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1.
於祖相 《矿物学报》1998,18(1):12-16
铂双峰矿产在纯橄榄岩铝矿体中。在铝矿石及矿体邻近的砂矿中均可找到。呈块状聚集体或板片状自形晶,与疏钻矿、含锇自然铱紧密共生。脉状的宽20~301μm,长400~500μm,一般10μm×20μm。金属光泽。条痕黑色。HM=3.05。VHN20=92kg/mm2(平均)。{0001}解理完全。性脆。计算密度为10.21g/cm2。反射色;亮黄白带淡蓝色。内反射无。非均质性中等,偏光色为淡蓝或淡黄。双反射或反射多色性在空气中或油中均未见。5个电子探针分析数据平均(wt%):Cu0.2,Te57.2,Ir24.5,Pt17.2,Bi0.4,总量99.5。实验式为:(IR0.57Pt0.39Cu0.01)0.98(Te1.99Bi0.01)2.00。简化理论式为(11,Pt)Te2。4条最强X射线粉晶衍射线hkl,d,I为:101,2.87(100);102,2.10(70);110,1.98(60);103,1.58O(50)。根据X射线粉晶数据进行指标化,获得铂双峰矿晶胞数据:三方晶系,P3ml,a=0.3973(5),c=0.5315(5)um,V=0.0727nm3,Z=1。铂双峰矿是笔者对双峰矿研究的继续与补充。  相似文献   

2.
四川大水沟碲矿床是世界唯一的独立碲矿床,楚碲铋矿是该矿床中重要的碲矿物之一。它存在于辉碲铋矿和磁黄铁矿晶粒之间,或包裹在辉碲铋矿中。呈银灰色,金属光泽,一组底面解理发育。显微压入硬度为80.5kg/mm2(15g负荷)。反光显微镜下为白色,非均质性清楚,反射率为58.0~59.9(λ=546nm)。X射线粉晶衍射分析的主要谱线有:4.797(60),3.229(100),2.368(80),2.169(50)。矿物的化学组成据11个电子探针分析的平均值为(重量%);Fe0.13,S0.04,Cu0.03,Te37.84,Bi61.37,Se0.01,Sb0.16;总量99.58,其化学成分式为;BiTe。楚碲铋矿形成于贫硫环境中。  相似文献   

3.
一个新的铋亚碲酸盐矿物—平谷矿   总被引:1,自引:0,他引:1  
孙志富  雒克定 《矿物学报》1994,14(4):315-321
平谷矿是在北京市平谷县一小型金矿氧化带中发现的一种新矿物。共生和伴生矿物有褐铁矿、孔雀石、磷氯铝矿、泡铋矿、自然金、银金矿、石英、方解石和白钨矿。通常呈粒状集合体出现,单体板柱状,极为细小(0.3~0.6μm),黄绿色,玻璃至金刚光泽。实测密度=8.44g/cm3,计算密度8.64g/cm3。维氏硬度449~572kg/mm2,相当摩氏硬度5~6。反射率=13.25%,折射率>2.0,计算折射率为2.145,电子探针分析结果Bi2O379.56%、TeO220.17%,总和99.73wt%,化学式Bi5。8043Te2。1475O13理想式Bi6Te2O13。X射线粉晶分析主要强线3.146(100)(12)、2.841(80)(200)、2.694(20)(040)、1.695(20)(321)、1.956(10)(240)、1.631(10)(16),斜方品系,a=0.5689(1),b=1.0791、c=0.5308(1)um,晶胞体积V=0.3258um3,Z=1。  相似文献   

4.
铋砷黝铜矿在中国的发现与研究   总被引:1,自引:0,他引:1  
铋砷黝铜矿产于广东陆丰中低温热液黄铁矿矿床中,呈它形粒状嵌布在黄铁矿内,粒径0.05~0.22mm,与黄铜矿、针硫铋铝矿共生。反射免呈灰色微带蓝色,均质性。显微硬度Hv=295.5kg/mm2。电子探针成分分析(平均值)为:S24.4%,Cu38.25%,As13.03%,Bi17.人83%,Sb0.48%,Zn2.39%,Fe2.13%,Te1.47%,化学式为:Cu10(Fe0.65Zn0.63Cu0.49)1.77(As2.97Bi1.46Sb0.07)4、50(S12.8Te0.20)13。X射线粉晶衍射强线:2.95(10),2.55(3),1.866(5),1.727(4),1.041(5)。晶胞参数α=1.0218nm。  相似文献   

5.
一个新的铋,铬氧化物——铬铋矿   总被引:3,自引:1,他引:3  
周新春  炎金才  王冠鑫  王世忠  刘良  舒桂明 《矿物学报》1996,16(4):335-339,T001
铬铋矿(Bi16.006Cr0.997O27)是在陕西省洛南县驾鹿金矿床中发现的一种新矿物。该矿物通常呈不规则状微细晶集合体,柱状小晶体大小在0.005mm×0.002mm~0.05mm×0.025mn。之间,集合体大小约0.01~0.5mm。呈桔黄或黄棕色,性脆,半透明,条痕棕黄色,金刚光泽,具不完全解理;一轴晶,正光性。实测密度为9.80(3)g/cm3。计算密度9.85(1)g/cm3。维氏硬度95.8~128kg/mm2,摩氏硬度3~4。折射率ω=2.50(2),ε=2.55(2)。15个电子探针平均成分Bi2O3为97.25%,CrO3为2.6%,总和99.95%,化学式:Bi16.006Cr0.997O27,理论式:Bi16CrO27。X射线粉晶衍射主要强线d(I)(hkl)为:0.319(100),(123);0.273(40),(310);0.198(40),(316);0.1932(20),(420),0.1715(30),(219);0.1655(55),(503,·433)。根据指标化求得铬铋矿为四方晶系,可能的空间群为I4,I4或I4/m;a=0.8649(3)um,c=1.724(1)nin,c/a=1.9933;V=1.2896(6)nm3,Z=2。1-Kp/Kc=0.025。铬铋矿作为新矿物及其命名已被国际矿物学协会新矿物和矿物命名委员会批准通过,其样品存放中国地质博物馆。  相似文献   

6.
硫碲铋铅金矿在我国的首次发现和研究   总被引:1,自引:0,他引:1  
田澍章  陈静渝 《矿物学报》1994,14(3):241-246
硫碲铋铅金矿(AuPb2BiTe2S3)是1991年国际新矿物及矿物命名委员会(CNMMNIMA)批准的新矿物,产于美国科罗拉多(Colorado)州的巴克霍恩(Buckhoun)矿山。我们于1986年发现了该矿物,但呈报CNMMNIMA晚于美国。我国的硫碲铋铅金矿产于河南灵宝出岔-乱石和桐沟两个石英脉型金矿。该矿物为柱板状晶体,粒径0.03~0.2mm,黑色,一组解理发育,金属光泽。显微硬度为64~129kg/mm2,(负荷10g),反射色为灰色,微带蓝色色调,非均质性明显,无内反射,以等能光源(SE)对R1和R2计算的颜色指数分别为:x0.323,y0.326,Y%42.69,λd480,Pe%0.04;和x0.326,y0.326,Y%43.70,λd476,Pe%0.03。电子探针分析结果为:CU0.02,Au16.96,Ph35.34,Bi15.93,Te20.79,S8.21。化学式为:Au1.03Ph2.04Bi0.91Te1.95S3.06,斜方晶系,a=0.41,b=1.25,c=0.95nm,V=0.487nm3。理论比重Dx=7.94。  相似文献   

7.
小秦岭金矿田中的两种罕见矿物—碲铅铋矿和自然碲   总被引:2,自引:0,他引:2  
碲铅铋矿和自然碲产于河南省小秦岭含金石英脉矿床中。碲铅铋矿化学成分平均值(%)为:Te44.06,Bi40.24,Pb14.23,并含有微量的Ag、Au、Hg、Fe、Ni、Cu等元素。理论化学式为(Bi,Pb)_3Te_4,其中Bi>Pb。共生矿物有自然金、碲金矿、破银矿、碲铅矿、碲金银矿、碲铋矿;方铅矿、闪锌矿、黄铁矿、黄铜矿等。 自然碲反射色为纯白微带乳色,非均质性清楚,偏光色为蓝灰-棕灰色。显微硬度为H_v=85.1kg/mm~2(25g)。共生矿物有碲金银矿、碲银矿、黄铜矿等。化学成分中碲含量达98.44%,并含Ag、Cu、W、Fe、Pt等微量元素。  相似文献   

8.
叶碲铋矿研究中存在问题分析   总被引:1,自引:0,他引:1       下载免费PDF全文
叶碲铋矿最初定名为wehrlite,结构式为Bi2 xTe3-x,后于1982年改名为pilsenite,结构式相应改为Bi4Te3。楚碲铋矿(BiTe)的成分介于原叶碲铋矿的成分范围之内。有些研究者仍用原成分确定叶碲铋矿或把楚碲铋矿当作叶碲铋矿,本文旨在提醒研究者注意,避免误用。  相似文献   

9.
楚碲铋矿、赫磅铋矿是两种光见矿物,其化学成分特征是亏Bi而富S,An,Cu等杂质,它们呈细小的(0.05-0.15mm)的嵌晶被包裹在黄铁矿晶体中,在黄铁矿(单矿物)中含量最高可达2300ug/g,使其具有重要的综合利用价值。它们的生成是由于两种不同性质的初始热液在运移途中相偶,引起磅元素迅速淀积的结果,其化学成分特征反映出S,Au,Cu等都是该区可利用的重要有益组分,因此具找矿意义。  相似文献   

10.
官田黄铁矿矿床中楚碲铋矿、赫碲铋矿的成因及找矿意义   总被引:2,自引:0,他引:2  
楚碲铋矿、赫碲铋矿是两种少见矿物 ,其化学成分特征是亏Bi而富S、Au、Cu等杂质 ,它们均呈细小的 (0 .0 5~ 0 .15mm)的嵌晶被包裹在黄铁矿晶体中 ,在黄铁矿 (单矿物 )中含量最高可达 2 30 0 μg/ g ,使其具有重要的综合利用价值。它们的生成是由于两种不同性质的初始热液在运移途中相遇 ,引起碲元素迅速淀积的结果。其化学成分特征反映出S、Au、Cu等都是该区可利用的重要有益组分 ,因此具找矿意义  相似文献   

11.
Changchengite occurs in chromite orebodies in dunite and in platinum placer deposits in chromite orebodies nearby. The mineral occurs as massive aggregates or veinlets on margins of iridisite (IrS2) and replaces it. Opaque. Lustre metallic. Colour steel-black. Streak black. Hm = 3.7. VHN20= 165 kg/ mm2. Isotropic. Cleavage none. Density 11.96 g/ cm3. Seven electron microprobe analyses give the following mean chemical results (wt. %): S 7.2, Cu 0.3, Te 0.4, Ir 41.2, Pt 2.8 and Bi 47.3 with total 99.1. The simplified formula is IrBiS. The strongest X-ray powder diffraction lines (hkl, d, I) are 210, 2.75 (70); 211, 2.51 (60); 311, 1.860 (100); 440. 1.090 (50) and 600, 1.027 (50). The X-ray powder diffraction pattern is similar to that of mayingite. After the diffraction data are indexed the mineral is determined to be cubic. The space group is P213 with a = 0.6164(4) nm, V = 0.2342 nm3 and Z = 4.  相似文献   

12.
新矿物双峰矿—铱的二碲化物   总被引:2,自引:1,他引:2  
於祖相 《矿物学报》1994,14(4):322-326,T002
双峰矿产在纯橄榄岩体铬矿体中。在铬矿石及矿体邻近的砂矿中均可找到,呈块状聚集体或板片状与硫铱矿、锇自然铱矿紧密共生。直径0.5 ̄0.2mm,脉状的宽0.05 ̄0.10mm,长0.5 ̄1.0mm。金属光泽。条痕黑色。H(M)3。VHN20108kg/mm^2(平均)。解理:(0001)完全。性脆。计算密度为10.14g/cm^3。反射色:亮黄白带蓝色调。内反射无。非均质性中等,偏光色为淡蓝或淡黄。双  相似文献   

13.
铂族元素矿物共生组合(英文)   总被引:1,自引:2,他引:1  
CHEN Yuan 《现代地质》2001,15(2):131-142
由于铂族元素能有效地降低汽车尾气的污染 ,其需求量日益增加 ,对铂族元素矿床的寻找已是当务之急。着重从矿物矿床学角度对铂族元素的矿物共生特点进行了探讨。铂族元素可呈独立矿床产出 ,主要产于基性超基性层状侵入体、蛇绿岩套及阿拉斯加式侵入体中。铂族元素也伴生于铜镍矿床中 ,该类铜镍矿床主要与苏长岩侵入体、溢流玄武岩及科马提岩有关。产于基性超基性层状侵入体中的铂族矿物有铂钯硫化物、铂铁合金、钌硫化物、铑硫化物、铂钯碲化物、钯砷化物及钯的合金。这些铂族矿物可与硫化物矿物共生 ,也可与硅酸盐矿物共生 ,还可与铬铁矿及其他氧化物矿物共生。产于蛇绿岩套中的铂族矿物主要是钌铱锇的矿物 ,而铂钯铑的矿物则较少出现 ,这些铂族矿物可呈合金、硫化物、硫砷化物以及砷化物 4种形式出现。产于阿拉斯加式侵入体中的铂族矿物主要有铂铁合金、锑铂矿、硫铂矿、砷铂矿、硫锇矿及马兰矿等少数几种 ,其中铂铁合金与铬铁矿及与其同时结晶的高温硅酸盐矿物共生 ,而其他的铂族矿物则与后来的变质作用及蛇纹岩化作用中形成的多金属硫化物及砷化物共生。产于铜镍矿床中的铂族矿物主要是铂和钯的矿物。产于基性超基性层状侵入体、蛇绿岩套及阿拉斯加式侵入体中的铂族矿物的共同特点是它们均与铬铁矿?  相似文献   

14.
Lisiguangite, CuPtBiS3, is a new mineral spedes discovered in a PEG-bearing, Co-Cu sulfide vein in garnet pyroxenite of the Yanshan Mountains, Chengde Prefecture, Hebei Province, China. It is associated with chaicopyrite and bornite, galena, minor pyrite, carrolite, molybdenite and the platinum-group minerals daomanite (CuPtAsS2), Co-bearing malanite (Cu(Pt, Co)2S4) sperrylite, moncheite, cooperite and malyshevite (CuPdBiS3), rare damiaoite (Pt2In3) and yixunite (Pt3In). Lisiguangite occurs as idiomorphic crystals, tabular or lamellae (010) and elongated [100] or as aggregates, up to 2 mm long and 0.5 mm wide. The mineral is opaque, has lead-gray color, black streak and metallic luster. The mineral is non-fluorescent. The observed morphology displays the following forms: pinacoids {100}, {010}, {001}, and prism {110}. No twining is observed. The a:b:c ratio, calculated from unit-cell parameters, is 0.6010:1:0.3836. Cleavage: {010} perfect, {001} distinct, {100} may be visible. H Mohs: 21/2; VHN25=46.7-49.8 (mean 48.3) kg/mm2. Tenacity: brittle. Lisiguangite is bright white with a yellowish tint. In reflected light it shows neither internal reflections nor bireflectance or pleochroism. It has weak to moderate anisotropy (blue-greenish to brownish) and parallel-axial extinction. The reflectance values in air (and in oil) for R3, R4 and (imR3,/imR4), at the standard Commission on Ore Mineralogy wavelengths are: 37.5, 35.7 (23.4, 22.3) at 470 nm; 38.6, 36.5 (23.6, 22.6) at 546 nm; 39.4, 37.5 (23.6, 22.7) at 589 nm and 40.3, 38.2 (23.7, 22.9) at 650 nm. The average of eight electron-microprobe analyses: Cu 12.98, Pt 30.04, Pd 2.69, Bi 37.65 and S 17.55, totaling 100.91%, corresponding to Cu1.10(Pt0.83, Pd0.14)∑0.97Bi0.97S2.96 based on six atoms apfu. The ideal formula is CuPtBiS3. The mineral is orthorhombic. Space group: P212121,a=7.7152(15)A, b=12.838(3) A, c=4.9248(10)A, V=487.80(17)A3, Z=4. The six strongest lines in the X-ray powder-diffraction pattern [d in A (I) (h k l) are 6.40(30)(020), 3.24(80)(031), 3.03(100)(201), 2.27(40)(051), 2.14(50)(250), 1.865(60)(232).  相似文献   

15.
来自蛇绿岩地幔的硫(砷)化物矿物组合   总被引:1,自引:0,他引:1  
近来在西藏雅鲁藏布江蛇绿岩带的罗布莎蛇绿岩块的地幔豆荚状铬铁矿中发现一个包括金刚石、柯石英、自然元素、合金、氧化物以及硫(砷)化物组成的地幔矿物群。该矿物群的硫(砷)化物具有特殊化学成分并呈包裹体分布在贱金属(BM)和铂族元素(PGE)或它们的合金中,大量化学成分分析得知它们主要由下列元素组成:S、As、Te、Fe、Ni、Co、Cu、Pt、Pd、Ru、Rh、Os、Ir、Mn和Ti。根据化学成分可辨别出约30种硫(砷)化物矿物:FeS、NiS、(Ni,Fe)S、Fe3S2、Ni3S2、(Ru,Os,Ir)S2、Rh7As3、Rh5Ni(Cu)As4、Pd4Rh3As3、Pd8As2、Pd3TeAs、Pd7Te3、RuAs、PtAs2、Ni4Rh3As3、Rh(As,S)2、(Rh,Ir)(As,S)2、Ir(As,S)2、MnS、Ti7S3、Ti7N3、Rh3.5Se3.5CuS2、RhS、Ir2S3、(Ir,Cu)2、S3(Co,Ni,Fe)2(As,S)3、(Ir,Pt)(As,S)2、Ru3(As,S)7以及(BM)x(PGE)yS10-(x y)等,其中包括已定名和未定名的矿物。由于矿物粒度小(<25μm),缺乏X射线分析资料,有待进一步研究。  相似文献   

16.
It is of great importance to understand the origin of UG2 chromitite reefs and reasons why some chromitite reefs contain relatively high contents of platinum group elements(PGEs: Os, Ir, Ru, Rh,Pt, Pd) or highly siderophile elements(HSEs: Au, Re, PGE). This paper documents sulphide-silicate assemblages enclosed in chromite grains from the UG2 chromitite. These are formed as a result of crystallisation of sulphide and silicate melts that are trapped during chromite crystallisation. The inclusions display negative crystal shapes ranging from several micrometres to 100 μm in size.Interstitial sulphide assemblages lack pyrrhotite and consist of chalcopyrite, pentlandite and some pyrite. The electron microprobe data of these sulphides show that the pentlandite grains present in some of the sulphide inclusions have a significantly higher iron(Fe) and lower nickel(Ni) content than the pentlandite in the rock matrix. Pyrite and chalcopyrite show no difference. The contrast in composition between inter-cumulus plagioclase(An_(68)) and plagioclase enclosed in chromite(An_(13)), as well as the presence of quartz, is consistent with the existence of a felsic melt at the time of chromite saturation.Detailed studies of HSE distribution in the sulphides and chromite were conducted by LA-ICP-MS(laser ablation-inductively coupled plasma-mass spectrometry), which showed the following.(Ⅰ) Chromite contained no detectable HSE in solid solution.(Ⅱ) HSE distribution in sulphide assemblages interstitial to chromite was variable. In general, Pd, Rh, Ru and Ir occurred dominantly in pentlandite, whereas Os,Pt and Au were detected only in matrix sulphide grains and were clearly associated with Bi and Te.(Ⅲ)In the sulphide inclusions,(a) pyrrhotite did not contain any significant amount of HSE,(b) chalcopyrite contained only some Rh compared to the other sulphides,(c) pentlandite was the main host for Pd,(d)pyrite contained most of the Ru, Os, Ir and Re,(e) Pt and Rh were closely associated with Bi forming a continuous rim between pyrite and pentlandite and(f) no Au was detected. These results show that the use of ArF excimer laser to produce high-resolution trace element maps provides information that cannot be obtained by conventional(spot) LA-ICP-MS analysis or trace element maps that use relatively large beam diameters.  相似文献   

17.
Chengdeite occurs in chromite orebodies in dunite as well as in placers in their neighbourhood. The mineral occurs as granular aggregates in association with inaglyite and in some cases occurs as graphic intergrowths with native iridium. It is opaque with a metallic lustre, colour steel-black, streak black,HM = 5.2, VHN50=452 kg/mm2, cleavage not observed, fracture not observed, strongly magnetic. Its reflection colour is bright white with a yellowish tint. It has no internal reflection, bireflectance or pleochrism, and shows isotropism.Thirteen chemical analyses were carried out by means of the electron microprobe. The mean percentages of the data obtained in the 13 analyses ares S 0.001, Fe 7.9, Ni 0.03, Co 0.03, Cu 0.83, As 0.02, Rh 0.19, Pd 0.00, Os 0.06, Ir 88.5, Ft 2.2 and Pb 0.00. The simplified formula is Ir3Fe, which requires Ir 91.17 and Fe 8.83, the total being 100.00 (% ).Five strongest lines of X-ray powder diffraction (hkl, d, I)are: 111, 2.18 (80);200, 1.89 (60); 220, 1.34 (70);311, 1.142  相似文献   

18.
云南大硐厂铅锌矿床中的硫碲铋矿A   总被引:1,自引:0,他引:1  
战新志  蒋国贤 《矿物学报》1995,15(4):422-424
硫碲铋矿A产于云南省大硐厂铅锌矿床,与自然铋、辉铋铅矿共生。晶体呈柱状,粒度0.02 ̄0.3mm。反光显微镜下呈淡黄色,弱非均质性,反射率Rc′=52.4%,R0=48.8%(波长为540nm),显微压入硬度Hv=46 ̄72kg/mm^2。主要粉晶谱线:3.065(10),2.120(7),1.346(5),2.220(4)。三方晶系,空间群为D3d^5-R3↑-m,晶胞参数a=0.4241nm,  相似文献   

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