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1.
本文应用LAM-ICPMS技术测定了柴达木盆地北缘花岗片麻岩带中的锡铁山东全吉河花岗岩和都兰县北部沙柳河花岗岩的锆石U-Pb年龄,利用LAM-MC-ICPMS技术选择测定了沙柳河花岗岩锆石Hf同位素成分。全吉河花岗岩岩浆结晶锆石的谐和年龄为910 15/-17Ma;捕虏晶锆石的~(207)Pb/~(206)Pb年龄为1351Ma;~520Ma的变质锆石(~(232)Th/~(238)U=0.04) ~(206)Pb/~(238)U年龄可能是前高压超高压构造事件的产物。沙柳河花岗岩的岩浆锆石普遍含有继承碎屑锆石核。21个颗粒测得21个数据中,代表岩浆结晶锆石的10个点的Robust(Median)平均~(206)Pb/~(238)U年龄为920 31/-17Ma,碎屑锆石核~(207)Ph/~(206)Pb年龄大于1250Ma。在沙柳河花岗岩30颗锆石的30个Hf同位素分析点中,27个代表纯粹岩浆结晶锆石的~(176)Hf/~(177)Hf=0.282081~0.282222,平均0.282178 0.000009/-0.000015,以920Ma计算的Hf_1=0.28206~0.28220,平均值0.28215 /-0.00003;ε_(Hf)值的变化范围 0.21~-4.70,Robust(Median)加权平均值为-1.53 0.41/-0.52;锆石Hf的地壳模式年龄(T_(DM)~C)范围是1.59~1.75Ma,Robust(Median)加权平均值为1.68 0.03/-0.02Ma。其余2个锆石为继承性锆石,其~(176)Hf/~(177)Hf比值分别为0.281892和0.281792,Hf_1和ε_(Hf)值分别为0.28186~0.28178,和-11.83~-14.82,T_(DM)~C=2.18~2.33Ga。结合前人的研究结果,柴北缘花岗片麻岩的岩浆作用持续时间为~950Ma~~910Ma。峰值年龄为~920Ma,以沙柳河花岗岩为代表的柴北缘过铝S-型花岗片麻岩的岩浆来自现今剥露于地表的沙柳河岩群之下具高度再循环上地壳物质的基底表壳岩系;该物质的形成年龄可约束在1.4~1.7Ga,保存了蚀源区~1.7Ga和~2.3Ga的地壳增生事件的年代学记录。  相似文献   

2.
东昆仑早古生代花岗岩锆石U-Pb年龄及其地质意义   总被引:5,自引:0,他引:5  
应用激光烧蚀多接收器电感耦合等离子体质谱(LA-MC-ICPMS)方法,对东昆仑五龙沟地区花岗岩样品进行了锆石 U-Pb 定年研究。结果表明,黄龙沟中部的糜棱岩化二长花岗岩(B20-14)中岩浆锆石206Pb/238U年龄平均值为(417.7±2.0) Ma,黄龙沟上部的糜棱岩化二长花岗岩(B21-2)中岩浆锆石206Pb/238U年龄平均值为(419.7±2.3) Ma,深水潭粗中粒二长花岗岩(B20-8)中岩浆锆石206Pb/238U 年龄平均值为(419.9±2.0) Ma,红旗沟中部的粗中粒二长花岗岩(B25-9)岩浆锆石206Pb/238U年龄平均值为(419.0±2.0) Ma。它们代表了五龙沟地区所研究花岗岩的形成年龄,其形成时代均为晚志留世,记录了东昆仑早古生代的岩浆活动。本文获得的东昆仑五龙沟地区的晚志留世花岗岩可能与东昆仑早古生代洋盆闭合后的碰撞造山作用有关。花岗岩中1861 Ma、1666 Ma古元古代继承锆石的发现,表明东昆仑造山带的基底物质为古元古代。  相似文献   

3.
内蒙古林西县双井片岩北缘混合岩LA-ICPMS锆石U-Pb年龄   总被引:9,自引:0,他引:9  
内蒙古林西地区双井片岩北缘混合岩中的浅色体和暗色体锆石在阴极发光下均可观察到再生长边.浅色体中锆石的自形和生长环带显示其岩浆结晶锆石特征.LA-ICPMS分析结果显示其核部206Pb/238U加权平均年龄为270.2 Ma±1.4 Ma,边部年龄在250 Ma±3 Ma~266 Ma±3 Ma之间.暗色体中存在碎屑锆石和岩浆锆石,且显示不同程度的重结晶.碎屑锆石中除一颗锆石核部给出了3 377 Ma±7 Ma的207Pb/206Pb年龄外,其余变化于2 190 Ma±8 Ma~1 804 Ma±25 Ma;岩浆锆石核部和边部的206Pb/238U加权平均年龄分别为262.6 Ma±2.2 Ma和248.3 Ma±3.4 Ma;发生明显重结晶作用的锆石拟合的不一致线与谐和线的上、下交点年龄分别为2 112 Ma±350 Ma和256 Ma±17 Ma,与碎屑锆石和岩浆锆石的年龄分别对应.推测双井地区可能存在古元古代的结晶基底,在270.2 Ma±1.4 Ma发生岩浆活动,导致结晶基底的重熔以及混合岩化,随着岩浆的上升,温度和压力都不断降低,重熔的暗色体中在262.6 Ma±2.2 Ma结晶大量的锆石,由于岩浆的持续活动,这些先期结晶的锆石又受到不同程度的熔蚀并重结晶.暗色体被岩浆注入以后共同经历了一次热事件改造,形成了今天看到的双井地区混合岩的面貌.  相似文献   

4.
为探讨滇东南瑶山群的原岩年龄以及后期经历的岩浆-变质-构造事件年龄,开展了SHRIMP锆石U-Pb定年研究。结果表明,阴极发光(CL)分析和光学显微分析显示瑶山群的锆石组成比较复杂,可以分为继承锆石、变质锆石、深熔锆石/岩浆锆石等几大类。除少量测点207Pb/206Pb年龄为新元古代外,继承锆石206Pb/238 U表面年龄变化范围集中在235±1.7Ma~261±3.6Ma,加权平均值为250.8±9.8Ma(N=4,MSWD=4.1);深熔/岩浆锆石206Pb/238 U表面年龄显示出~85Ma和~75Ma两个峰值;变质增生锆石206Pb/238 U表面年龄为49~30Ma,且主要集中在32Ma、37Ma和42Ma左右。结合区域地质情况,初步推测:250.8±9.8Ma的继承锆石峰值年龄表明,瑶山群主体的原岩时代可能不早于二叠纪;变质锆石、深熔锆石/岩浆锆石的206Pb/238 U表面年龄可分为~85Ma、~75Ma、~42Ma、~37Ma和~32Ma等5组,可能代表了红河断裂南段自燕山晚期以来5期较强烈构造-岩浆-变质事件的时限。  相似文献   

5.
滇西腾冲地块片麻状花岗岩的锆石U-Pb年龄   总被引:7,自引:1,他引:6  
丛峰 《地质学报》2009,83(5):651-658
报道了滇西腾冲地块片麻状花岗岩的锆石U-Pb年龄。区域地质和岩相特征表明,片麻状花岗岩为岩浆成因,并经历了后期深熔作用。24颗锆石测得24个年龄数据中,1颗继承锆石的206Pb/238U年龄为537.5±5.6Ma,2颗岩浆锆石的206Pb/238U平均年龄为456Ma,3颗深熔锆石的206Pb/238U平均年龄为117Ma,18颗深熔锆石的Robust (Median) 206Pb/238U年龄为66.2+7/-4Ma。上述结果表明,花岗岩形成于早古生代,而后在白垩纪发生深熔作用,可能是特提斯演化过程中的岩浆响应。  相似文献   

6.
桐柏造山带中秦岭群中出露有志留纪麻粒岩,然而其原岩形成时代和变质年龄却没有得到有效的约束。本文对北桐柏秦岭群中长英质麻粒岩中锆石开展了详细的形貌学、阴极发光图像、微量元素以及U-Pb年代学研究。LA-ICP-MS锆石U-Pb定年结果表明继承碎屑锆石给出了2.7~0.55 Ga的年龄,岩浆锆石给出了478±7 Ma(MSWD=0.73)的206Pb/238U加权平均年龄,代表了桐柏长英质麻粒岩原岩的形成年龄。变质锆石区域获得了437±7 Ma(MSWD=1.3,n=10)的206Pb/238U加权平均年龄。结合锆石微量元素特征和前人研究结果表明437±7 Ma可能代表了前进变质阶段的年龄。而最外层的增生边给出了406±8 Ma(MSWD=0.72,n=4)的206Pb/238U加权平均年龄,代表了退变质年龄。我们认为在480 Ma时,商丹洋已开始向北俯冲,导致480 Ma左右的岩浆作用,由于持续的俯冲消减,在440~420 Ma时,洋中脊与弧交汇,发生洋脊俯冲导致志留纪麻粒岩相变质作用以及岩浆作用的发生。  相似文献   

7.
滇西地区沿金沙江-哀牢山断裂带广泛发育新生代富碱斑岩,其中六合富碱斑岩中发现了与镁铁-超镁铁质深源包体紧密共生的花岗岩包体。本文对花岗岩包体中锆石进行了阴极发光图像、LA-ICP-MS微量元素分析和U-Pb定年研究。研究表明,该花岗岩包体中锆石可分为岩浆锆石、老核新壳的复合岩浆锆石和变质交代成因锆石;复合岩浆锆石的新壳206Pb/238U平均加权年龄为39.2±2Ma,代表花岗岩包体的成岩年龄,与寄主富碱斑岩的成岩年龄基本一致;复合岩浆锆石的老核206Pb/238U平均加权年龄为828.1±7.1Ma,代表基底岩石年龄。变质锆石的206Pb/238U平均加权年龄为108.4±4.4Ma,与角闪石化金云石榴透辉岩中角闪石Ar-Ar年龄102.87±1.19Ma基本吻合,代表地幔流体交代矿物的结晶年龄,表明地幔流体交代作用过程可能在白垩纪前后延续一个相当长的时期。结合岩相学研究,认为该花岗岩包体被捕获运移时处于熔融态;花岗质熔浆的形成很可能与地幔流体作用引发的地壳部分熔融与壳幔岩浆混合作用密切相关。  相似文献   

8.
伊舒地堑基底花岗岩的锆石U-Pb年代学及其构造意义   总被引:5,自引:0,他引:5  
为了探讨伊舒地堑与松辽盆地基底的构造演化历史, 对位于伊舒地堑中的2个基底花岗岩进行了锆石LA-ICP-MS U-Pb定年研究, 并与松辽盆地基底花岗岩进行了对比.研究结果表明, 伊舒地堑基底花岗岩中的锆石呈自形或半自形, 并具有典型的岩浆生长环带, 个别发育有核边结构, 锆石的Th/U比值介于0.32 ~ 2.76, 暗示其岩浆成因.CH11井花岗岩中锆石18个测点206Pb/238U加权平均年龄为162±2 Ma, X13井花岗岩中锆石13个测点206Pb/238U加权平均年龄为159 ± 3 Ma, 其核部存在176 ±1 Ma的谐和年龄.上述结果表明, 伊舒地堑中基底花岗岩形成于中侏罗世晚期或晚侏罗世早期, 它们与松辽盆地基底中最晚期花岗岩的形成时间相同.这暗示伊舒地堑与松辽盆地自燕山期以来具有类似的基底演化历史. 176 ±1 Ma继承锆石的存在也证明了上述认识.   相似文献   

9.
紫金山矿田位于华南褶皱系东部,闽西南凹陷西南部,是我国大型-超大型浅成低温热液铜金矿床,区内发现多个与岩浆活动密切相关的金、银、铜等金属矿床.对紫金山矿田东南矿段与成矿密切相关的细粒黑云母花岗岩开展了详细野外地质调查、岩相学和锆石稀土元素、U-Pb年代学和Hf同位素研究.LA-ICP-MS法获得细粒黑云母花岗岩中岩浆结晶锆石206Pb/238U-207Pb/235U谐和年龄为109.5±1.9 Ma(MSWD=0.74,N=16),206Pb/238U加权平均年龄为107.44±0.94 Ma(MSWD=1.06,N=16),二者在误差范围内结果一致,结合锆石稀土元素和岩浆振荡环带特征及Th/U比值,上述年龄结果可代表岩石的结晶年龄,表明细粒黑云母花岗岩侵位于燕山期早白垩世.细粒黑云母花岗岩锆石Hf同位素初始比值εHf(t)均为负,介于-4.99~-1.06(平均值为-2.99);两阶段Hf模式年龄(tDM2)介于1 233.7~1 485.4 Ma(平均值为1 362.4 Ma).样品的εHf(t)、Hf同位素地壳模式年龄分布范围变化较小,暗示岩体的岩浆来源具有较为均一的锆石Hf同位素组成.紫金山矿田东南矿段早白垩世花岗岩体的锆石U-Pb年龄和Hf同位素特征,反映了闽西南早白垩世的岩浆成矿活动时间和源区特征,其成因与中国东南部岩石圈伸展减薄和壳源物质参与岩浆形成演化密切相关.   相似文献   

10.
续海金  宋衍茹  叶凯 《岩石学报》2013,29(5):1594-1606
威海-荣成地区混合岩化花岗质片麻岩为研究超高压地体折返过程中的部分熔融提供了理想的窗口。本文通过对荣成地区鲍村花岗质片麻岩中浅色条带野外观察、岩相学以及锆石的CL图像、U-Pb定年、微量元素和Lu-Hf同位素的系统研究表明,鲍村花岗质片麻岩中的浅色条带为部分熔融的产物,其主要矿物组成为石英+斜长石+钾长石+黑云母。锆石CL图像显示清楚的核-边结构:继承岩浆核和新生岩浆边。继承核的206Pb/238U协和年龄为620±8~784±7Ma(Mean=701±33Ma);具有典型的岩浆锆石的微量元素特征,如重稀土(HREE)和Y富集,强烈的正Ce异常和负Eu异常,以及极低的(Gd/Lu)N和Hf/Y比值;εHf(t=700Ma)值为-13.0~-8.0(Mean=-10.9±0.8),相应的tDM2为2120~2429Ma(Mean=2303±51Ma)。新生边的206Pb/238U协和年龄为211±6~244±5Ma(226±10Ma);虽然微量元素的整体含量低于继承核,但也具有岩浆锆石的微量元素特征,如稀土元素配分模式显示HREE明显上翘的特征,正Ce异常和负Eu异常,以及极低的(Gd/Lu)N比值;εHf(t=225Ma)值为-17.3~-14.2(Mean=-15.2±0.6),相应的tDM2为2152~2347Ma(Mean=2214±33Ma)。上述特征表明,部分熔融的原岩是由古元古代(2.2~2.3Ga)的地壳物质在新元古代(701±33Ma)重熔而成,部分熔融可能发生在超高压地体折返早期的热折返阶段(榴辉岩相-高压麻粒岩相条件下),时代应为226±10Ma。威海-荣成混合岩化片麻岩内广泛发育的富含钾长石和石英的酸性岩脉(约220~210Ma),可能为折返晚期的角闪岩相冷凝阶段,部分熔融形成的熔体经历了结晶分异作用的产物。  相似文献   

11.
刘小驰  吴元保  汪晶  彭敏  焦文放 《岩石学报》2009,25(9):2209-2223
西大别浒湾高压变质带是研究秦岭-大别-苏鲁造山带演化的关键区域.本文对该变质带熊店和学河两地的两个榴辉岩样品进行了LA-(MC)-ICPMS锆石U-Pb定年、微量元素分析及Hf同位素测定.熊店榴辉岩岩浆锆石得到的年龄为406±14Ma,具有高的εHf(t)值(εHf(t)=11.3±1.3),年轻的亏损地幔模式年龄(tDM=578±52Ma),其来源可能为亏损地幔,进而说明它们的原岩可能为古特提斯洋壳物质;学河榴辉岩岩浆锆石的年龄为703±8Ma,具有略低的εHf(t)值(εHf(t)=4.11±0.94),较老的亏损地幔模式年龄(tDM=1105±37Ma),其原岩可能为扬子克拉通新元古代裂谷岩浆作用产生的新生陆壳物质.这些结果表明浒湾地区存在原岩形成于新元古代和志留纪两个时期的榴辉岩.熊店榴辉岩中变质锆石的微量元素特征与岩浆锆石类似,可能为完全重结晶成因锆石,其206Ph/238U加权平均年龄为316±1Ma,代表了洋壳榴辉岩榴辉岩相峰期变质的最早时间.学河榴辉岩变质锆石以低Th/U、Nb/Ta比值为特征,其REE组成模式为不明显的Eu负异常,HREE呈平坦型.这些特征反映了这些锆石形成时出现了较大数量的石榴子石与金红石,而缺乏长石.根据锆石Ti温度计计算学河榴辉岩变质锆石形成的温度范围是704~741℃,与榴辉岩相变质温度一致.它们对应的206Pb/238U加权平均年龄为312±3Ma,可作为浒湾变质带榴辉岩相峰期变质年龄,这一结果表明浒湾变质带陆壳成因榴辉岩存在石炭纪榴辉岩相变质事件.空间上相近的古生代洋壳和新元古代陆壳具有相同的榴辉岩相变质年龄表明,浒湾变质带的洋壳和陆壳榴辉岩可能存在石炭纪的耦合俯冲作用.  相似文献   

12.
The Late Jurassic Jingshan granite located at the south-eastern margin of the North China Craton contains abundant garnets which can be subdivided into three types based on texture and composition: (i) euhedral garnet in mafic biotite and garnet rich enclave (Grt I), (ii) coarse-grained garnet (Grt II) in the host granite, and (iii) small euhedral garnet in aplite (Grt III). In general, Grt I has higher FeO, CaO and lower MnO contents than Grt II. Grt III has higher Mn, but lower Ca contents than others. Grt I has lower MREE and HREE contents than Grt II. Grt III has prominent and distinctly negative Eu anomaly as well as higher MREE composition compared to the others. Systematic variations in oxygen isotope compositions are observed among the three garnet types, with δ18O values of <3.8‰ in most of Grt I, 3.8–4.7‰ in most Grt II (for inclusion-free garnets), and typically >4.7‰ in Grt III. Some of the Grt II and Grt III display two distinct zonings with cores having similar major and trace element compositions to Grt I.Cathodoluminescence (CL) images revealed that the zircons from different garnet-bearing samples possess fine-scale oscillatory zoned magmatic rims with inherited cores. In situ zircon U–Pb dating and trace element analyses show that the dark-luminescent magmatic rims all have Jurassic concordia ages (∼160 Ma) and similar trace element patterns. Most of the inherited cores also display similar Triassic ages of 210–236 Ma, which is similar to the ages of ultrahigh pressure (UHP) metamorphic rocks of the Dabie–Sulu orogen (230 Ma). In addition, Jurassic concordia ages were also found in a zircon inclusion in Grt I, implying that the Grt I was formed shortly before the main magmatic event. The age data suggest that the three different garnet types may be genetically related and modified by cogenetic magmatic events.Based on the zircon U–Pb ages from different garnet-bearing samples, the major element, trace element, oxygen isotope, and zoning textures of the three kinds of garnet we suggest that Grt I may be peritectic garnet, whereas Grt II and III are probably the results of magmatic dissolution–precipitation processes and re-equilibration of garnets with changing magmatic conditions during melting, differentiation, crystallization, and cooling within the granite. We conclude from the oxygen isotopic character of the garnets and ages of the zircons that the source rocks for the Jingshan granites are from Dabie–Sulu orogen representing the South China Craton.  相似文献   

13.
范家埠金矿是胶东半岛苏鲁地体内规模最大的石英脉型金矿。含金石英脉中锆石阴极发光和LA-ICP-MS微量元素及U-Pb同位素分析结果表明,含金石英脉中的锆石均为捕获围岩(新元古代威海片麻状花岗岩)的岩浆锆石,其中15个颗粒在U-Pb图解上位于谐和线上,其206Pb/238U加权平均年龄为(726±14)Ma(MSWD=4.6);另外7颗锆石位于不一致线上,其上交点年龄为(758±25)Ma,下交点年龄为(123±11)Ma(MSWD=0.45)。这些锆石的下交点年龄与金矿脉旁侧斜闪煌斑岩脉的角闪石40Ar/39Ar年龄分别为(118.8±1.6)Ma和(117.5±1.5)Ma,在误差范围内一致,表明范家埠金矿的成矿时代为120Ma左右。由此认为,苏鲁地体和胶北地体的金矿成矿作用均发生于早白垩世晚期120Ma前后,与目前多数人认为的华北克拉通岩石圈减薄的峰期时间一致,表明苏鲁地体的金矿成矿受岩石圈减薄的构造背景控制。范家埠金矿床成矿流体具中高温、中高盐度15.5%~23.2%(NaCleq)、低δ18OH2O(-3.84‰~-4.05‰)和低δDH2O(-82.5‰~-80.8‰)值等特点,载金矿物黄铁矿富32S(δ34S=-5.5‰~-9.1‰),与含油气盆地热卤水的组成相近,暗示范家埠金矿的成矿流体可能来源于中生代胶莱盆地。这种盆地流体沿断裂——五莲—米山深大断裂及其次级构造迁移,同时萃取基底岩石中的金形成含矿热液并在还原的环境中成矿。相反,胶北地体大量金矿床成矿流体具有低盐度、高δ18OH2O和δDH2O,δ34S(‰)为正值等特点。胶北和苏鲁地体早白垩世金成矿强度和成矿作用的差异可能反映了两者在地壳基底、流体来源和成矿环境等方面的不同。  相似文献   

14.
辽西医巫闾山变质核杂岩经历过两阶段演化,晚侏罗世发育了围绕核部医巫闾山岩体周缘展布的长环形韧性剪切带(称为医巫闾山剪切带),早白垩世西侧叠加了北北东走向瓦子峪伸展韧性剪切带.在医巫间山剪切带及其变形下盘中侵入了大量的晚侏罗世花岗岩脉,其所含的锆石包括古老继承锆石、新生岩浆锆石、热液锆石等多种类型.根据锆石阴极发光图像、...  相似文献   

15.
赵苗  杨竹森  张洪瑞 《地球科学》2019,44(6):2187-2196
伊朗乌尔米耶-达克塔尔弧岩浆带(Urumieh-Dokhtar magmatic arc,UDMA)是特提斯域最重要的斑岩铜矿省,发育大量中新世大型超-大型斑岩铜矿床;同时,该带也发育大量同时代无矿岩体,但控制岩体成矿潜力的关键因素尚不清楚.为此,选择该带中段、成矿及无矿岩体同时发育的大理矿区,针对成矿及无矿岩体开展了系统的锆石岩相学、年代学、微量元素地球化学及Hf同位素地球化学对比.结果显示,无矿闪长岩(锆石U-Pb年龄:17.4±0.3 Ma)比成矿石英闪长斑岩(锆石U-Pb年龄:15.6±0.1 Ma)形成略早,但近乎同期;闪长岩εHf(t)值变化介于+2^+4,石英闪长斑岩εHf(t)值变化介于+2^+5,两者具有类似的Hf同位素组成;闪长岩中锆石常含老的继承核(172~920 Ma),石英闪长斑岩则不发育继承锆石;闪长岩及石英闪长斑岩中的中新世锆石具有类似的稀土配分模式,且Eu负异常不明显,而闪长岩中的锆石继承核则显示出明显的Eu负异常,配分模式与中新世锆石不同.基于上述结果,我们提出大理矿区的两套中新世岩体具有相同的岩浆源区,但经历了不同的地壳演化过程,成矿的石英闪长斑岩浆形成后,与古老地壳没有明显交互,而无矿的闪长岩浆,在上升过程中与地壳物质、特别是古老还原性物质发生了交互,交互过程中岩浆氧逸度降低,是该套岩浆不成矿的主要原因.进而我们提出UDMA带中段斑岩成矿与否不仅与前人所认为的受岩浆源区控制,也与岩浆演化过程密不可分.  相似文献   

16.
大别山高压?超高压片麻岩核?边结构锆石成因探讨*   总被引:1,自引:1,他引:0       下载免费PDF全文
大别山高压?超高压片麻岩中的锆石在阴极发光(CL)显示核?边结构:韵律环带的岩浆锆石核,较强发光的变质边。本文对核?边结构的锆石进行了包裹体、微区U?Pb年龄和微量元素研究。结果表明变质边由两种不同的机制形成:变质重结晶和变质增生。变质重结晶锆石的U?Pb年龄和稀土总量逐渐降低,稀土配分模式不变。变质增生锆石比变质重结晶锆石具有更低Th/U比值,重稀土严重亏损,Eu负异常不明显,低的Nb、Ta含量。  相似文献   

17.
J. M. Hanchar  R. L. Rudnick   《Lithos》1995,36(3-4):289-303
The use of cathodoluminescence (CL) and/or back-scattered electron (BSE) imaging techniques with in situ ion probe analyses of zircons can help unravel complex crustal histories of metamorphic rocks that otherwise might remain elusive. Using these techniques we have imaged zircons from three lower crustal xenolith suites that have previously been dated by SHRIMP (sensitive high-resolution ion microprobe). In all three cases, the zircons are featureless in transmitted light but CL and BSE reveal internal structures that correlate with distinct growth events. Generally, CL and BSE images reveal similar structures, with CL showing finer detail. Neither imaging technique is capable of delineating all growth features in every sample and the best results are obtained using a combination of the two techniques. Igneous cores in zircons commonly emit a different color CL emission. In many cases zoning in the cores is truncated, indicating that the zircons either spent time in the supracrustal environment after their initial crystallization and prior to the granulite facies event (s) or that part of the core zircon was resorbed during the subsequent metamorphic event. Metamorphic rims, when present, are commonly 10 to 30 μm thick, and are nearly always unzoned and featureless.

Igneous cores and metamorphic overgrowths commonly have distinctive CL emission spectra and trace element concentrations. However, the CL spectra can only be used to qualify chemical differences, as a linear relationship has not been shown to exist between CL intensity and trace element concentration in natural zircons. In many cases the Hf, Y, P, U and the heavy rare-earth elements (HREEs) concentrations can be correlated to igneous and metamorphic growth using a combination of CL and BSE imaging techniques and in situ trace element analyses with either the electron microprobe or PIXE (particle induced X-ray emission).  相似文献   


18.
The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies. These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ LuN ≥ 14) and 176Lu/177Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and 176Lu/177Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf model ages (T DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

19.
Mangakino, the oldest rhyolitic caldera centre delineated in the Taupo Volcanic Zone of New Zealand, generated two very large (super-sized) ignimbrite eruptions, the 1.21 ± 0.04 Ma >500 km3 Ongatiti and ~1.0 Ma ~1,200 km3 Kidnappers events, the latter of which was followed after a short period of erosion by the ~200 km3 Rocky Hill eruption. We present U/Pb ages and trace-element analyses on zircons from pumice clasts from these three eruptions by Secondary Ion Mass Spectrometry (SIMS) using SHRIMP-RG instruments to illustrate the evolution of the respective magmatic systems. U–Pb age spectra from the Ongatiti imply growth of the magmatic system over ~250 kyr, with a peak of crystallisation around 1.32 Ma, ~100 kyr prior to eruption. The zircons are inferred to have then remained stable in a mush with little crystallisation and/or dissolution before later rejuvenation of the system at the lead-in to eruption. The paired Kidnappers and Rocky Hill eruptions have U–Pb zircon ages and geochemical signatures that suggest they were products of a common system grown over ~200 kyr. The Kidnappers and Rocky Hill samples show similar weakly bimodal age spectra, with peaks at 1.1 and 1.0 Ma, suggesting that an inherited antecrystic population was augmented by crystals grown at ages within uncertainty of the eruption age. In the Kidnappers, this younger age peak is dominantly seen in needle-shaped low U grains with aspect ratios of up to 18. In all three deposits, zircon cores show larger ranges and higher absolute concentrations of trace elements than zircon rims, consistent with zircon crystallisation from evolving melts undergoing crystal fractionation involving plagioclase and amphibole. Abundances and ratios of many trace elements frequently show variations between different sectors within single grains, even where there is no visible sector zoning in cathodoluminescence (CL) imaging. Substitution mechanisms, as reflected in the molar (Sc + Y + REE3+)/P ratio, differ in the same growth zone between the sides (along a-axis and b-axis: values approaching 1.0) and tips (c-axis: values between 1.5 and 5.0) of single crystals. These observations have implications for the use of zircons for tracking magmatic processes, particularly in techniques where CL zonation within crystals is not assessed and small analytical spot sizes cannot be achieved. These observations also limit applicability of the widely used Ti-in-zircon thermometer. The age spectra for the Ongatiti and Kidnappers/Rocky Hill samples indicate that both magmatic systems were newly built in the time-breaks after respective previous large eruptions from Mangakino. Trace element variations defining three-component mixing suggest that zircons, sourced from multiple melts, contributed to the population in each system.  相似文献   

20.
Zircon U-Pb age, trace elements, and Hf isotopes were determined for granulite and gneiss at Huaugtuling (黄土岭), which is hosted by ultrahigh-pressure metamorphic rocks in the Dabie(大别) orogen, east-central China. Cathodolumineseence (CL) images reveal core-rim structure for most zircons in the granulite. The cores show oscillatory zoning, relatively high Th/U and 176 Lu/177 Hf ratios, and high rare earth element (HREE)-enriched pattern, consistent with magmatic origin. They gave a weighted mean 207 Pb/206 Pb age of (2 766±9) Ma, dating magma emplacement of protolith. The rims are characterized by sector ur planar zoning, low Th/U and 176 Lu/177 Hf ratios, negative Euanomalies and flat HREE patterns, consistent with their formation under granulite-facies metamorphicconditions. Zircon U-Pb dating yields an age of (2 029±13) Ma, which is interpreted as a record ofmetamorphic event during the assembly of the supercontinent Columbia. The gneiss has a protolith ageof (1982±14) Ma, which is similar to the zircon U-Pb age for the granulite-facies metamorphism,suggesting complementary processes to granulite-facies metamorphism and partial melting. A fewinherited cores with igneous characteristics have 207 pb/206 Pb ages of approximately 3.53, 3.24, and 2.90Ga, respectively, suggesting the presence of Mesoarchean to Paleoarchean crustal remnants. A fewTriassic and Cretaceous metamorphic ages were obtained, suggesting the influences by the Triassiccontinental collision and postcollisional collapse in response to the Cretaceous extension. Comparingwith abundant occurrence of Triassic metamorphic zircons in ultrahigh-pressure eclogite and granitehydrous melt is evident for zircon growth in theHuangtuling granulite and gneiss during thecontinental collision. The magmatic protolithzircons from the granulite show a large variationin 176 Hf/177 Hf ratios from 0.280 809 to 0.281 289,corresponding to era(t) values of-7.3 to 6.3 andHf model ages of 2.74 to 3.34 Ga. The 2.90 Gainherited zircons show the similar Hf isotope features. These indicate that both growth of juvenile crust and reworking of ancient crust took place at the time of zircon formation. It is inferred that the Archean basement of the Yangtze block occurs in thenorth as the Dabie orogen, with ca. 2.90-2.95 Ga and 2.75-2.80 Ga as two major episodes of crustalformation.  相似文献   

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