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1.
A low‐grade metamorphic “Coloured Mélange” in North Makran (SE Iran) contains lenses and a large klippe of low temperature, lawsonite‐bearing blueschists formed during the Cretaceous closure of the Tethys Ocean. The largest blueschist outcrop is a >1,000 m thick coherent unit with metagabbros overlain by interlayered metabasalts and metavolcanoclastic rocks. Blueschist metamorphism is only incipient in coarse‐grained rocks, whereas finer grained, foliated samples show thorough metamorphic recrystallization. The low‐variance blueschist peak assemblage is glaucophane, lawsonite, titanite, jadeite±phengitic mica. Investigated phase diagram sections of three blueschists with different protoliths yield peak conditions of ~300–380°C at 9–14 kbar. Magnesio‐hornblende and rutile cores indicate early amphibolite facies metamorphism at >460°C and 2–4 kbar. Later conditions at slightly higher pressures of 6–9 kbar at 350–450°C are recorded by barroisite, omphacite and rutile assemblages before entering into the blueschist facies and finally following a retrograde path through the pumpellyite–actinolite facies across the lawsonite stability field. Assuming that metamorphic pressure is lithostatic pressure, the corresponding counterclockwise P–T path is explained by burial along a warm geothermal gradient (~15°C/km) in a young subduction system, followed by exhumation along a cold gradient (~8°C/km); a specific setting that allows preservation of fresh undecomposed lawsonite in glaucophane‐bearing rocks.  相似文献   

2.
北祁连山硬柱石蓝片岩p-T条件相平衡计算及其岩石学意义   总被引：2，自引：0，他引：2  
北祁连硬柱石蓝片岩主要分布在甘肃省肃南县九个泉一带,是目前中国唯一报道的、确切地含有硬柱石的蓝片岩。文中在详细的岩石学和矿物学研究基础上,根据矿物共生组合的不同,将北祁连低温蓝片岩进一步划分为绿纤石蓝片岩、硬柱石蓝片岩和绿帘石蓝片岩。绿纤石蓝片岩的特征变质矿物组合为蓝闪石(>40%)+绿纤石(30%)+绿泥石(10%)+钠长石(8%)+石英(5%)+硬柱石(<3%)±方解石/文石(<1%)。硬柱石蓝片岩的矿物组合为蓝闪石(35%~40%)+硬柱石(35%~40%)+绿泥石(10%)+钠长石(10%)+石榴石(1%~2%)+黝帘石/斜黝帘石(<2%)+石英(<1%),副矿物有磷灰石和榍石,总含量小于2%。绿帘石蓝片岩的矿物组合为蓝闪石(30%~35%)+黝帘石/斜黝帘石/绿帘石(~30%)+绿泥石(15%)+钠长石(15%)+石榴石(2%)+石英(<2%),副矿物有金红石、磷灰石和磁铁矿,总含量小于2%。利用矿物内部一致性热力学数据和Domino/Theriak软件计算了这三种类型的蓝片岩形成的峰期温压条件,它们分别是绿纤石蓝片岩为320~350℃,0.75~0.85GPa;硬柱石蓝片岩为335~355℃,0.8~0.95GPa;绿帘石蓝片岩为345~375℃;0.75~0.85GPa。北祁连低温蓝片岩带由硬柱石蓝片岩相到绿帘石蓝片岩相的转化代表了俯冲变质过程中的递进变质过程。  相似文献   

3.
Eclogites, blueschists and greenschists are found in close proximity to one another along a 1‐km coastal section where the Cyclades Blueschist Unit (CBU) is exposed on SE Syros, Greece. Here, we show that the eclogites and blueschists experienced the same metamorphic history: prograde lawsonite blueschist facies metamorphism at 1.2–1.9 GPa and 410–530°C followed, at 43–38 Ma, by peak blueschist/eclogite facies metamorphism at 1.5–2.1 GPa and 520–580°C. We explain co‐existence of eclogites and blueschists by compositional variation probably reflecting original compositional layering. It is also shown that the greenschists record retrogression at 0.34 ± 0.21 GPa and T = 456 ± 68°C. This was spatially associated with a shear zone on a scales of 10–100‐m and veins on a scale of 1–10‐cm. Greenschist facies metamorphism ended at (or shortly after) 27 Ma. We thus infer a period of metamorphic quiescence after eclogite/blueschist facies metamorphism and before greenschist facies retrogression which lasted up to 11–16 million years. We suggest that this reflects an absence of metamorphic fluid flow at that time and conclude that greenschist facies retrogression only occurred when and where metamorphic fluids were present. From a tectonic perspective, our findings are consistent with studies showing that the CBU is (a) a high‐P nappe stack consisting of belts in which high‐P metamorphism and exhumation occurred at different times and (b) affected by greenschist facies metamorphism during the Oligocene, prior to the onset of regional tectonic extension.  相似文献   

4.
The Neotethyan oceanic Diamante‐Terranova unit (DIATU; southern Apennines–Calabria–Peloritani Terrane system) includes basic rocks that during the Cenozoic were subducted and metamorphosed to lawsonite‐blueschist facies conditions. Petrological and structural observations (both at the meso‐ and micro‐scale) show that lawsonite growth was continuous during three distinctive ductile deformation stages (D1–D3). These likely occurred close to the metamorphic peak, estimated at 350–390°C and 0.9–1.1 GPa, producing an equilibrium assemblage made of blue Na‐amphibole, lawsonite, chlorite and pumpellyite. Locally, pods dominated by quartz and epidote (plus chlorite, calcite and green Ca‐amphibole) developed at similar conditions (350–370°C, 0.8–0.9 GPa). Post‐peak evolution during the final exhumation of the DIATU along the subduction channel, also consisted of three deformation stages, defined by folding (D4) and normal faulting (D5) and finally by strike‐slip faulting (D6), affecting both the blueschist unit and the unconformably overlying Tortonian conglomerates. Vorticity analysis on syn‐tectonic lawsonite crystals indicates that severe flattening occurred during the D2 stage, with a significant secondary non‐coaxial strain component along the W–E plane. This is associated with an eastward tectonic vergence, consistent with the subsequent D3 and D4 folding stages characterized by a dominant ENE tectonic transport. It is suggested that exhumation started from the D2 stage and continued during D3 at similar HP/LT metamorphic conditions. The widespread occurrence of unreacted lawsonite crystals suggests that exhumation was very fast and supports the idea that concurrent ductile deformation might play a role in its preservation.  相似文献   

5.
Low‐T, intermediate to high‐P assemblages indicative of the prehnite–pumpellyite, greenschist and blueschist facies are preserved in mélange zones and slivers of oceanic crust within two major fault zones of the turbidite‐dominated Lachlan Orogen. In one of these fault zones (Governor Fault Zone), blueschists occur as Franciscan‐like blocks in a serpentinite/talc matrix that is interleaved with phyllites and slates, and structurally overlain by a fault slice or duplex of predominantly pillow basalt, chert, and turbidite. The blueschist metavolcanics are interpreted to have formed at < 450 °C and at a depth of approximately 21–27 km. The presence of blue amphibole in the blocks, rinds and matrix indicate that the metavolcanics were emplaced in the matrix prior to blueschist metamorphism. Blocks and matrix were partially exhumed, interleaved with tectonic slices of phyllite and slate, and subsequently folded at about 10–12 km depth, inferred from bo values of the dominant mica fabric in the phyllites and slates. Metamorphic P–T is highest in the structurally lowest slice (mélange zone) and lowest in the overlying ophiolitic fault slice, suggestive of an accretionary burial metamorphic pattern formed by underplating of the mélange. In the other fault zone (Heathcote Fault Zone), blueschists transitional to greenschist facies are interpreted to have formed at < 450 °C and at a depth of approximately 15–21 km. They occur as blocks in serpentinite/talc‐matrix mélange and are also associated with fault slices of oceanic crust. Textural and mineralogical evidence suggests that the protoliths for the blueschists in both fault zones were boninitic pillow lavas. The metamorphic facies and patterns, and the structural and lithological associations, can be interpreted in terms of disruption of oceanic crust and overlying sediments during subduction, and formation of serpentinite‐matrix mélange overprinted by blueschist metamorphism either prior to or during underplating of the mélange and duplex formation. The presence of blueschist metavolcanics indicate that these processes occurred at considerable depth. These interpretations have implications for the evolution of large‐scale fault zones in noncollisional, convergent oceanic settings.  相似文献   

6.
New sandstone petrology and petrostratigraphy provide insights on Palaeogene (Middle Eocene to Oligocene) clastics of the Thrace Basin in Greece, which developed synchronously with post‐Cretaceous collision and subsequent Tertiary extension. Sandstone petrofacies are used as a tool to unravel complex geodynamic changes that occurred at the southern continental margin of the European plate, identifying detrital signals of the accretionary processes of the Rhodope orogen, as well as subsequent partitioning related to extension of the Rhodope area, followed by Oligocene to present Aegean extension and wide magmatic activity starting during the Early Oligocene. Sandstone detrital modes include three distinctive petrofacies: quartzolithic, quartzofeldspathic and feldspatholithic. Major contributions are from metamorphic basement units, represented mostly by low to medium‐grade lithic fragments for the quartzolithic petrofacies and high‐grade metamorphic rock fragments for the quartzofeldspathic petrofacies. Volcaniclastic sandstones were derived from different volcanic areas, with a composition varying from dominantly silicic to subordinate intermediate products (mainly rhyolitic glass, spherulites and felsitic lithics). Evolution of detrital modes documents contributions from three key source areas corresponding to the two main crystalline tectonic units: (i) the Variegated Complex (ultramafic complex), in the initial stage of accretion (quartzolithic petrofacies); (ii) the Gneiss–Migmatite Complex (quartzofeldspathic petrofacies); and (iii) the Circum‐Rhodope Belt. The volcaniclastic petrofacies is interbedded with quartzofeldspathic petrofacies, reflecting superposition of active volcanic activity on regional erosion. The three key petrofacies reflect complex provenance from different tectonic settings, from collisional orogenic terranes to local basement uplift and volcanic activity. The composition and stratigraphic relations of sandstones derived from erosion of the Rhodope orogenic belt and superposed magmatism after the extensional phase in northern Greece provide constraints for palaeogeographic and palaeotectonic models of the Eocene to Oligocene western portions of the Thrace Basin. Clastic detritus in the following sedimentary assemblages was derived mainly from provenance terranes of the Palaeozoic section within the strongly deformed Rhodope Massif of northern Greece and south‐east Bulgaria, from the epimetamorphic units of the Circum‐Rhodope Belt and from superposed Late Eocene to Early Oligocene magmatism related to orogenic collapse of the Rhodope orogen. The sedimentary provenance of the Rhodope Palaeogene sandstones documents the changing nature of this orogenic belt through time, and may contribute to a general understanding of similar geodynamic settings.  相似文献   

7.
The Altınekin Complex in south central Turkey forms part of the south‐easterly extension of the Tavşanlı Zone, a Cretaceous subduction complex formed during the closure of the Neo‐Tethys ocean. The protoliths of metamorphic rocks within the Altınekin Complex include peridotites, chromitites, basalts, ferruginous cherts and flysch‐facies impure carbonate sediments. Structurally, the complex consists of a stack of thrust slices, with massive ophiolite tectonically overlying a Cretaceous sediment‐hosted ophiolitic mélange, in turn overlying a sequence of Mesozoic sediments. Rocks within the two lower structural units have undergone blueschist–facies metamorphism. Petrographic, mineral–chemical and thermobarometric studies were undertaken on selected samples of metasedimentary and metabasic rock in order to establish the time relations of deformation and metamorphism and to constrain metamorphic conditions. Microstructures record two phases of plastic deformation, one predating the metamorphic peak, and one postdating it. Estimated peak metamorphic pressures mostly fall in the range 9–11 kbar, corresponding to burial depths of 31–38 km, equivalent to the base of a continental crust of normal thickness. Best‐fit peak metamorphic temperatures range from 375 to 450°C. Metamorphic fluids had high H2O:CO2 ratios. Peak metamorphic temperature/depth ratios (T/d values) were low (c. 10–14°C/km), consistent with metamorphism in a subduction zone. Lawsonite‐bearing rocks in the southern part of the ophiolitic mélange record lower peak temperatures and T/d values than epidote blueschists elsewhere in the unit, hinting that the latter may consist of two or more thrust slices with different metamorphic histories. Differences in peak metamorphic conditions also exist between the ophiolitic mélange and the underlying metasediments. Rocks of the Altınekin Complex were subducted to much shallower depths, and experienced higher geothermal gradients, than those of the NW Tavşanlı Zone, possibly indicating dramatic lateral variation in subduction style. Retrograde P–T paths in the Altınekin Complex were strongly decompressive, resulting in localized overprinting of epidote blueschists by greenschist–facies assemblages, and of lawsonite blueschists by pumpellyite–facies assemblages. The observation that the second deformation was associated with decompression is consistent with, but not proof of, exhumation by a process that involved deformation of the hanging‐wall wedge, such as gravitational spreading, corner flow or buoyancy‐driven shallowing of the subduction zone. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

8.
In this study, we have deduced the thermal history of the subducting Neotethys from its eastern margin, using a suite of partially hydrated metabasalts from a segment of the Nagaland Ophiolite Complex (NOC), India. Located along the eastern extension of the Indus‐Tsangpo suture zone (ITSZ), the N–S‐trending NOC lies between the Indian and Burmese plates. The metabasalts, encased within a serpentinitic mélange, preserve a tectonically disturbed metamorphic sequence, which from west to east is greenschist (GS), pumpellyite–diopside (PD) and blueschist (BS) facies. Metabasalts in all the three metamorphic facies record prograde metamorphic overprints directly on primary igneous textures and igneous augite. In the BS facies unit, the metabasalts interbedded with marble show centimetre‐ to metre‐scale interlayering of lawsonite blueschist (LBS) and epidote blueschist (EBS). Prograde HP/LT metamorphism stabilized lawsonite + omphacite (XJd = 0.50–0.56 to 0.26–0.37) + jadeite (XJd = 0.67–0.79) + augite + ferroglaucophane + high‐Si phengite (Si = 3.6–3.65 atoms per formula unit, a.p.f.u.) + chlorite + titanite + quartz in LBS and lawsonite + glaucophane/ferroglaucophane ± epidote ± omphacite (XJd = 0.34) + chlorite + phengite (Si = 3.5 a.p.f.u.) + titanite + quartz in EBS at the metamorphic peak. Retrograde alteration, which was pervasive in the EBS, produced a sequence of mineral assemblages from omphacite and lawsonite‐absent, epidote + glaucophane/ferroglaucophane + chlorite + phengite + titanite + quartz through albite + chlorite + glaucophane to lawsonite + albite + high‐Si phengite (Si = 3.6–3.7 a.p.f.u.) + glaucophane + epidote + quartz. In the PD facies metabasalts, the peak mineral assemblage, pumpellyite + chlorite + titanite + phengitic white mica (Si = 3.4–3.5 a.p.f.u.) + diopside appeared in the basaltic groundmass from reacting titaniferous augite and low‐Si phengite, with prehnite additionally producing pumpellyite in early vein domains. In the GS facies metabasalts, incomplete hydration of augite produced albite + epidote + actinolite + chlorite + titanite + phengite + augite mineral assemblage. Based on calculated T–M(H2O), T–M(O2) (where M represents oxide mol.%) and P–T pseudosections, peak P–T conditions of LBS are estimated at ~11.5 kbar and ~340 °C, EBS at ~10 kbar, 325 °C and PD facies at ~6 kbar, 335 °C. Reconstructed metamorphic reaction pathways integrated with the results of P–T pseudosection modelling define a near‐complete, hairpin, clockwise P–T loop for the BS and a prograde P–T path with a steep dP/dT for the PD facies rocks. Apparent low thermal gradient of 8 °C km?1 corresponding to a maximum burial depth of 40 km and the hairpin P–T trajectory together suggest a cold and mature stage of an intra‐oceanic subduction zone setting for the Nagaland blueschists. The metamorphic constraints established above when combined with petrological findings from the ophiolitic massifs along the whole ITSZ suggest that intra‐oceanic subduction systems within the Neotethys between India and the Lhasa terrane/the Karakoram microcontinent were also active towards east between Indian and Burmese plates.  相似文献   

9.
Serpentinite/talc‐matrix mélanges, bearing blocks of blueschist metavolcanics, occur within the Heathcote and Governor Fault Zones of the southern Lachlan Orogen. In the Heathcote Fault Zone, serpentinite‐matrix mélange consists of blocks or small pods of boninite, andesite, ultramafic rocks, chert and volcanogenic sandstone variably metamorphosed to prehnite‐pumpellyite, greenschist, or greenschist to blueschist facies. In the Governor Fault Zone, blueschist metavolcanics occur as blocks within serpentinite/talc matrix that is interleaved with prehnite‐pumpellyite to greenschist facies, intermediate pressure slate and phyllite. Ar/Ar dating of white mica from slaty mud‐matrix (broken formation) indicates that the main fabric development occurred at 446 ± 2 Ma. U–Pb (SHRIMP) dating of titanite from blueschists in the Governor Fault Zone indicates that metamorphism occurred at approximately 450 Ma, close to the time of mélange formation. Previously published, Ar/Ar dating of white mica from phyllite and biotite from metadiorite in the Heathcote Fault Zone suggest that blueschist metamorphism occurred at a similar time. These ages are supported by field relationships. Illite crystallinity and b0 data from white mica, and the preservation of blueschist blocks indicate that these fault zones maintained low temperatures both during and after intermediate‐ to high‐pressure metamorphism. Occurrences of blueschists in the Arthur Lineament of the Tyennan (Delamerian) Orogen in Tasmania, and in the New England Orogen, have different ages, and in conjunction with the occurrences described here, suggest that subduction‐accretion processes contributed significantly to the development of the Tasmanides from Cambrian through to Carboniferous times.  相似文献   

10.
The Sivrihisar Massif, Turkey, is comprised of blueschist and eclogite facies metasedimentary and metabasaltic rocks. Abundant metre‐ to centimetre‐scale eclogite pods occur in blueschist facies metabasalt, marble and quartz‐rich rocks. Sivrihisar eclogite contains omphacite + garnet + phengite + rutile ± glaucophane ± quartz + lawsonite and/or epidote. Blueschists contain sodic amphibole + garnet + phengite + lawsonite and/or epidote ± omphacite ± quartz. Sivrihisar eclogite and blueschist have similar bulk composition, equivalent to NMORB, but record different P–T conditions: ～26 kbar, 500 °C (lawsonite eclogite); 18 kbar, 600 °C (epidote eclogite); 12 kbar, 380 °C (lawsonite blueschist); and 15–16 kbar, 480–500 °C (lawsonite‐epidote blueschist). Pressures for the Sivrihisar lawsonite eclogite are among the highest reported for this rock type, which is rarely exposed at the Earth's surface. The distribution and textures of lawsonite ± epidote define P–T conditions and paths. For example, in some lawsonite‐bearing rocks, epidote inclusions in garnet and partial replacement of matrix epidote by lawsonite suggest an anticlockwise P–T path. Other rocks contain no epidote as inclusions or as a matrix phase, and were metamorphosed entirely within the lawsonite stability field. Results of the P–T study and mapping of the distribution of blueschists and eclogites in the massif suggest that rocks recording different maximum P–T conditions were tectonically juxtaposed as kilometre‐scale slices and associated high‐P pods, although all shared the same exhumation path from ～9–11 kbar, 300–400 °C. Within the tectonic slices, alternating millimetre–centimetre‐scale layers of eclogite and blueschist formed together at the same P–T conditions but represent different extents of prograde reaction controlled by strain partitioning or local variations in fO2 or other chemical factors.  相似文献   

11.
Lawsonite pseudomorphs are used to identify and distinguish the kinematic records of subduction and exhumation in blueschist‐facies rocks from Syros (Cyclades; Greece). Lawsonite is a hydrous mineral that crystallizes at high‐pressure and low‐temperature conditions. During decompression, lawsonite is typically pseudomorphed by an aggregate dominated by epidote and paragonite. Such aggregates are easily deformable and if deformation occurs after the lawsonite breakdown, the pseudomorphs are difficult to distinguish from the matrix. The preservation of the lawsonite crystal shape, despite complete retrogression, indicates therefore that the host blueschist rock has not been affected by penetrative deformation during exhumation, thus providing indication of strain‐free conditions. Therefore, tracking the lawsonite growth and destabilization along the P–T path followed by the rocks during a subduction/exhumation cycle provides information about the subduction/exhumation‐related deformation. Using microstructural observations and P–T pseudosections calculated with thermocalc , it is inferred that top‐to‐the‐south sense of shear preserved in lawsonite pseudomorph‐bearing blueschists on Syros occurred during the prograde metamorphic path within the lawsonite stability field, and is therefore associated with subduction. On the contrary, the deformation with a top‐to‐the‐north sense of shear is observed in surrounding rocks, where lawsonite pseudomorphs are deformed or apparently lacking. This deformation occurred after the lawsonite breakdown during exhumation. At the regional scale, exhumation‐related deformation is heterogeneous, allowing the preservation of lawsonite pseudomorphs in significant volumes of blueschists of the central and southern Cyclades. It is argued that such successive shearing deformation events with opposite senses more likely correspond to an exhumation process driven by slab rollback, in which subduction and exhumation are not synchronous.  相似文献   

12.
Low‐temperature eclogite and eclogite facies metapelite together with serpentinite and marble occur as blocks within foliated blueschist that was originated from greywacke matrix; they formed a high‐pressure low‐temperature (HPLT) subduction complex (mélange) in the North Qilian oceanic‐type suture zone, NW China. Phengite–eclogite (type I) and epidote–eclogite (type II) were recognized on the basis of mineral assemblage. Relic lawsonite and lawsonite pseudomorphs occur as inclusions in garnet from both types of eclogite. Garnet–omphacite–phengite geothermobarometry yields metamorphic conditions of 460–510 °C and 2.20–2.60 GPa for weakly deformed eclogite, and 475–500 °C and 1.75–1.95 GPa for strongly foliated eclogite. Eclogite facies metasediments include garnet–omphacite–phengite–glaucophane schist and various chloritoid‐bearing schists. Mg‐carpholite was identified in some high‐Mg chloritoid schists. P–T estimates yield 2.60–2.15 GPa and 495–540 °C for Grt–Omp–Phn–Gln schist, and 2.45–2.50 GPa and 525–530 °C for the Mg‐carpholite schist. Mineral assemblages and P–T estimates, together with isotopic ages, suggest that the oceanic lithosphere as well as pelagic to semi‐pelagic sediments have been subducted to the mantle depths (≥75 km) before 460 Ma. Blueschist facies retrogression occurred at c. 454–446 Ma and led to eclogite deformation and dehydration of lawsonite during exhumation. The peak P–Tconditions for eclogite and metapelite in the North Qilian suture zone demonstrate the existence of cold subduction‐zone gradients (6–7 °C km?1), and this cold subduction brought a large amount of H2O to the deep mantle in the Early Palaeozoic times.  相似文献   

13.
Geothermobarometric and geochronological work indicates a complete Eocene/early Oligocene blueschist/greenschist facies metamorphic cycle of the Cycladic Blueschist Unit on Naxos Island in the Aegean Sea region. Using the average pressure–temperature (P–T) method of thermocalc coupled with detailed textural work, we separate an early blueschist facies event at 576 ± 16 to 619 ± 32°C and 15.5 ± 0.5 to 16.3 ± 0.9 kbar from a subsequent greenschist facies overprint at 384 ± 30°C and 3.8 ± 1.1 kbar. Multi‐mineral Rb–Sr isochron dating yields crystallization ages for near peak‐pressure blueschist facies assemblages between 40.5 ± 1.0 and 38.3 ± 0.5 Ma. The greenschist facies overprint commonly did not result in complete resetting of age signatures. Maximum ages for the end of greenschist facies reworking, obtained from disequilibrium patterns, cluster near c. 32 Ma, with one sample showing rejuvenation at c. 27 Ma. We conclude that the high‐P rocks from south Naxos were exhumed to upper mid‐crustal levels in the late Eocene and early Oligocene at rates of 7.4 ± 4.6 km/Ma, completing a full blueschist‐/greenschist facies metamorphic cycle soon after subduction within c. 8 Ma. The greenschist facies overprint of the blueschist facies rocks from south Naxos resulted from rapid exhumation and associated deformation/fluid‐controlled metamorphic re‐equilibration, and is unrelated to the strong high‐T metamorphism associated with the Miocene formation of the Naxos migmatite dome. It follows that the Miocene thermal overprint had no impact on rock textures or Sr isotopic signatures, and that the rocks of south Naxos underwent three metamorphic events, one more than hitherto envisaged.  相似文献   

14.
Lawsonite eclogite (metabasalt and metadolerite) and associated metasedimentary rocks in a serpentinite mélange from an area just south of the Motagua fault zone (SMFZ), Guatemala, represent excellent natural records of the forearc slab–mantle interface. Pseudosection modelling of pristine lawsonite eclogite reproduces the observed predominant mineral assemblages, and garnet compositional isopleths intersect within the phase fields, yielding a prograde P–T path that evolves from 20 kbar, 470 °C (M1) to 25 kbar, 520 °C (M2). The dominant penetrative foliation within the eclogite blocks is defined by minerals developed during the prograde evolution, and the associated deformation, therefore, took place during subduction. Thermometry using Raman spectra of carbonaceous material in metasedimentary rocks associated with the SMFZ eclogites gives estimates of peak‐T of ～520 °C. Barometry using Raman spectroscopy shows unfractured quartz inclusions in garnet rims retain overpressures of up to ～10 kbar, implying these inclusions were trapped at conditions just below the quartz/coesite transition, in agreement with the results of phase equilibrium analysis. Additional growth of Ca‐rich garnet indicates initial isothermal decompression to 20 kbar (M3) followed by hydration and substantial cooling to the lawsonite–blueschist facies (M4). Further decompression of the hydrated eclogite blocks to the pumpellyite–actinolite facies (3–5 kbar, 230–250 °C) is associated with dehydration and veining (M5). The presence of eclogite as m‐ to 10 m‐sized blocks in a serpentinite matrix, lack of widespread deformation developed during exhumation and derived prograde P–T path associated with substantial dehydration of metabasites within the antigorite stability field suggest that the SMFZ eclogites represent the uppermost part of the forearc slab crust sampled by an ascending serpentinite diapir in an active, moderate‐T subduction zone.  相似文献   

15.
The pumpellyite–actinolite facies proposed by Hashimoto is defined by the common occurrence of the pumpellyite–actinolite assemblage in basic schists. It can help characterize the paragenesis of basic and intermediate bulk compositions, which are common constituents of various low-grade metamorphic areas. The dataset of mutually consistent thermodynamic properties of minerals gives a positive slope for the boundary between the pumpellyite–actinolite and prehnite–pumpellyite facies in P–T space. In the Sanbagawa belt in Japan, the mineral parageneses of hematite-bearing and -free basic schists, as well as pelitic schists have been well documented. The higher temperature limit of this facies is defined by the disappearance of the pumpellyite+epidote+actinolite+chlorite assemblage in hematite-free basic schists with XFe3+ of epidote around 0.20–0.25 and the appearance of epidote+actinolite+chlorite assemblage with XEpFe3+≤0.20. In hematite-bearing basic schists, there is a continuous change of paragenesis to higher grade, epidote–glaucophane or epidote–blueschist facies. In pelitic schists, the albite+lawsonite+chlorite assemblage does occur but only rarely, and its assemblage cannot be used to determine the regional thermal structure. The lower temperature equivalence of the pumpellyite–actinolite assemblage is not observed in the field. The Mikabu Greenstone complex and the northern margin of the Chichibu complex, which are located to the south of the Sanbagawa belt, are characterized by clinopyroxene+chlorite or lawsonite+actinolite assemblages, which are lower temperature assemblages than the pumpellyite+actinolite assemblage. These three metamorphic complexes belong to the same subduction-metamorphic complex. The pumpellyite–actinolite facies or subfacies can be useful to help reveal the field thermal structure of metamorphic complexes  相似文献   

16.
Lawsonite blueschists are important markers of cold subduction zones, subjected to intense fluid circulation. This is because lawsonite preservation in exhumed blueschists and eclogites is typically linked to cold exhumation paths, accompanied by hydration. In the Catena Costiera (Calabria, southern Italy), lawsonite–clinopyroxene blueschists of the Diamante–Terranova Unit, affected by ductile shearing and retrogression, are exposed. Blueschists contain zoned clinopyroxene crystals, showing core–rim compositional variation from diopside to omphacite and hosting primary inclusions of lawsonite and titanite. Thermodynamic modelling of phase equilibria in the NCKFMASHTO system revealed peak metamorphic conditions of 2.0–2.1 GPa and 475–490°C for the Alpine subduction in Calabria. The subsequent post-peak metamorphic evolution mainly proceeded along a decompression and cooling path up to ~1.1 GPa and ~380°C. The final exhumation stages are recorded in the sheared blueschists where a mylonitic to ultramylonitic foliation developed at ~0.7 GPa and 290–315°C. Therefore, the P–T evolution of the Diamante–Terranova blueschists mostly occurred in the stability field of lawsonite, sustained by H2O-saturated conditions during the exhumation path. The results of this study indicate that the blueschists underwent peak metamorphic conditions higher than previously thought, reaching a maximum depth of ~70 km under a very cold geothermal gradient (~6.6°C/km), during the Eocene subduction of the Ligurian Tethys oceanic crust in Calabria.  相似文献   

17.
The Pouébo and Diahot terranes of NE New Caledonia mostly comprise eclogite to blueschist facies metabasite and metasedimentary rocks that experienced c. 40 Ma metamorphism. This Eocene high‐P event has been linked with the SW‐directed obduction of the New Caledonian Ophiolite, an extensive ultramafic nappe that dominates outcrop in the south of the island. In the north, ultramafic lithologies are found only as sheets or discrete lenticular masses interleaved with, but separated from, the eclogites and blueschists by foliated talc–chlorite–serpentine–carbonate‐bearing rocks. The base of the largest and best‐preserved ultramafic body at Yambé is marked by a distinctive (2 m thick) layer of high‐P mylonite that preserves evidence for early blueschist facies conditions (S1) as inclusions in eclogite facies minerals. Textural evidence preserved in olivine‐bearing serpentinites and their bounding mafic mylonites suggest that the ultramafic bodies were emplaced within the structurally highest levels of the high‐P terrane as serpentinite tectonites sourced from hydrated mantle, formerly in the hangingwall of the Eocene subduction zone. Serpentinite emplacement accompanied burial of the NE New Caledonian margin at T<500 °C and P<16 kbar. The ultramafic fragments were buried to depths of 50–60 km in the subduction zone, where olivine was stable and coarse‐grained garnet–omphacite‐rich assemblages developed in low strain domains within enclosing mylonites. Host metabasic and metasedimentary rocks from the structurally highest portions of the high‐P belt have a prograde record identical to that of the ultramafic tectonites. The early emplacement and similar P–T history of host rocks and ultramafic masses suggest that NE New Caledonia preserves a fossil slab/mantle–wedge boundary reactivated during exhumation.  相似文献   

18.
The Chinese western Tianshan high-pressure/low-temperature (HP–LT) metamorphic belt, which extends for about 200 km along the South Central Tianshan suture zone, is composed of mainly metabasic blueschists, eclogites and greenschist facies rocks. The metabasic blueschists occur as small discrete blocks, lenses, bands, laminae or thick beds in meta-sedimentary greenschist facies country rocks. Eclogites are intercalated within blueschist layers as lenses, laminae, thick beds or large massive blocks (up to 2 km2 in plan view). Metabasic blueschists consist of mainly garnet, sodic amphibole, phengite, paragonite, clinozoisite, epidote, chlorite, albite, accessory titanite and ilmenite. Eclogites are predominantly composed of garnet, omphacite, sodic–calcic amphibole, clinozoisite, phengite, paragonite, quartz with accessory minerals such as rutile, titanite, ilmenite, calcite and apatite. Garnet in eclogite has a composition of 53–79 mol% almandine, 8.5–30 mol% grossular, 5–24 mol% pyrope and 0.6–13 mol% spessartine. Garnet in blueschists shows similar composition. Sodic amphiboles include glaucophane, ferro-glaucophane and crossite, whereas the sodic–calcic amphiboles mainly comprise barroisite and winchite. The jadeite content of omphacite varies from 35–54 mol%. Peak eclogite facies temperatures are estimated as 480–580 °C for a pressure range of 14–21 kbar. The conditions of pre-peak, epidote–blueschist facies metamorphism are estimated to be 350–450 °C and 8–12 kbar. All rock types have experienced a clockwise P–T path through pre-peak lawsonite/epidote-blueschist to eclogite facies conditions. The retrograde part of the P–T path is represented by the transition of epidote-blueschist to greenschist facies conditions. The P–T path indicates that the high-pressure rocks formed in a B-type subduction zone along the northern margin of the Palaeozoic South Tianshan ocean between the Tarim and Yili-central Tianshan plates.  相似文献   

19.
Lawsonite eclogite pods ranging in size from 3 cm to 6 m occur in lawsonite blueschist and eclogite facies metasedimentary and metabasaltic rocks in the Sivrihisar Massif, Turkey. Some pods have a core of lawsonite eclogite surrounded by alternating, centimeter-scale layers of lawsonite blueschist, eclogite, and transitional eclogite–blueschist, all with similar basaltic bulk composition. These pods also contain texturally late lawsonite-rich veins and layers. Most eclogites and blueschists within the pods lack reaction textures, but some blueschists near pod margins contain texturally complex garnet as well as glaucophane rims on omphacite, suggesting retrogression of eclogite to blueschist. Phase diagrams (pseudosections) calculated for the lawsonite eclogite core of a meter-scale pod indicate that the eclogite equilibrated at ∼22–24 kbar, ∼520°C. Lawsonite eclogite and blueschist at the tectonized margin of the same pod equilibrated at similar temperatures and slightly lower pressures. The composite eclogite–blueschist pod is foliated, lineated, and folded. An earlier generation of lineated omphacite in the pod core has a different spatial orientation than the lineation at the pod margin, although electron backscattered diffraction data show that core and rim omphacite have similar lattice preferred orientation patterns. Petrologic and structural data are consistent with mechanical formation of pods by folding and dissection of eclogite layers at high-P, and localized retrogression at pod margins during initial stages of exhumation at P–T conditions >425°C, 16 kbar.  相似文献   

20.
The north Qilian high‐pressure (HP)/low‐temperature (LT) metamorphic belt is composed mainly of blueschists, eclogites and greenschist facies rocks. It formed within an Early Palaeozoic accretionary wedge associated with the subduction of the oceanic crust and is considered to be one of the best preserved HP/LT metamorphic belts in China. Here we report new lawsonite‐bearing eclogites and eclogitic rocks enclosed within epidote blueschists in the North Qilian Mountains. Five samples contain unaltered lawsonite coexisting with omphacite and phengite as inclusions in garnet, indicating eclogite facies garnet growth and lawsonite pseudomorphs were observed in garnet from an additional 11 eclogites and eclogitic rocks. Peak pressure conditions estimated from lawsonite omphacite‐phengite‐garnet assemblages were 2.1–2.4 GPa at temperatures of 420–510 °C, in or near the stability field of lawsonite eclogite, and implying formation under an apparent geothermal gradient of 6–8 °C km?1, consistent with metamorphism in a cold subduction zone. SHRIMP U‐Pb dating of zircon from two lawsonite‐bearing eclogitic metabasites yields ages of 489 ± 7 Ma and 477 ± 16 Ma, respectively. CL images and mineral inclusions in zircon grains indicate that these ages reflect an eclogite facies metamorphism. An age of 502 ± 16 Ma is recorded in igneous cores of zircon grains from one lawsonite pseudomorph‐bearing eclogite, which is in agreement with the formation age of Early Ordovician for some ophiolite sequences in the North Qilian Mountains, and may be associated with a period of oceanic crust formation. The petrological and chronological data demonstrate the existence of a cold Early Palaeozoic subduction zone in the North Qilian Mountains.  相似文献   

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