where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   

2.
Leathery turtle (reptilia: Chelonia) in Foveaux Strait (note)     
D. Eggleston 《新西兰海洋与淡水研究杂志》2013,47(3-4):522-523
Further records of the leathery turtle, Dermochelys coriacea (Linnaeus), augment earlier records and perhaps indicate that this species may be a regular visitor.  相似文献   

3.
Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins   总被引:1,自引:0,他引:1  
Raffaela Biesuz  Giancarla Alberti  Girolamo D'Agostino  Emanuele Magi  Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189
The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log αM(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 1020 M− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log αM(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

4.
Sexual size dimorphism in calanoid copepods (Centropagidae) from Patagonia (Argentina)     
RD Garcia  M Reissig 《新西兰海洋与淡水研究杂志》2013,47(4):504-514
Calanoid copepods of the genus Boeckella and Parabroteas (P. sarsi) are dominant in zooplankton communities of Patagonian lakes and ponds. This study addresses the occurrence of sexual size dimorphism in calanoid copepods of the genus Boeckella and in the monospecific genus Parabroteas occurring in 12 lakes and ponds of Patagonia (Argentina). The morphometric analysis performed showed that in all the species studied the female is larger than the male, although the difference in size among sexes was found to be variable between species. Interestingly, all species showed significant intraspecific stability in their sexual size dimorphism despite potential differences in their environments regarding predation pressure, environmental stability (permanent or temporary waters) and altitude distribution of populations. Finally, we discuss the potential implications of sexual dimorphism in terms of resource use and vulnerability to predation among other environmental forces which may play a role in promoting larger female to male size.  相似文献   

5.
Chromium(III) — chromium(VI) interconversions in seawater     
C. H. Van Der Weijden  M. Reith 《Marine Chemistry》1982,11(6):565-572
The stable form of dissolved chromium in oxygenated seawater is Cr(VI). But Cr(III)-species are also present at an analytically significant level. It is shown that Cr(III) is oxidized only slowly by dissolved oxygen, and that manganese oxide is a strong catalyst for such oxidation. However, the low oceanic concentration of suspended MnO2 impedes the conclusion that the former process is quantitatively less important than the latter one. The distribution of dissolved chromium among Cr(VI)- and Cr(III)-species is probably kinetically controlled.  相似文献   

6.
7.
九龙江河口区水体中的226Ra和228Ra   总被引:8,自引:0,他引:8  
谢永臻  黄奕普 《台湾海峡》1994,13(4):394-399
用MnO2-纤维富集大体积水样中的Ra同位素,并用直接射气法测定226Ra和228Ac的β计数法测定228Ra的方法,研究了九龙江河口区226Ra,228Ra的行为,结果表明:在该河口区226Ra,228Ra均呈非保守行为,226Ra,228Ra的最高值分别在盐度为19和9处测得。228Ra/226Ra)A.R.值在盐度小于19的区域约为3左右。与世界其他河口区相比,九龙江河口区的226Ra,22  相似文献   

8.
Precocious male quinnat salmon oncorhynchus tshawytscha (walbaum) in New Zealand (note)     
M. Flain 《新西兰海洋与淡水研究杂志》2013,47(2):217-222
Samples of yearling parr of quinnat salmon Oncorhynchus tshawytscha (Walbaum) from Lake Heron and the Glenariffe Stream were examined, and precocious ripe males were found. The proportion in the population (29.2%) was higher than is recorded in North America (2.6%).  相似文献   

9.
Isolation By Distance (IBD) signals in the deep-water rose shrimp Parapenaeus longirostris (Lucas, 1846) (Decapoda,Panaeidae) in the Mediterranean Sea     
《Marine environmental research》2013
The identification of boundaries of genetic demes is one of the major goals for fishery management, and few Mediterranean commercial species have not been studied from a genetic point of view yet. The deep-water rose shrimp Parapenaeus longirostris (Lucas, 1846) is one of the most important components of commercial landings in Mediterranean, its fishery aspects have received much attention, regrettably without any concern for the genetic architecture of its populations. The population structure in the central and eastern Mediterranean Sea (captures from six Italian and two Greek landings) has been analysed on the basis of surveys carried out with mitochondrial and AFLP markers. Data revealed the presence of a gradual discrepancy along a west–east axis. This species, occurring mainly at a depth of between 100 and 400 m, is not strongly confined in isolated demes, but it demonstrates an ‘Isolation By Distance’ model, within the Mediterranean Sea, which includes geographical areas with a some degree of isolation. The role of hydrodynamic forces, such as currents, water fronts, is discussed; and a further evidence of the ‘Levantine isolation’ within Mediterranean basin is shown.  相似文献   

10.
旋链角毛藻和小普林藻对二甲基硫和二甲巯基丙酸的释放研究     
高原  朱蓉  杨桂朋  张洪海 《中国海洋大学学报(自然科学版)》2012,(12):59-64
通过实验室培养研究了旋链角毛藻(Chaetoceros curvisetus Cleve)和小普林藻(Prymnesium parvum Carter)生长周期内培养液中二甲基硫(DMS)和二甲巯基丙酸(DMSP)的含量。结果表明,2种微藻均能释放DMS,但小普林藻单细胞释放的DMS浓度约是旋链角毛藻的500倍。在藻类生长的不同阶段,它们释放DMS和DMSP的能力存在较大差异,但2种藻类DMS大量释放均出现在衰亡期。同时研究了盐度对2种微藻DMS释放的影响,结果表明高盐度会促进小普林藻DMS和DMSP的释放,而对旋链角毛藻DMSP的释放未有显著影响。  相似文献   

11.
Nematopsis N. Sp. (Sporozoa: Gregarinia) in Perna canaliculus (note)     
J. B. Jones 《新西兰海洋与淡水研究杂志》2013,47(4):567-568
Spores of a new species of Nematopsis have been found in the green‐lipped mussel Perna canaliculus Gmelin. This is the first record of a sporozoan parasite of a New Zealand shellfish.  相似文献   

12.
Halosaurus pectoralis McCulloch (Pisces: Halosauridae) in the New Zealand region (note)     
D. G. McKnight 《新西兰海洋与淡水研究杂志》2013,47(3):555-556
Halosaurus pectoralis McCulloch is recorded from off Gisborne, New Zealand, and from south‐east of Lord Howe Island, thus adding a second species of the order Heteromi to the New Zealand fauna.  相似文献   

13.
东山湾海水中Fe(II)和Fe(III)相互转化围隔实验研究   总被引:1,自引:0,他引:1  
黄旭光  李顺兴  陈乙平  蔡添寿 《海洋科学》2012,36(2):103-109
根据2008 年8 月与11 月在东山湾海域获得的调查资料对表层水中溶解态Fe(II)和Fe(III)含量、浮游植物叶绿素a、营养元素及其浓度等环境参数进行分析。结果表明, 夏、秋季海水中Fe(II)浓度及其在总溶解铁中所占比例均与浮游植物叶绿素a 呈正相关, 其相关系数分别为0.7959、0.9219。现场围隔实验表明, 海水中总溶解态Fe 含量在24 h 内有较大的变化, 最大减少量达到17.4%。DS2 站点海水中Fe(II)浓度及其在总溶解铁中所占比例随光照强度增加而增加。最高值与初始值相比较, 叶绿素a 较高的DS2 站点海水中Fe(II)浓度增加较叶绿素a 较低的DS5 号站点高0.053μg/L。Fe(II)和Fe(III)加富实验研究了溶解态的Fe(II)和Fe(III)在海水中相互转化。高浓度的Fe(II)在海水中被氧化成Fe(III),海水中浮游植物也会引发光还原作用使Fe(III)还原成Fe(II)。  相似文献   

14.
Swimming behaviour in a pycnogonid (note)     
W. C. Clark  Alan Carpenter 《新西兰海洋与淡水研究杂志》2013,47(3):613-615
Four adult specimens of the pycnogonid Ammothea magniceps were observed swimming at the sea surface at night at Kaikoura. Even after capture the animals continued to swim at the surface of the water for over an hour. Such swimming behaviour is considered important in explaining the presence of “benthic” animals in plankton samples.  相似文献   

15.
Bioaccumulation of polybrominated diphenyl ethers (PBDEs) in flounder (Platichthys flesus) in the southern Baltic Sea     
《Marine environmental research》2012
Concentrations of seven polybrominated diphenyl ether (PBDE) congeners were examined in flounder (Platichthys flesus) and sediment in three southern Baltic Sea sites, representing a range of exposure conditions, in order to evaluate spatial differences in PBDE contamination. Additionally, PBDEs were measured in muscle, liver, and gonads of flounder from one of the sites in order to examine inter-tissue distribution. Mean muscle Σ7PBDE levels, in the range of 10–21 ng g−1 lipid, showed inter-site differences attributed to the distance from the Gulf of Gdańsk, and were overall lower than reported earlier in herring, sprat, and salmon. Biota sediment accumulation factors (BSAFs) for Σ7PBDE and individual BDE congeners, in the range of 0.5–24.5, were generally consistent with predicted models for persistent hydrophobic halogenated contaminants. Wet weight (wet wt) PBDE levels in muscle and liver, but not in gonads, were related to tissue lipid content and did not correlate with the fish length and weight. These tissues differed in PBDE levels and profiles as a result of varying lipid content and presumably lipid composition and congener-specific physico-chemical properties.  相似文献   

16.
The speciation of Fe(II) and Fe(III) in natural waters     
Frank J. Millero  Wensheng Yao  Jennifer Aicher 《Marine Chemistry》1995,50(1-4)
The interactions of Fe(II) and Fe(III) with the inorganic anions of natural waters have been examined using the specific interaction and ion pairing models. The specific interaction model as formulated by Pitzer is used to examine the interactions of the major components (Na+, Mg2+, Ca2+, K+, Sr2+, Cl, SO4, HCO3, Br, CO32−, B(OH)4, B(OH)3 and CO2) of seawater and the ion pairing model is used to account for the strong interaction of Fe(II) and Fe(III) with major and minor ligands (Cl, SO42−, OH, HCO3, CO32− and HS) in the waters. The model can be used to estimate the activity and speciation of iron in natural waters as a function of composition (major sea salts) and ionic strength (0 to 3 M). The measured stability constants (KFeX*) of Fe(II) and Fe(III) have been used to estimate the thermodynamic constants (KFeX) and the activity coefficient of iron complexes (γFeX) with a number of inorganic ligands in NaClO4 medium at various ionic strengths: In(KFeXFeγX) = InKFeX − In(γFeX) The activity coefficients for free ions (γFe, γx) needed for this extrapolation have been estimated from the Pitzer equations. The activity coefficients of the ion pairs have been used to determine Pitzer parameters (BFeX, BFeX0, CFeXφ) for the iron complexes. These results make it possible to estimate the stability constants for the formation of Fe(II) and Fe(III) complexes over a wide range of ionic strengths and in different media. The model has been used to determine the solubility of Fe(III) in seawater as a function of pH. The results are in good agreement with the measurements of Byrne and Kester and Kuma et al. When the formation of Fe organic complexes is considered, the solubility of Fe(III) in seawater is increased by about 25%.  相似文献   

17.
18.
Pfiesteria shumwayae (Pfiesteriaceae) in New Zealand     
Lesley L. Rhodes  Joann M. Burkholder  Howard B. Glasgow  Parke A. Rublee  Coy Allen  Janet E. Adamson 《新西兰海洋与淡水研究杂志》2013,47(3):621-630
Pfiesteria shumwayae Steidinger et Burkholder is now known to be present in New Zealand and occurs in estuaries around the country. The presence of Pfiesteria was initially determined by a polymerase chain reaction (PCR)‐based detection assay, using oligonucleotide primers targeted at ribosomal DNA extracted from estuarine water and sediments. Presence was confirmed by isolation from fresh sediments in the presence offish (Oreochromis mossambicus), followed by identification by scanning electron microscopy. The New Zealand isolates of P. shumwayae were ichthyotoxic in bioassays, but there is no historic evidence offish kills in New Zealand associated with the dinoflagellate.  相似文献   

19.
Phosphate Utilization in Phaeocystis pouchetii (Haptophyceae)     
M.J. W. Veldhuis    F. Colijn  W. Admiraal 《Marine Ecology》1991,12(1):53-62
Abstract. .The phosphate uptake kinetics of single cells and colonies of the haptophycean alga Phaeocystis pouchetii were investigated in short- and long-term experiments. In phosphate-deprived cultures, the highest nutrient uptake rate (Vmax) of both growth forms appeared to be similar. However, the half-saturation constant for phosphate uptake of the cells embedded in a colony (Ks= 3.08 μM) was considerably higher than that of the single cells (Ks= 0.31 μM). This is consistent with the existence of a diffusion barrier formed by the colony membrane and colonial mucus. Over a 24 h light/dark cycle, the phosphate assimilation rate in moderately limited colonies and single cells was nearly identical during the light period. In the following dark phase, colony cells maintained this uptake rate, whereas the uptake of the single cells diminished by 70 %. The high dark uptake rate in colonies ran parallel with the absorption and degradation of intracolonial carbon compounds, suggesting that the dissimilation of these compounds covers the energy requirements for phosphate uptake in the dark. In Phaeocystis cultures during a transition to phosphate depletion, a significant amount of phosphate was found in the colonial mucus, isolated by selective filtration. The possible absorption of phosphate by the mucus and the role of mucus in the energy budget seem to be an essential feature of phosphate uptake of colonies. Short-term measurement of phosphate uptake in colony cells may therefore underestimate the phosphate uptake of the whole colony.  相似文献   

20.
Environmental Instability and Demographic Variability in Acrocnida brachiata (Echinodermata: Ophiuroidea) in Douarnenez Bay (Brittany: France)     
A. Bourgoin  M. Guillou  M. Glémarec 《Marine Ecology》1991,12(2):89-104
Abstract. The recruitment and growth modalities of two populations of Acrocnida brachiata (Echinodermata: Ophiuroidea) from the intertidal and from a depth of 20 m in Douarnenez Bay (Brittany) were compared. This study was conducted in order to establish whether the populations developed differently according to environmental stability. The results were compared with those found in another amphiurid, Amphiura filiformis , distributed along a similar gradient of disturbance in the subtidal zone. The purpose was to determine whether the biological parameters from different species vary in a similar manner along such a gradient and. if not, what is the role of biotic and physical factors in the control of demographic structure in intertidal and subtidal populations.  相似文献   

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1.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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