首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 78 毫秒
1.
云南东川地区昆阳群的形成时代及地层层序一直令人关注,已获得的一些数据虽然具有参考意义,但高质量的SHRIMP定年还很缺乏。在东川地区昆阳群黑山组中上段发育的近180m厚的具有地层意义的晶屑、岩屑凝灰岩中采集样品D0202一件,选出锆石百余粒,获得SHRIMPU-Pb加权平均年龄为(1503±17)Ma。样品D0202的锆石Th/U大于0.48,并具清晰的振荡环带结构,均为岩浆成因的锆石,表明黑山组形成于中元古代早期。这一年龄表明昆阳群的形成时代至少大于1500Ma,为准确地标定昆阳群的时代和层序提供了新的参考依据。  相似文献   

2.
滇中地区中元古界"昆阳群"、"东川群"的地层层序是长期争议的重大基础地质问题。本次在峨山地区东川群黑山组中发育的厚近5m厚的流纹质碎斑熔岩采集样品D0023一件,选出120余粒锆石,获得的锆石LA-ICP-MS U-Pb加权平均年龄为(1569. 2±4. 5) Ma。样品锆石的Th/U值均大于0. 5,具有清晰的振荡环带结构,均为岩浆成因的锆石,表明东川群黑山组形成于中元古代早期,属非造山相关的火山岩系,可能是哥伦比亚超大陆裂解作用在扬子陆块的响应,为东川群的地层时代和层序研究增添了新资料。  相似文献   

3.
滇中昆阳群一直是华南前寒武纪地质研究的热点之一,其地层序列、时代与区域对比长期存在争议。通过对滇中易门县小街乡普家村-岔河水库剖面禄表组2个凝灰岩样品进行SHRIMP锆石U-Pb定年,获得禄表组凝灰岩的锆石206Pb/238U年龄为878.5±4.7Ma和878.0±4.0Ma,首次证实禄表组的形成时代为新元古代中期。禄表组凝灰岩SHRIMP锆石U-Pb年龄的获得,有利于正确认识昆阳群的划属关系,并为西南地区青白口纪地层格架的建立和对比提供可靠的年代学依据。  相似文献   

4.
滇中玉溪—昆阳一带广泛出露的中元古界昆阳群是一套与晋宁运动密切相关的浅变质火山-沉积岩系,其形成时代、沉积充填序列及大地构造属性一直存在争议。出露于峨山县美党地区的昆阳群黑山头组富良棚段发育有厚近百米的安山质熔结凝灰岩、晶屑凝灰岩、玄武岩及岩屑凝灰岩。对样品D0121-1及D0121-2进行同位素年代学研究,分别获得LA-ICP-MS锆石U-Pb年龄加权平均值为1007±13Ma和1005±18Ma;同时,样品D0121-2中还获较多的2200±15Ma继承性锆石,推测滇中地区应存在古元古代的地质体。2件样品锆石的Th/U值均大于0.3,均具清晰的振荡环带结构,均为岩浆成因的锆石,表明黑山头组富良棚段形成于中元古代晚期,属于与造山作用相关的火山岩系,可能是罗迪尼亚超大陆事件在扬子陆块的响应,是全球格林维尔期造山过程的组成部分。  相似文献   

5.
对河上镇群底部骆家门组2个凝灰岩样品进行锆石测年,得到的2组SHRIMP 锆石U-Pb年龄分别为824±5Ma和832±6Ma、791±15Ma。同时,对骆家门组底部花岗岩砾石中的锆石进行了测试,获得的SHRIMP 锆石U-Pb年龄为901±9Ma。由此进一步约束了骆家门组的形成时代。骆家门组年龄的标定对于浙江地区神功运动界面上、下地层双溪坞群和河上镇群年龄的完善,进而确定江南造山带的地层格架和地层对比具有重要意义。这些地层年龄和已经获得的角度不整合于骆家门组之下双溪坞群的年龄数据,为神功运动时限的约束和对比提供了重要依据。  相似文献   

6.
云南东川望厂组熔结凝灰岩锆石SHRIMP U Pb年龄及其意义   总被引:3,自引:0,他引:3  
本文报道了云南东川地区望厂组中熔结凝灰岩锆石的SHRIMP U-Pb年龄。其中自形结构、环带清晰锆石的不一致曲线与谐和线上交点的207Pb/206Pb年龄分别为2317±13Ma(n=13,MSWD=3.3),13个点的加权平均年龄为2299±14Ma(n=13,MSWD=5.9),表明望厂组地层的沉积时代为古元古代早—中期。东川地区下四组地层与滇中昆阳群(黄草岭组—美党组)和四川会理群(淌塘组—天宝山组)的沉积时代相差近1.0Ga。为了区别于昆阳群和会理群,建议对本区下四组地层(洒海沟组、望厂组、菜园湾组、平顶山组)独立建群,即汤丹群。汤丹群是目前为止康滇地区已发现的最古老的地层建造之一,经历过古元古代中期的挤压过程(东川运动)和古元古代末期的拉张过程,可能是相对于扬子古陆核独立存在、并构成早—中元古宙Columbia超级大陆的一个小的古老陆块。  相似文献   

7.
对河上镇群底部骆家门组2个凝灰岩样品进行锆石测年,得到的2组SHRIMP锆石U-Pb年龄分别为824±5Ma和832±6Ma、791±15Ma。同时,对骆家门组底部花岗岩砾石中的锆石进行了测试,获得的SHRIMP锆石U-Pb年龄为901±9Ma。由此进一步约束了骆家门组的形成时代。骆家门组年龄的标定对于浙江地区神功运动界面上、下地层双溪坞群和河上镇群年龄的完善,进而确定江南造山带的地层格架和地层对比具有重要意义。这些地层年龄和已经获得的角度不整合于骆家门组之下双溪坞群的年龄数据,为神功运动时限的约束和对比提供了重要依据。  相似文献   

8.
对出露于松潘-甘孜褶皱带四川茂县渭门一带的渭门组的形成时代一直令人关注,但迄今为止未见其形成年龄的报道,在开展1∶25万绵阳幅区域地质调查(修测)时,在渭门组中上段发育近100 m厚的具地层意义的凝灰岩中采集高精度SHRIMP测年样品一件,获得SHRIMP U-Pb加权平均年龄为530.1±4.3 Ma(MSWD=1.5)。样品中的锆石Th/U介于0.36~1.09 Ma之间,并具清晰的振荡环带结构,均为岩浆成因的锆石,表明渭门组形成于早寒武世,为准确地界定渭门组的时代和层序提供了新的参考依据,对正确认识松潘-甘孜褶皱带的地层格架和构造濱化具有重要意义。  相似文献   

9.
通安组是扬子克拉通西南缘褶皱基底的组成部分,可分为5个岩性段。本文利用凝灰质粉砂岩(样品100620-1)中碎屑锆石和侵入通安组的辉长-闪长岩脉(样品100620-1-1和样品100620-2-2)中岩浆锆石的LA-ICP-MSU-Pb年龄探讨通安组的形成时代。通安组三段中凝灰质粉砂岩的碎屑锆石有两个主要的峰值年龄,分别为1.8~1.9Ga和2.28~2.38Ga,这表明通安组三段的沉积物来自不同的物源区。该凝灰质粉砂岩中最年轻的3粒锆石的207Pb/206Pb平均年龄为1806Ma。从侵入到通安组第三段的辉长-闪长岩的岩浆锆石中获得了1513±13Ma的207Pb/206Pb加权平均年龄(样品100620-2-1)和1531±18Ma的上交点年龄(样品100620-2-2)。这些新获得的年龄数据可以限定通安组的形成时限为1.8~1.5Ga。辉长-闪长岩脉1513Ma和1531Ma的年龄数据与东川群黑山组火山凝灰岩1503±7Ma的年龄结果相似,表明侵入到通安组三段中的辉长-闪长岩脉与东川群黑山组的火山凝灰岩形成于一个岩浆旋回的同一阶段。因此,通安组三段大致相当于云南东川群的黑山组。  相似文献   

10.
本文报道了云南东川地区望厂组中熔结凝灰岩锆石的SHRIMP U Pb年龄.其中自形结构、环带清晰锆石的不一致曲线与谐和线上交点的207Pb/206Pb年龄分别为2317±13 Ma(n=13,MSWD=33),13个点的加权平均年龄为2299±14 Ma(n=13,MSWD=59),表明望厂组地层的沉积时代为古元古代早—中期.东川地区下四组地层与滇中昆阳群(黄草岭组—美党组)和四川会理群(淌塘组—天宝山组)的沉积时代相差近1.0Ga.为了区别于昆阳群和会理群,建议对本区下四组地层(洒海沟组、望厂组、菜园湾组、平顶山组)独立建群,即汤丹群.汤丹群是目前为止康滇地区已发现的最古老的地层建造之一,经历过古元古代中期的挤压过程(东川运动)和古元古代末期的拉张过程,可能是相对于扬子古陆核独立存在、并构成早—中元古宙Columbia超级大陆的一个小的古老陆块.  相似文献   

11.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

15.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

16.
17.
18.
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.  相似文献   

19.
20.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号