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1.
水体石油类信息遥感提取模式研究   总被引:2,自引:0,他引:2  
石油类是水体有机污染物中的一种,其对水体吸收系数的影响主要体现在有色可溶性有机物(chromophoric dissolved organic matter,CDOM)的光吸收特性上。在水色遥感领域,CDOM光吸收特性主要用其在参考波段的吸收系数和光谱斜率来表征。利用2008年5月、2009年8月和2010年6月在辽宁省盘锦市辽河油田境内获取的CDOM吸收系数、水体表观光学特性以及石油类污染浓度等试验数据,确定表征石油类污染水体CDOM吸收光谱特性的光谱斜率;根据光谱斜率以及表征CDOM浓度的440 nm参考波段吸收系数,建立遥感反演水体石油类污染浓度的模式,并利用31个野外现场实测值对模式精度进行了验证,结果表明,该模式的相对误差为7%;将该模式应用于国产卫星环境一号遥感数据,获取双台子河及辽东湾近岸水体石油类污染空间分布图。  相似文献   

2.
舟山海域陆源溶解有机质变化及其对近岸羽状流的响应   总被引:5,自引:1,他引:4  
2007年夏季在东海舟山海域河口锋区开展了陆源溶解有机质的调查研究。测定了有色溶解有机质(CDOM)在激发波长370 nm/发射波长460 nm处的荧光强度和在λ=355 nm处的吸收系数,用于代表陆源CDOM浓度,并测定了荧光指数以指示CDOM来源。结果表明,CDOM的荧光值和紫外吸收系数之间呈显著正相关性,陆源CDOM浓度大体有向海方向降低的趋势,但是纵向上存在一些"突跃"现象。在舟山海域东北角不时观测到表层水体含有高浓度的CDOM,但变异性很大,推测可能该海区受到长江口羽状流的影响。在连续观测站发现陆源CDOM浓度在低平潮时往往比高平潮时要高。河海水在混合过程中CDOM浓度与盐度呈显著的线性负相关关系。在低盐度的悬沙锋区(S<24)CDOM浓度明显低于理论稀释值,而在较高盐度的羽状锋区,CDOM浓度接近于理论稀释值。在盐度为24~31范围内,大部分水样的荧光指数在1.50上下波动,表明其中CDOM来源以陆地来源为主;在较低盐度(S<24)的水样中荧光指数在1.70至1.90以上,表明CDOM以海洋来源为主,这与其陆源组分在高浊度的低盐度区存在显著的去除过程有关。研究表明,舟山海域水质存在着显著的变异性,与近岸羽状流密切相关,陆源溶解有机质的分布特征对此有较好的响应。  相似文献   

3.
于2014年10月和2015年6月对东海海水和大气中挥发性卤代烃(VHOCs)的浓度分布、来源及海-气通量进行了系统的研究。结果表明:秋季东海海水中二氟二氯甲烷(CFC-12)、三氯氟甲烷(CFC-11)、三氟三氯乙烷(CFC-113)的浓度普遍高于夏季。秋季和夏季3种CFCs的水平分布均呈现近岸高,外海低的趋势,其分布主要受到陆源输入和长江冲淡水的影响。海水中碘甲烷(CH3I)的分布表现出明显的季节变化,浓度高值出现在夏季。CH3I的分布受到陆源输入、浮游植物释放和光化学合成的影响。夏季东海大气中3种氟氯烃CFC-12、CFC-11和CFC-113的浓度分布主要受陆源气团输送和气象条件的影响;CH3I的来源除陆源释放外,海洋释放也十分重要。总体来说夏季东海海域是大气中CFC-12和CFC-11的汇,是CH3I的源。  相似文献   

4.
夏季黄东海颗粒有机碳的分布特征   总被引:2,自引:0,他引:2  
根据2006年6~7月对黄东海大面调查的资料,分析研究了黄东海颗粒有机碳(particulate organic carbon,POC)的浓度和分布特征。结果表明,夏季黄东海POC的浓度范围是6.07~2 204.17μg.L-1,平均浓度为147.15μg.L-1。POC整体上呈现近岸浓度较高、远岸浓度较低,北部浓度较高,南部浓较低的分布特点;在长江口外及浙江近岸海区存在POC的高值区,特别是长江口外,表层和底层POC浓度很高,这主要是受到长江陆源输入的重要影响。在垂直分布上,南黄海区POC的浓度分布整体上呈现上层水体浓度较低,下层水体浓度较高的特点,这主要是受底质再悬浮的影响。而东海区呈现近岸POC浓度较高,离岸POC浓度较低的特点,这主要是受长江冲淡水输入的影响。  相似文献   

5.
长江是亚洲第一大河,巨大的迳流流入东海后,与外海水发生湍流混合,使本海区温盐结构随其发生变化.众所周知,某海区的盐度场结构及其变化是取决于该海区盐量收支的平衡规律.然而,考虑到长江冲淡水区是口股水系交汇的海区,所以影响盐度场的因子众多而复杂.运用统计相关分析,虽然能给出各因子和海水盐度分布的某种程度的相关关系,但对长江冲淡水的动力结构及其混合过程并未揭示.为此,本文想通过对夏季长江冲淡水远岸段的表层平均盐度分布,给出一个可能的数字模式.为进一步探讨长江冲淡水的动力结构及其混合过程提供一些启示,以期对该区的认识乃至预报有所裨益.  相似文献   

6.
依据2012年6—7月在东海陆架区所取得的悬浮体、温度、盐度和叶绿素资料,探讨了该区悬浮体有效密度的分布特征及其影响因素。结果表明,研究区的悬浮体有效密度总体上表现为近岸低、外海高的分布特征。随深度的增加,近岸海域悬浮体有效密度逐渐增大,底层水体较上层水体呈现为高值;外海区悬浮体有效密度则相对稳定,底层水体较上层水体呈现为低值。研究区悬浮体有效密度的空间分布主要受到长江冲淡水、浙江沿岸上升流和海底沉积环境的影响,其中长江冲淡水和浙江沿岸上升流对该区的"叠加"影响是主要因素。  相似文献   

7.
对于本研究采用的动力学模型及其垂直环流的模拟结果已在第Ⅰ部分论述。作者将对与垂直环流对应的温、盐结构进行分析。温度和盐度模拟结果表明:冬季东海沿岸海区的温、盐分布均为近岸低、外海高;近岸温、盐呈垂直均匀分布,在外海出现分层,其温度为表层高、底层低,而盐度却为表层和底层高,中层偏低,长江口以南的近表层以下形成自近岸伸向外海的弱低盐水舌;长江冲淡水区及长江口以北和其以南外海的近表层有温、盐跃层生成,深底层温、盐呈均匀分布,且保持低温高盐特征;随着海区自北往南纬度的降低,岸坡和水深的增大及沿岸下降流的增强,温度和盐度自近岸至外海的垂直均匀分布跨度逐渐变窄;外海近表层的温、盐跃层强度自北至长江口逐渐增强,而自长江口至南逐渐减弱,其位置自北往南逐渐上移;冬季沿岸下降流使长江冲淡水区的盐跃层变厚。夏季海区的温度分布为近岸和外海高,近岸稍远出现冷水涌升,垂向上呈现显著分层,盐度分布为近岸低、外海高;长江冲淡水区及杭州湾以南外海的次表层存在温、盐跃层,其跃层以上出现混合层,且保持高温低盐特征,跃层以下温、盐大致呈均匀分布,并保持低温高盐特征;随着海区自南往北纬度的增高、岸坡和水深的减小及沿岸上升流自南至长江口和自长江口至北的增强和继而减弱,长江冲淡水区的温、盐跃层强度自南至长江口逐渐增强,而自长江口至北逐渐减弱,外海次表层的温、盐跃层强度却自南至长江口逐渐减弱,自长江口至北又逐渐增强,其温、盐跃层的位置自南往北逐渐上移;夏季沿岸上升流使长江冲淡水区的盐跃层变薄。  相似文献   

8.
长江口及其邻近海域CDOM光谱吸收特性分析   总被引:3,自引:0,他引:3  
研究了长江口及其邻近海域有色可溶性有机物(CDOM)的光吸收特性,分析了CDOM浓度(吸收系数a(440))、光谱斜率(Sg)与盐度的关系。结果表明:长江口及其邻近海域CDOM的a(440)变化范围为0.21~0.85m-1,平均值为0.44m-1;Sg值的范围为0.013 3~0.016 7nm-1,平均值为0.014nm-1;a(440)的水平分布表现为长江口海区比外海区高,Sg的水平分布表现为长江口海区比外海区低,反映了长江口海区CDOM中的腐殖酸成分比外海区大。研究区内a(440)与盐度、Sg与盐度明显线性相关,表明CDOM在河口混合行为中呈保守行为,CDOM具有良好的保守性质。  相似文献   

9.
厦门湾有色溶解有机物的光吸收特性研究   总被引:3,自引:0,他引:3  
研究了厦门湾九龙江河口区、西海域、同安湾及东侧水道海水中有色溶解有机物(CDOM)的光吸收特性,分析了CDOM的河口行为,并讨论了CDOM光吸收特性与其荧光性质之间的关系。结果表明,厦门湾表层海水CDOM光吸收系数a(355)的水平分布表现为河口区最高、东侧水道最低、西海域和同安湾介于两者之间,底层水a(355)的分布与表层基本相似,表明陆源河流输入是厦门湾CDOM的主要来源;a(355)的垂直分布为表层高于底层,主要受水文和生物因素控制。厦门湾表层水CDOM光谱斜率S的平均值介于0.014—0.018nm-1,但河口低盐度区S值较小,反映陆源腐殖质的影响。a(355)在河口混合中呈保守行为,表明CDOM具有良好的保守性质。CDOM的吸收系数a(355)与其荧光强度之间表现为较好的相关关系,指示可以用灵敏度更高的荧光方法来研究CDOM的分布和行为。  相似文献   

10.
水体中有色可溶性有机物的研究进展   总被引:12,自引:0,他引:12  
有色可溶性有机物(CDOM)是水体中一类重要的光吸收物质,在短波的吸收大大降低了紫外辐射在水体的衰减,因而其光学行为和生物地球化学循环将对水体生态系统产生重要影响。CDOM在水体生态系统、水色遥感和全球碳循环研究中具有广阔的应用前景。文章综述了国内外CDOM研究现状与动态,其中包括CDOM的光吸收特性、荧光特性、光化学降解以及CDOM和DOC浓度的水色遥感,最后提出在内陆水体湖泊中开展CDOM研究的设想。  相似文献   

11.
基于2007年8月海洋光学浮标在珠江口投放期间获得的近16天的实测生物光学数据, 对一次藻华过程中水体总吸收系数和水色光谱的变化特性及其相互关系进行了研究。结果表明, 藻华前后水体中非藻类物质尤其是有色溶解有机物在蓝光波段具有较强的吸收贡献, 而当藻华爆发时, 随着叶绿素a浓度的急剧增大, 浮游植物的吸收贡献明显增强; 各波段之间总吸收系数呈现出较好的线性相关关系, 吸收光谱蓝绿波段比值的变化对遥感反射率的光谱分布有重要的贡献; 据此建立了对水体总吸收系数反演的经验关系模型, 表现出较高的反演精度, 计算值与实测值之间相对偏差的均方根在可见光波段可控制在24%以内。  相似文献   

12.
用于海洋-大气辐射传递计算的光学参数数据库   总被引:2,自引:1,他引:1  
开发和建立了用于海洋-大气辐射传递计算的光学参数数据库.它包括海中主要成分(纯海水、浮游植物、悬移质、可溶有机物)的固有光学参数(光谱吸收系数、光谱散射系数等)及大气中主要气溶胶的有关光学参数.在这些光学参数中,大多数是来自现场的直接测量,一些是间接测量获取,还有一些是通过理论计算得到.  相似文献   

13.
有色可溶性有机物(chromophoric dissolved organic matter,CDOM)是水体中一类重要的光吸收物质,在水色遥感中,其光学特性主要以440 nm处的吸收系数和光谱斜率来表征,利用这些光学特性进行水环境要素遥感反演具有较广泛的应用前景.化学需氧量(chemical oxygen deman...  相似文献   

14.
The quantity of chromophoric or coloured dissolved organic matter (CDOM) released by eleven species of intertidal and sub-tidal macroalgae commonly found on UK shores was investigated. The subsequent breakdown of CDOM was also measured by exposing collected CDOM samples to light and dark conditions for over two weeks. CDOM absorption properties were compared at a fixed wavelength of 440 nm and across two integrated wave - bands; UV-A (400–315 nm) and UV-B (315–280 nm). Absorption spectra of macroalgal CDOM samples were typically characterized by peaks and shoulders in the UV bands, features which were species specific. The spectral slope, derived using the log-linear method, proved to be very specific to the species and to the effect of light. Slope measurements ranged from 0.010 to 0.027 nm−1, in the range of normal seawater values. Significantly more CDOM was produced by algae which were illuminated, providing evidence for a light driven exudation mechanism. Averaged across all species, exudation in the dark accounted for 63.7% of that in the light in the UV-B band. Interspecific differences in exudation rate encompassed an order of magnitude, with the highest absorption measurements attributable to brown algae. However, some brown algae produced considerably less CDOM (e.g. Pelvetia canaliculata), which were more comparable to the green and red species. Over an exposure time of 16 days, significant photochemical degradation of CDOM was observed using a natural summer sunlight regime, showing that natural solar radiation could be an important removal mechanism for newly produced algal CDOM. Though the most obvious effect was a decrease in absorption, photo-bleaching also caused a significant increase in the spectral slope parameter of 0.004 nm−1.  相似文献   

15.
The retrieval of dissolved organic carbon (DOC) distribution by remote sensing is mainly based on the empirical relationship of DOC concentration and colored dissolved organic matter (CDOM) concentration in many literatures. To investigate the nature of this relationship, the distributions and mixing behaviors of DOC and CDOM are reviewed in the world’s major estuaries and bays. It is found that, generally, the CDOM concentration is well correlated with the salinity in most estuaries, while DOC usually shows a nonconservative behavior which leads to a weak correlation between the DOC concentration and the CDOM concentration. To establish a good satellite reversion of the DOC concentration, the East China Sea(ECS) was taken as an example, and the mixing behavior of DOC and CDOM as well as the influence of biogeochemical processes were analyzed except for the physical mixing process with the data from late autumn (November, 2010) and winter (December, 2009) cruises. In the two ECS cruises, the CDOM concentration was found to be tightly correlated with the salinity, influenced little by the photochemical or biological processes. The data from the winter cruise show that DOC followed a conservative mixing along the salinity gradient, while in the late autumn cruise it was significantly affected by the biological activities, resulting in a poor correlation between the DOC and the CDOM. Accordingly, an improved DOC algorithm (CSDM) was proposed: when the biological influence was significant (Chl a greater than 0.8 μg/dm3 ), DOC was retrieved by the conservative and biological model, and if the conservative mixing was dominant (Chl a less than 0.8 μg/dm3 ), the direct DOC concentration and CDOM concentration relationship was used. Based on the proposed algorithm, a reasonable DOC distribution for the ECS from satellite was obtained in this study, and the proposed method can be applied to the other large river-dominant marginal sea.  相似文献   

16.
浒苔的暴发会对水体生态环境产生巨大的影响, 对此进行遥感监测具有十分重要的意义。本文基于现场同步实测的有色溶解有机物(colored dissolved organic matter, CDOM)吸收系数、叶绿素浓度以及光谱数据建立遥感反演模型,再结合MODIS卫星影像提取山东半岛南侧近岸海域在各年份浒苔暴发前后CDOM与叶绿素浓度的时空分布特征。结果表明, 浒苔的消亡分解会在水体中产生大量的CDOM, 但浒苔的生长繁殖同样会消耗CDOM, 此外CDOM还受到浒苔暴发时期强烈的光降解作用。在各种因素的综合作用下, 研究区海域CDOM浓度在浒苔暴发时期微弱升高, 浒苔消亡后CDOM浓度则开始回落。浒苔在暴发期会抑制其他浮游微藻的生长, 使研究区海域叶绿素浓度有所降低, 而浒苔消亡后叶绿素浓度有所上升。水体中的叶绿素受多种生物地球化学因素的影响, 因此叶绿素浓度的降低与浒苔的暴发强度之间没有明确的相关性。遥感反演可以大范围快速地提取水体中各种要素的分布情况, 但就浒苔的暴发对海水中各要素的影响机制而言, 还需要结合各种生态环境因子进行综合分析。  相似文献   

17.
The effects of monochromatic and polychromatic UV and visible (VIS) radiation on the optical properties (absorption and fluorescence) of chromophoric dissolved organic matter (CDOM) were examined for a Suwannee River fulvic acid (SRFA) standard and for water from the Delaware and Chesapeake Bays. The primary (direct) loss of absorption and fluorescence occurred at the irradiation wavelength(s), with smaller secondary (indirect) losses occurring outside the irradiation wavelength(s). The efficiency of both direct and indirect photobleaching decreased monotonically with increasing wavelength. Exposure to polychromatic light increased the CDOM absorption spectral slope (S), consistent with previous field measurements. An analysis of the monochromatic photobleaching kinetics argues that a model based on a simple superposition of multiple chromophores undergoing independent photobleaching cannot apply; this conclusion further implies that the absorption spectrum of CDOM cannot arise solely from a simple superposition of the spectra of numerous independent chromophores. The kinetics of CDOM absorption loss with the monochromatic irradiation were employed to create a simple, heuristic model of photobleaching. This model allowed us to examine the importance of the indirect photobleaching losses in determining the overall photobleaching rates as well as to model the photobleaching of natural waters under polychromatic light fields. Application of this model to natural waters closely predicted the change in the CDOM spectral shape caused by photodegradation. The time scale of this process was consistent with field observations acquired during the summertime for coastal waters in the Middle Atlantic Bight (MAB). The results indicate that the ratio of the photodegradation depth to the mixed layer depth is a key parameter controlling the rate of the photobleaching in surface waters.  相似文献   

18.
Spatial and temporal variability of the absorption properties of colored dissolved organic matter (CDOM) in the Taiwan Strait was investigated in summer (July to August of 2006) and winter (from December 2006 to January of 2007) seasons. The CDOM absorption coefficient at 280 nm (a 280 ) showed a decreasing trend from nearshore to offshore areas while the spectral slope coefficient parameter calculated between wavelengths 275-295 nm (S 275 295 ) showed an increase, indicative of decreasing aromaticity and molecular weight of the CDOM. The average a 280 in winter (1.47 ± 0.50 m 1 ) was significantly higher than in summer (1.10 ± 0.41 m 1 ), while the average S 275 295 in winter (26.7 ± 5.2 μm 1 ) was significantly lower than in summer (30.6 ± 5.5 μm 1 ), demonstrating clear seasonal variation in CDOM abundance and properties in the Taiwan Strait. A three-end- member conservative mixing model showed that local terrestrial CDOM inputs from several rivers along the western coast were small (<5%). However, the distribution of CDOM in the Taiwan Strait is mainly controlled by water mass movement [i.e., the Zhe-min Coastal Current (ZCC) and the Kuroshio Branch Current (KBC) in winter and the South China Sea Water (SCSW) in summer]. Biological activity was also an important factor affecting the distribution of CDOM in the offshore region in summer months.  相似文献   

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