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1.
Roland Stalder Andreas Kronz Klaus Simon 《Contributions to Mineralogy and Petrology》2008,156(5):653-659
The incorporation of hydrogen in enstatite in a hydrous system containing various amounts of NaCl was investigated at 25 kbar.
The hydrogen content in enstatite shows a clear negative correlation to the NaCl-concentration in the system. The most favourable
explanation is the reduction of water fugacity due to dilution. Other reasons for the limited hydrogen incorporation at high
NaCl levels, such as a significant influence of Na+ on the defect chemistry or an exchange between OH- and Cl−in enstatite, appear much less important. A partition coefficient D
Na
En/Fluid = 0.0013 could be determined, demonstrating that Na is less incompatible in enstatite than H. The new results support the
idea that dissolved components have to be considered when the total hydrogen storage capacity in nominally anhydrous minerals
is estimated, especially in geological settings with high levels of halogens, such as subduction zones. 相似文献
2.
Engineering activities lead to the anthropogenic transformation of engineering–geological conditions in different areas of Russia. A differential estimate has been made for changes in individual components of engineering–geological structures: relief, upper section soils, underground waters, depth of seasonal soil freezing and thawing, and current geological processes. The general integrated evaluation of the anthropogenic transformation of engineering–geological megastructures in Russia has been made on the basis of differential estimates of the components. 相似文献
3.
《Applied Geochemistry》2001,16(11-12):1377-1386
The heavy metal contamination and seasonal variation of the metals in soils, plants and waters in the vicinity of an abandoned metalliferous mine in Korea were studied. Elevated levels of Cd, Cu, Pb and Zn were found in tailings with averages of 8.57, 481, 4,450 and 753 mg/kg, respectively. These metals are continuously dispersed downstream and downslope from the tailings by clastic movement through wind and water. Thus, significant levels of the elements in waters and sediments were found up to 3.3 km downstream from the mining site, especially for Cd and Zn. Enriched concentrations of heavy metals were also found in various plants grown in the vicinity of the mining area, and the metal concentrations in plants increased with those in soils. In a study of seasonal variation on the heavy metals in paddy fields, relatively high concentrations of heavy metals were found in rice leaves and stalks grown under oxidizing conditions rather than a reducing environment (P<0.05). 相似文献
4.
The Guanajuato epithermal district is one of the largest silver producers in Mexico. Mineralization occurs along three main vein systems trending dominantly northwest–southeast: the central Veta Madre, the La Luz system to the northwest, and the Sierra system to the east. Mineralization consists dominantly of silver sulfides and sulfosalts, base metal sulfides (mostly chalcopyrite, galena, sphalerite, and pyrite), and electrum. There is a broad zonation of metal distribution, with up to 10 % Cu+Pb+Zn in the deeper mines along the northern and central portions of the Veta Madre. Ore occurs in banded veins and breccias and as stockworks, with gangue composed dominantly of quartz and calcite. Host rocks are Mesozoic sedimentary and intrusive igneous rocks and Tertiary volcanic rocks. Most fluid inclusion homogenization temperatures are between 200 and 300 °C, with salinities below 4 wt.% NaCl equivalent. Fluid temperature and salinity decreased with time, from 290 to 240 °C and from 2.5 to 1.1 wt.% NaCl equivalent. Relatively constant fluid inclusion liquid-to-vapor ratios and a trend of decreasing salinity with decreasing temperature and with increasing time suggest dilution of the hydrothermal solutions. However, evidence of boiling (such as quartz and calcite textures and the presence of adularia) is noted along the Veta Madre, particularly at higher elevations. Fluid inclusion and mineralogical evidence for boiling of metal-bearing solutions is found in gold-rich portions of the eastern Sierra system; this part of the system is interpreted as the least eroded part of the district. Oxygen, carbon, and sulfur isotope analysis of host rocks, ore, and gangue minerals and fluid inclusion contents indicate a hydrothermal fluid, with an initial magmatic component that mixed over time with infiltrating meteoric water and underwent exchange with host rocks. Mineral deposition was a result of decreasing activities of sulfur and oxygen, decreasing temperature, increasing pH, and, in places, boiling. 相似文献
5.
Two types of persistent extreme weather events, the cold–wet spell (CWS) and the persistent wet-freezing event (PWFE), are defined by considering the persistence of both extreme low temperature (ELT) and precipitation. Regional CWS and PWFE are identified based on temporal persistence and spatial contiguity of single-station-based CWS event and PWFE, respectively. Relevant factors are further discussed to reveal the features of spatial distribution and temporal variability of such events. The results indicate that: (1) station-based CWSs are mostly observed in southern China, especially in eastern part of southwest China and south China. PWFEs are relatively frequently observed immediate south of middle reach of the Yangtze River. Both CWS and PWFE of longer duration are frequently observed in the northern part of the Yunnan–Guizhou Plateau. Further analyses indicate that the occurrence of these events in southern China is positively related to elevation. (2) A total of 48 regional CWSs and 21 regional PWFEs are identified during cold season over 1951–2011 in China. The long-lasting ELT and rainy (snowy)/freezing condition render the event in southern China in 2008, the most severe one in the last five decades. (3) Precipitation is the limitation condition for the occurrence of CWS and PWFE in northern China, while ELT is the dominant factor for CWS and PWFE in southern China. 相似文献
6.
Debris flow occurs frequently in mountainous regions in China. Because of the difficulties involved in predicting and catching
live debris flows, an assessment of the potential for debris flow is crucial in hazard mitigation. Magnitude–frequency (MF)
relations are of special significance in such assessments. In previous studies, MF relations have been inferred by analyzing
environmental factors and historical records and using empirical relations. This paper is concerned with the derivation of
MF relations at regional and valley scales, using a large database of statistics. At the regional scale, it is represented
by the distribution of the valley area, because the area is often taken to indicate the potential magnitude of debris flow.
Statistics from over 5,000 debris flow valleys in various provinces in China show that a power law holds for the distribution,
i.e., p(A) ∼ A
−n
, where p(A) is the percentage of valleys with area A and n varies with region and thus describes regional differences. At the valley scale, a case study focusing on Jiangjia Gully
(JJG) was conducted, and the MF relations derived from it were expressed by the distributions of discharge and runoff (i.e.,
the total volume) of living debris flows observed over the last 40 years. The distributions can be expressed as exponential
functions where the exponents vary with the events. These MF relations provide not only a potential quantitative reference
for practical purposes but also hint at the intrinsic properties of the debris flow. 相似文献
7.
Evacuations represent an integral aspect of protecting public safety in locations where intense, fast-spreading forest fires
co-occur with human populations. Most Canadian fire management agencies have as their primary objective the protection of
people and property, and all fire management agencies in Canada recommend evacuations when public safety is in question. This
study provides the first national assessment of wildfire-related evacuations in Canada and documents the loss of homes that
coincided with evacuation events. The most striking finding is that despite the intensity and abundance of wildfire in Canada,
wildfires have displaced a relatively small number of people. Between 1980 and 2007, the median number of evacuees and home
losses per year in Canada were 3,590 and 2, respectively. Evacuees’ homes survived in 99.3% of cases. Patterns of evacuations
and home losses reflected the distributions of forests, wildfire, and people across the Canadian landscape. Most evacuations
occurred in boreal areas, which have relatively low population densities but among the highest percent annual area burned
in Canada. Evacuations were less common in southern parts of the country, where most Canadians reside, but individual wildfires
in these areas had significant impacts. Interactions between wildfire and people in Canada exhibited a unique regional pattern,
and within the most densely populated regions of the country they can be considered ‘low-probability, high-consequence’ events.
This Canadian context is fundamentally different from places such as California, where concentrations of fires and people
overlap across large areas and therefore calls for a fundamentally different fire management response. 相似文献
8.
We carried out experiments on crystallization of Fe-containing melts FeS2Ag0.1–0.1xAu0.1x (x = 0.05, 0.2, 0.4, and 0.8) with Ag/Au weight ratios from 10 to 0.1. Mixtures prepared from elements in corresponding proportions were heated in evacuated quartz ampoules to 1050 ºC and kept at this temperature for 12 h; then they were cooled to 150 ºC, annealed for 30 days, and cooled to room temperature. The solid-phase products were studied by optical and electron microscopy and X-ray spectroscopy. The crystallization products were mainly from iron sulfides: monoclinic pyrrhotite (Fe0.47S0.53 or Fe7S8) and pyrite (Fe0.99S2.01). Gold–silver sulfides (low-temperature modifications) are present in all synthesized samples. Depending on Ag/Au, the following sulfides are produced: acanthite (Ag/Au = 10), solid solutions Ag2–xAuxS (Ag/Au = 10, 2), uytenbogaardtite (Ag/Au = 2, 0.75), and petrovskaite (Ag/Au = 0.75, 0.12). They contain iron impurities (up to 3.3 wt.%). Xenomorphic micro- (<1–5 μm) and macrograins (5–50 μm) of Au–Ag sulfides are localized in pyrite or between the grains of pyrite and pyrrhotite. High-fineness gold was detected in the samples with initial ratio Ag/Au ≤ 2. It is present as fine and large rounded microinclusions or as intergrowths with Au–Ag sulfides in pyrite or, more seldom, at the boundary of pyrite and pyrrhotite grains. This gold contains up to 5.7 wt.% Fe. Based on the sample textures and phase relations, a sequence of their crystallization was determined. At ~1050 ºC, there are probably iron sulfide melt L1 (Fe,S ? Ag,Au), gold–silver sulfide melt L2 (Au,Ag,S ? Fe), and liquid sulfur LS. On cooling, melt L1 produces pyrrhotite; further cooling leads to the crystallization of high-fineness gold (macrograins from L1 and micrograins from L2) and Au–Ag sulfides (micrograins from L1 and macrograins from L2). Pyrite crystallizes after gold–silver sulfides by the peritectic reaction FeS + LS = FeS2 at ~743 ºC. Elemental sulfur is the last to crystallize. Gold–silver sulfides are stable and dominate over native gold and silver, especially in pyrite-containing ores with high Ag/Au ratios. 相似文献
9.
Acta Geotechnica - This paper proposes and validates a thermo-mechanical ratcheting mechanism that explains the cumulative displacement of soil–continuum interfaces when subjected to... 相似文献
10.
Klaus Kost 《GeoJournal》1998,46(4):285-291
The number of Anti-Semitic opinions found in geographical and geopolitical literature gives evidence of a wide-spread hostility towards Jews before 1945. Only very few critical dissidents branded Anti-Semitism as propaganda of political rightists. The extent to which Anti-Semitism served as an ideological bridge between geography and geopolitics in Germany till 1945 must be established. But independent from geopolitics, there are lots of proof for an autochthonously developed Anti-Semitism among German university geographers long before geopolitics was created. All in all geopolitics had no innovative effect on the research and the theory of political geography in Germany till 1945. Its main topics, epistemological premises and methodological apparatus grew on the substratum of authochthonous traditions created in the 19th century. Geopolitics only takes up basic reflections that already exist. 相似文献
11.
The incorporation of OH defects in quartz from the systems quartz–water, quartz–albite–water and granite–water at pressures between 5 and 25?kbar and temperatures between 800 and 1,000?°C was investigated by IR spectroscopy. The two most important OH absorption features can be assigned to hydrogarnet defects (absorption band at 3,585?cm?1) and coupled substitutions involving Al3+ (Al–H defects, absorption bands at 3,310, 3,378 and 3,430?cm?1). Al incorporation in quartz is controlled by mineral/melt partitioning (D Al Qz/Melt ?=?0.01) and exhibits a negative pressure dependence. This trend is not clearly reflected by the concentration of Al–H defects, which shows positive deviations from the theoretical 1:1 correlation of Al/H for some samples. In contrast to the Al–H defects, formation of hydrogarnet defects appears to be positively correlated to pressure and water activity, and may be used a petrological indicator. The overall water concentration exhibits only minor changes with pressure and temperature, but a clear correlation of water activity (controlled by various amounts of dissolved salts) and hydrogarnet substitution could be established. 相似文献
12.
Spatial variations in the relationship between topography and mean annual and seasonal rainfalls in southwestern Saudi Arabia are examined using Kruskal–Wallis one-way analysis of variance. The topographic factors include physiographic features (topography), altitude, slope, proximity to a ridge or crest of mountains, and proximity to the Red Sea. There is a statistically significant effect of topographic factors on the mean annual rainfall, but the results are more significant for the mean seasonal rainfall. The largest amount of mean rainfall in the study area occurs during spring, when rainfall displays a significant relationship with topographic factors, in which more orographic rainfall patterns are associated with higher altitude, greater proximity to a ridge and steeper slopes. Higher altitudes do not necessarily receive more rain; some low altitude locations (i.e., the southern part of the study area) receive more rain during summer and fall because they are located on the windward side of the Asir Mountains and are exposed to the moist air masses brought by the southwest monsoonal system in summer and by the northwest air flow from the Mediterranean and Red Sea in the fall in addition to local convective rainfall patterns. Rainfall in winter increases in the foothills of the Asir Mountains above the coastal plain of the Red Sea. The steep western slopes (windward side) receive more rainfall than the gentle eastern slopes (leeward side): this may be due to the Asir Mountains forcing moist air masses carried by the westerly and northwest winds to rise and cool before they descend and warm on the leeward side. 相似文献
13.
The data of rogue wave accidents reported in mass media during 2006–2010 years are collected and analysed. The collection
includes 106 events, which are classified by their validity as true (78) and possible (28) and by the location of their occurrence:
we distinguish deep, shallow and coastal rogue waves, which occurred in deep/shallow waters or at the coast. The validity
of the event has been estimated by the rogue wave height, which should be twice larger than the significant wave height (significant
wave height has been taken from satellite data), and/or by the associated hazard. It is shown that rogue waves cause especially
high damage in shallow waters and at the coast. 相似文献
14.
Batch and flow-through experiments were performed on quartz–feldspar granular aggregates at hydrothermal conditions (up to ≈150 °C, up to 5 MPa effective pressure, and near-neutral pH) for up to 141 days. The effect of dissolution–precipitation reactions on the surface morphology of the mineral grains was investigated. The starting materials as well as the solids and fluids resulting from the experiments were characterized using BET, energy dispersive X-ray spectroscopy, electron microprobe analysis, inductively coupled plasma-optical emission spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, and X-ray fluorescence spectroscopy. The electrical conductivity of fluid samples was used as a proxy for the evolution of the fluid composition in the experiments. The chemical analyses of the fluids in combination with hydrogeochemical simulations with PHREEQC suggested the precipitation of Al–Si-bearing solid phases. Electron microscopy confirmed the formation of secondary amorphous Al–Si-bearing solid phases. The microscopic observations are consistent with a process of stoichiometric dissolution of the mineral grains, transport of dissolved ions in the fluid phase, and spatially coupled precipitation of sub-μm sized amorphous particles on mineral surfaces. These findings shed light onto early stages of diagenesis of quartz–feldspar sands and indicate that amorphous phases may be precursors for the formation of crystalline phases, for example, clay minerals. 相似文献
15.
A.B. Kampunzu J.L.H. Cailteux A.F. Kamona M.M. Intiomale F. Melcher 《Ore Geology Reviews》2009,35(3-4):263-297
Stratabound epigenetic sulphide Zn–Pb–Cu ore deposits of the Central African Copperbelt in the Democratic Republic of Congo and Zambia are mostly hosted in deformed shallow marine platform carbonates and associated sedimentary rocks of the Neoproterozoic Katanga Supergroup. Economic orebodies, that also contain variable amounts of minor Cd, Co, Ge, Ag, Re, As, Mo, Ga, and V, occur mainly as irregular pipe-like bodies associated with collapse breccias and faults as well as lenticular bodies subparallel to bedding. Kipushi and Kabwe in the Democratic Republic of the Congo and Zambia, respectively, are the major examples of carbonate-hosted Zn–Pb–Cu mined deposits with important by-products of Ge, Cd, Ag and V in the Lufilian Arc, a major metallogenic province famous for its world-class sediment-hosted stratiform Cu–Co deposits. The carbonate-hosted deposits range in age from Neoproterozoic to early Palaeozoic (680 to 450 Ma). The formation of the relatively older Neoproterozoic deposits is probably related to early collision events during the Lufilian Orogeny, whereas the younger Palaeozoic deposits may be related to post-collisional processes of ore formation. Fluid inclusion and stable isotope data indicate that hydrothermal metal-bearing fluids evolved from formation brines during basin evolution and later tectonogenesis. Ore fluid migration occurred mainly along major thrust zones and other structural discontinuities such as karsts, breccias and faults within the Katangan cover rocks, resulting in ore deposition within favourable structures and reactive carbonates of the Katangan Supergroup. 相似文献
16.
Abhishek Moharana Anurag Mishra Deepak C. Srivastava 《International Journal of Earth Sciences》2013,102(7):1837-1849
The Main Central Thrust demarcates the boundary between the Lesser Himalaya and the Higher Himalaya in the Himalayan orogen. Several definitions of the Main Central Thrust have been proposed since it was originally described as the southern boundary of the crystalline rocks (the Main Central Thrust mass) in the Kumaun-Garhwal Himalaya. The long-held contention that the Munsiari Thrust represents the Main Central Thrust has been negated by recent isotopic studies. One way to define the Main Central Thrust is that it is a ductile shear zone that is delimited by the Munsiari Thrust (MCT-I) in south and the Vaikrita Thrust (MCT-II) in north. The alternative proposition that the Vaikrita Thrust represents the Main Central Thrust is fraught with practical limitations in many parts of the Himalaya, including the study area. In the metamorphic rocks bounded between the Vaikrita Thrust and the Munsiari Thrust, the isoclinal folds of the earliest phase are routinely ascribed to the pre-Himalayan orogeny, whereas all subsequent folding phases are attributed to the Himalayan orogeny. This article elucidates the structural characteristics of the kilometre-thick Munsiari Thrust Zone and revisits the issue of pre-Himalayan orogenic signatures in the thrust zone. With the help of high-resolution field mapping and the analyses of mesoscopic scale structures, we demonstrate that the Munsiari Thrust is a typical fault zone that is made up of a fault core and two damage zones. The fault core traces the boundary between the quartzite and the biotite-gneiss. The damage zones consist of the low-grade metasedimentary rocks in the footwall and the gneiss-migmatite in the hanging wall. The entire fault zone shares an essentially common history of progressive ductile shearing. Successively developed mesoscopic folds trace various stages of progressive ductile shearing in the damage zones. Two recognizable stages of the shearing are represented by the early isoclinal folds and the late kink folds. As the strain during progressive deformation achieved the levels that were too high for accommodation by ductile flow, it was released by development of a tectonic dislocation along a mechanically weak boundary, the Munsiari Thrust. The isoclinal folds and the Munsiari Thrust were developed at different stages of a common progressive deformation during the Himalayan orogeny. Contrary to the popular notion of consistency with respect to orientation, the stretching lineations show large directional variability due to distortion during the late folding. 相似文献
17.
This study addresses the long-term trends in heat-related mortality across 29 US metropolitan areas from 1975 to 2004 to discern
the spatial patterns and temporal trends in heat vulnerability. Mortality data have been standardized to account for population
trends, and seasonal and interannual variability. On days when a city experienced an “oppressive” air mass, mean anomalous
mortality was calculated, along with the likelihood that oppressive days led to a mortality response at least one standard
deviation above the baseline value. Results show a general decline in heat-related mortality from the 1970s to 1990s, after
which the decline seems to have abated. The likelihood of oppressive days leading to significant increases in mortality has
shown less of a decline. The number of oppressive days has stayed the same or increased at most metropolitan areas. With US
homes near saturation in terms of air-conditioning availability, an aging population is still significantly vulnerable to
heat events. 相似文献
18.
Y. Be’eri-Shlevin Y. Katzir J. Blichert-Toft I. C. Kleinhanns M. J. Whitehouse 《Contributions to Mineralogy and Petrology》2010,160(2):181-201
Multi-isotope study including whole-rock Nd–Sr, single zircon Hf, and SIMS δ18O analyses of zircons sheds light on magma sources in the northernmost Arabian–Nubian Shield (ANS) during ~820–570 Ma. Reconnaissance
initial Nd and Sr isotope data for the older rocks (~820–740 Ma) reaffirms previous estimates that early crustal evolution
in this part of the shield involved some crustal contamination by pre-ANS material. Prominent isotope provinciality is displayed
by post-collisional calc-alkaline and alkaline igneous rocks of ~635–570 Ma across a NW-SE transect across basement of the
Sinai Peninsula (Egypt) and southern Israel. Silicic rocks of the NW-region are characterized by lower εNd(T)–εHf(T) and higher
Sri and δ18O compared with rocks of the SE-region, and the transition between the regions is gradual. Within each region isotope ratios
are independent of the extent of magma fractionation, and zircon cores and rims yield similar δ18O values. Comparison with southern segments of the ANS shows that the source for most ~635–570 Ma rocks can be modeled as
the isotopically aged lower-intermediate crust in the ANS core (SE-region) and its northern, more contaminated ANS margins
(NW-region). Nevertheless, Nd–Sr isotope enrichment of the lithospheric mantle is indicated by some basic magmas of the NW-region
displaying the most enriched Nd–Sr isotope compositions. Comparison of Nd and Hf depleted mantle model ages for rocks of the
SE-region may indicate that crustal formation events in the ANS geographical core took place at 1.1–1.2 Ga and were followed
by crustal differentiation starting at ~0.9 Ga. 相似文献
19.
L. G. Bragina 《Stratigraphy and Geological Correlation》2016,24(6):575-601
Radiolarian paleobiogeography for the late Albian–Santonian is proposed for the first time. The paleobiogeographic differentiation is found to be different for the Albian, Cenomanian, Turonian, and Coniacian–Santonian. The Tethyan and Boreal superrealms can be recognized for the Albian–Santonian. For the Albian–Santonian, the Tethyan Superrealm can be subdivided into realms: Atlantic-Mediterranean, Carpathian-Caucasian, and Tropical-Pacific. The boundaries of these realms changed throughout geological time. The Boreal Superrealm recognized for the Albian so far cannot be subdivided into realms, whereas in the Cenomanian it included the East European and Western Siberian realms without a clear definition of the boundaries and the Boreal-Pacific (in the North Pacific). The Boreal Superrealm is subdivided in the Turonian into two realms (European-Western Siberian and Boreal-Pacific), and in the Coniacian–Santonian, it is subdivided into three realms (European, Western Siberian, and Boreal-Pacific). The Austral Superrealm can be recognized only for the Albian and Cenomanian, and because of the lack of data, it cannot be delineated for the Turonian and Coniacian–Santonian. 相似文献
20.
《China Geology》2018,1(2):236-256
The continent of China is grouped into Pan–Cathaysian blocks, Laurasia and Gondwana Continental margins and relics of three oceans-Paleoasian, Tethys, and Pacific as a whole. In detail, the continent of China grew up by coalescence of three blocks or platforms (North China, Tarim and Yangtze) and eight orogenic belts (Altay–Inner Mongolia–Daxinganling, Tianshan–Junggar–Beishan, Qinling–Qilian– Kunlun, Qiangtang–Sanjiang, Gangdisê, Himalaya, Cathaysia, Eastern Taiwan) during the processes of oceanic crust disappearance and acceretionary-collision of continental crusts. In the orogenic belts, six convergent crustal consumption zones (Ertix–Xar Moron, South Tianshan, Kuanping–Foziling, Bangong co–Shuanghu–Nujiang–Changning–Menglian, Yarlung–Tsangpo, Jiangshao–Chenzhou–Qinfang) have been distinguished. Correspondingly, the strata of the continent of China are subdivided into 17 tectonic-strata superregions, which tectonically belong to three blocks or platforms, six convergent crustal consumption zones and eight orogenic series, respectively. This division is based mainly on differences of tectonic environment and tectonic evolution among blocks, zones and belts, including the timing of when the oceanic crusts transferred into continental crusts, the paleobiogeographic features, and the types of strata. 相似文献