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1.
The limited geochronology and geochemistry data available for the Early Cretaceous igneous rocks of the southern Gangdese Belt, southern Tibet, has resulted in the proposal of conflicting geodynamic models for the generation of the widespread Cretaceous igneous rocks in the middle and northern parts of the belt. To explore this issue, we present SHRIMP U–Pb zircon data and geochemical and Sr–Nd–Pb–Hf isotopic data for the Mamen andesites from the southern margin of the Gangdese Belt. The Mamen andesites, emplaced at 136.5 Ma, are sodic (Na2O/K2O = 1.2–2.3) and have geochemical characteristics typical of adakites (i.e., high Al2O3, high La/Yb ratios and Sr contents, low Y and HREE contents, and positive Eu anomalies), except for high Cr, Ni, and MgO contents. The andesites have initial (87Sr/86Sr)t ratios of 0.70413–0.70513, positive εNd(t) values of 3.7–5.8, and (206Pb/204Pb)t ratios of 18.37–18.51, (207Pb/204Pb)t ratios of 15.59–15.65, and (208Pb/204Pb)t ratios of 38.43–38.72. In situ Hf isotopic analyses of zircons that had previously been dated by SHRIMP yielded positive initial εHf(t) values ranging from +11.0 to +15.5. A model calculation using trace element and Sr–Nd–Pb isotopic data indicates that several percent of subducted sediment is required to generate the Mamen andesites, which were derived via the partial melting of subducted Neo-Tethyan slab (MORB + sediment + fluid) and subsequently hybridized by peridotite in the mantle wedge. Our data indicate that the Neo-Tethyan oceanic crust was subducted northward beneath the Gangdese Belt during the Early Cretaceous at a high angle. Our results are inconsistent with a tectonic model that advocates the low-angle or flat-slab subduction of Neo-Tethyan oceanic crust in generating the widespread Cretaceous magmatism recorded in the Gangdese Belt.  相似文献   

2.
Whole rock elemental and Sr–Nd isotope geochemistry and in situ K-feldspar Pb isotope geochemistry were used to identify the sources involved in the genesis of Neoproterozoic granites from the Embu Terrane, Ribeira Belt, SE Brazil. Granite magmatism spanned over 200 Ma (810–580 Ma), and is dominated by crust-derived relatively low-T (850–750 °C, zircon saturation) biotite granites to biotite-muscovite granites. Two Cryogenian plutons show the least negative εNdt (−8 to −10) and highest mg# (30–40) of the whole set. Their compositions are strongly contrasted, implying distinct sources for the peraluminous (ASI ∼ 1.2) ∼660 Ma Serra do Quebra-Cangalha batholith (metasedimentary rocks from relatively young upper crust with high Rb/Sr and low Th/U) and the metaluminous (ASI = 0.96–1.00) ∼ 630 Ma Santa Catarina Granite. Although not typical, the geochemical signature of these granites may reflect a continental margin arc environment, and they could be products of a prolonged period of oceanic plate consumption started at ∼810 Ma. The predominant Ediacaran (595–580 Ma) plutons have a spread of compositions from biotite granites with SiO2 as low as ∼65% (e.g., Itapeti, Mauá, Sabaúna and Lagoinha granites) to fractionated muscovite granites (Mogi das Cruzes, Santa Branca and Guacuri granites; up to ∼75% SiO2). εNdT are characteristically negative (−12 to −18), with corresponding Nd TDM indicating sources with Paleoproterozoic mean crustal ages (2.0–2.5 Ga). The Guacuri and Santa Branca muscovite granites have the more negative εNdt, highest 87Sr/86Srt (0.714–0.717) and lowest 208Pb/206Pb and 207Pb/206Pb, consistent with an old metasedimentary source with low time-integrated Rb/Sr. However, a positive Nd–Sr isotope correlation is suggested by data from the other granites, and would be consistent with mixing between an older source predominant in the Mauá granite and a younger, high Rb/Sr source that is more abundant in the Lagoinha granite sample. The Ediacaran granites are coeval with profuse granite magmatism attributed to continental arc magmatism in northern Ribeira and Araçuaí belts. However, their evolved compositions with low mg# and dominantly peraluminous character are unlike those of magmatic arc granites, and they are more likely products of post-collisional magmatism or correspond to an inner belt of crust-derived granites.  相似文献   

3.
Miocene igneous rocks in the 1,600 km-long E–W Gangdese belt of southern Tibet form two groups separated at longitude ～89° E. The eastern group is characterized by mainly intermediate–felsic calc-alkaline plutons with relatively high Sr/Y ratios (23 to 342), low (87Sr/86Sr)i ratios (0.705 to 0.708), and high εNdi values (+5.5 to ?6.1). In contrast, the western group is characterized by mainly potassic to ultrapotassic volcanic rocks with relatively high Th and K2O contents, low Sr/Y ratios (11 to 163), high (87Sr/86Sr)i ratios (0.707 to 0.740), and low εNdi values (?4.1 to ?17.5). The eastern plutonic group is associated with several large porphyry Cu–Mo ± Au deposits, whereas the western group is largely barren. We propose that the sharp longitudinal distinction between magmatism and metallogenic potential in the Miocene Gangdese belt reflects the breakoff of the Greater India slab and the extent of underthrusting by the Indian continental lithosphere at that time. Magmas to the east of ～89° E were derived by partial melting of subduction-modified Tibetan lithosphere (mostly lower crust) triggered by heating of hot asthenospheric melt following slab breakoff. These magmas remobilized metals and volatile residual in the crustal roots from prior arc magmatism and generated porphyry Cu–Mo ± Au deposits upon emplacement in the upper crust. In contrast, magmas to the west of ～89° E were formed by smaller volume partial melting of Tibetan lithospheric mantle metasomatized by fluids and melts released from the underthrust Indian plate. They are less hydrous and oxidized and did not have the capacity to transport significant amounts of metals into the upper crust.  相似文献   

4.
《Gondwana Research》2014,25(1):401-419
This study reports new zircon U–Pb and Hf isotopes and whole-rock elemental and Sr–Nd isotopic data for the gneissic granite and leucogranite from the Nabang metamorphic zone, Yingjiang area (West Yunnan, SW China). The metamorphosed granitoids crystallized during the early Eocene (~ 55–50 Ma) with zircons showing εHf(t) values from + 11 to − 5.3 and crustal model ages of 1.5 to 0.42 Ga, comparable to those of coeval I-type granitoids from the Gangdese batholith, southern Lhasa. The rocks are characterized by metaluminous and weakly peraluminous hornblende-bearing gneissic granites with A/CNK = 0.95–1.09, Na2O > K2O, coupled with low initial Sr isotopic values of 0.7049–0.7070 and high εNd(t) values from + 1.1 to − 7.1. The rocks were derived from crustal materials involving ancient upper crust/sedimentary and juvenile mantle-derived rocks. Together with available data from nearby regions, it is proposed that the early Eocene granitoids in the Nabang and Tengliang area can be correlated to the Gangdese granitoids and represent the southeastward continuation of the magmatic arc resulting from the Neotethyan subduction in southern Tibet. The petrogenesis of early Eocene granitoids in western Yunnan was probably related to the rollback of the subducting Neotethyan slab that caused the remelting of the crustal materials newly modified by the underplated basaltic magma.  相似文献   

5.
The Zhunuo Cu-bearing porphyries are located in the westernmost part of the Miocene Gangdese porphyry Cu (Mo–Au) deposit belt. Zircon U–Pb dating of the diorite porphyry, K-feldspar granite porphyry, and monzonitic granite porphyry in Zhunuo yielded crystallization ages of 12.5 ± 0.4 Ma, 12.3 ± 0.3 Ma, and 12.4 ± 0.3 Ma, respectively. The diorite porphyry is characterized by low SiO2 (58.61–61.14 wt.%) and Th (0.30–0.76 ppm) concentrations, low Th/La (0.05–0.1) ratios, and high Mg# (> 49) values coupled with low (87Sr/86Sr)i (0.703777–0.703783) and high εNd(t) (+ 4.07 to + 4.90) values. They also have adakite-like affinities, such as low Y (10.5–12.0 ppm), and high Sr/Y ratios (61–65). They were probably derived from a thickened juvenile lower continental crust. The K-feldspar granite porphyry probably originated in the middle–upper continental crust because of their high SiO2 (73.59–74.98 wt.%) and Th (50.1–52.1 ppm) concentrations, high Th/La (1.67–2.10), and low Sr/Y (20.2–20.7) ratios and Mg# (32–38) values, combined with high (87Sr/86Sr)i (0.710921–0.712008), low εNd(t) (− 8.47 to − 9.26) isotopic compositions and old Nd model ages (1.16–1.25 Ga). Their magmas were most likely partial melts of the preserved ancient crust similar to the central Lhasa subterrane. The geochemical characteristics and Sr–Nd isotopic compositions of the monzonitic granite porphyry display trends that lie between those of the diorite porphyry and K-feldspar granite porphyry, and they are therefore likely to be production of hybridization between the above two melts. The ore-bearing diorite porphyry and monzonitic granite porphyry have higher zircon Ce4 +/Ce3 + ratios than the ore-barren K-feldspar granite porphyry, indicating a higher oxygen fugacity in the ore-bearing magmas. We suggest that metals were released from the re-melting of arc-related cumulates which formed during lower crustal growth and thickening. This mechanism provides a reasonable explanation for the significant flare-up of mineralization during the Miocene in the Gangdese region. The lower continental crust beneath southern Lhasa subterrane probably was uniformly juvenile but the region to the west of Zhunuo was not mineralized due to input of large ancient crustal materials in the source of these ore-barren adakite-like rocks.  相似文献   

6.
The late Paleozoic Bailingshan intrusions and volcanic rocks are located in the Aqishan–Yamansu arc belt in the southern part of the eastern Tianshan and are associated with an important group of iron skarn deposits. The exposed intrusive rocks are mainly granodiorite, monzonitic granite, and granite. Zircon U–Pb dating of the Tugutublak Formation tuffaceous dacitic lava yields an age of 324 Ma, whereas dates of the Bailingshan granodiorite, monzonitic granite, and granite yields ages of 317 Ma, 313 Ma, and 307 Ma, respectively. The results indicate that the Bailingshan granitoids were emplaced soon after the eruption of the Tugutublak dacite. All these rocks studied show calc-alkaline to high-K calc-alkaline and metaluminous affinities, with A/CNK values ranging 0.83–1.10. They are enriched in Rb, K, and Pb, depleted in Nb, Ta, Ti, and P, and contain low Sr/Y (4.16–23.7) and Sr (109.0–347.0 ppm) values, displaying typical arc geochemical affinities. The tuffaceous dacitic lava has low Nb/Ta (10.3–14.1) values, a wide range of Mg# (6–64), positive zircon εHf(t) (3.2–7.5) values, and elevated whole-rock εNd(t) (2.03–4.41), but low ISr values (0.70427–0.70530), indicating that the source magma may have been derived from the juvenile lower crust with minor mantle input. The Bailingshan I-type intrusions also exhibit a mixed source signal, as constrained by Nb/Ta ratios, Mg#, and isotopes characteristics. Because the granodiorite, monzonitic granite, and granite intrusions have higher zircon εHf(t) (3.3–7.5, 11.8–13.5, and 10.2–14.4, respectively) and εNd(t) (3.90, 5.78, and 5.94, respectively) values than those of the tuffaceous dacitic lava, it is suggested that mantle-derived materials may have played a more prominent role with their petrogenetic evolution. Integrating our new geological, age, geochemical and isotopic data we propose that the Aqishan–Yamansu iron skarn belt may have formed in a back-arc position or within an intra-arc basin generated by the southward subduction of the Kanggur oceanic plate beneath the Yili–Central Tianshan block during the late Paleozoic, with felsic-intermediate magmatism occurring during the basin inversion.  相似文献   

7.
Remnants of the Proto-Tethys are mainly preserved in the region between south of the North China-Tarim Block and north of Qiangtang-Sibumasu/Baoshan Blocks. Magmatic-metallogenic events related to the Proto-Tethyan subductions were rarely reported, and the subduction history and polarity of the Proto-Tethyan are still under debate. Here, we presented new data of zircon UPb ages, whole-rock Sr–Nd–Pb isotopes, major and trace elements and zircon Hf isotopes for the volcanic rocks in the northeastern Altyn Mountains. Information of over 14 volcanic-hosted deposits/prospects in the region has been compiled. These volcanic ore hosts consist mainly of basaltic andesite, andesite, dacite and rhyolite rocks. The andesite and rhyolite rocks are newly zircon UPb dated to be Late Cambrian-Early Ordovician (andesite: 490.5 ± 5.2 Ma; rhyolite: 492.6 ± 2.9 Ma and 491.6 ± 5.6 Ma), representing the timing of volcanism and VMS (Volcanogenic Massive Sulfide) mineralization. All the volcanic rocks belong to the high-K calc-alkaline and shoshonite series: the andesite rocks from the Kaladawan area in north of the region display arc geochemical affinities and contain (87Sr/86Sr)i (0.7082–0.7083) and εNd(t) (−9.7 to −7.6), indicating that they were likely formed by partial melting of the mantle wedge with subducted sediment inputs. The rhyolite rocks from the Kaladaban area in south of the region are characterized by high SiO2 (64.46–78.55 wt%), low alkali (Na2O + K2O, 3.46–7.17 wt%), and contain (87Sr/86Sr)i (0.7063–0.7095), εNd(t) (−6.6 to −1.5), and zircon εHf(t) (−5.5 to 5.4), indicating that they were likely derived from partial melting of the lower crust with depleted mantle inputs. Rock assemblage and geochemistry suggest that volcanic rocks in the northeastern Altyn Mountains may have formed in a continental arc setting. Their spatial distributions with respect to the ophiolites in the region suggest that the subduction was likely south-dipping. This subduction-related arc magmatism may have formed the many important VMS and porphyry–skarn deposits in the region.  相似文献   

8.
The Tibetan Plateau is one of the most significant Cu poly-metallic mineralization regions in the world and preserves important information related to subductional and collisional porphyry Cu mineralization. This study investigates a new occurrence of Cu mineralization-related andesitic porphyries in the western domain of the Gangdese magmatic belt and assesses its petrologic, zircon U-Pb geochronology, whole-rock chemistry, and Sr-Nd-Hf-Pb isotope data. Zircon U-Pb dating of three ore-related porphyries yields crystallization ages of 212–211 Ma. These ages are consistent with previous molybdenite Re-Os dating, indicating a late Triassic magmatic and Cu mineralization event in the western Gangdese magmatic belt. Nb, Ta, and Ti depletion, Th and LREE enrichment, and high La/Yb and Th/Yb ratios in addition to high U/Yb ratios from zircons suggest that the magma was generated in an active continental arc setting. The porphyries have radiogenic isotopic compositions with (87Sr/86Sr)i 0.70431–0.70473, εNd(t) +1.1 to +3.8, (207Pb/204Pb)i 15.601–15.622, and (208Pb/204Pb)i 38.450–38.693, as well as high positive zircon εHf(t) values from +6.2 to +10.6 (mean value 8.3), corresponding to model ages (TDM) ranging from 509 Ma to 819 Ma (mean 646 Ma). This suggests that the andesitic magmatism was dominantly sourced from depleted mantle materials that were modified by subducted oceanic sediment-derived melts during the subduction of the Neo-Tethys Ocean. The mineralization-related porphyries contain amphibole and epidote, as well as high whole-rock Fe2O3/FeO and zircon Ce4+/Ce3+ ratios, suggesting hydrous and highly oxidized parent magmas. Considering the existing Cu mineralization and highly oxidized magma of the well-preserved Triassic andesitic igneous rocks in the western Gangdese belt, the subduction-related continental arc magma system is favorable for subduction-related porphyry Cu deposits. The existence of Luerma porphyry mineralization demonstrates that there are at least five generations of porphyry Cu-(Mo-Au) mineralization in the Gangdese magmatic belt, which advances the timeframe of porphyry mineralization to the late Triassic.  相似文献   

9.
The ~545 Ma-old syn-collisional Otjimbingwe alkaline complex is composed of pyroxene-amphibole-biotite-bearing, mildly nepheline-normative to quartz-normative rocks ranging in composition from monzogabbro to monzonite, syenite and granite. The alkaline rocks have moderate to high SiO2 (50.5–73.0 wt%) and Na2O + K2O (5.1–11.5 wt%) and moderate to low MgO (6.6–0.2 wt%) concentrations. All samples have high large ion lithophile element (LILE: Ba up to 4600 ppm) and high-field-strength element contents (HFSE; Zr: 155–1328 ppm; Nb: 16–110 ppm; Ta: 1.4–7.1 ppm and Hf: 4–24 ppm) and have strongly fractionated LREE patterns ((La/Yb)N = 14–51). The most primitive members lack significant negative Eu anomalies. Mantle-normalized multi-element diagrams show depletion in Ba, Rb, Nb (Ta), P and Ti. The alkaline rocks have moderate radiogenic initial 87Sr/86Sr ratios (0.7061–0.7087) and unradiogenic initial ɛNd values (−3.9 to −6.1). This isotope signature, associated with high LREE/HFSE ratios indicates that the parental melts were generated in enriched portions of the shallow lithospheric mantle, which was probably affected by previous subduction zone processes. In addition, correlations between Sr and Nd isotopes indicate that some of these variations result from combined crustal assimilation and fractional crystallization (AFC) processes. A new model of flat subduction is presented that explains most of the unsolved problems in the orogenic evolution of the Damara orogen, namely (i) the absence of early intrusive rocks with a clear subduction zone setting, (ii) the absence of high-pressure rocks such as blueschists and eclogites, (iii) the unusual distribution of igneous rocks with a clear predominance of granite and granodiorite and (iv) the need for a asthenospheric window during a classical subduction to explain the high T/moderate P granulite facies conditions in the overriding plate.  相似文献   

10.
We performed geochronological and geochemical analyses of the A-type granite in the Hongol area, central Inner Mongolia, to determine its age, petrogenesis and tectonic setting, which are significant for clarifying the Late Paleozoic tectonic evolution of the Xing'an Mongolian Orogenic Belt(XMOB). The rock type of the A-type granite in the Hongol area is alkali-feldspar granite, and it constitutes a western part of the Baiyinwula-Dongujimqin A-type granite belt. Zircon U-Pb geochronology yields ~(206)Pb/~(238)U ages ranging from 293 to 286 Ma for the alkali-feldspar granite, indicating this granitic pluton formed in the Early Permian. The alkali-feldspar granite is high in silica(SiO_2=75.13 wt%-80.17 wt%), aluminum(Al_2 O_3=10.59 wt%-13.17 wt%) and alkali(Na_2 O+K_2 O=7.33 wt%-9.11 wt%), and low in MgO(0.08 wt%-0.39 wt%) and CaO(0.19 wt%-0.70 wt%). It is obviously enriched in LILEs such as Rb, Th and K,depleted in HFSEs such as Nb, Ti, La and Ce, with pronounced negative anomalies of Nb, Ti, P, Eu, Sr and Ba. Its Sr-Nd-Pb isotopic compositions show positive ε_(Nd)(t)(+0.72-+3.08), low T_(DM2)(805-997 Ma),and high radioactive Pb with(~(206)Pb/~(204)Pb)_i of 18.710-19.304,(~(207)Pb/~(204)Pb)_i of 15.557-15.604 and(~(208)Pb/~(204)Pb)_i of 37.887-38.330. Petrological characteristics and geochemical data suggest that the alkalifeldspar granite in the Hongol area belongs to aluminous A-type granite. This A-type granite formed in a post-collisional extensional setting and was generated by the partial melting of felsic rocks in the middlelower crust resulting from post-collisional slab breakoff. It is suggested that the Paleo-Asian Ocean was closed before the Permian in central Inner Mongolia.  相似文献   

11.
The Indosinian orogeny is recorded by Triassic angular unconformities in Vietnam and South China and by widely occurring granitoids in the Yunkai-Nanling and the Xuefengshan belts of South China. The Longtan pluton in the northwestern part of the Xuefengshan belt is a typical high-K, calc-alkaline, I-type granitoid, which can shed light on the relationship between the Indosinian tectonic and magmatic activity in the region. Three precise zircon U–Pb ages yielded a mean of 218 ± 0.8 Ma, which is taken as the age of crystallization. The pluton consists of both granodiorite (64.59–68.01 % SiO2 and 3.25–4.22 % K2O) and granite (70.49–71.80 % SiO2 and 4.07–4.70 % K2O). The granodiorites are characterized by relatively high Mg# (54–57), low contents of Na2O (3.2–4.3 wt%), low abundances of incompatible elements (LILE, Nb and P), high initial 87Sr/86Sr (0.7175–0.7184) and negative εNd(t) (?9.98 to ?9.72). REE patterns show moderate fractionation ((La/Yb)cn = 8.07–18.80) with negative Eu anomalies (Eu/Eu* = 0.62–0.86). Compared with the granodiorite, the granite has a wider range of Mg# (49–59), lower contents of Na2O (2.8–4.2 wt%), higher initial 87Sr/86Sr (0.7232–0.7243) and more negative εNd(t) (?12.07 to ?11.24) values. REE patterns are relatively flat ((La/Yb)cn = 14.73–29.37) with smaller negative Eu anomalies (Eu/Eu* = 0.48–0.63). The granodiorite has lower K2O/Na2O and Al2O3/(MgO + FeOTot) values than the granite. Based on major and trace element geochemistry and Sr–Nd isotopes, we interpret the Longtan granodioritic magma to have been derived by partial melting of interlayered Proterozoic metabasaltic to metatonalitic source rocks, whereas the granite was probably derived from a mixture of Proterozoic metagraywackes and metaigneous rocks. Field, petrographic and geochemical evidence indicate that partial melting and fractional crystallization were the dominant mechanism in the evolution of the pluton. The Longtan granodiorites and granites are petrologically and geochemically similar to typical Indosinian varieties and are considered to have been produced in a similar manner. The Indosinian granitoids in the region show a magmatic peak age of ~238 Ma from the Yunkai-Nanling belt in the southeast and a magmatic peak age of ~218 Ma of the Xuefengshan belt to the northwest. These early and late magmatic episodes of the Indosinian granitoids also display slight variations of regular compositions, εNd(t) values and T DM ages. Thus, we propose a syncollisional extension model that Indosinian granitoids were generated by decompressional partial melting of crustal materials triggered by two extensions during collision of the Indochina and South China blocks. The Longtan pluton in the northwesternmost part of the orogenic belt marks the termination of the Indosinian magmatism and orogenesis.  相似文献   

12.
The Miao'ershan uranium ore district is one of the most important granite-hosted uranium producers in South China. There are several Triassic granite plutons in the Miao'ershan batholith, but uranium ore deposits mainly occur within the Douzhashan granitic body. Precise zircon U–Pb dating indicated that these Triassic granite plutons were emplaced during 204 to 215 Ma. The Douzhashan U-bearing granite lies in the central part of the Miao'ershan batholith, and has higher U contents (8.0 to 26.1 ppm, average 17.0 ppm) than the nearby Xiangcaoping granite (5.0 to 9.3 ppm, average 7.0 ppm) and the Yangqiaoling granite (6.4 to 18.3 ppm, average 11.5 ppm) in the south part of the batholith. The Douzhashan granite is composed of medium-grained two-mica granite, whereas the Xiangcaoping and Yangqiaoling granites are composed of porphyritic biotite granite. Both the Xiangcaoping and Douzhashan granites have high A/CNK ratios (> 1.10), high (87Sr/86Sr)i ratios (> 0.720) and low εNd(t) values (− 11.3 to − 10.4), suggesting that they belong to strongly peraluminous S-type granites. The Douzhashan granite has low CaO/Na2O ratios, high Rb/Sr and Rb/Ba ratios, indicating a partial melting origin of clay-rich pelitic rocks. In contrast, the Xiangcaoping granite formed from clay-poor psammite-derived melt. The Yangqiaoling granite shows different geochemical characteristics with the Douzhashan and Xiangcaoping granites, indicating a different magma source. The Yangqiaoling granite has higher εNd(t) of − 9.4 to − 8.3 and variable A/CNK values from 0.98 to 1.19, suggesting a mixture source of meta-sedimentary rocks and meta-igneous rocks. Crystallization fractionation is not the main mechanism for U enrichment in the Douzhashan granite. We suggest that U-rich pelitic rock sources may be the key factor to generate peraluminous U-bearing granites in South China. Searching for those granites which are reduced, strongly peraluminous and were derived from U-rich pelitic rocks, is the most effective way for exploring granite-hosted U deposits.  相似文献   

13.
Volcanic rocks preserved in the Lampang–Den Chai area in NW Thailand are important components of the giant Paleotethyan igneous belt. Constraining their age and petrogenesis is critical for better understanding their temporal-spatial relationship with the Lancangjiang igneous zone and the Paleotethyan tectonic evolution in SE Asia. The volcanic suite is constituted by intermediate to acid rocks with zircon U–Pb ages of 240.4 ± 1.7 Ma and 240.6 ± 1.9 Ma for the representative andesitic and rhyolitic samples, respectively. Volcanic sequence is dominated by calc-alkaline andesites, dacites and rhyolites. The andesitic and dacitic samples are characterized by high Mg# (37–57) and TiO2 (0.91–1.59 wt%), and can be classified as high-Mg series. They are enriched in LILEs and LREEs and depleted in HFSEs. Representative andesitic samples have 87Sr/86Sr (i) ratios of 0.70398–0.70567, εNd (t) values of +3.6–+3.9, zircon εHf (t) values of +2.8–+8.0 and δ18O values of 7.01–8.11‰, respectively. The rhyolitic samples are characterized by high Mg# (38–70) and low TiO2 (0.25–0.61 wt%). They are enriched in LILEs and LREEs, along with 87Sr/86Sr (i) = 0.70468–0.70645, εNd (t) = +2.0–+4.3 and zircon εHf (t) = +5.7–+13.6. Geochemical signatures suggest that the andesitic and dacitic samples might originate from a newly modified mantle source by slab-derived fluids and recycled sediments, and rhyolitic samples were derived from juvenile mafic crust. It is proposed that the Middle Triassic high-Mg volcanic rocks in the Lampang–Den Chai area formed in response to slab roll-back during transition of tectonic regime from subduction to continental collision between the Sibumasu and Indochina blocks. These rocks constitute part of the Chiang Khong–Lampang–Tak igneous zone, and can northerly link with the Lancangjiang igneous zone and southerly extend to the Chanthaburi, Malaysia and Singapore areas.  相似文献   

14.
The Paleozoic granitoids of the Sierra de San Luis comprise the Ordovician tonalite suite (OTS; metaluminous to mildly peraluminous calcic tonalite–granodiorites) and granodiorite–granite suite (OGGS; peraluminous calcic to calc-alkaline granodiorite–monzogranites), as well as the Devonian granite suite (DGS; peraluminous alkali-calcic monzogranites) and monzonite–granite suite (DMGS; metaluminous alkali-calcic quartz monzonite–monzogranite ± granodiorite, mildly peraluminous alkalicalcic monzogranites). The OTS has relatively high K2O, CaO, and YbN and low Cr, Ni, Ba, Sr, Rb/Sr, Sr/Y, and (La/Yb)N, as well as negative Eu/Eu1, high 87Sr/86Sr (0.70850–0.71114), and unradiogenic εNd(470Ma) (−5.3 to −6.0), which preclude an origin of variably fractionated mantle melts and favour a mafic lower crustal source. The OGGS consists of two granitoids: (1) high-temperature characterized by low Al2O3/TiO2, Rb/Sr, and (La/Yb)N, a smooth negative Eu/Eu1, and relatively high CaO and (2) low-temperature with high Al2O3/TiO2 and Rb/Sr, low CaO, (La/Yb)N, and Sr/Y, and negative Eu/Eu1. Melting of metagreywackes at pressures below 10 kbar with a variable supply of water could account for the chemistry of the high-T OGGS, whereas dehydration melting of biotite-bearing metasedimentary sources at low pressures is proposed for the low temperature OGGS. Melting of crustal sources relates to a contemporaneous mafic magmatism.Devonian magmatism is characterized by high Ba, Sr, K2O, Na2O, Sr/Y, and (La/Yb)N. Sources for the DGS include metasedimentary or metatonalitic protoliths. Biotite dehydration melting triggered by the addition of heat, supplied by mantle-derived magmas, is proposed. High Ba, Sr, LREE, MgO, Cr, Ni, Zr, and V of the monzonites suggest an enriched lithospheric mantle source. Low Yb and Y and high Sr and (La/Yb)N indicate a garnet-rich residual assemblage (P ⩾ 10 kbar). Melts for the peraluminous rocks may have derived from a metasedimentary or metaigneous source at lower pressures in a process dominated by biotite consumption and plagioclase in the residue.The Ordovician granitoids are synkinematic with compressive deformation related to the early stages of Famatinian convergence. The Devonian magmatism is synkinematic with a system of shear zones that were active during the Achalian cycle.  相似文献   

15.
The Huangyangshan alkaline pluton is located within the southern part of the Eastern Junggar orogenic belt in Xinjiang Province, and forms part of the Kalamaili alkaline granite belt. The pluton hosts the Huangyangshan super-large graphite deposit, which develops unique spherical structure and coexists with metal sulfides. This study examines the genetic relationship between the alkaline magmatism that formed the pluton and the graphite mineralization using zircon LA–ICP–MS U–Pb dating, geochemical analysis for representative rock types in the Huangyangshan pluton, and new Re–Os isotope dating for the graphite in the Huangyangshan graphite deposit. Zircons from medium-grained arfvedsonite granite, medium–fine-grained amphibole granite, medium-grained biotite granite, and fine-grained biotite granite phases of the Huangyangshan pluton yield weighted mean U–Pb ages of 322.7 ± 4.5, 318.3 ± 4.0, 303.9 ± 2.1, and 301.1 ± 3.6 Ma, respectively, indicating that all of the granite phases were emplaced during the Late Carboniferous over a period of around 20 Myr. Six graphite samples from the deposit yield a Re–Os isochron age of 332 ± 53 Ma. Combining these ages with the genetic relationship between the graphite mineralization and magmatism in the study area and the relatively large uncertainty on the Re–Os isochron age for the graphite suggests that the mineralization formed at ca. 320 Ma. The graphite samples yield an initial 187Os/188Os value of 0.38 ± 0.2, indicative of carbon derived from a mixture of organic and mantle-derived sources. The different granite phases in the Huangyangshan pluton are geochemically similar with relatively high SiO2 (75.6–78.2 wt%) and Na2O + K2O (8.01–9.04 wt%) and relatively low CaO (0.18–0.7 wt%), MgO (0.06%–0.13 wt%) and Fe2O3 (TFe2O3 = 1.08–2.06 wt%) contents. The granites are enriched in light rare earth elements (LREE), large-ion lithophile elements (LILEs) (e.g. Rb, Th, and K), and high field strength elements (HFSEs) (e.g. Zr and Hf), depleted in heavy rare earth elements (HREEs), and have negative Ba, Sr, P, Ti, and Eu anomalies. These geochemical characteristics are indicative of derivation from juvenile basaltic oceanic crustal materials in the lower crust. This suggests that the Huangyangshan pluton formed from magmas generated by partial melting caused by mantle-derived magma underplating, with the magmas then undergoing mixing, separation, and significant fractional crystallization. Diorite enclaves within the granites have weaker trace element anomalies that are indicative of magma mixing. In addition, the mantle-derived intermediate–basic end-member involved in the magma mixing is likely one of the important carriers of carbon and metal. In summary, the Late Carboniferous Huangyangshan pluton and its associated graphite mineralization formed in a post-collision extensional tectonic setting in the Kalamaili area.  相似文献   

16.
The newly discovered Dadaoshan Sn deposit is located in the eastern Guangdong Sn–W province, coastal SE China. The Sn mineralization, hosted in Jurassic porphyritic granite and the Lower Jurassic Jinji Formation sedimentary wall rocks, is considered to be granite-related. In this study, the porphyritic granite was LA–ICP–MS zircon U–Pb dated to be 153.2 ± 1.2 Ma, consistent with the syn-mineralization molybdenite Re–Os age of 152.6 ± 1.8 Ma. The porphyritic granite samples are weakly peraluminous (A/CNK = 1.0–1.1) and high-K calc-alkaline. The rocks contain high SiO2 (72.9–75.6 wt%), moderate Rb/Sr (5–9) and low ΣREE (136–223 ppm). They are enriched in F, Li, Rb and Sn, depleted in Ba, Sr, P, Zr, Th, Nb and Y, and have distinct negative Eu anomalies (δEu = 0.09–0.18), suggesting that the porphyritic granite is highly fractionated I-type granite. The calculated initial 87Sr/86Sr (0.711582–0.715173), relatively low ɛNd(t) (−9.48 to −8.54; TDM2 = 1638–1814 Ma), and the zircon εHf(t) (−14.2 to −5.1; two-stage model ages = 1528–2103 Ma) all suggest that the granite was mainly crustal-derived with little mantle input. Sulfur isotopic compositions for the sulfides (arsenopyrite and chalcopyrite: δ34S = −1.1 to 1.4‰, average = −0.1) imply a dominantly magmatic sulfur source. The calculated zircon Ce4+/Ce3+ and EuN/EuN1 ratios of the Dadaoshan granite range from 1.0 to 112 (mean = 31.7) and from 0.04 to 0.37 (mean = 0.14), respectively, indicating a low oxygen fugacity for the magma. The reducing and highly fractionated nature of the Dadaoshan granitic magma may have played a key role in the Sn mineralization.It was previously argued that the Jurassic Sn–W mineralization and its causative magmatism were largely confined in the South China interior, e.g., the Nanling Range. Our new data suggest that the Late Jurassic Sn–W mineralization and its causative magmatism actually extended to the SE China coastal area. The Dadaoshan granite may have been generated from partial crustal melting led by underplating of mantle-derived magmas in an extensional environment. Regional extension may have been related to the west-directed, flat-slab subduction and delamination of the Paleo-Pacific (Izanagi) plate beneath the South China block. Another suite of Early Cretaceous Sn–W-bearing granitic rocks in eastern Guangdong may have mainly been crustal-derived with minor mantle input, and likely occurred under back-arc extensional setting led by the Paleo-Pacific subduction rollback.  相似文献   

17.
The Jinping–Fan Si Pan (JFP) Cenozoic magmatic and Cu–Mo–Au metallogenic belt in the southeastern part of the Ailao Shan shear zone host the Tongchang, Chang′an, Habo, and Chinh Sang Cu–Mo–Au deposits. These deposits form an integrated epithermal-porphyry regional mineralization system associated with 40–32 Ma high-K alkaline magmatism. The magmatic rocks in the belt have relatively low TiO2 (<0.73 wt%), P2O5 (<0.29 wt%), and FeO* (<4.99 wt%), and high Na2O (2.86–4.75 wt%) and K2O (4.01–7.98 wt%). They also have high contents of incompatible trace elements, and are enriched in LILE (Rb, Ba, K, Sr) and LREE. They have marked Nb, Ta, Ti and P depletion in primitive mantle-normalized spidergrams, and plot close to the EMII mantle field in the Sr–Nd isotopic diagram. These characteristics are similar to those of the Eocene high-K alkaline rocks along the northern Ailao Shan belt, eastern Tibet plateau. The sulfur and lead isotope analyses of sulfide minerals from both the ores and related magmatic rocks confirm the involvement of a magmatic ore fluid. The Cenozoic alkaline intrusions and Cu–Mo–Au mineralization in the JFP were formed prior to the initiation of left-lateral shearing along the Ailao Shan shear zone. The magmas appear to have been derived from enriched mantle, possibly with mixing of materials from the buried Tethyan oceanic lithosphere, and/or crust.  相似文献   

18.
Continental subduction and its interaction with overlying mantle wedge are recognized as fundamental solid earth processes, yet the dynamics of this system remains ambiguous. In order to get an insight into crust–mantle interaction triggered by partial melting of subudcted continental crust during its exhumation, we carried out a combined study of the Shidao alkaline complex from the Sulu ultrahigh pressure (UHP) terrane. The alkaline complex is composed of shoshonitic to ultrapotassic (K2O: 3.4–9.3 wt.%) gabbro, pyroxene syenite, amphibole syenite, quartz syenite, and granite. Field studies suggest that the mafic rocks are earlier than the felsic ones in sequence. LA-ICPMS zircon U–Pb dating on them gives Late Triassic ages of 214 ± 2 to 200 ± 3 Ma from mafic to felsic rocks. These ages are slightly younger than the Late Triassic ages (225–210 Ma) of the felsic melts from partial melting of the Sulu UHP terrane during exhumation. The alkaline rocks have wide ranges of SiO2 (49.7–76.7 wt.%), MgO (8.25–0.03 wt.%), Ni (126.0–0.07 ppm), and Cr (182.0–0.45 ppm) contents. The contents of MgO, total Fe2O3, CaO, TiO2 and P2O5 decrease with increasing SiO2 contents. The contents of Na2O, K2O, and Al2O3 increase from gabbro to amphibole syenite, and decrease from amphibole syenite to granite, respectively. The alkaline rocks have characteristics of an arc-like pattern in trace element distribution, e.g., enrichment of LREE, LILE (Rb and Ba), Th and U, depletion of HFSE (Nb, Ta, P and Ti), and positive Pb anomalies. From the mafic rocks to the felsic rocks, the (La/Yb)N ratios and the contents of the total REE, Sr and Ba decrease but the Rb contents increase. The alkaline rocks with high SiO2 contents also display features of an A2-type granitoids, e.g., high contents of total alkalis, Zr and Nb and high ratios of Fe2O3T/MgO, Ga/Al, Yb/Ta and Y/Nb, suggesting a post-collisional magmatism during exhumation of the Sulu UHP terrane. The alkaline rocks have homogeneous initial 87Sr/86Sr ratios (0.7058–0.7093) and negative εNd(t) values (− 18.6 to − 15.0) for whole-rock. The Sr–Nd isotopic data remain almost unchanged with varying SiO2 and MgO contents, suggesting a fractional crystallization (FC) process from the same parental magma. Our studies suggest a crust–mantle interaction in continental subduction interface as follows: (1) hydrous felsic melts from partial melting of subducted continental crust during its exhumation metasomatized the overlying mantle wedge to form a K-rich and amphibole-bearing mantle; (2) partial melting of the enriched lithospheric mantle generated the Late Triassic alkaline complex under a post-collisional setting; and (3) the alkaline magma experienced subsequent fractionational crystallization mainly dominated by olivine, clinopyroxene, plagioclase and alkali feldspar.  相似文献   

19.
Whole rock major and trace element and Sr-, Nd- and Hf-isotope data, together with zircon U-Pb, Hf- and O-isotope data, are reported for the Nb-Ta ore bearing granites from the Lingshan pluton in the Southeastern China, in order to trace their petrogenesis and related Nb-Ta mineralization. The Lingshan pluton contains hornblende-bearing biotite granite in the core and biotite granite, albite granite and pegmatite at the rim. In addition, numerous mafic microgranular enclaves occur in the Lingshan granites. Zircon SIMS U-Pb dating gives consistent crystallization ages of ca. 132 Ma for the Lingshan granitoids and enclaves, consistent with the Nb-Ta mineralization age of ∼132 Ma, indicating that mafic and felsic magmatism and Nb-Ta mineralization are coeval. The biotite granites contain hornblende, and are metaluminous to weakly peraluminous, with high initial 87Sr/86Sr ratios of 0.7071–0.7219, negative εNd(t) value of −5.9 to −0.3, εHf(t) values of −3.63 to −0.32 for whole rocks, high δ18O values and negative εHf(t) values for zircons, and ancient Hf and Nd model ages of 1.41–0.95 Ga and 1.23–1.04 Ga, indicating that they are I-type granites and were derived from partial melting of ancient lower crustal materials. They have variable mineral components and geochemical features, corresponding extensive fractionation of hornblende, biotite and feldspar, with minor fractionation of apatite. Existence of mafic microgranular enclaves in the biotite granites suggests a magma mixing/mingling process for the origin of the Lingshan granitoids, and mantle-derived mafic magmas provided the heat for felsic magma generation. In contrast, the Nb-Ta mineralized albite granites and pegmatites have distinct mineral components and geochemical features, which show that they are highly-fractionated granites with extensive melt and F-rich fluid interaction in the generation of these rocks. The fluoride-rich fluids induce the enrichment in Nb and Ta in the highly evolved melts. Therefore, we conclude that the Nb-Ta mineralization is the result of hydrothermal process rather than crystal fractionation in the Lingshan pluton, which provides a case to identify magmatic and hydrothermal processes and evaluate their relative importance as ore-forming processes.  相似文献   

20.
Ore-forming porphyries and barren granitoids from porphyry Cu deposits differ in many ways, particularly with respect to their adakitic affinity and calc-alkaline characteristics. In this study, zircon U–Pb and molybdenite Re–Os dating, whole rock geochemistry, whole rock Sr–Nd–Pb and zircon O–Hf isotopic analyses were carried out on the ore-forming granitoids from the Kounrad, Borly and Sayak deposits, and also on pre-ore and post-ore granitoids in adjacent regions of Central Kazakhstan. Geochronology results indicate that pre-ore magmatism occurred in the Late Devonian to Early Carboniferous (361.3–339.4 Ma), followed by large scale Cu mineralization (325.0–327.3 Ma at Kounrad, 311.4–315.2 Ma at Borly and 309.5–311.4 Ma at Sayak), and finally, emplacement of the Late Carboniferous post-ore barren granitoids (305.0 Ma). The geochemistry of these rocks is consistent with calc-alkaline arc magmatism characterized by strong depletions in Nb, Ta and Ti and enrichments in light rare earth elements and large ion lithophile elements, suggesting a supra-subduction zone setting. However, the ore-forming rocks at Kounrad and Sayak show adakitic characteristics with high Sr (517.5–785.3 ppm), Sr/Y (50.60–79.26), (La/Yb)N (9.37–19.62) but low Y (6.94–11.54 ppm) and Yb (0.57–1.07 ppm), whereas ore-forming rocks at Borly and barren rocks from northwest of Borly and Sayak have normal arc magma geochemical features. The Sr–Nd–Hf–O isotopic compositions show three different signatures: (1) Sayak granitoids have very young juvenile lower crust-derived compositions ((87Sr/86Sr)i = 0.70384 to 0.70451, ɛNd (t) = + 4.9 to + 6.0; TDM2 (Nd) = 580 to 670 Ma, ɛHf (t) = + 11.3 to + 15.5; TDMC (Hf) = 330 to 600 Ma, δ18O = 6.0 to 8.1‰), and were probably generated from depleted mantle-derived magma with 5–15% sediment melt addition in the magma source; (2) the Kt-1 granite from northwest of Sayak shows extremely enriched Sr–Nd isotopic compositions ((87Sr/86Sr)i = 0.71050, ɛNd (t) = − 7.8, TDM2 (Nd) = 1700 Ma), likely derived from partial melting of ancient continental crust; (3) other granitoids have transitional Sr–Nd compositions between the Sayak and Kt-1 samples, indicating a juvenile lower crust source with the addition of 10–30% of ancient crustal material. The pre-ore magmatism was probably related to partial melting of juvenile lower crust due to northward subduction of the Junggar–Balkhash Ocean, whereas the ore-forming adakitic rocks at Aktogai, Kounrad and Sayak formed by partial melting of thickened lower crust which subsequently delaminated. The ore-forming rocks at Borly, and the later post-ore barren granites, formed by partial melting of juvenile lower crust with normal thickness. This tectonic setting supports the existence of an Andean-type magmatic arc in the Devonian to the Late Carboniferous, resulting from the subduction of the Junggar–Balkhash oceanic plate. The link between whole rock geochemistry and scale of mineralization suggests a higher metallogenic potential for adakitic rocks than for normal arc magmatism.  相似文献   

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