共查询到20条相似文献，搜索用时 312 毫秒
1.
辉锑矿中稀土及多元素地球化学特征 总被引：3，自引：0，他引：3
锑矿床和微细浸染型金矿床中辉锑矿的稀土元素地球化学指标对比分析,表明锑矿床中辉锑矿稀土元素含量低于金矿床中含金辉锑矿。锑矿床中辉锑矿的ＬＲＥＥ／ＨＲＥＥ小于金矿中含金辉锑矿。从辉锑矿的多元素地球化学特征的分析,认为金矿床中辉锑矿主元素锑含量较低,富含金、银、砷杂质元素,而锑矿床中辉锑矿的锑含量较高,金、银、砷含量较低。利用辉锑矿稀土元素及杂质元素地球化学特征,可间接或直接评价微细浸染型金矿床。 相似文献
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双道氢化物原子荧光法同时测定天然水中痕量的砷和锑 总被引：4，自引：0，他引：4
在天然水、(湖水、井水和泉水等)中经常有一定量的砷和锑存在,而其含量变化则与金矿床、锑矿床及多金属矿床有密切的关系,因此在水化学测量中砷和锑是极为重要的探途元素。水化学测量与水系沉积物测量相似,而某些元素可能在水中形成的异常比水系沉积物更宽阔,成为区域化探中更易找到目标的找矿手段[1]。同时文献[2]指出水化学找矿法也是找寻盲矿体的有效方法。 相似文献
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粉末压片-波长色散X射线荧光光谱法测定金矿型构造叠加晕样品中18种次量元素 总被引：1，自引：1，他引：0
金矿床型构造叠加晕样品中的砷锑铋银锡钨等金属元素含量对金矿多期次多阶段成矿具有指示意义。此类样品采集于金矿中,样品各元素含量范围大,从克吨级至百分之几,分布也不均匀。采用常规的检测方法分析时,存在元素间干扰不易消除、记忆效应严重等问题。本文建立了粉末压片-波长色散X射线荧光光谱法测定金矿型构造叠加晕样品中砷锑铋等18种次量元素的定量分析方法。通过研究角度扫描图,选择了干扰少、强度高的分析线;充分混匀样品,消除了偏析效应;选用与样品基体类似的国家标准样品建立工作曲线,通过数学校正和内标法校正了谱线重叠干扰和基体效应。方法检出限为0. 14～2. 23μg/g,精密度(RSD,n=12)小于4%。本方法可快速、准确地测定金矿床型构造叠加晕样品中各元素的含量。 相似文献
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花山锑金矿床位于皖南东至县境内, 是皖南地区代表性金-多金属矿床之一。 本次工作对花山锑金矿床开展了野外地质、岩相学特征观察以及金属硫化物电子探针分析, 得到以下结论：1） 花山锑金矿床主要成矿阶段可分为毒砂-黄铁矿（PyⅠ）阶段、黄铜矿-黄铁矿 （PyⅡ）阶段和方解石-辉锑矿阶段。 2） 金在不同阶段硫化物中均有赋存, 其矿化伴随整个热液成矿过程, 且以毒砂-PyⅠ阶段和黄铜矿-PyⅡ阶段为主。 毒砂-PyⅠ阶段和黄铜矿-PyⅡ阶段发育金矿化, 无锑矿化, 方解石-辉锑矿阶段发育锑、金共生矿化。 3） 早阶段即毒砂 -PyⅠ阶段和黄铜矿-PyⅡ阶段载金矿物为黄铁矿、毒砂及黄铜矿, 成矿物质来源以地层为 主;晚阶段即方解石-辉锑矿阶段载金矿物为辉锑矿, 成矿物质来源以燕山期岩浆岩为主。 本次工作对东至及皖南地区金矿床的寻找勘探具有重要的指示意义。 相似文献
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龙王江锑砷金矿床具明显的层控特征,空间分布严格受构造控制,褪色蚀变带是矿床赋存的重要标志,矿化主要与毒砂化和硅化有关。原生晕综合异常是成矿作用的地球化学标志。矿石中的金、砷含量呈正相关,金和砷的相关系数近于1。毒砂可作为寻找锑砷金矿床的标型矿物,而砷则是其标型地球化学指示元素。成矿作用是在中低温(330—178℃)条件下进行的,硫同位素组成具变质还原硫特点。该矿属于与元古界浅变质岩有关的变质热液型金矿床。 相似文献
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广东河台金矿中Se和Te及其找矿意义 总被引：1，自引：0，他引：1
本文研究了河台金矿Se和Te的地球化学特征。金矿中Se和Te一般作为矿化剂出现,是金矿床中常见元素。尽管Se、Te作为金矿指示元素已有一些报道,但多缺乏系统性。文中研究了河台金矿矿床矿体、围岩及土壤中Se、Te分布特征,初步搞清了Se、Te与金矿化的关系,指出了Se,Te的找矿意义和进一步找矿的方向。 相似文献
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老豆金矿床是西秦岭夏河—合作矿集区典型金矿床之一。本文通过显微镜下观察和电子探针分析,确认矿石中存在黄铁矿、毒砂、方铅矿、闪锌矿、辉锑矿、辉锑铅矿、脆硫锑铅矿、块硫锑铜矿、方黝锡矿等多种矿物,确定老豆金矿成矿金属元素组合为Au-As-Sb-Cu-Pb-Zn,根据金元素含量特点判断金元素主要以超显微纳米级自然金(Au0)和固溶体金(Au+)的形式附存于闪锌矿等载金矿物中,方黝锡矿等还原性矿物特征指示矿床形成于氧逸度较低,硫逸度较高的还原环境中。 相似文献
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一地质依据我国的金矿床类型很多,而金与黄铁矿、黄铜矿,毒砂等矿物共生的金矿床占大多数,这对应用核物探x射线荧光法寻找金矿,十分有利。由于携带式x射线荧光仪能在野外现场直接测定铜、砷、铅、锌、汞、锑、钨、硒、铋等元素的含量变化规律,并利用其相关关系,则可在野外立即圈定金矿远景区及其隐伏矿体,从而达到勘查金矿的目的。 相似文献
10.
新疆查汗沙拉锑矿床地质特征及成因初探 总被引：1，自引：0，他引：1
新疆察汗萨拉锑矿床位于西南天山中部的萨阿尔明晚古生代沟弧带的西段,它与萨瓦亚尔顿金锑银矿、卡拉脚古牙锑金矿、古勒克达坂卡堤锑金矿构成察汗萨拉锑金矿带。矿区总体受控于一大型逆冲推覆构造带,处于查汗沙拉锑异常区浓集中心域内,矿体产于阿尔腾克斯组含炭碎屑岩中,显示多元素多期次的成矿特征。成矿物质来自于赋矿地层,成矿热液则是由岩浆水和天水组成的混合水,属沉积改造型锑银多金属矿床。 相似文献
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高岭土作为重要的铝硅酸盐,其微量元素的含量决定着高岭土产品的性能指标.高岭土的三种国家标准物质成分GBW03121、GBW03122、GBW03122a中均未含有As、Sb等10种微量元素的标准值,在高岭土的检测中只能采用近似的岩石标准物质作为监控物质,对高岭土组分的准确分析有一定影响.本文通过微波消解技术,对比了硝酸... 相似文献
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Environmental geochemistry of high arsenic groundwater at Hetao plain was studied on the basis of geochemical survey of the
groundwater and a core sediment. Arsenic concentration in groundwater samples varies from 76 to 1093 μg/L. The high arsenic
groundwater mostly appears to be weakly alkaline. The concentrations of NO3− and SO42− are relatively low, while the concentrations of DOC, NH4+, dissolved Fe and sulfide are relatively great. Analysis of arsenic speciation in 21 samples shows that arsenic is present
in the solution predominantly as As(III), while particulate arsenic constitutes about 10% of the total arsenic. Methane is
detected in five samples with the greatest content being 5107 μg/L. The shallow aquifer in Hangjinhouqi of western Hetao plain
is of strongly reducing condition. The arsenic content in 23 core sediment samples varies from 7.7 to 34.6 mg/kg, with great
value in clay and mild clay layer. The obvious positive relationship in content between Fe2O3, Mn, Sb, B, V and As indicates that the distribution of arsenic in the sediments may be related to Fe and Mn oxides, and
the mobilization of Sb, B and V may be affected by similar geochemical processes as that of As. 相似文献
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The alleged reputation of the horsetail (Equisetum) as an accumulator of gold was studied by analysis of a number of specimens from various localities, mainly from Nova Scotia. None of the samples had appreciable gold concentrations but with one exception, all the specimens collected from auriferous ground had high concentrations of arsenic ranging up to 738 μg/g dry mass. To a lesser extent this was also true for antimony. The evidence tends to refute the previous belief that horsetails accumulate gold, but does show that the genus is not only tolerant of arseniferous ground but is also an arsenic accumulator. Because of the common geochemical association of gold and arsenic, it is suggested that analysis of horsetails for arsenic may be a useful prospecting tool where geologic or other evidence suggests the possible presence of auriferous ground. 相似文献
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通过电感耦合等离子体质谱法测定化探样品中As的分析方法,利用1:1王水在沸水浴中溶矿,用ICP-MS直接测定。方法的检出限为0.0113μg/g,精密度RSD%小于3%,用国家标准物质验证的结果与标准值一致。方法简便快速,适合应用于大批量化探样品中As的测定。 相似文献
18.
In this paper a porcedute of pyrohydrolysis spectrophotometric determination has been established for chlorine in rocks and minerals. The selection of accelerator and its required quantity, the time and temperature of sample decomposition and the influence of interferring elements and other factors are also discussed in detail. Because samples are usually fused with alkalis, higher blank is an insurmountable problem. However, with our procedure, the above-mentioned drawback can be effectively overcome, and the determination of trace chlorine either in large or in minor quantities of samples also is rather ideal. The determined results indicate that the relative standard deviations are 8.7% in the former and 4.5% in the latter case. This procedure is simple, rapid and well reproduceable. The detection limit of the method is 10 ppm. The results obtained by our procedure are in good agreement with the proposed values from two reference samples in China (DZΣ-1 and DZΣ-2) and one international geochemical reference sample (RGM-1). This method has proved itself to be reliable. 相似文献
19.
Reliable Determination of Ge in Solid Environmental Samples Using a Chemical Preparation Procedure Developed for Si Isotopes and ICP‐MS Analysis 
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下载免费PDF全文 Camille Delvigne Bernard Angeletti Abel Guihou Isabelle Basile‐Doelsch Jean‐Dominique Meunier 《Geostandards and Geoanalytical Research》2018,42(1):139-149
Germanium (Ge) exists at trace levels in the Earth's crust and is a powerful geochemical tracer of the silicon (Si) cycle. This study proposes a simple and reliable method for determining Ge contents in environmental samples using ICP‐MS. As Si and Ge have very similar chemical properties, we investigated the applicability of the chemical preparation procedure developed for Si isotopes for the determination of Ge in environmental samples. Advantages of this procedure are as follows: (a) efficient removal of the matrix and main interferences affecting Ge determinations by ICP‐MS, (b) a low limit of detection (6 ng l?1), (c) relative repeatability of approximately 3% obtained on 74Ge and (d) robustness and accuracy based on agreement within errors with the published Ge values for rock reference materials (BHVO‐2, AGV‐2 and BCR‐2). This procedure allowed revision of the Ge values of three soil reference materials (1.67 ± 0.09 μg g?1, 2.41 ± 0.18 μg g?1, 1.89 ± 0.10 μg g?1 for GBW 07401, GBW 07404 and GBW 07407, respectively) and proposal of a value for the plant reference material ERM‐CD281 (70 ± 3 μg g?1). This method provides a convenient procedure for determining Ge mass fractions in environmental samples and opens the possibility of coupling two tracers of the Si biogeochemical cycle with a single measurement procedure. 相似文献
20.
The behavior of arsenic and antimony at Pezinok mining site,southwestern part of the Slovak Republic
Renata Flakova Zlatica Zenisova Ondra Sracek David Krcmar Ivana Ondrejkova Martin Chovan Bronislava Lalinská Miriam Fendekova 《Environmental Earth Sciences》2012,66(4):1043-1057
Arsenic and antimony contamination is found at the Pezinok mining site in the southwest of the Slovak Republic. Investigation of this site included sampling and analysis of water, mineralogical analyses, sequential extraction, in addition to flow and geochemical modeling. The highest dissolved arsenic concentrations correspond to mine tailings (up to 90,000 μg/L) and the arsenic is present predominately as As(V). The primary source of the arsenic is the dissolution of arsenopyrite. Concentration of antimony reaches 7,500 μg/L and its primary source is the dissolution of stibnite. Pore water in mine tailings is well-buffered by the dissolution of carbonates (pH values between 6.6 and 7.0) and arsenopyrite grains are surrounded by reaction rims composed of ferric iron minerals. Based on sequential extraction results, most solid phase arsenic is in the reducible fraction (i.e. ferric oxyhydroxides), sulfidic fraction, and residual fraction. Distribution of antimony in the solid phase is similar, but contents are lower. The principal attenuation mechanism for As(V) is adsorption to ferric oxide and hydroxides, but the adsorption seems to be limited by the competition with Sb(V) produced by the oxidation of stibnite for adsorption sites. Water in mine tailings is at equilibrium with gypsum and calcite, but far from equilibrium with any arsenic and antimony minerals. The concentrations of arsenic and antimony in the surrounding aquifer are much lower, with maximum values of 215 and 426 μg/L, respectively. Arsenic and antimony are transported by ground water flow towards the Blatina Creek, but their loading from ground water to the creek is much lower compared with the input from the mine adits. In the Blatina Creek, arsenic and antimony are attenuated by dilution and by adsorption on ferric iron minerals in stream sediments with resulting respective concentrations of 93 and 45 μg/L at the site boundary south of mine tailing ponds. 相似文献