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1.
Exposures in many quarries in southern India exhibit field evidence for incipient charnockitization of tonalitic and granitic gneiss (prograde relationship), or retrogression of charnockite to produce tonalitic gneiss (retrograde relationship). Few systematic geochemical relationships exist between adjacent gneisscharnockite sample pairs during either prograde or retrograde reactions. Most elements and element ratios exhibit inconsistent variations; however, prograde chamockites appear enriched in Ta, Pb, volatiles (chiefly CO2), and in transition metals relative to Mg, and depleted in REE and Y compared to adjacent gneiss protoliths. Retrograde gneisses have higher Rb, Pb, Th, Hf, Zn relative to Co, Nb relative to Ta, Hf relative to Zr, and volatiles (chiefly H2O) compared to parental charnockites. Of those elements (U, Th, Rb, Cs, Pb) significantly depleted in high-pressure charnockites exposed south of the prograde transition zone, only Pb is significantly replenished during retrogression. Evidence suggests that prograde fluids are relatively rich in CO2 and retrograde fluids in H2O and that the typical non-systematic geochemical variations during prograde and retrograde reactions reflect local effects at the wave front.  相似文献   

2.
Origin of granites in an Archean high-grade terrane,southern India   总被引：4，自引：0，他引：4  
Archean deep-level granites in southern India are similar geochemically to young granites from continentalmargin arc systems. They exhibit light REE enriched patterns with variable, but chiefly positive Eu anomalies. This is in striking contrast to the negative Eu anomalies typical in high-level Archean granites. In addition, the deep-level granites are relatively enriched in Ba and Sr and depleted in total REE and high field strength elements (HFSE). One pluton, the Sankari granite, has unusually low contents of REE and HFSE. Most of the deep-level granites appear to represent cumulates with variable amounts of trapped liquid and of minor phases, resulting from fractional crystallization of a granitic parent. Such parental granitic magmas can be produced by batch melting of Archean tonalite at middle to lower crustal depths. The Sankari granite requires a tonalitic source depleted in REE and HFSE. Archean tonalites and tonalitic charnockites exhibit original igneous geochemical signatures and their average composition does not show a significant Eu anomaly. Hence, they cannot represent the positive Eu-anomaly complement to the negative Eu-anomaly, high-level granites. Our results suggest that Archean deep-level granites may represent this complement. Such granite may form in waterrich zones in the middle or lower crust and be produced in response to dehydration of the lower crust by a rising CO2-rich fluid phase.  相似文献   

3.
Archaean granulites from the type charnockite locality of Pallavaram, Madras City, Tamil Nadu, southern India consist of a bimodal suite of basic and silicic orthogneisses, associated with metasedimentary gneisses (khondalites). Charnockite is the dominant rock type. Basic granulites display a tholeiitic trend of strong iron enrichment accompanied by an increase in the concentration of the rare earth elements (REE), and the development of appreciable negative europium anomalies. These trends are considered to reflect low pressure fractional crystallisation of pyroxene-plagioclase assemblages under conditions of lowf O 2. Ultramafic granulites may represent the cumulus material of such a process. The silicic granulites (charnockites) are generally K2O rich and in marked contrast to the low K2O (tonalitic) silicic gneisses which dominate most granulite facies terrains. Their REE abundances, however, embrace the complete range of patterns observed in both K-rich and K-poor Archaean gneisses. The presence of a large number of pre-granulite facies potassic pegmatites in the area suggests metasomatism of an originally less potassic suite of rocks. Trace element considerations lead to a model whereby metasomatism and partial fusion of silicic gneisses in the terrain preceded the granulite facies metamorphic event. This sequence of events is best related to fluctuations in the composition of metamorphic fluids in the lower crust.  相似文献   

4.
Geological mapping and zircon U–Pb laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) dating has identified a Mesoarchean (2857 ± 17 Ma) geological unit in the Luanjiajie area of the northern margin of the North China Craton, within the northern part of Liaoning Province, China. This unit is dominated by tonalitic and trondhjemite gneisses that form part of a typical tonalite–trondhjemite–granodiorite (TTG) rock assemblage. These Mesoarchean gneisses are enriched in Na and depleted in K, yield K2O/Na2O ratios of 0.34–0.50, have Rittmann index (σ) values of 1.54–3.04, and are calc-alkaline. They have EuN/EuN* values of 0.77–1.20 (average of 1.03), indicating that these samples have negligible Eu anomalies, and yield high LaN/YbN values (4.92–23.12). These characteristics indicate that these Mesoarchean gneisses have fractionated rare earth element (REE) compositions that are enriched in the light REE (LREE) and depleted in the heavy REE (HREE), with steeply dipping chondrite-normalized REE patterns. These gneisses are also enriched in Rb, Th, K, Zr, and Hf, and are relatively depleted in Ta, Nb, P, and Ti. In summary, the magma that formed these tonalitic and trondhjemite gneisses was most likely derived from the partial melting of lower-crustal basaltic rocks during subduction. The timing of formation (2.85 Ga) of the Luanjiajie tonalite and trondhjemite gneisses probably represents the timing of initiation of plate tectonics within the LongGang Block during a SE-directed subduction event. The presence of inherited zircons with ages of >3.0 Ga within the Luanjiajie gneisses suggests that this area may contain as yet undiscovered rocks that formed before 3.0 Ga.  相似文献   

5.
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6.
《Geochimica et cosmochimica acta》1999,63(13-14):2071-2088
Twenty-three clastic metasediments from the Kongling high-grade terrain of the Yangtze craton, South China were analyzed for major, trace and rare earth elements and Sm-Nd isotopic ratios. Associated dioritic-tonalitic-trondhjemitic (DTT) and granitic gneisses as well as amphibolites were also analyzed in order to constrain provenance. The results show that the clastic metasediments can be classified into 3 distinct groups in terms of mineralogical, geochemical and Sm-Nd isotopic compositions. Group A is characterized by having no to slight negative Eu anomalies (Eu/Eu1 = 0.82–1.07), being high in Cr (191–396 ppm) and Ni (68–137 ppm), and low in Th (3.3–7.8 ppm) and REE (ΣREE = 99–156 ppm). These characteristics are similar to those of metasediments from Archean greenstone belts. In addition, the Group A metasediments have the value of the Chemical Index of Alteration (CIW) close to felsic gneisses. Their Sm-Nd isotopic, REE and trace element compositions can be interpreted by mixtures of the DTT gneisses and amphibolites. Dating of detrital zircons from 2 Group A samples by SHRIMP reveals a major concordant age group of 2.87–3.0 Ga, which is identical to the age of the trondhjemitic gneiss. These results strongly suggest that Group A was principally the first-cycle erosion product of the local Kongling DTT gneiss and amphibolite. Moreover, the higher than amphibolite Cr content and slight Eu depletion exhibited by some samples from this group infer that ultramafic rocks like komatiite and granite of probably 3.0–3.3 Ga in age also played a role.Group B is characterized by the presence of graphite and shows a more evolved composition similar to post-Archean shales with a prominent negative Eu anomaly (Eu/Eu1 = 0.48–0.77) and high CIW. On paired Cr/Th vs La/Co and Co/Th plots, Group B samples conform to a two-end member mixing line of the Kongling granitic gneiss and amphibolite. However, data on Nd model age and CIW suggest that the granite component should be younger than the sampled granitic gneiss and derived from a distal source.Both Groups A and B exhibit a clear positive correlation between CIW and TDM and a negative one between CIW and Eu/Eu1. These correlations point to the crustal evolution of the Yangtze craton towards coupled increasing CIW and Eu depletion with decreasing age. This in turn reflects the change of granitoid magmatism from local Na-rich dioritic-tonalitic-trondhjemitic rocks to widespread K-feldspar granite. The change led to the intracrustal differentiation, stabilization and growth of the craton.Group C is restite and contains abundant sillimanite and garnet and unusually high ilmenite (7–11vol%), which can be seen to be dehydration melting products of biotite under the microscope. This group shows extremely varied REE distributions from LREE enriched to depleted and from negative to strong positive (Eu/Eu1 = 1.63) Eu anomalies. Compared to Groups A and B, Group C is severely depleted in Na2O, K2O, LREE, Rb and Ba, whereas TiO2, Co, V, Sc and HREE and Y are considerably enriched. This is accompanied by anomalous high Sm/Nd (0.21–0.28), 147Sm/144Nd (0.1361–0.1738) and 143Nd/144Nd (0.511589–0.511958) ratios. TDM correlates clearly with Sm/Nd ratio and 2 out of 3 samples give significantly older to unrealistic TDM (3.9–4.9 Ga). The results document redistribution of REE and an open behavior of the Sm-Nd isotope system during the biotite dehydration melting of metasediments.  相似文献   

7.
The Eastern Ghats Granulite Belt (EGGB) forms part of a continuous Precambrian metamorphic terrain in Gondwana. It is characterised by widespread development of an Archaean khondalite suite of metasedimentary rocks, Archaean to Late-Proterozoic charnockites and Late Proterozoic anorthositic, granitic and syenitic emplacements. A 1900 Ma megacrystic granitoid suite, containing varying proportions of charnockites and granites, forms an important and widely distributed litho-unit in the central khondalite and eastern migmatite zones of the EGGB. It contains metasedimentary enclaves, megacrystic K-feldspar, quartz, plagioclase ovoids, biotite, garnet (porphyroblasts and coronas), apatite, zircon, ilmenite, magnetite, etc. Hypersthene is present in the charnockite phase. Monazite is present in some garnet-free granites. It is characterised by low Na2O/K2O ratios, high alumina saturation index, CaO, MgO, and ÝREE, negative correlation of TiO2, Al2O3, Fe2O3t, MgO, MnO, CaO, P2O5, Ba, Sr, Zr and V with SiO2, positive correlation of K2O, REE, Th and Rb with SiO2, fractionated LREE, relatively flat HREE and negative Eu anomalies.The data suggest S-type nature of the suite. Fractionation of the granitic magma and local variations in pH2O and fCO2 caused the formation of megacrystic charnockites. Formation of the corona garnet is related to the reworking of the suite during late Proterozoic (ca. 1250 Ma) isothermal decompression associated with channelised CO2-rich fluid flux along narrow shear zones.  相似文献   

8.
A suite of crustal xenoliths from Tertiary basaltic tuffs of the Northern Hessian Depression (NHD) volcanic field comprises abundant meta-igneous pyroxene granulites of mafic, noritic to anorthositic, IAT and tonalitic composition. Less abundant are granitic, tonalitic and leucogranitic gneisses and metasedimentary xenoliths. A total of 49 samples were analyzed for modal compositions, for major and trace elements (including Li, Rb, Sr, Ba, Cs, V, Sc, Cr, Co, Ni, Y, Zr, Nb, Ta, Hf, Th and REE) and oxygen isotopes. Two-pyroxene thermometry yields temperatures between 700 and 900° C for mafic and noritic granulites. Feldspar thermometry indicates temperatures of 660°–710° C for tonalitic granulites and 470°–520° C for granitic and tonalitic gneisses. One highly depleted sillimanite-rich metasediment contains cordierite and garnet which have equilibrated at temperatures of 780° C. The general lack of garnet in the mafic and noritic granulites and the presence of sillimanite in felsic xenoliths indicates that metamorphic pressures have not exceeded 10 kb. Major and trace element data and oxygen isotope compositions of the mafic granulites are compatible with an origin from spilitized enriched-type MORB rocks (enrichment in 18O to 11 and in Li to 34 ppm at average SiO2 contents of 44.1 wt%). These low-T spilites were transformed into amphibolites and then pyroxene granulites during subsequent high temperature metamorphic events. Low Si, Al, K, and Rb concentrations along with An contents in plagioclase ranging from near 50 to 98 mole percent suggest that amphibolite facies protoliths have generated tonalitic melts during partial melting at temperatures above 700° C. The mafic granulite xenoliths are interpreted as restites whereas the tonalitic samples probably represent the extracted partial melts derived by 20 to 30 percent degree of melting. Metasedimentary xenoliths strongly depleted in granitic component could represent restites from which granitic S-type partial melts have been extracted. Tonalitic and leucogranitic gneisses including one trondhjemite xenolith have many chemical characteristics (e.g. REE distribution) in common with tonalite-trondhjemite-granodiorite suites of the North Atlantic region but cannot be accounted for a more specific origin. Estimated elastic properties of the main types of NHD xenoliths yield P-wave velocities of 6.0–6.4 km-1 for granitic, tonalitic and trondhjemite gneisses including tonalitic granulites and 6.5–7.0 for the more mafic xenoliths. When compared with two seismic depths-Vp profiles these data are in accordance with a model where the mafic, andesitic, noritic and tonalitic granulites comprise abundant rock types at depths between 29 km (Moho) and 20 km which mainly consists of old oceanic crust including subduction related volcanic products. The more felsic xenoliths probably represent material from depths between 12 and 20 km.  相似文献   

9.
Summary Rare Earth Element (REE) data of 34 samples of magmatic rocks from the Lofoten Islands in Norway lend support to the derivation of anorthosites, ferrodiorites and jotunites by fractionation and cumulus processes from typical basaltic magma. Both REE concentration and Eu anomalies (expressed as Eu/Eu*) form continuous linear trends from anorthosite towards gabbro, ferrodiorite and jotunite in discrimination diagrams against molar CaO/Al2O3 ratios indicating the predominant accumulation of plagioclase. Eu/Eu* decreases from about 4 in the cumulates (anorthosites) to around 1 in the fine-grained gabbroic dikes and to below 1 in some ferrodiorites and the jotunite. The various types of ferrodiorites and the jotunite are regarded as residual liquids, in some cases with variable amounts of cumulus plagioclase. The whole fractionation series from gabbro towards anorthosites and ferrodiorites can be observed in a single intrusion. With increasing fractionation, the REE patterns generally change from flat, slightly LREE-enriched or LREE-depleted to steep and strongly LREE-enriched. These changes and the REE abundances are mainly controlled by the abundance of apatite. Temporally and spatially related mangerites and charnockites form a trend from low-SiO2 mangerites with Eu/Eu* > 1 to intermediate-SiO2 acidic mangerites with Eu/Eu* ≈ 1 and charnockites with Eu/Eu* < 1. Accordingly, the low-SiO2 mangerites are interpreted as alkali feldspar-rich cumulates and the charnockites as residual liquids derived from the acidic mangerites. The mangerites with Eu/Eu* around 1 have patterns similar to those of some highly evolved ferrodiorites possibly indicating a genetic link. Received December 12, 1999; revised version accepted November 15, 2000  相似文献   

10.
Seventeen rocks from the Lewisian Gneiss of the Inner Hebrides of Scotland, which represent three distinct lithological types at granulite to greenschist facies of metamorphism show rare-earth element patterns which seem not to have been disturbed by their complex metamorphic history. Some indication of their origin can be obtained by simple geochemical models.Three tonalitic pyroxene gneisses are characterized by: (1) light REE enrichment and heavy REE depletion; (2) low total REE contents; (3) moderate Eu enrichment. Their REE chemistry can be approximated by a model involving 10% partial melting of various garnet-bearing basaltic source materials. Alternatively, they may be some form of crystal cumulate, preserving their original anhydrous mineralogy, representing 30% crystallization of a parent tonalitic magma.Three tonalitic to granodioritic hornblende-biotite gneisses are characterized by: (1) light REE enrichment and heavy REE depletion; (2) significantly higher total REE contents than the pyroxene gneisses; (3) moderate Eu depletion. Their REE patterns can be approximated by a residual silicic melt in a model involving 30% fractional crystallization of solids with the modal mineralogy of the pyroxene gneisses or 40% removal of pure anorthosite from a parent dacitic magma.Two strongly metasomatised diopside-actinolite gneisses and one highly sheared epidote-chlorite gneiss have REE patterns which are not significantly different from the hornblende-biotite gneisses which were their precursors before metasomatism and late greenschist-facies shearing. This suggests that strong alteration has not enciphered the REE systematics of the gneisses.Basic gneisses of quartz tholeiite composition occurring as early dykes, which shared the same metamorphic history as the tonalitic to granodioritic gneisses, are characterised by: (1) slight enrichment in light REE relative to heavy REE; (2) variable total REE contents; (3) little difference between granulite and amphibolite facies types. Their REE patterns can be matched by models involving 5–15% partial melting of ultrabasic mantle with 3 times chondritic REE abundances, leaving a residue of olivine and orthopyroxene.  相似文献   

11.
Rock samples representing various igneous and metamorphic rocks of southern Obudu Plateau were analyzed for rare-earth element ( REE ) behavior by ICP-MS. Results of the analyses indicate a range of REE abundances and distinctive patterns from highly fraetionated patterns with negative Eu anomalies in granitic rocks to relatively low abundances and less REE fractionated flat patterns with little Eu anomaly in some paragneisses, schists, enderbites and dolerites to unfractionated patterns with positive Eu anomalies in some paragneisses and charnockites. Over all, there are low to high ∑ REE contents with negative to positive Eu anomalies. The ratios of different parameters, especially La/Yb and Ce/Yb, show behaviors consistent with crustal to mantle derivation. The heterogeneity of REE abundances and REE patterns reflects mantle to crustal petrogenetic variations of different rock suites on the Plateau. The LREE content is higher than the HREE content in the highly differentiated rocks, as evidenced by their La/Yb,Ce/Yb and La/Sm ratios, which are normally higher in residual products than in primary melts. The dominantly intermediate nature of the source rock of the orthogneisses is suggested by the generally low ∑ REE. The granites enriched in LREE and depleted in HREE and some of the charnockites with negative Eu anomalies were probably formed by partial melting and crystallization.  相似文献   

12.
Phlogopite-amphibole-pyroxenite xenoliths contained in the alkali basic-ultrabasic subvolcanic complex in Langao, Shaanxi Province, are composed of diopside, Ti-rich pargasite, phlogopite apatite, sphene and ilmenite, which have subsolidus metamorphism-deformation textures such as triple-points, cataclastic boundaries and kink-bands. Mineral chemical characteristics show that the diposide, Ti-rich paragasite and phlogopite are derived from the mantle and are the products of mantle metasomatism. Compared with normal mantle-derived spinel-lherzolites, the xenoliths are enriched in TiO2, Fe2O3, CaO, Na2O and K2O, with apparent depletion in MgO. Chondrite-normalized REE patterns and primordial-mantle normalized trace elements data show that they are enriched in REE (especially LREE) and incompatible trace elements. The petrographic, mineralogical and petrochemical characteristics indicate that the xenoliths are metasomatized mantle xenoliths, which offers the evidence for mantle metasomatism and represents the anomalous mantle beneath the Early Paleozoic rift in northern Daba Mountains. The agents of mantle metasomatism are probably derived from the rising of mantle hot plumes. The processes of metasomatism varied from limited-range fluid metasomatism in deep mantle (>90 km) to pervasive metasomatism of silicate melt. This project was financially supported by the National Natural Science Foundation of China (No. 49402035).  相似文献   

13.
孟恩  刘福来  刘建辉  施建荣 《岩石学报》2012,28(9):2793-2806
本文对辽东南长海地区花岗质片麻岩进行了系统的岩石学和地球化学研究,以便对其原岩性质及形成的构造环境给予制约。研究结果表明,研究区内花岗质片麻岩类可划分为富钠和富钾两类花岗质岩石,前者包括黑云二长花岗质片麻岩和花岗闪长质片麻岩,矿物组成主要包括斜长石、石英、黑云母及少量的钾长石等,后者则主要包括花岗质、二长花岗质和糜棱岩化花岗质片麻岩,其矿物组成以钾长石、斜长石、石英和次要的白云母和黑云母为主。地球化学分析结果显示,富钠花岗质片麻岩具有富硅、富钠、高铝、富集LREEs和LILEs、强烈亏损HREEs和HFSEs(Nb、Ta、P、Ti)、轻重稀土强烈分馏、并显示弱负Eu异常和Ba的相对亏损等特征;而富钾花岗质片麻岩则显示高硅、富钾、过铝质的地球化学属性、富集LREEs和LILEs、亏损HREEs和HFSEs,与富钠花岗质岩石相比,轻重稀土分馏程度相对较弱、HFSEs以及Ba相对于Rb和Th的亏损程度更强,并显示中等负Eu异常和强烈的Sr负异常等特征。上述特征表明,辽东南长海地区富钠花岗质片麻岩应起源于中酸性陆壳物质的部分熔融,并可能有玄武质物质的加入,原岩应为具有活动大陆边缘属性的花岗闪长岩,其形成应与狼林地块(或胶辽地块)东南及南部先存洋盆向陆块之下的俯冲作用相联系;而富钾花岗质片麻岩应形成于中酸性陆壳物质的部分熔融,原岩为具有碰撞型花岗岩属性的碱性花岗岩,其形成应与洋壳消减闭合、陆陆碰撞拼贴相联系。  相似文献   

14.
Abstract: The North granitic body of the Miyako pluton is located in the Northern Kitakami belt, Northeast Japan. The formation of the scheelite–chalcopyrite–magnetite–bearing aplitic veins and scheelite–chalcopyrite–magnetite–bearing Yamaguchi skarn deposit was closely associated with the formation of the Miyako plutons. Petrographic facies of the North granitic body vary from quartz diorite in marginal zone (zone A), to tonalite and granodiorite (zone B), and to granite (zone C) in the central. The large numbers of aplitic veins distributed around the Yamaguchi mining area are divided into two groups: barren and scheelite–mag–netite–chalcopyrite–bearing aplitic veins. The latter cut massive clinopyroxene skarns of the Yamaguchi deposit, and are composed of plagioclase, K‐feldspar and titanite. Some plagioclase crystals have dusty cores with irregularly shaped K‐feldspar flakes, and clear rims of albite. Textures of plagioclase in the mineralized aplitic veins are different from the idiomorphic textures with sharp plagioclase crystal boundaries that occur in the North granitic body and barren aplitic veins. These textural data suggest that the mineralized aplitic veins were formed from hydrothermal fluid. Changes in the contents of major and minor (Rb, Sr, Sc, Co, Th, U) elements in the North Miyako granitic body are similar to those of zoned plutons formed by typical magmatic differentiation processes. On the other hand, concentrations of REE, especially middle to heavy REE, of granitic rocks in zone C and barren aplitic veins are significantly lower than those of granitic rocks in zones A and B. The hypothetical chondrite‐normalized REE patterns, calculated assuming fractional crystallization from zone B granitic melt, suggest that REE concentrations of the residual melt increased with the degree of fractional crystallization, and changed into a pattern with enriched LREE and strongly negative Eu anomaly. However, the REE patterns of granitic rocks in zone C are different from the hypothetical patterns. Moreover, the REE patterns of magnetite–scheelite–chalcopyrite aplitic veins are quite different from those of granitic rocks. The Cu contents of granitic rocks in the North Miyako body increase from zone A (5–26 ppm) to zone B (10–26 ppm), and then clearly decrease to zone C (5–7 ppm) and drastically increase to the barren aplitic veins (39–235 ppm). Concentrations of Cu in the mineralized aplitic veins are also higher than those of the granitic rocks in zone C. The decrease in REE and Cu contents of granitic rocks from zone B to zone C is not a result of simple magmatic fractional differentiation. Fluid inclusions in quartz from mineralized aplitic veins contain 3.3 wt% NaCl equivalent and 5.8 wt% CO2. It was also demonstrated experimentally that the removal of MREE and HREE by fluid from melt enabled the formation of complexes of REE and ligands of OH‐ and CO32‐. Based on the possibility that the melt of the granitic rocks of zone C and the mineralized aplitic veins coexisted with CO2‐bearing fluid, it is thought that REE were extracted from the melt to the CO2‐bearing fluid, and that the REE in the mineralized aplitic veins were transported by the CO2‐bearing fluid. It is likely that the low HREE and Cu contents of the granitic rocks in zone C could have been caused by the removal of those elements from the granitic melt by the fluid coexisting with the melt. The expelled materials could have been the sources of scheelite–magnetite–chalcopyrite–bearing aplitic veins and copper mineralization of the Yamaguchi Cu‐W skarn deposit.  相似文献   

15.
Through detailed studies we have delineated a suite of banded TTG gneisses from the Zanhuang Complex. The protolith of the gneisses, predominantly tonalite, has undergone intensive metamorphism, deformation and anatexis and in a banded structure is intimately associated with melanocratic dioritic gneiss and leucocratic trondhjemitic veins. SHRIMP Zircon U–Pb data show that the tonalite was formed ca. 2692 ± 12 Ma ago. The tonalitic gneiss has the features of high SiO2 (67.76–73.31%), high Al2O3 (14.38–15.83%), rich in Na2O (4.48–5.07%) and poor in K2O (0.77–1.93%). The gneiss is strongly fractioned in REE ((La/Yb)N = 12.02–24.65) and shows a weak positive Eu anomaly (Eu/Eu* = 1.05–1.64). It has high contents of Ba (199–588 ppm) and Sr (200–408 ppm), low contents of Yb (0.32–1.00 ppm) and Y (3.41–10.3 ppm) with high Sr/Y ratios (21.77–96.77) and depletion in HFSE Nb, Ta and Ti. These characteristics are similar to those of the high-Si adakitic rocks. The melanocratic dioritic gneiss has low SiO2 (59.81%), high MgO (6.34%), high Al2O3 (14.02%) contents, rich in Na2O (3.7%) and poor in K2O (1.79%), with high Mg index (Mg# = 67). REE and trace elements are on the whole similar to that of the tonalitic gneiss, but compatible element abundances V (116 ppm), Cr (249 ppm), Co (37 ppm) and Ni (179 ppm) are higher. The leucocratic felsic bands (approximating trondhjemite in composition) have major oxides similar to that of the TTG gneisses but the REE and compatible elements are extremely low, which are indicative of the products of anatexis. The tonalitic gneiss has positive εNd(t) (2.37–3.29) and low initial Sr (0.69719–0.70068) values with depleted mantle Nd model age of ca. 2.8 Ga, suggesting its generation from partial melting of mantle-derived juvenile crust. The dioritic gneiss was also derived from subduction environment, but has undergone significant metasomatism of mantle wedge. The delineation of the ca. 2.7 Ga TTG gneisses in the Zanhuang Complex further proves that the North China Craton experienced large-scale continental crustal accretion in early Neoarchean, and gives new constraints on the subdivision of the early blocks and greenstone belts of the craton.  相似文献   

16.
戚学祥  齐金忠 《现代地质》2006,20(4):555-563
二云花岗片麻岩是组成苏鲁地体南缘超高压变质带朐山杂岩体的重要岩石类型,虽然经历了超高压变质作用,但仍保留了花岗岩的岩石学特征。常量元素和微量元素分析结果表明该片麻岩具有高w(K2O)、低w(CaO)、高w(TFeO)/w(MgO)比值、铝饱和指数偏高的A型花岗岩的特征,岩石类型为高钾碱性过铝质A型花岗岩。稀土元素中轻稀土富集、分馏程度高、Eu强烈亏损,微量元素中Ba、P、Ti、Sc具有明显的负异常,w(Sr)/ w(Y)、w(La)/ w(Yb)和w(Rb)/ w(Sr)、w(Rb)/ w(Ba)较高,尤其是w(TiO2)＜0.2％和w(Y)/ w(Nb)＞1.2的特征,以及在w(Rb)-w(Yb+Ta）和w(Rb)-w(Y+Nb）判别图解上样品投点位于板内环境区等,表明该片麻岩的原岩形成于板内与裂谷有关的非造山环境。锆石SHRIMP U-Pb测年结果揭示其侵位时代为新元古代中晚期((722±32）Ma）,与杂岩体中早期侵位的二长花岗片麻岩及杂岩体上覆地层中的变质火山岩同为Rodinia大陆裂解、扬子地块陆内裂谷形成过程中伴随的岩浆活动的产物。  相似文献   

17.
迁安紫苏花岗岩的稀土元素地球化学   总被引：5，自引：0，他引：5       下载免费PDF全文
迁安断块隆起或称迁安花岗岩片麻岩穹隆是冀东高级变质地体的一个重要组成部分,它的四周为大型古断裂所切割,仅在西侧保留了边缘褶皱束,在褶皱束内有同构造的或构造后的纵向断裂(钱祥麟,1981)。本文讨论的紫苏花岗岩,大致沿西部边缘褶皱束的纵向断裂分布。  相似文献   

18.
The charnockite patches that occur within leptynite host, in and around Jenapore, northern sector of the Eastern Ghats granulite belt, are disposed in a linear fashion and generally have sharp lithological contact with the host leptynite. Sometimes the patches and foliations of the host are cofolded. Also, the patches sometimes have the internalS 1 foliation, while the host leptynite records onlyS2 foliation. Mineralogically and chemically patchy charnockites and host leptynites are distinct entities, and cannot be related by any prograde and retrograde reactions. Particularly important is the peraluminous granitic composition and high Rb/Sr ratios of the leptynites, presumably resulting from biotite-dehydration melting; as against metaluminous granodioritic to tonalitic composition and low Rb/Sr ratios of the patchy charnockites, presumably resulting from hornblende-dehydration melting. The charnockite patches here can be interpreted as caught up patches or xenolith within granitic melt (leptynite). Mg-rich rims of garnet in the charnockite patch were probably caused by heat from the crystallising melt or decompression during ascent of melt.  相似文献   

19.
In progressing from a granitoid mylonite to an ultramylonite in the Brevard shear zone in North Carolina, Ca and LOI (H2O) increase, Si, Mg, K, Na, Ba, Sr, Ta, Cs and Th decrease, while changes in Al, Ti, Fe, P, Sc, Rb, REE, Hf, Cr and U are relatively small. A volume loss of 44% is calculated for the Brevard ultramylonite relative to an Al–Ti–Fe isocon. The increase in Ca and LOI is related to a large increase in retrograde epidote and muscovite in the ultramylonite, the decreases in K, Na, Si, Ba and Sr reflect the destruction of feldspars, and the decrease in Mg is related to the destruction of biotite during mylonitization. In an amphibolite facies fault zone separating grey and pink granitic gneisses in the Hope Valley shear zone in New England, compositional similarity suggests the ultramylonite is composed chiefly of the pink gneisses. Utilizing an Al–Ti–Fe isocon for the pink gneisses, Sc, Cr, Hf, Ta, U, Th and M-HREE are relatively unchanged, Si, LOI, K, Mg, Rb, Cs and Ba are enriched, and Ca, Na, P, Sr and LREE are lost during deformation. In contrast to the Brevard mylonite, the Hope Valley mylonite appears to have increased in volume by about 70%, chiefly in response to an introduction of quartz. Chondrite-normalized REE patterns of granitoids from both shear zones are LREE-enriched and have prominent negative Eu anomalies. Although REE increase in abundance in the Brevard ultramylonites (reflecting the volume loss), the shape of the REE pattern remains unchanged. In contrast, REE and especially LREE decrease in abundance with increasing deformation of the Hope Valley gneisses. Mass balance calculations indicate that ≥95% of the REE in the Brevard rocks reside in titanite. In contrast, in the Hope Valley rocks only 15–40% of the REE can be accounted for collectively by titanite, apatite and zircon. Possible sites for the remaining REE are allanite, fluorite or grain boundaries. Loss of LREE from the pink gneisses during deformation may have resulted from decreases in allanite and perhaps apatite or by leaching ofy REE from grain boundaries by fluids moving through the shear zone. Among the element ratios most resistant to change during mylonitization in the Brevard shear zone are La/Yb, Eu/Eu*, Sm/Nd, La/Sc, Th/Sc, Th/Yb, Cr/Th, Th/U and Hf/Ta, whereas the most stable ratios in the Hope Valley shear zone are K/Rb, Rb/Cs, Th/U, Eu/Eu*, Th/Sc, Th/Yb, Sm/Nd, Th/Ta, Hf/Ta and Hf/Yb. However, until more trace element data are available from other shear zones, these ratios should not be used alone to identify protoliths of deformed rocks.  相似文献   

20.
北大别东部大山坑片麻岩主要由钾长石、斜长石和石英组成,少量角闪石、黑云母和褐帘石,成分为二长花岗质。岩石以富碱（Na2O＋K2O）尤其是 K2O、贫Al2O3为特征,地球化学性质上表现为富集 K、Rb、Th、La、Ce等大离子亲石元素而亏损Nb、Ta、U等高场强元素及Sr元素,高的Ga含量、强的负Eu异常（δEu＝0．37）和相对较强的轻重稀土分馏程度（（La／Yb）N＝16．75）。岩石地球化学的总体特征与南大别水吼地区的 A型花岗片麻岩类似,意味着其原岩与南大别的 A型花岗片麻岩一样,可能也是在拉张状态下形成的一套偏碱性的花岗岩。该二长花岗片麻岩的锆石 U-Pb年龄为229．2±5．5 Ma,也与南大别超高压变质的年龄相似,指示北大别正片麻岩印支期可能也经历过超高压变质作用。南、北大别造山带可能具有相同的形成与演化历史,现南、北大别变质带之间的差异可能更多的是后造山历史不同,尤其是燕山期花岗岩侵入对两个带影响的不同造成的。  相似文献   

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