of an area in the south-eastern part of the interior with low flushing is suggested to result from a number of physical factors including the presence of quasi-stationary eddies which entrain age, leading to relatively older water residing there. 相似文献
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潮汐淹水时间对秋茄幼苗生长的影响 总被引：16，自引：0，他引：16
模拟正规半日潮淹水的条件下,不同淹水时间对秋茄[Kandelia candel(L.)Druce]幼苗生长的影响.应用沙和土两种培养基质,制备盐度为15的人工海水栽培幼苗培养时间为70 d.不淹水(0 h)和长时间淹水(>8 h)对秋茄幼苗的生长有一定的抑制作用,而短时间淹水(淹水2~4 h)对幼苗生长有所促进.较长时间的淹水可促进贮气根的数量增加和长度的增长.在当前培养条件下,秋茄幼苗生长的最佳淹水时间是每个潮水循环淹水2~4 h.2 h处理的沙培秋茄幼苗总生物量和成熟叶面积最大,胚轴失重最小,土培幼苗也有相应的变化趋势.秋茄幼苗生长的临界淹水时间是每个潮水循环淹水8 h.秋茄幼苗有较强的抗淹水能力,适当的淹水对其生长有利. 相似文献
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Influence of waterlogging time on the growth of Kandelia candel(L.) Druce seedlings grown for 70 d in the artificialtidal tanks‘ simulated semidiurnal tide under greenhouse is studied. Sand and soil act as the substrate and artificial seawater with salinity of 15 is used in cultivation. Shorter waterlogging time (inundated for about 2 ～ 4 h) promotes the growth of K candel seedlings, while longer time (inundated more than 8 h) or no waterlogging (0 h) inhibits their growth. The number and length of aerating roots increase with the increase of waterlogging time. Under existing conditions, the optimal waterlogging time for the growth of K. candel seedlings is about 2 ～ 4 h in every tide cycle. Compared with other treatments, the 2 h sanded treatments obtain the highest biomass of seedlings, have the lowest mass loss ofhypocotyl and broaden the photosynthetic area by increasing the area per leaf after 70-d cultivation. And the soil treatments have the similar tendency. However, waterlogging for 8h in every tide cycle is critical for normal development of seedlings.K. candel seedlings are highly tolerant to waterlogging and a proper waterlogging is beneficial to the growth of K. candel seedlings. 相似文献
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褐藻酸钠硫酸酯是以褐藻酸为原料合成的硫酸酯钠盐系列物。首次报道该系列化合物（Ⅰ，Ⅱ，Ⅲ，Ⅳ，主要是Ⅰ）的抗血栓和抗凝血作用。实验发现，褐藻酸钠硫酸酯系列物均有抗凝血作用。其作用具有浓度和磺化度依赖性。实验测定化合物Ⅰ，Ⅱ，Ⅲ，Ⅳ的抗凝效价，分别相当于肝素钠的22．5％，16．7％，11．1％和11．7％。以该化合物10mg·kg－1静脉注射能增加小鼠的出血量并能抑制大鼠实验性动脉血栓的形成。化合物Ⅰ还具有延长大鼠凝血酶原时间和抑制静脉血栓形成的作用。结果提示：褐藻酸钠硫酸酯的抗凝血与抗血栓作用的活性基团可能为该化合物上的硫酸根，具有肝素样作用。 相似文献
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在验证良好的三维斜压潮流数学模型的基础上,以溶 解态的保守性物质为示踪剂,建立对流-扩散型的海湾水交换数值模型,计算了象山港水体半交换时间和平均滞留时间,并研究了斜压动力对湾内外水交换的贡献。研究结果表明,象山港水交换速度的区域性变化较大,水体半交换时间和平均滞留时间由象山港口门向湾顶逐渐增加,口门附近半交换时间在5d以内,平均滞留时间为5~10 d;湾顶水交换速度缓慢,水体半交换时间为30~35 d,平均滞留时间为35~40d。斜压动力对狭湾外段水交换影响较弱,对狭湾内段有较大的影响。 相似文献