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1.
Rates of sediment accumulation and microbial mineralization were examined at three Kandelia candel forests spanning the intertidal zone along the south coastline of the heavily urbanized Jiulongljiang Estuary, Fujian Province, China. Mass sediment accumulation rates were rapid (range: 10–62 kg m−2 y−1) but decreased from the low- to the high-intertidal zone. High levels of radionuclides suggest that these sediments originate from erosion of agricultural soils within the catchment. Mineralization of sediment carbon and nitrogen was correspondingly rapid, with total rate of mineralization ranging from 135 to 191 mol C m−2 y−1 and 9 to 11 mol N m−2 y−1; rates were faster in summer than in autumn/winter. Rates of mineralization efficiency (70–93% for C; 69–92% for N) increased, as burial efficiency (7–30% for C; 8–31% for N) decreased, from the low-to the high-intertidal mangroves. Sulphate reduction was the dominant metabolic pathway to a depth of 1 m, with rates (19–281 mmol S m−2 d−1) exceeding those measured in other intertidal deposits. There is some evidence that Fe and Mn reduction-oxidation cycles are coupled to the activities of live roots within the 0–40 cm depth horizon. Oxic respiration accounted for 5–12% of total carbon mineralization. Methane flux was slow and highly variable when detectable (range: 5–66 μmol CH4 m−2 d−1). Nitrous oxide flux was also highly variable, but within the range (1.6–106.5 μmol N2O m−2 d−1) measured in other intertidal sediments. Rates of denitrification were rapid, ranging from 1106 to 3780 μmol N2 m−2 d−1, and equating to 11–20% of total sediment nitrogen inputs. Denitrification was supported by rapid NH4 release within surface deposits (range: 3.6–6.1 mmol m−2 d−1). Our results support the notion that mangrove forests are net accumulation sites for sediment and associated elements within estuaries, especially Kandelia candel forests receiving significant inputs as a direct result of intense human activity along the south China coast.  相似文献   

2.
The effect of ionic interactions on the kinetics of disproportionation of HO2, and the oxidation of Fe(II) and Cu(I) has been examined. The interactions of O2 with Mg2+ and Ca2+ ions in seawater increases the lifetime by 3–5 times compared to water. The effect of OH− on the oxidation of Fe(II) in water and seawater shows a second degree dependence from 5 to 45°C. The effect of salinity on the oxidation of Fe(II) was found to be independent of temperature, while the effect of temperature was found to be independent of salinity. The energy of activation for the overall rate constant was found to be 7 ± 0.5 kcal mol−1.The effect of pH, temperature, salinity and ionic composition on the oxidation of Cu(I) has also been examined. In NaCl solutions from 0.5 to 6 M, the log k for the oxidation was a linear function of pH (6–8) with a slope of 0.2 ± 0.05. The reaction was strongly dependent on the Cl− concentration with variation of from 0.3 to 340 min from 0.5 to 6 M Cl−. The rates of oxidation of Cu+ and CuCl0 responsible for these effects are dependent upon ionic strength. The energy of activation for the reaction was 8.5–9.9 kcal mol−1 from 0.5 to 6 M. Studies of the oxidation in various NaX salts (X = I−, Br− and Cl−) give rates in the order Cl− > Br− > I− as expected, due to complex formation of Cu+ with X−.  相似文献   

3.
Five transects across the NW Iberian margin were studied in the framework of the EU-funded Ocean Margin EXchange II (OMEX II) project, to determine and establish recent sediment and organic carbon transport and accumulation processes and fluxes.On the Galician shelf and shelf edge, resuspension of sediments resulting in well-developed bottom nepheloid layers was observed at all stations, but transport of suspended sediment appears largely confined to the shelf. On the continental slope, only very dilute bottom nepheloid layers were present, and intermediate nepheloid layers were only occasionally seen. This suggests that cross-slope transfer of particles is limited by the prevailing northerly directed shelf and slope currents.Optical backscatter and ADCP current measurements by the BOBO lander, deployed at 2152 m depth on the Galician slope, indicated that particles in the bottom boundary layer were kept in suspension by tidal currents with highest speeds between 15–25 cm s−1. Net currents during the recording period August 6th–September 10th 1998, were initially directed along-slope toward the NNW, but later turned off-slope toward the SW.The separation of the water masses on the slope from the sediment-laden shelf water by the along-slope current regime is reflected in the recent sedimentary deposits of the Galician shelf and slope. Apart from compositional differences, shelf deposits differ from those on the slope by their higher flux of excess 210Pb (0.57–5.37 dpm cm−2y−1 versus 0.11–3.00 dpm cm−2y−1), a much higher sediment accumulation rate (315.6–2295.9 g m−2y−1 versus 10.9–124.7 g m−2y−1) and organic carbon burial rate (1.01–34.30 g m−2y−1 versus 0.01–0.69 g m−2y−1).In contrast to the observations on the Galician margin, pronounced nepheloid layers occurred in the Nazaré Canyon, which extended to considerably greater water depths. This indicates that significantly greater transport of fine-grained particles in both the INL and the BNL was occurring within the canyon, as reflected in the exceptionally high 210Pb excess flux (up to 34.09 dpm cm−2y−1), mass accumulation rates (maximum 9623.1 g m−2y−1) and carbon burial fluxes (up to 180.91 g m−2y−1) in the sediment. However, radioisotope fluxes in the lower canyon were only slightly higher than at comparable depths on the Galician margin. This suggests that transport and rapid accumulation is focused on the upper and middle part of the canyon, from where it is episodically released to the deep sea. Compared to the Galician margin, the Nazaré Canyon may be considered as an important organic carbon depocenter on short time-scales, and a major conduit for particulate matter transport to the deep sea on >100 y time-scales.  相似文献   

4.
Calibration of a chalcogenide glass membrane, Fe(III)ISE [Fe2.5(Ge28Sb12Se60)97.5], in buffered saline media has been undertaken in order to assess the suitability of this ISE for seawater analyses. The electrode slopes in saline citrate and salicylate buffers were 26.3 and 28.2 mV/decade, respectively, for Fe3+ concentrations ranging from 10−10 M to less than 10−25 M Fe3+. The calibration lines in the citrate and salicylate buffers were essentially collinear with the response in unbuffered chloride-free standards containing >10−5 M Fe3+, demonstrating that the response of the FeISE is unaffected by chloride ions. A mechanism involving a combination of charge transfer and ion-exchange of Fe(III), at the electrode diffusion layer, can be used to explain the ≈30 mV/decade slope of the FeISE. The response of the FeISE in UV photooxidised seawater containing 8 nM total Fe was measured as the pH was changed from 8.27 to 3.51. The slope of the response was 24.2 mV/decade [Fe3+] calculated as a function of pH using Fe(III) hydrolysis constants for seawater. Moreover, the response was essentially collinear with that in citrate buffers and in unbuffered solutions containing >10−5 M Fe3+ and the slope for the combined data was 26.2 mV/decade. This study was restricted to organic-free seawater because the certainty in Fe(III)–ligand stability constants is insufficient to warrant the selection of an ideal calibration buffer system, and there is evidence that powerful chelating ligands (e.g., EDTA along with humic and fulvic acids) may alter the response of the Fe(III)ISE. The Fe dissolution rate of the FeISE in UV photooxidised seawater was found to be 1.6×10−2 nmol Fe/min, as measured by cathodic stripping voltammetry (CSV). This would contaminate a 100-ml sample by 0.8–1.6 nM Fe over a typical measurement period of 5–10 min obtained using a stability criterion of 0.5 mV/min. Various methods are proposed for reducing the level of contamination in open ocean samples that contain sub-nanomolar concentrations of iron. The FeISE has the potential to detect free Fe3+ at concentrations typically found in natural seawater.  相似文献   

5.
The vertical flux of particulate matter at 330 m depth in San Lázaro Basin off southern Baja California ranged from 63 to 587 mg m−2 d−1 between August and November 1996. Organic carbon contents were between 5.6 and 14.8%, yielding flux rates of 9–40 mgC m−2 d−1. In December 1997 and January 1998, at the height of the strong El Niño event, the respective fluxes (47–202 mg m−2 d−1 and 3–8 mgC m−2 d−1) were comparable. The February–June 1998 records, however, revealed sharply reduced mass (1–6 mg m−2 d−1) and organic carbon (0.2–0.8 mgC m−2 d−1) fluxes. The organics collected in 1996 were predominantly autochthonous (δ13C=−22‰; C/N=8). The variations in δ15N (8.3–11.0‰) suggest an alternation of new and regenerated production, possibly associated with fluctuations in the intensity of deep mixing during that autumn. The relatively high organic matter fluxes in December 1997 appear to be associated with regenerated production. The average composition from February to June 1998 (δ13C=−23.6‰; 15N=11.7‰; C/N=10.5) indicates degraded material of marine origin. The maximum δ15N value found (14‰) suggests that deeper, denitrified waters were brought to the surface and possibly advected laterally. Regime changes in the waters of the basin occur at 6–10 week intervals, evidenced by concurrent shifts in most of the measured parameters, including fecal pellet types and metal chemistry. The marine snow-dominated detritus collected showed a shift from a mixed diatom-rich-radiolarian-coccolith assemblage in late 1996 to a coccolith-dominated assemblage, including the contents of fecal pellets, during the 1997–1998 El-Niño period. T–S profiles, plankton analysis and chlorophyll contents of the upper water column indicated that the strong phytoplankton bloom, normally associated with seasonal upwelling along the Pacific coast of Baja, did not occur during the spring of 1998. The persistence of oligotrophic conditions during the 1997–1998 El Niño event favored the dominance of nanoplankton and reduced the vertical flux of particles.  相似文献   

6.
This study focused on the causes of the variation in microphytobenthic biomass and the effects of this variation on macrobenthic animals in the western Seto Inland Sea, Japan, where the importance of microphytobenthos as the primary food source for benthic animals has been recently reported. We investigated the microphytobenthic biomass together with light attenuation of seawater, phytoplanktonic biomass, macrobenthic density and biomass at eight stations (water depth = 5–15 m) during four cruises in 1999–2000. The increased light attenuation coefficient of the water column associated with increased concentration of the phytoplanktonic Chl-a caused a decrease in light flux that reached the seafloor. The biomass of the microphytobenthos within the upper 1 cm of the sediment, 1.9–46.5 mg Chl-a m−2, was inversely correlated with the phytoplanktonic biomass in the overlying water column, 10.9–65.0 mg Chl-a m−2. Thus, interception of light by phytoplankton is considered to be a main cause of the variation in the microphytobenthic biomass. The microphytobenthos biomass showed a significant positive correlation with the macrobenthic density (78–9369 ind. m−2) and biomass (0.4–78.8 gWW m−2). It appears that the increase in oxygen production by the microphytobenthos allowed macrobenthic animals to become more abundant, as a consequence of oxygenation of the organically enriched muddy sediments (14.5 ± 2.69 mg TOC g−1). This study suggests that the variation in the microphytobenthic biomass is influenced by the phytoplanktonic biomass due to shading effect, and the balance between these two functional groups might affect the variability in the macrobenthic density and biomass.  相似文献   

7.
Lagrangian experiments with short-term, drifting sediment traps were conducted during a cruise on RRS Charles Darwin to the NW coast of Spain to study the vertical flux and composition of settling biogenic matter. The cruise was split into two legs corresponding to (i) a period of increased production following an upwelling event on the continental shelf (3–10 August 1998) and (ii) an evolution of a cold water filament originating from the upwelled water off the shelf (14–19 August). The export of particulate organic carbon (POC) from the upper layer (0–60m) on the shelf was 90–240mgC.m−2.d−1 and off the shelf was 60–180mgC.m−2.d−1. Off shelf the POC flux at 200m was 50–60mg.m−2.d−1. A modest sedimentation of diatoms (15–30mgC.m−2.d−1) after the upwelling was associated with increased vertical flux of chlorophyll a (1.8–2.1mg.m−2.d−1) and a decrease of the POC:PON molar ratio of the settled material from 9 to 6.4. Most of the pico-, nano-, and microplankton in the settled material were flagellates; diatoms were significant during the on shelf and dinoflagellates during the off shelf leg. Off shelf, the exponential attenuation of POC flux indicated a strong retention capacity of the plankton community between 40 and 75m. POC:PON ratio of the settled particulate matter decreased with depth and the relative portion of flagellates increased, suggesting a novel, flagellate and aggregate mediated particulate flux in these waters. Export of POC from the euphotic layer comprised 14–26% of the integrated primary production per day during the on shelf leg and 25–42% during the off shelf leg, which characterises the importance of sedimentation in the organic carbon budget of these waters.  相似文献   

8.
The release of ammonium from the photochemical degradation of dissolved organic matter (DOM) has been proposed by earlier studies as a potentially important remineralisation pathway for refractory organic nitrogen. In this study the photochemical production of ammonium from Baltic Sea DOM was assessed in the laboratory. Filtered samples from the Bothnian Bay, the Gulf of Finland and the Arkona Sea were exposed to UVA light at environmentally relevant levels, and the developments in ammonium concentrations, light absorption, fluorescence and molecular size distribution were followed. The exposures resulted in a decrease in DOM absorption and loss of the larger sized fraction of DOM. Analysis of the fluorescence properties of DOM using parallel factor analysis (PARAFAC) identified 6 independent components. Five components decreased in intensity as a result of the UVA exposures. One component was produced as a result of the exposures and represents labile photoproducts derived from terrestrial DOM. The characteristics of DOM in samples from the Bothnian Bay and Gulf of Finland were similar and dominated by terrestrially derived material. The DOM from the Arkona Sea was more autochthonous in character. Photoammonification differed depending on the composition of DOM. Calculated photoammonification rates in surface waters varied between 121 and 382 μmol NH4+ L− 1 d− 1. Estimated areal daily production rates ranged between 37 and 237 μmol NH4+ m− 2 d− 1, which are comparable to atmospheric deposition rates and suggest that photochemical remineralisation of organic nitrogen may be a significant source of bioavailable nitrogen to surface waters during summer months with high irradiance and low inorganic nitrogen concentrations.  相似文献   

9.
Coastal marine sediment, air and seawater samples were collected at six sampling stations in the Eastern Mediterranean Sea distant from pollutant point sources. All sediment samples were analyzed to determine polycyclic aromatic hydrocarbon (PAH), black carbon (BC) and organic carbon (OC) contents. The PAH contents of gaseous and seawater samples of the study were determined in order to evaluate the role of air–sea exchange as PAH nonpoint source to the marine sediments. The average concentration of the total PAHs (∑PAHs) in the sediments varied from 2.2 to 1056.2 ng g−1 dry weight. The average BC and OC contents varied from 0.3 to 5.6 and from 2.9 to 21.4 mg g−1 dry weight, respectively. ∑PAH concentration in the marine atmosphere varied from 20.0 to 83.2 ng m−3. Air–water exchange flux (FA–W) estimation has indicated air transport as a significant source of PAHs to pristine marine sediments of Eastern Mediterranean. In addition, the significant correlation between the PAHs and the organic and soot carbon content further suggests the importance of atmospheric input of PAHs to the sediments.  相似文献   

10.
Submarine groundwater discharge (SGD) to coastal southern Rhode Island was estimated from measurements of the naturally-occurring radioisotopes 226Ra (t1/2 = 1600 y) and 228Ra (t1/2 = 5.75 y). Surface water and porewater samples were collected quarterly in Winnapaug, Quonochontaug, Ninigret, Green Hill, and Pt. Judith–Potter Ponds, as well as nearly monthly in the surface water of Rhode Island Sound, from January 2002 to August 2003; additional porewater samples were collected in August 2005. Surface water activities ranged from 12–83 dpm 100 L− 1 (60 dpm = 1 Bq) and 21–256 dpm 100 L− 1 for 226Ra and 228Ra, respectively. Porewater 226Ra activities ranged from 16–736 dpm 100 L− 1 (2002–2003) and 95–815 dpm 100 L− 1 (2005), while porewater 228Ra activities ranged from 23–1265 dpm 100 L− 1. Combining these data with a simple box model provided average 226Ra-based submarine groundwater fluxes ranging from 11–159 L m− 2 d− 1 and average 228Ra-derived fluxes of 15–259 L m− 2 d− 1. Seasonal changes in Ra-derived SGD were apparent in all ponds as well as between ponds, with SGD values of 30–472 L m− 2 d− 1 (Winnapaug Pond), 6–20 L m− 2 d− 1 (Quonochontaug Pond), 36–273 L m− 2 d− 1 (Ninigret Pond), 29–76 L m− 2 d− 1 (Green Hill Pond), and 19–83 L m− 2 d− 1 (Pt. Judith–Potter Pond). These Ra-derived fluxes are up to two orders of magnitude higher than results predicted by a numerical model of groundwater flow, estimates of aquifer recharge for the study period, and values published in previous Ra-based SGD studies in Rhode Island. This disparity may result from differences in the type of flow (recirculated seawater versus fresh groundwater) determined using each technique, as well as variability in porewater Ra activity.  相似文献   

11.
Multiple tracers of groundwater input (salinity, Si, 223Ra, 224Ra, and 226Ra) were used together to determine the magnitude, character (meteoric versus seawater), and nutrient contribution associated with submarine groundwater discharge across the leeward shores of the Hawai'ian Islands Maui, Moloka'i, and Hawai'i. Tracer abundances were elevated in the unconfined coastal aquifer and the nearshore zone, decreasing to low levels offshore, indicative of groundwater discharge (near-fresh, brackish, or saline) at all locations. At several sites, we detected evidence of fresh and saline SGD occurring simultaneously. Conservative estimates of SGD fluxes ranged widely, from 0.02–0.65 m3 m− 2 d− 1at the various sites. Groundwater nutrient fluxes of 0.04–40 mmol N m− 2 d− 1 and 0.01–1.6 mmol P m− 2 d− 1 represent a major source of new nutrients to coastal ecosystems along these coasts. Nutrient additions were typically greatest at locations with a substantial meteoric component in groundwater, but the recirculation of seawater through the aquifer may provide a means of transferring terrestrially-derived nutrients to the coastal zone at several sites.  相似文献   

12.
Production of the marine calanoid copepod Acartia steueri was measured from 2 October 1991 to 8 October 1992 at a station in Ilkwang Bay, on the southeastern coast of Korea. Phytoplankton standing stock ranged over 1.0 to 9.3 mg chl.a m−3, and annual primary productivity (by the C-14 method) at three stations was estimated at 200 gC m−2 yr−1. Acartia steueri (nauplii + copepodids + adults) were present in the plankton throughout the year, with seasonal variation in abundance. Biomass of A. steueri, excluding the NI stage, was 0.01–4.55 mgC m−3 (mean: 0.68 mgC m−3) with peaks in November, February, May and July-early August, and relatively low biomass in September– January. Instantaneous growth rates of the nauplius stages were higher than the copepodid stages. Annual production of A. steueri was 25.1 mgC m−3 yr−1 (or 166 mgC m−2 yr−1), showing peaks in November, May and July–August with a small peak in February, and low production in December–April and September–October. There were no significant relationships between the daily production rate of A. steueri and temperature or chlorophyll a concentration, indicating that unknown other factors might be related to the variation of the production rate.  相似文献   

13.
An array of five bottom-tethered moorings with 19 PARFLUX time-series sediment trap at three depths (1 and 2 km below the surface, and 0.7 km above the sea-floor) was deployed in the western Pacific sector of the Southern Ocean, along 170°W. The five stations were selected to sample settling particles in the main hydrological zones of the Southern Ocean. The sampling period spanned 425 days (November 28, 1996–January 23, 1998) and was divided into 13 or 21 synchronized time intervals. A total of 174 sequential samples were recovered and analyzed to estimate fluxes of total mass (TMF), organic carbon, carbonate, biogenic silica, and lithogenic particles. The fluxes of biogenic material were higher than anticipated, challenging the notion that the Southern Ocean is a low-productivity region. Organic carbon fluxes at 1 km depth within the Polar Frontal Zone and the Antarctic Zone were relatively uniform (1.7–2.3 g m−2 yr−1), and about twice the estimated ocean-wide average (ca. 1 g m−2 yr−1). Carbonate fluxes were also high and uniform between the Subantarctic Front and ca. 64°S (11–13 g m−2 yr−1). A large fraction of the carbonate flux in the Antarctic Zone was due to the presence of pteropod shells. Coccoliths were found only to the north of the Polar Front, and calcium carbonate became the dominant phase in the Subantarctic Zone. In contrast, carbonate particles were nearly absent near 64°S. Latitudinal variations in biogenic silica fluxes were substantial. The large opal flux (57 g m−2 yr−1) measured in the Antarctic Zone suggests that opal productivity in this region has been previously underestimated and helps to explain the high sedimentary opal accumulation often found south of the Polar Front. Unlike biogenic material, fluxes of lithogenic particles were among the lowest measured in the open-ocean (0.12–0.05 g m−2 yr−1), reflecting a very low dust input.  相似文献   

14.
Physical forcing plays a major role in determining biological processes in the ocean across the full spectrum of spatial and temporal scales. Variability of biological production in the Bay of Bengal (BoB) based on basin-scale and mesoscale physical processes is presented using hydrographic data collected during the peak summer monsoon in July–August, 2003. Three different and spatially varying physical processes were identified in the upper 300 m: (I) anticyclonic warm gyre offshore in the southern Bay; (II) a cyclonic eddy in the northern Bay; and (III) an upwelling region adjacent to the southern coast. In the warm gyre (>28.8 °C), the low salinity (33.5) surface waters contained low concentrations of nutrients. These warm surface waters extended below the euphotic zone, which resulted in an oligotrophic environment with low surface chlorophyll a (0.12 mg m−3), low surface primary production (2.55 mg C m−3 day−1) and low zooplankton biovolume (0.14 ml m−3). In the cyclonic eddy, the elevated isopycnals raised the nutricline upto the surface (NO3–N > 8.2 μM, PO4–P > 0.8 μM, SiO4–Si > 3.5 μM). Despite the system being highly eutrophic, response in the biological activity was low. In the upwelling zone, although the nutrient concentrations were lower compared to the cyclonic eddy, the surface phytoplankton biomass and production were high (Chl a – 0.25 mg m−3, PP – 9.23 mg C m−3 day−1), and mesozooplankton biovolume (1.12 ml m−3) was rich. Normally in oligotrophic, open ocean ecosystems, primary production is based on ‘regenerated’ nutrients, but during episodic events like eddies the ‘production’ switches over to ‘new production’. The switching over from ‘regenerated production’ to ‘new production’ in the open ocean (cyclonic eddy) and establishment of a new phytoplankton community will take longer than in the coastal system (upwelling). Despite the functioning of a cyclonic eddy and upwelling being divergent (transporting of nutrients from deeper waters to surface), the utilization of nutrients leading to enhanced biological production and its transfer to upper trophic levels in the upwelling region imply that the energy transfer from primary production to secondary production (mesozooplankton) is more efficient than in the cyclonic eddy of the open ocean. The results suggest that basin-scale and mesoscale processes influence the abundance and spatial heterogeneity of plankton populations across a wide spatial scale in the BoB. The multifaceted effects of these physical processes on primary productivity thus play a prominent role in structuring of zooplankton communities and could consecutively affect the recruitment of pelagic fisheries.  相似文献   

15.
In the spring and summer of 2002 primary production in the Chukchi Sea was measured, using 14C uptake experiments. Our cruise track encompassed the shelf and continental slope area of the Chukchi and Beaufort Seas progressing into deep water over the Canada Basin. The study area experienced upwards of 90% ice cover during the spring, with ice retreating into the basin during the summer. Production in the spring was light-limited due to ice cover, with average euphotic zone production rates of <0.3 g C m−2 d−1. Values of 8 g C m−2 d−1 were observed in association with surface bloom conditions during the initial ice breakup. Considerable nutrient reduction in the surface waters took place between the spring and summer cruise, and although not observed, this was attributed to a spring bloom. Decreased ice cover and increased clarity of surface waters in the summer allowed greater light penetration. The highest rates of production during the second cruise were found at 25–30 m, coincident with the top of the nutricline. Daily euphotic zone productivity in the summer averaged 0.78 g C m−2 d−1 on the shelf and 0.32 g C m−2 d−1 on the edge of the Canada basin. These data provide an estimated annual production of 90 g C m−2 yr−1 in the study area.  相似文献   

16.
The U-Tapao Canal is the main source of freshwater draining into the outer part of Songkhla Lake, which is the most important estuarine lagoon in Thailand. Songkhla Lake is located in southern Thailand between latitudes 7°08' and 7°50' N and longitudes 100°07' and 100°37' E. Acetic acid (HOAc)-soluble Cu, Fe, Mn, Pb, and Zn and the total concentration of these metals along with Al concentration, organic carbon, carbonate, sand, silt, and clay contents were determined in 4 sediment cores obtained at selected intervals from the mouth of the canal to 12 km upstream. Readily oxidizable organic matter in the cores varies from 1.52% to 7.30% and is generally found to decrease seaward. Total concentrations of Al (61.7–99.0 g kg−1; 2.29–3.67 mol kg−1), Cu (12.4–28.2 mg kg−1; 195–444 μmol kg−1), Fe (25.2–42.0 g kg−1; 451–752 mmol kg−1), Mn (0.22–0.49 g kg−1; 4.0–8.9 mmol kg−1), Pb (16.7–43.1 mg kg−1; 80.6–208 μmol kg−1), and Zn (48.6–122.7 mg kg−1; 0.74–1.88 mmol kg−1) vary to a certain extent vertically and seaward in the U-Tapao Canal core sediments. These concentrations are at or near natural levels and show no indication of anthropogenic contamination.Overall, the data show that total metal concentrations in the surface and near surface core sediments are enriched in varying degrees relative to Al in the order of Zn>Mn>Pb>Fe>Cu. Chemical partitioning shows that the enrichment in the surface and near surface sediments is related to the relatively high proportion of the total metal concentrations (Mn>Zn>Fe>Cu>Pb) that occur in the acetic acid-soluble (nondetrital) fraction, and they generally decrease with depth. Nondetrital Cu, Pb, and Zn likely derive from those metals held in ion exchange positions, certain carbonates, and from easily soluble amorphous compounds of Mn and perhaps those of Fe. Diagenetic processes involving Mn and to a lesser extent, Fe compounds, as well as the vertical changes in the oxidizing/reducing boundaries, appear to be the most important factors controlling the behavior of the metals in these cores. Organic matter and the aluminosilicate minerals, however, appear to be less important carriers of the metals studied.  相似文献   

17.
We examined the effect of light on water column and benthic fluxes in the Pensacola Bay estuary, a river-dominated system in the northeastern Gulf of Mexico. Measurements were made during the summers of 2003 and 2004 on 16 dates distributed along depth and salinity gradients. Dissolved oxygen fluxes were measured on replicate sediment and water column samples exposed to a gradient of photosynthetically active radiation. Sediment inorganic nutrient (NH4+, NO3−, PO43−) fluxes were measured. The response of dissolved oxygen fluxes to variation in light was fit to a photosynthesis–irradiance model and the parameter estimates were used to calculate daily integrated production in the water column and the benthos. The results suggest that shoal environments supported substantial benthic productivity, averaging 13.6 ± 4.7 mmol O2 m−2 d−1, whereas channel environments supported low benthic productivity, averaging 0.5 ± 0.3 mmol O2 m−2 d−1 (±SE). Estimates of baywide microphytobenthic productivity ranged from 8.1 to 16.5 mmol O2 m−2 d−1, comprising about 16–32% of total system productivity. Benthic and water column dark respiration averaged 15.2 ± 3.2 and 33.6 ± 3.7 mmol O2 m−2 d−1, respectively Inorganic nutrient fluxes were generally low compared to relevant estuarine literature values, and responded minimally to light exposure. Across all stations, nutrient fluxes from sediments to the water column averaged 1.11 ± 0.98 mmol m−2 d−1 for NH4+, 0.58 ± 1.08 mmol m−2 d−1 for NO3−, 0.01 ± 0.09 mmol m−2 d−1 for PO43−. The results of this study illustrate how light reaching the sediments is an important modulator of benthic nutrient and oxygen dynamics in shallow estuarine systems.  相似文献   

18.
The nitrogen inputs from atmospheric deposition and bottom water entrainment to the surface layer were modelled in the summer period (May–September) over a 11-year period (1989–1999) and compared to investigate the significance of these fluxes for generating blooms in the Kattegat. In the summer periods the average atmospheric deposition was 2.81 mg N m−2 d−1 compared to average entrainment fluxes of 5.42 mg N m−2 d−1, 1.21 mg N m−2 d−1 and 1.15 mg N m−2 d−1 for the northern, central and southern part of the Kattegat, respectively. Atmospheric nitrogen deposition alone could not sustain biomass increases associated with observed blooms and entrainment fluxes dominated the high nitrogen inputs to the surface layer. The potential for a bloom through growth was typically obtained after several days of high nitrogen inputs from entrainment in the frontal area of the northern Kattegat and to some extent from atmospheric deposition. The modelled nitrogen input in this area could account directly for 30% of the observed blooms in the Northern sub-basin, and through advective transport 24% and 19% of the observed blooms in the central and southern Kattegat. The direct nitrogen inputs through atmospheric deposition and entrainment to the central and southern sub-basins were small and could not be linked to any bloom observation.  相似文献   

19.
In March and September 1995, bacterial production was measured by the 3H-leucine method in the oligotrophic Cretan Sea (Aegean Sea, Eastern Mediterranean) in the framework of the CINCS/MTP program. Samples were obtained from four stations (a coastal, a continental shelf and 2 open-sea stations) for the construction of vertical profiles of bacterial abundance and production. Bacterial production ranged from 0.1 μg C m−3 h−1 at 1500 m depth, to 82 μg C m−3 h−1 in March at 50 m at the coastal station. Higher bacterial integrated production was observed in March at the coastal station (131 mg C m−2 d−1 for the 0–100 m layer). Bacterial production, integrated through the water-column, was similar in March and September for the open-sea stations (60–70 mg C m−2 d−1). Relative to production, bacterial concentrations varied little between stations and seasons ranging from 9×105 ml−1 to 3×105 ml−1. Relationships between bacterial biomass and bacterial production indicated seasonal differences, likely reflecting resource limitation of bacterial biomass in March (bloom situation), and predator limitation of bacterial biomass in September (post-bloom situation).  相似文献   

20.
The seasonal variability of leaf litter removal by crabs was observed from May 2006 to April 2007 in a Kandelia candel mangrove forest in Jiulongjiang Estuary, China. Daily average quantities of leaf fall ranged 0.85–3.86 gDW m−2 d−1, with high values in May, August, October and November. The whole-year's leaf fall was 6.48 t ha−1 yr−1 (1.81 gDW m−2 d−1). The standing stock of leaf litter on the forest floor was 7.78 gDW m−2 averaged from the whole year's data, with the lowest value in December (1.23 gDW m−2) and the highest in April (16.18 gDW m−2). Annually averaged removal (consumption on mangrove floor + burial in burrows) rate of leaf litter by crabs was 0.59 gDW m−2 d−1. High seasonal variability was observed in the removal rates of leaf litter by crabs. Removal rates in the winter months (December, January and February) were 0.07–0.09 gDW m−2 d−1, much lower than those in other months with values of 0.59–1.18 gDW m−2 d−1. Annually averaged percentage of leaf fall removed by crabs was 33%, with the highest values in September (reached 76%) and the lowest values in winter months. Of leaf litter removed by crabs, a large proportion was buried by crabs, and only 12% was consumed by crabs on the forest floor. Leaf litter removal rate, consumption rate on the forest floor, percentages of leaf fall and standing stock removed on the forest floor were significantly positively correlated with air temperature, indicating that leaf removal ability by crabs was higher in warm months than in cold months.  相似文献   

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