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1.
天然紫晶与合成紫晶的鉴别是国内外珠宝鉴定实验室的一个难题,前人主要从双晶、色带、包裹体、红外吸收光谱特征等方面开展了研究。在利用红外光谱鉴别天然紫晶与合成紫晶时,不同的学者尚对3595cm-1或3543cm-1吸收峰作为诊断性还是指示性的判据存在不同认识。本文系统采集了典型的天然紫晶与合成紫晶样品,研究了利用红外光谱测试技术鉴别天然紫晶与合成紫晶的局限性,并尝试将偏振拉曼光谱应用于紫晶成因鉴别。结果表明:利用3595cm-1、3543cm-1红外吸收峰进行紫晶鉴别仅具有指示性意义,不能作为决定性的判定依据,偏振拉曼光谱可作为重要的补充。天然紫晶的偏振拉曼光谱(偏振方向:HH)均出现400cm-1的拉曼峰,而该峰在合成紫晶偏振拉曼光谱中缺失;合成紫晶的偏振拉曼光谱(偏振方向:HH)均具有795cm-1、448cm-1的拉曼峰,而这两个峰在天然紫晶偏振拉曼光谱中缺失。偏振拉曼光谱产生差异的原因可能与天然紫晶和合成紫晶内部晶格变形程度的不同有关。本文揭示的400cm-1、448cm-1和795cm-1偏振拉曼峰可作为鉴别紫晶成因的新依据。 相似文献
2.
天然萤石的热释光研究 总被引：1，自引：1，他引：1
本文对采自国内11个萤石矿床的萤石样品,进行了系统的天然和人工热释光测试研究,探讨了有关萤石热释光特征与成因类型、杂质成分、颜色等之间的关系。 相似文献
3.
无色-近无色高温高压合成钻石的谱图特征及其鉴别方法 总被引：4，自引：4，他引：0
实验室发现大量小颗粒的无色高温高压(HPHT)合成钻石与天然钻石混杂镶嵌在各种饰品中,前人提出荧光和磷光特征是主要的快速区分特征,然而荧光、磷光特征的差异并不能完全将HPHT合成钻石与天然钻石区分开来。本文将常规的宝石学观察分析与多种高精度谱学测试相结合,对五粒不同的无色-近无色HPHT合成钻石样品进行深入研究。结果表明,五粒钻石在紫外可见吸收光谱无270 nm吸收或是只有极弱的270 nm吸收,随着颜色级别的降低,270 nm吸收越明显。红外光谱测试显示,各粒样品中都含有不等量的硼元素。光致发光光谱测试表明,HPHT合成钻石含有与微量N、Ni、Si等相关的晶格缺陷。超短波紫外光源激发下,所有的HPHT合成钻石都有强磷光,在钻石观察仪下可以观测到清晰的八面体和立方体分区特征。显然,不同的合成钻石的特征略有差异,但综合其荧光及磷光特征以及红外、紫外、光致发光光谱特征,可以准确地将无色HPHT合成钻石与对应的天然钻石区分开来。 相似文献
4.
铍扩散处理是一种较新的刚玉处理方法,目前在国内还未见相关的实验研究报道。运用类质同象替代原理与扩散原理,以焰熔法合成无色刚玉和山东天然蓝宝石为实验对象,在一定的温度环境下,加入适量的BeO或金属Be粉末及其它添加剂,进行了铍扩散处理实验。实验结果显示,样品的颜色色调及浓度有明显的改善,表明铍扩散处理可以使样品的颜色变为粉红色、黄色和橙红色,也可以使山东天然蓝宝石样品的颜色变浅。 相似文献
5.
天然宝石和合成宝石的鉴别标志 总被引：1，自引：0，他引：1
张传荣 《矿物岩石地球化学通报》1989,(3)
宝石可分为四类:天然宝石(包括处理宝石)、合成宝石、人造宝石和假宝石。自然界中已发现的矿物约3100种,可作为宝玉石的天然矿物有230种(包括它们的种、变种、族).比较重要的近百种,如钻石、红蓝宝石,祖母绿、海蓝宝石、紫晶、翡翠、绿松石等。合成宝石是一种与天然矿物相应的人工复制品,具有相同的化学成分和物理性质。主要种类有合成的钻石、红蓝宝石、祖母绿、尖晶石、绿松石、黄玉、水晶、蛋白石、孔雀石等. 相似文献
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7.
天然含钒金红石样品经过1273K加热、淬火和高能电子辐照处理后性质发生不同程度的变化。XRD谱峰显示处理前后样品没有发生物相变化，显微IR图谱证明原样、加热、淬火样品的表面有少量吸附水存在，而辐射样品的显微IR图谱上没有检测到吸附水的吸收峰。用XPS分析比较了处理前后样品表面主要元素Ti、O和V的价态及含量，结果表明，原样经过处理后表面钒和氧的原子百分含量增加，其中淬火样品表面吸附水和钒的含量相对于原样增加最为明显，光催化活性相应较高；加热样品表面的吸附水和钒的含量比原样稍有增加，光催化活性与原样相当；电子辐射样品表面钒的原子百分含量相对原样增加不明显，而对水的吸附能力相对原样较低，光催化效率也略低。 相似文献
8.
研究了天然土壤样品热释光测量最佳条件。天然样品热释光测量强度与升温区间、升温速率及仪器灵敏度有关。在不同的地质条件下分别采集样品(北方砂岩,南方花岗岩及重庆滑坡),通过测量,对发光曲线进行对比分析,确定了几种不同地质条件下天然土壤样品热释光测量最佳条件。 相似文献
9.
第四纪沉积物天然热释光测量方法技术研究——山东草桥油田研究实例 总被引：13，自引：0，他引：13
第四纪沉积物天然热释光测量是一种累积间接油气勘查新方法。文中给出了首次系统研究的成果 ,从数百个样品中总结出的适用油气勘探的预热线形升温、恒温最佳加热程序 ,升温速率以 β=6℃ /s为宜 ,恒温温度 40 0℃ ,40 0℃恒温时间为 12s。在沉积物辐射剂量响应及日光晒退实验数据的基础上 ,总结了样品采集、预处理及测量方法。通过对山东草桥油田第四纪沉积物天然热释光与游离气烃野外实测资料的分析 ,发现天然热释光异常与气烃异常完全吻合 ,在油水边界上方 ,热释光、甲烷、乙烷出现高值异常 ,油田上方是低值带 ,为串珠状异常模式。热释光最大值为 2 0 4.2 μGy ,平均值为 79.45μGy ,标准差为 3 4 .14 μGy ;甲烷浓度异常下限为 2 5μL/L ,乙烷浓度异常下限为 4.4μL/L。 相似文献
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11.
In natural amethyst samples subjected to shock pressures between 10 and 50 GPa (1 GPa=109 Pa), thermoluminescence (TL) was observed after subsequent X-ray irradiation, in some cases even without high energy irradiation. The glow curves could be decomposed into at most five components of Gaussian shape, but no reliable activation energies could be determined from them, perhaps due to a wide distribution of trap depths. With increasing shock pressures traps of higher thermal stability were favored. Emission bands with maxima near 14000 cm?1 were observed independent of shock pressure. They appear to be characteristic of defects created during the shock events, but it is uncertain whether the observed TL is connected with the iron impurities characteristic for amethyst. In natural amethyst samples of the same origin no TL could be observed, even after additional X-ray irradiation. It is concluded that TL in amethysts reported in the literature was actually caused by defects associated with aluminium impurities, not by destruction of Fe4+. 相似文献
12.
S. Karampelas E. Fritsch T. Zorba K. M. Paraskevopoulos S. Sklavounos 《Mineralogy and Petrology》2005,85(1-2):45-52
Summary The infrared absorption spectrum of amethyst in the region of stretching vibrations of X–OH groups reveals several bands that
have been used for the separation of natural from synthetic amethyst. The intensity and shape of these bands have been measured
as a function of crystallographic orientation. Using a resolution of 0.5 cm−1 the 3595 cm−1 band is present in all infrared spectra of natural amethyst and in some rare synthetic ones. If present in synthetic amethyst,
its full width at half maximum (FWHM) is about 7 cm−1 whereas it is about 3 cm−1 in all natural samples. This new criterion, unlike the previous ones, seems appropriate to separate natural from synthetic
amethyst in all cases. 相似文献
13.
采用显微观察、红外光谱、可见吸收光谱和低温光致发光谱等分析方法,对9颗俄罗斯高温高压处理钻石样品进行了研究。结果表明,该类钻石样品的内部多见石墨化现象,尤以彩色钻石样品更明显;金黄色、紫红色、黄绿色样品为ⅠaAB型,浅黄色样品为ⅠaB型,近无色样品为Ⅱa型;样品的可见吸收光谱因颜色不同而差异显著,其中金黄色样品可见475 nm处的吸收宽带,紫红色样品可见638,614,595 nm处的吸收峰,黄绿色和浅黄色样品可见415,475,503 nm处的吸收峰,近无色样品则为较光滑的平直曲线。此外,该类样品在低温光致发光谱中可见575 nm与637 nm处强发光峰。这些特征为探讨该类钻石的晶格缺陷与呈色机理提供了一定的科学依据。 相似文献
14.
球粒陨石的冲击作用与热释光特征研究 总被引：1，自引：0，他引：1
测定了我国部分球粒陨石的自然热释光峰温、峰半高宽度和灵敏度, 强冲击型陨石的热释光灵敏度偏低,峰温、峰半高宽温度则偏高。岩庄陨石属天然冲击球粒陨石,具有强烈的冲击特征。测定岩庄陨石两种不同颜色冲击脉体的热释光,其强度明显地不一样,并发现该陨石的热释光具有β辐照诱发热释光位移和退火热释光位移现象。冲击作用明显地改变着热释光的各种特性。 相似文献
15.
Thermoluminescence, electron paramagnetic resonance and optical absorption properties of rhodonite, a natural silicate mineral,
have been investigated and compared to those of synthetic crystal, pure and doped. The TL peaks grow linearly for radiation
dose up to 4 kGy, and then saturate. In all the synthetic samples, 140 and 340°C TL peaks are observed; the difference occurs
in their relative intensities, but only 340°C peak grows strongly for high doses. Al2O3 and Al2O3 + CaO-doped synthetic samples presented several decades intenser TL compared to that of synthetic samples doped with other
impurities. A heating rate of 4°C/s has been used in all the TL readings. The EPR spectrum of natural rhodonite mineral has
only one huge signal around g = 2.0 with width extending from 1,000 to 6,000 G. This is due to Mn dipolar interaction, a fact proved by numerical calculation
based on Van Vleck dipolar broadening expression. The optical absorption spectrum is rich in absorption bands in near-UV,
visible and near-IR intervals. Several bands in the region from 540 to 340 nm are interpreted as being due to Mn3+ in distorted octahedral environment. A broad and intense band around 1,040 nm is due to Fe2+. It decays under heating up to 900°C. At this temperature it is reduced by 80% of its original intensity. The pink, natural
rhodonite, heated in air starts becoming black at approximately 600°C. 相似文献
16.
A. Bluszcz 《Quaternary Science Reviews》1988,7(3-4)
The paper presents some preliminary results of studies carried out in the Gliwice TL Lab. A set of 10 samples of mineral grains separated from natural sediments of different age and origin was investigated in order to find whether the optical bleaching used for reducing NTL causes the change of thermoluminescence sensitivity. The laboratory bleaching was performed using natural sunlight and artifical light from the mercury lamp. Additional results completed during the TL dating by the regeneration method are also included. In most cases the changes in sensitivity are not significant. 相似文献
17.
Javier Garcia-Guinea E. Crespo-Feo V. Correcher J. Rubio M. V. Roux P. D. Townsend 《Physics and Chemistry of Minerals》2009,36(8):431-438
Natural hydrothermal ZnCO3 crystal aggregates are nominally anhydrous phases with interfacial water, with substitutional divalent cations and decarbonation
c. 300°C. All these common features must be involved during the experimental heating of a thermoluminescence (TL) glow curve
up to 500°C: dehydration–dehydroxylation, phase transition and ion transition of point defects in Zn2+ positions. A representative specimen of natural smithsonite was analysed by X-ray fluorescence spectrometry, field emission
scanning electron microscopy (FESEM) with a chemical probe of energy dispersive spectrometer, high temperature in situ X-ray
diffraction, differential scanning calorimetry, differential thermal analyses coupled to thermogravimetry, TL, radioluminescence
and high resolution spectra thermoluminescence (3DTL), to gain an overview of the spectra emission and defects linkages modified
by heating from room temperature up to 500°C. The ZnCO3 specimen contains minor amounts of Ca, Cu, Cr, Cd, Pb, Ce, Co, Ni, Mn and Fe. Under FESEM, it displays CaCO3 clusters and oscillatory zoning distribution with lamellae ranging from Ca0.11Zn0.89 to Ca0.19Zn0.81. The analytical results suggest assignments of defects and processes to measured 3DTL emission bands, as follows: (1) peak
at ~260°C, ~360 nm bonds, breaking during the thermal decarbonation process; (2) peak ~120°C, ~340 nm: non-bridging oxygen
centres associated to a complex dehydration–dehydroxylation process and (3) peak at ~170°C, ~650 nm, crystal field effects
on the thermoluminescence of Mn2+ centres and associated transitional elements in the ZnCO3 phase.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
18.
本文指出紫晶目前在市面上的地位和它具有的作用,对紫晶的矿物成分、化学成分、物理性质及其晶系与内部显微结构等宝石学特征作了简明而系统的论述,阐明了紫晶与合成紫晶、紫色方柱石、紫色萤石等相似宝石的区别标志． 相似文献