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1.
A total of seventeen vertical profiles of ozone were obtained during an Indo-USSR collaborative experiment on ozonesonde intercomparison conducted at Thumba during March 1983. The vertical distribution of ozone was measured using rocket-borne, balloon-borne as well as ground-based instruments. Four different rocket ozonesondes from India and USSR and the balloon ozonesonde were used to makein situ observations of ozone concentrations in addition to the Dobson spectrophotometric observations of total ozone and Umkehr. The rocket and the balloon launchings were effected in three salvos and measurements were made at different times of the day as well as during night. The results of all these measurements are used to obtain a mean ozone vertical distribution over Thumba foT the spring equinoxial period. The mean profile shows the maximum ozone concentration at 27 km with a value of (3.86±0-52)×1012 molecules per cc. Comparison of this mean profile with available satellite data for the equatorial regions shows that, in general, the Thumba values are lower by 10–15% at altitudes below 40 km and larger at altitudes above 50 km compared to the satellite results. The data also show evidence for a day-to-day variability and a possible day-to-night variability in the ozone vertical distribution with the night-time values higher than the daytime values at all altitudes above 35 km and the difference is found to increase with the increasing altitude.  相似文献   

2.
Airborne measurements of the number concentration and size distribution of aerosols from 13 to 700 nm diameter have been made at four vertical levels across a coastline at Bhubaneswar (20°25′N, 85°83′E) during the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB) programme conducted in March–April 2006. The measurements made during the constant-level flights at 0.5, 1, 2 and 3 km altitude levels extend ～100 km over land and ～150km over ocean. Aerosol number concentrations vary from 2200 to 4500 cm?3 at 0.5 km level but are almost constant at ～ 6000 cm?3 and ～ 800 cm?3 at 2 and 3 km levels, respectively. At 1km level, aerosol number concentration shows a peak of 18,070 cm?3 around the coastline. Most of the aerosol size distribution curves at 0.5 km and 1 km levels are monomodal with a maxima at 110nm diameter which shifts to 70 nm diameter at 2 and 3 km levels. However, at the peak at 1 km level, number concentration has a bimodal distribution with an additional maximum appearing in nucleation mode. It is proposed that this maxima in nucleation mode at 1 km level may be due to the formation and transport of new particles from coastal regions.  相似文献   

3.
Results are presented of two instrumented rocket experiments performed from an equatorial station, one at night and the other shortly after sunrise. The ion neutral composition as well as electron density and the amplitude of plasma irregularities were monitored. During the latter flight, a sharp layer of ionisation with its lower boundary at 100 km was observed. The layer had a half width close to 1 km and a peak electron density of 5·6× 104cm?3. Large amplitude of plasma irregularities, noticed on the negative gradient portion of the layer indicates a downward direction of the polarisation electric field during the observations. The resulting downward drift of photoions as they are produced at sunrise followed by the local decrease of the drift is suggested to be the cause of the layer formation at that altitude. The long lasting nature of such layers once identified on ionograms indicates that they are constituted of metallic ions possibly of micrometeoritic origin deposited overnight in the lower thermosphere. The required photoionisation rate of production of the metallic ions at sunris eis about 2 cm?3 sec?1.  相似文献   

4.
北京上空大气臭氧垂直分布的特征   总被引：10，自引：1，他引：9  
利用我国自行研制的探空仪和地面接收设备首次较系统地获得了北京地区连续一年（2001年 3月至2002年 2月）的大气臭氧垂直分布资料。结果分析表明：①北京地区上空臭氧浓度极大值的季节均值的变化范围为15．1～16．7 mPa,其高度位于20．7～25．1km之间,极小值的季节均值的变化范围为 2．0～2．8 mPa,其高度在对流层顶附近。②边界层和平流层下部是臭氧浓度变化的活跃区域,并具有明显的季节变化,在边界层内夏季臭氧积分浓度高于冬季相应值的 1．7倍之多,而在平流层下部,冬季臭氧积分浓度则高于夏季的相应值。夏季边界层中臭氧浓度偏高,表明臭氧是北京地区夏季重要的污染气体之一。③北京上空臭氧垂直廓线的形态呈多样性,夏秋季节以单峰为主,冬春季节经常出现双峰和多峰结构;次峰出现的区域一般在10～18km高度范围内。  相似文献   

5.
Aeolian sand and dust in polar regions are transported offshore over sea ice and released to the ocean during summer melt. This process has long been considered an important contributor to polar sea floor sedimentation and as a source of bioavailable iron that triggers vast phytoplankton blooms. Reported here are aeolian sediment dispersal patterns and accumulation rates varying between 0·2 g m?2 yr?1 and 55 g m?2 yr?1 over 3000 km2 of sea ice in McMurdo Sound, south‐west Ross Sea, adjacent to the largest ice free area in Antarctica. Sediment distribution and the abundance of southern McMurdo Volcanic Group‐derived glass, show that most sediment originates from the McMurdo Ice Shelf and nearby coastal outcrops. Almost no sediment is derived from the extensive ice free areas of the McMurdo Dry Valleys due to winnowed surficial layers shielding sand‐sized and silt‐sized material from wind erosion and because of the imposing topographic barrier of the north‐south aligned piedmont glaciers. Southerly winds of intermediate strength (ca 20 m sec?1) are primarily responsible for transporting sediment northwards and offshore. The results presented here indicate that sand‐sized sediment does not travel more than ca 5 km offshore, but very‐fine sand and silt grains can travel >100 km from source. For sites >10 km from the coast, the mass accumulation rate is relatively uniform (1·14 ± 0·57 g m?2 yr?1), three orders of magnitude above estimated global atmospheric dust values for the region. This uniformity represents a sea floor sedimentation rate of only 0·2 cm kyr?1, well below the rates of >9 cm kyr?1 reported for biogenic‐dominated sedimentation measured over much of the Ross Sea. These results show that, even for this region of high‐windblown sediment flux, aeolian processes are only a minor contributor to sea floor sedimentation, excepting areas proximal to coastal sources.  相似文献   

6.
NighttimeF-region temperatures have been obtained over Mount Abu (24·6°N, 72·7°E geographic, 15·0° geomagnetic latitude) by monitoring OI 6300 Å line widths, using Fabry-Perot spectrometer. Enhancement in neutral temperatures associated with spread-F activity over Thumba (8·5°N, 76·8°E geographic, 0·6°S geomagnetic), which is on the magnetic equator were reported earlier. Additional data over Mt Abu for seven days bring out the following major features. (i) In theF-region over Mt Abu, the neutral temperature enhancements upto 200°K are observed on most of the nights when there is spread-F activity over the magnetic equator. (ii) There are no occasions which show temperature enhancements over Mt Abu without spread-F activity over the equator. On such occasions the observed atmospheric temperatures agree very well with those calculated on the basis of the Jachhia atmospheric model, both for magnetically quiet as well as disturbed days. (iii) There is a good indication that the increase inF-region temperature over Mt Abu is delayed with respect to the onset of spread-F over Thumba by approximately 15–30 min.  相似文献   

7.
The concentrations and physico-chemical states of 210Pb have been measured in Bikini Atoll and Washington State coastal waters, and 210Po in Washington coastal waters. Lead-210 concentrations of 113–133 dpm · m?3 were found in surface water collections near Bikini Atoll and 29–153 dpm · m?3 in Bikini Lagoon. The concentrations of 210Pb in near Bikini and in Washington State waters increased with depth in the upper 150m at a rate of 0.35–0.45dpm·m?3 · m?1. In the North Equatorial Current waters near Bikini Atoll 210Pb was found associated predominantly with the soluble (colloidal) fraction, but in Washington coastal waters 210Pb and 210Po were found associated with the paniculate (> 0.3 μm) fraction. The mean residence times of 210Pb, calculated from the atmospheric input to marine waters from precipitation and the concentrations measured in surface water, were consistent with the physico-chemical states of 210Pb found in samples collected in deep ocean and coastal waters. Approximate values of the mean residence times were calculated, for the upper 50 m, to be as follows: 58 days in the Strait of Juan de Fuca, 128 days at the 5-mile (8 km) station off Cape Flattery (Washington), 163 days at the 12-mile (19 km) station off Cape Flattery, and 2.6 yr near Bikini Atoll. It appears that 210Pb and 210Po can be used to trace particle removal rates in the upper layers of marine waters.  相似文献   

8.
Abstract A study of the seafloor of the Gulf of Cadiz west of the Strait of Gibraltar, using an integrated geophysical and sedimentological data set, gives new insights into sediment deposition from downslope thermohaline bottom currents. In this area, the Mediterranean Outflow (MO) begins to mix with North Atlantic waters and separates into alongslope geostrophic and downslope ageostrophic components. Changes in bedform morphology across the study area indicate a decrease in the peak velocity of the MO from >1 m s?1 to <0·5 m s?1. The associated sediment waves form a continuum from sand waves to muddy sand waves to mud waves. A series of downslope‐oriented channels, formed by the MO, are found where the MO starts to descend the continental slope at a water depth of ≈700 m. These channels are up to 40 km long, have gradients of <0·5°, a fairly constant width of ≈2 km and a depth of ≈75 m. Sand waves move down the channels that have mud wave‐covered levees similar to those seen in turbidite channel–levee systems, although the channel size and levee thickness do not decrease downslope as in typical turbidite channel systems. The channels terminate abruptly where the MO lifts off the seafloor. Gravity flow channels with lobes on the basin floor exist downslope from several of the bottom current channels. Each gravity flow system has a narrow, slightly sinuous channel, up to 20 m deep, feeding a depositional lobe up to 7 km long. Cores from the lobes recovered up to 8·5 m of massive, well‐sorted, fine sand, with occasional mud clasts. This work provides an insight into the complex facies patterns associated with strong bottom currents and highlights key differences between bottom current and gravity flow channel–levee systems. The distribution of sand within these systems is of particular interest, with applications in understanding the architecture of hydrocarbon reservoirs formed in continental slope settings.  相似文献   

9.
HAIRUO Qing 《Sedimentology》1998,45(2):433-446
The petrography and geochemistry of fine- and medium-crystalline dolomites of the Middle Devonian Presqu’ile barrier at Pine Point (Western Canada Sedimentary Basin) are different from those of previously published coarse-crystalline and saddle dolomites that are associated with late-stage hydrothermal fluids. Fine-crystalline dolomite consists of subhedral to euhedral crystals, ranging from 5 to 25 μm (mean 8 μm). The dolomite interbedded with evaporitic anhydrites that occur in the back-barrier facies in the Elk Point Basin. Fine-crystalline dolomite has δ18Ο values between ?1·6 to –3·8‰ PDB and 87Sr/86Sr ratios from 0·7079–0·7081, consistent with derivation from Middle Devonian seawater. Its Sr concentrations (55–225 p.p.m., mean 105 p.p.m.) follow a similar trend to modern Little Bahama seawater dolomites. Its rare earth element (REE) patterns are similar to those of the limestone precursors. These data suggest that this fine-crystalline dolomite formed from Middle Devonian seawater at or just below the sea floor. Medium-crystalline dolomite in the Presqu’ile barrier is composed of anhedral to subhedral crystals (150–250 μm, mean 200 μm), some of which have clear rims toward the pore centres. This dolomite occurs mostly in the southern lower part of the barrier. Medium-crystalline dolomite has δ18O values between ?3·7 to ?9·4‰ PDB (mean ?5·9‰ PDB) and 87Sr/86Sr ratios from 0·7081–0·7087 (mean 0·7084); Sr concentrations from 30 to 79 p.p.m. (mean 50 p.p.m.) and Mn content from 50 to 253 p.p.m. (mean 161 p.p.m.); and negative Ce anomalies compared with those of marine limestones. The medium-crystalline dolomite may have formed either (1) during shallow burial at slightly elevated temperatures (35–40 °C) from fluids derived from burial compaction, or, more likely (2) soon after deposition of the precursor sediments by Middle Devonian seawater derived from the Elk Point Basin. These results indicate that dolomitization in the Middle Devonian Presqu’ile barrier occurred in at least two stages during evolution of the Western Canada Sedimentary Basin. The geochemistry of earlier formed dolomites may have been modified if the earlier formed dolomites were porous and permeable and water/rock ratios were large during neomorphism.  相似文献   

10.
The Ulster White Limestone Formation is an unusual chalk because it underwent a period of post-depositional emergence and erosion, followed by burial under 1·5–2·0 km of Tertiary basalts. A high degree of pressure solution and cementation produced a well-lithified limestone with low porosities (2·3–10·4%). The Ulster White Limestone shows no evidence of thermally induced textural alteration, except for thin (<0·5 m) pseudospar contact recrystallization zones adjoining basalt dykes. Whole-rock δ18O values of samples not associated with basalt dykes range from - 3·26%o to - 6·50%o (PDB). The δ18O values of macropore cements range from - 4·96%o to - 11·52%o (mean=-8·27%o). Modelling of the diagenesis of the Ulster White Limestone using trace element concentrations and carbon, oxygen and strontium isotopic ratios of whole rock and cement samples suggests a low water-rock ratio and either marine or mixed marine-meteoric pore water environment during the main episode of recrystallization. The maximum possible burial temperature was modelled to be ? 105°C. The diagenetic history of the Ulster White Limestone is similar to that of North Sea chalks that are at comparable burial depths as the Ulster White Limestone after basalt deposition. The geochemical data show no indication of hydrothermal alteration associated with the overlying basalts. The degree of alteration of fine-grained limestones composed predominantly of low-magnesium calcite, such as the Cretaceous/Tertiary chalks, appears to be controlled largely by the burial (effective stress) history of the limestone.  相似文献   

11.
Ancient evaporite deposits are geological archives of depositional environments characterized by a long‐term negative precipitation balance and bear evidence for global ocean element mass balance calculations. Here, Cretaceous selenite pseudomorphs from western Anatolia (‘Rosetta Marble’) — characterized by their exceptional morphological preservation — and their ‘marine’ geochemical signatures are described and interpreted in a process‐oriented context. These rocks recorded Late Cretaceous high‐pressure/low‐temperature, subduction‐related metamorphism with peak conditions of 1·0 to 1·2 GPa and 300 to 400°C. Metre‐scale, rock‐forming radiating rods, now present as fibrous calcite marble, clearly point to selenitic gypsum as the precursor mineral. Stratigraphic successions are recorded along a reconstructed proximal to distal transect. The cyclical alternation of selenite beds and radiolarian ribbon‐bedded cherts in the distal portions are interpreted as a two type of seawater system. During arid intervals, shallow marine brines cascaded downward into basinal settings and induced precipitation. During more humid times, upwelling‐induced radiolarian blooms caused the deposition of radiolarite facies. Interestingly, there is no comparable depositional setting known from the Cenozoic world. Meta‐selenite geochemical data (δ13C, δ18O and 87Sr/86Sr) plot within the range of reconstructed middle Cretaceous seawater signatures. Possible sources for the 13C‐enriched (mean 2·2‰) values include methanogenesis, gas hydrates and cold seep fluid exhalation. Spatially resolved component‐specific analysis of a rock slab displays isotopic variances between meta‐selenite crystals (mean δ13C 2·2‰) and host matrix (mean δ13C 1·3‰). The Cretaceous evaporite‐pseudomorphs of Anatolia represent a basin wide event coeval with the Aptian evaporites of the Proto‐Atlantic and the pseudomorphs share many attributes, including lateral distribution of 600 km and stratigraphic thickness of 1·5 to 2·0 km, with the evaporites formed during the younger Messinian salinity crisis. The Rosetta Marble of Anatolia may represent the best‐preserved selenite pseudomorphs worldwide and have a clear potential to act as a template for the study of meta‐selenite in deep time.  相似文献   

12.
A 4·7 km2 field of sediment waves occurs in front of the Slims River delta in Kluane Lake, the largest lake in the Yukon Territory. Slims River heads in the Kaskawulsh Glacier, part of the St Elias Ice Field and discharges up to 400 m3 s?1 of water with suspended sediment concentrations of up to 7 g l?1. The 19 km long sandur of Slims River was created in the past 400 years since Kaskawulsh Glacier advanced and dammed the lake and the sandur has advanced into Kluane Lake at an average rate of 48 m a?1. However, this rate is decreasing as flow is diverted from Slims River because of the retreat of the Kaskawulsh Glacier. The sandur and a road constructed on the delta remove coarse‐grained sediment, so the river delivers dominantly mud to the lake. Inflow during summer generates quasi‐continuous turbidity currents with velocities up to 0·6 m s?1. The front of the delta consists of a plane surface sloping lakeward at 0·0188 (1·08°). A field of sediment waves averaging 130 m in length and 2·3 m in amplitude has developed on this surface. Slopes on the waves vary from ?0·067 (?3·83°, i.e. sloping in the opposite direction to the regional slope) to 0·135 (7·69°). The internal structure of the sediment waves, as documented by seismic profiling, shows that sedimentation on the stoss portion of the wave averages 2·7 times that on the lee portion. Rates of sediment accumulation in the wave field are about 0·3 m a?1, so these lacustrine waves have formed in a much shorter period of time (less than 200 years) and are advancing upslope towards the delta much more quickly (1 to 2 m a?1) than typical marine sediment waves. These waves formed on the flat surface of the lake floor, apparently in the absence of pre‐existing forms, and they are altered and destroyed as the wave field advances and the characteristics of the turbidity currents change.  相似文献   

13.
Surat city of India, situated 100 km downstream of Ukai Dam and 19.4 km upstream from the mouth of River Tapi, has experienced the largest flood in 2006. The peak discharge of about 25,770 m3 s?1 released from the Ukai Dam was responsible for a disaster. To assess the flood and find inundation in low-lying areas, simulation work is carried out under the 1D/2D couple hydrodynamic modeling. Two hundred ninety-nine cross sections, two hydraulic structures and five major bridges across the river are considered for 1D modeling, whereas a topographic map at 0.5 m contour interval was used to produce a 5 m grid, and SRTM (30 and 90 m) grid has been considered for Surat and the Lower Tapi Basin. The tidal level at the river mouth and the release from the Ukai Dam during 2006 flood are considered as the downstream and upstream boundaries, respectively. The model is simulated under the unsteady flow condition and validated for the year 2006. The simulated result shows that 9th August was the worst day in terms of flooding for Surat city and a maximum 75–77% area was under inundation. Out of seven zones, the west zone had the deepest flood and inundated under 4–5 m. Furthermore, inundation is simulated under the bank protection work (i.e., levees, retaining wall) constructed after the 2006 flood. The simulated results show that the major zones are safe against the inundation under 14,430 m3 s?1 water releases from Ukai Dam except for the west zone. The study shows the 2D capability of new HEC-RAS 5 for flood inundation mapping and management studies.  相似文献   

14.
Methane produced in anoxic organic-rich sediments of Cape Lookout Bight, North Carolina, enters the water column via two seasonally dependent mechanisms: diffusion and bubble ebullition. Diffusive transport measured in situ with benthic chambers averages 49 and 163 μmol · m ?2 · hr ?1 during November–May and June–October respectively. High summer sediment methane production causes saturation concentrations and formation of bubbles near the sediment-water interface. Subsequent bubble ebullition is triggered by low-tide hydrostatic pressure release. June–October sediment-water gas fluxes at the surface average 411 ml (377 ml STP: 16.8 mmol) · m?2 per low tide. Bubbling maintains open bubble tubes which apparently enhance diffusive transport. When tubes are present, apparent sediment diffusivities are 1.2–3.1-fold higher than theoretical molecular values reaching a peak value of 5.2 × 10?5 cm2 · sec?1. Dissolution of 15% of the rising bubble flux containing 86% methane supplies 170μmol · m?2 · hr?1 of methane to the bight water column during summer months; the remainder is lost to the troposphere. Bottom water methane concentration increases observed during bubbling can be predicted using a 5–15 μm stagnant boundary layer dissolution model. Advective transport to surrounding waters is the major dissolved methane sink: aerobic oxidation and diffusive atmospheric evasion losses are minor within the bight.  相似文献   

15.
Sediment accumulation rate studies utilizing excess 210Pb and 137Cs were conducted as part of recent investigations of biogeochemical cycling at a single site in Cape Lookout Bight, a rapidly changing coastal basin on the Outer Banks of North Carolina (U.S.A.). Cores three meters in length reveal a depositional history for the bight interior characterized by a gradual transition in texture from coarse-grained to fine-grained material over the period 1946–1979. This transition is controlled by progressive enclosure of the bight by an active northerly migrating recurved spit. The textural gradation is periodically interrupted by layers of well-sorted sand associated with major storm events. Lead-210 data indicate that the upper meter of the sediment has accumulated at a rate of 3.35 to 4.71 g · cm?2 · yr?1 or approximately 8.4 to 11.8 cm · yr?1 (at ø = 0.84). Below 120 cm depth, dilution of clay and silt by low activity sand necessitates correction of the 210Pb profile in order to establish a geochronology. Grain size 210Pb distribution measurements at three depths reveal that the specific activity (dpm · g?1) of clay is 3.2 times that of silt and 24.7 times that of sand. Corrections of bulk sediment excess 210Pb activities based on these measurements lead to dates for textural changes which are consistent with charted changes in basin morphology and major storm events.Sixteen 137Cs measurements between 33–241 cm depth reveal a peak activity at 105–115 cm and indicate a minimum sedimentation rate of approximately 2.7 g · cm?2 · yr?1.  相似文献   

16.
Expansive playa‐lake systems situated in high‐altitude piggyback basins are important and conspicuous components of both modern and ancient cordilleran orogenic systems. Extant playa lakes provide vital habitat for numerous endemic species, whereas sediments from these deposystems may record signals of climate change or develop natural resources over geological time. Laguna de los Pozuelos (North‐west Argentina) provides the opportunity for an actualistic sedimentological and geochemical assessment of a piggyback basin playa lake in an area of critical interest for understanding Quaternary palaeoclimate dynamics. Silty clays and diatom ooze are the dominant playa‐lake centre microfacies, with concentrations of total organic carbon and biogenic silica commonly exceeding 1·5 wt% in this sub‐environment. Elemental and stable isotopic analyses point to a mixed organic matter composition in the playa‐lake centre, with substantial contributions from algae and transported aquatic macrophytes. Bulk sediment and organic mass accumulation rates in the southern playa‐lake centre approach 0·22 g cm?2 year?1 and 2·89 mg cm?2 year?1, respectively, indicating moderately rapid deposition with negligible deflation over historic time. Playa margin facies contain higher percentages of fragmented biogenic carbonate (ostracods and charophytes) and inorganically precipitated aragonite crusts due to seasonal pumping and evaporation of ground water. Organic matter accumulation is limited along these heavily bioturbated wet and dry mud flats. Fluvial–lacustrine transitional environments, which are key waterbird habitats, are either silty terminal splay (northern axis) or sandy deltas (southern axis) containing highly oxidized and partially allochthonous organic matter. Modern analogue data from Laguna de los Pozuelos provide key insights for: (i) environmental reconstructions of ancient lake sequences; and (ii) improving facies models for piggyback basins.  相似文献   

17.
Sound velocities to 37 GPa have been obtained for MgO based on new sideband measurements and sound velocities have been calculated for MgAl2O4 to 11 GPa based on previous sideband measurements. The basic principles of the sideband fluorescence method are presented and it is shown that the vibrational mode energies in the sidebands are independent of the impurity cation and represent modes of the undisturbed lattice. Furthermore, it is shown that the acoustic modes represent spherically averaged velocities by comparison of these results to the directional information provided by ultrasonic data. The resulting pressure derivatives of the elastic moduli for both materials are in excellent agreement with those derived from lower-pressure ultrasonic data. The velocities over the pressure range of this study may be described by the following relations: for MgO, vs=6.05 (1)+0.0381 (13) · P-3.6(4) × 10?4 · P2 and vP=9.70(2)+0.0704(20) · P-5.6(6)×10?4 · P2 and for MgAl2O4, vs=5.49(5)+0.001(11) · P and vP = 9.785 (11)+0.047 (5) · P-0.0010(5) · P2 where the pressure P is in GPa. Velocity is linear with density over the pressure range of this study.  相似文献   

18.
Cobalt, like Mg, may cause the precipitation of aragonite rather than calcite in aqueous solutions due to the adsorption and crystal poisoning of calcite by a hydrated ion. Solutions containing NaCl and CaCl2, having the ionic strength and Ca content of seawater (35‰ salinity), were spiked with known amounts of CoCl2. Calcium carbonate was precipitated by the addition of 0.7 ml of 1 M Na2CO3. All experimental runs were made at 25°C, and all products were examined by X-ray diffraction. At low concentrations of Co (< 5·?4M) calcite and vaterite formed. At concentrations from 5·10?4 M to 2·10?3M, the products consisted of combinations of calcite and vaterite; aragonite and calcite; aragonite and vaterite; calcite, vaterite and aragonite. In solutions of 3·10?3M CoCl2, most precipitates were aragonite with only one sample containing a small amount of calcite. All precipitates from 5·10?3M CoCl2 solutions either contained aragonite or were amorphous. Solutions with concentrations of 1 · 10?2M CoCl2 produced only amorphous precipitates. All precipitates contained an amorphous violet phase, assumed to be basic cobaltous carbonate (2CoCO3·Co(OH)2·H2O).  相似文献   

19.
Porewaters from a variety of Recent, Pleistocene, and Eocene lithified marine carbonate frameworks displayed similar chemical characteristics: highly depleted concentrations of dissolved oxygen (>20 μM), elevated levels of dissolved methane (25-5000 nM), and near-seawater sulphate levels. These porewaters also had low pH values (7·5-7·9), and contained elevated concentrations of sulphide (4–10 μM), dissolved inorganic carbon (2·05–2·46 mM), and inorganic nutrients. Hydrocarbon composition data indicate that the methane is biogenic, whereas the methane δ13C values (–47·4 ± 2·7%0) suggest that it has been subject to oxidation. The porewater dissolved inorganic carbon δ13C values varied from –0·6 to –39%0, suggesting input of carbon dioxide from organic matter oxidation. We conclude that anaerobic diagenesis involving bacterial degradation of organic matter is a common process in lithified marine carbonates and hypothesize that it may be an important factor controlling their carbonate geochemistry.  相似文献   

20.
One-dimensional photochemical diffusive model has been used to obtain the altitude and temporal variation of O3 in the range of 50 to 150km height. More than 60 chemical reactions and photo-dissociatons of oxygen-hydrogen atmosphere are incorporated. Their contribution in the formation or distribution directly or indirectly, is critically examined. In the altitude profile of O3 concentration, it is observed that there is slight increase in concentration around 85km which is due to the increase in production rate at that height through the following reaction as: O+O2+M→O3+M (M=total atmospheric concentration) and the sharp decrease above 90km is also through the same reaction. Two altitude profiles of ozone concentration, one from photochemical equilibrium and other from non-equilibrium model are obtained. It is seen that in the mesosphere these two profiles are comparable. Further it is also seen that the average night time concentration is more than that in the day. Results obtained are compared with experimental values.  相似文献   

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