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1.
The formation ages of global magmatic sulfide Ni-Cu deposits are from Archean to Mesozoic,the Neoarchean and Neoproterozoic are the two peaks.In China,the formation ages of magmatic sulfide deposits are from Proterozoic to Mesozoic,and the Neoproterozoic and late Paleozoic are the two peaks,.Compared with the global magmatic deposits,there is no case study of the Archean magmatic Ni-Cu sulfide deposits in China before.The nickel deposits formed in Neoproterozoic are located on the margin of the North China Block and Yangtze Block(e.g.Jinchuan,Dapoling),and those formed in the late Paleozoic are mainly distributed in the Central Asian Orogenic Belt(CAOB).Emeishan and Tarim Large Igneous Provinces(LIPs).such as Kalatongke,Yangliuping,and Pobei.  相似文献   

2.
This paper discussed the stabilities of heavy metals in soils treated with red mud. Soil has been polluted by heavy metals more and more seriously during recent several decades, and they are harmful to mankind and animals. The current tendency is to develop in-situ technique by using industrial processing waste as additives to stabilized heavy metals to minimize the disturbance of contaminated soils. Soil samples were collected from the Niujiaotang mining area, Guizhou Province, southwestern China. They were farmed soils polluted weakly by fly ash (QBT) and polluted badly by waste water (BXT) from smelter, respectively. One of the red mud samples (BRM) was collected from Bayer process and the other (CRM) from confederate process in the Alumina Plant of Guizhou. Free metal ion concentrations were analyzed with Donnan Membrane Technique and predicted with ECOSAT. The concentrations of free heavy metal ions in QBT increased after appending CRM, but decreased when adding BRM. The more the red mud was added, the higher the concentration would be, and the free concentrations of nickel and cadmium ions would vary more greatly than those of copper and zinc ions. When appending red muds into BXT, the free concentrations of copper and zinc ions varied little. While those of free nickel and cadmium decreased obviously at the ratio of 2.00%. The variation of the concentration was still biggish after appending BRM at the ratio of 0.50%, but smaller than that of 2.00%. The concentrations of free cadmium ions increased after adding CRM at the ratio of 0.50%. All experimental processes were modeled through ECOSAT. The predicted and measured results were consistent, except for zinc. Contributions of soil sorbents to the heavy metal adsorptions were also modeled through ECOSAT. The sorbents in soil included soil organic matter, iron hydroxides, clay and the Donnan gel of soil organic matter. Compared to the soils without red muds, no matter what kind of red mud and how much was added in soil, the contributions changed slightly.  相似文献   

3.
The Shilu iron ore deposit, located in the western Hainan Province, South China, is one of the most important iron-ore mining districts in China not only for its huge reserves of hematite- rich ores, but also for its potentially economic significance of associated metals of copper, cobalt, nickel, silver, lead and zinc, and of non-metals of dolomite, quartzite,barite,gypsum and sulfur.  相似文献   

4.
Acid rain is one of China’s major environmental problems and emissions of sulphur and nitrogen are still increasing. The acid rain situation in China is somewhat different from what is seen in Europe and North America. Sulfur deposition is very high, but…  相似文献   

5.
Study on Modern Plant C-13 in Western China and Its Significance   总被引:2,自引:0,他引:2  
Organic carbon isotopic composition(δ^13C) is one of the important proxies in paleoenvironment studies.In this paper modern plant δ^13C in the arid areas of China and Tibetan Plateau is studied.It is found that most terrestrial plant species in western China are C3 plants with δ^13C values ranging from -32.6‰ to -23.2‰ and only few species are C4 plants with δ^13C values from -16.8‰ to -13.3‰.The δ^13C is closely related to precipitation (or humidity),i.e., light δ^13C is related to high precipitation(or humid climate),while heavy δ^13C to low precipitation (or dry climate),but there is almost no relation between plant δ^13C and temperature.Submerged plants have δ^13C values ranging from -22.0‰ to -12.7‰,like C4 plants,while merged plants have δ^13C values ranging from -28.1‰ to -24.5‰,like C3 C4 plants,while marged plants have δ^13C values ranging from -28.1‰ to -24.5‰,like C3 plants.It can then be concluded that organic δ^13C variations in terrestrial sediments such as loeas and soil in western China can indicate precipitation changes,but those in lake sediments can reflect organic sources and the productivity of different types of aquatic plants.  相似文献   

6.
The Huayuan Pb-Zn ore district in China, located in western Hunan Province, is a giant carbonate-hosted Pb-Zn ore district. The source of ore-forming brines in this ore district remains poorly constrained. Whether the highly saline brines are derived from evaporated seawater or dissolved evaporates continues to be intensely debated. Carbonate minerals associated with Pb-Zn mineralization have δ13CV-PDB and δ18OV-SMOW values ranging from ?5.55‰ to +1.35‰ (mean value of ?0.69‰; n = 14) and +16.28‰ to +25.05‰ (mean value of +20.22‰; n = 14), respectively. This indicates that carbonate minerals are dominantly formed from dissolved ore-hosted carbonate rocks. The δ34S values of sulfides range from +20.2‰ to +36.8‰, with an average value of +30.0‰ (n = 27). These results suggest that sulfur is predominantly derived from the thermochemical sulfate reduction of marine sulfate. The crush-leach analyzed solute data of fluid inclusions in sphalerite show the ore-forming fluids have Cl/Br molar ratios range from 118 to 384, and Na/Br molar ratios from 39 to 160 (n = 8). These Cl/Br ratios of hydrothermal fluid are much lower than those of seawater (657 to 564), but are consistent with bittern brines through early halite precipitation. We propose that ore-forming fluids are mainly derived from evaporitic basin brines, which leached base metals from the basement and/or country rocks. The brine then migrated to the basin margins through clastic rocks of basement and then precipitated sul?des by thermochemical sulfate reduction.  相似文献   

7.
The nickel deposits mainly distributed in 19 provinces and autonomous regions in China are 339 ore deposits/occurrences, including 4 super large-scale deposits, 14 large-scale deposits, 26 middle-scale deposits, 75 small-scale deposits, and 220 mineralized occurrences. The prediction types of mineral resources of nickel deposits are magmatic type, marine sedimentary type and regolith type. The formation age is from the Neoarchean to the Cenozoic with two peaks in the Neoproterozoic and the late Paleozoic. The nickel deposits formed in the Neoproterozoic are located on the margin of the North China Block and Yangtze Block, and those formed in the late Paleozoic are mainly distributed in the Central Asian Orogenic Belt (CAOB), Emeishan and the Tarim Large Igneous Provinces (LIPs). Magmatic nickel deposits are mainly related with broken-up continental margin, post-collision extension of the orogenic belt and mantle plume. According to different tectonic backgrounds and main characteristics of magmatism, the Ni-Cu-Co-PGE metallogenic series types of ore deposits related with mantle-derived mafic-ultramafic rocks can be divided into 4 subtypes: (1) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in the broken-up continental margin, (2) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in mantle plume magmatism, (3) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in the subduction of the orogenic belt, and (4) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in post-collision extension of the orogenic belt. We have discussed in this paper the typical characteristics and metallogenic models for Neoproterozoic Ni-Cu-(PGE) deposits related with broken-up continental margin, Cambrian marine sedimentary Ni-Mo-V deposits related with black shale, early Permian Ni-Cu deposits related with post-collision extension of the orogenic belt, late Permian Ni-Cu-(PGE) deposits related with Large Igneous Provinces (LIPs), and Cenozoic Ni-Au deposits related with regolith. The broken-up continental margin, mantle plume and post-collision extension of the orogenic belt are important ore-forming geological backgrounds, and the discordogenic fault, mafic-ultramafic intrusion, high MgO primitive magma (high-MgO basaltic magma), deep magmatism, sulfur saturation and sulfide segregation are 6 important geological conditions for the magmatic nickel deposits.  相似文献   

8.
The Taiwan Strait is a part of the continental-margin rift of eastern China, which can tectonically be divided into the Taiwan Strait basin, southwestern Taiwan basin and Penhu-Beigang uplift. The basins are structurally semi-graban down-faulted ones in character. The Cretaceous-Cenozoic sedimentary strata in the basins have a maximum thickness of over 10,000 m. The formation and development of the Taiwan Strait rift were not only affected by both the East China Sea basin and South China Sea basin but also closely related to the Central Range collision orogen of Taiwan. In the Cenozoic, the Taiwan Strait area experienced, under the influence of a multiple of tectonic mechanisms, three stages of evolution: poly-centre downfault-ing, down warping-faulting and foreland basin formation. The depositional centres of the basins migrated from west to east during the Tertiary, resulting in the thinning of the Palaeogene strata from west to east but that of the Neogene in the reverse direction. All this determine  相似文献   

9.
There are giant mineral deposits, including the Jinding Zn-Pb and Baiyangping Ag-Co-Cu, and otherimportant mineral deposits (e.g., Baiyangchang Ag-Cu, Jinman Cu deposits, etc.) in the Lanping Mesozoic-Cenozoic Basin, Yunnan Province, China. The tabular ore-bodies and some veins hosted in terrestrial clastic rocks of the Mesozoic-Cenozoic age and no outcropping of igneous rocks in the giant deposits lead to the proposal of syngenetic origin, but the giant mineral deposits are not stratabound (e.g. MVT, sandstone- and Sedex-type). They formed in a continental red basin with intense crust movement. The mineralization is controlled by structures and lithology and occurs in different strata, and no sedimentary nature and no exhalative sediments are identified in the deposits. The deposits show some relations with organic matter (now asphalt and petroleum) and evaporates (gypsum). The middle-low-temperature (mainly 110℃ to 280℃) mineralization took place at a depth of about 0.9 km to 3.1 km during the early  相似文献   

10.
The Wadi Sikait area lies at about 95 km southwest of Marsa Alam City along the Red Sea Coast, Eastern Desert, Egypt. It is occupied by Precambrian rocks of ophiolitic mélange, metamorphosed sandstones (MSS), gab-bros and monzogranites which were later intruded by lamprophyre dykes and quartz veins. The lamprophyre dykes were extruded in NW-SE and NE-SW trends cutting monzogranites and metamor-phosed sandstones. The lamprophyres are porphyritic and composed of clinopyroxene, olivine and amphibole phenocrysts enclosed in a fine-grained groundmass of clinopyroxene, amphibole, opaque and lithium mica. The al-teration products are represented by amphibole (tremolite-actinolite and hornblende), carbonate, epidote, chlorite, iddingsite, clay minerals, limonite and serpentine. The Sikait lamprophyre dykes can be classified as alkaline lamprophyres characterized by silica contents rang-ing from 41.65 wt% to 50.88 wt% and Na2O>K2O. They are enriched in LILE, LREE and HFSE, but strongly de-pleted in compatible elements such as Cr and Ni relative to the primitive mantle. Sikait lamprophyres have moderate Zr/Hf (35.6-52.8) and Nb/Ta (20.5-22.5) ratios. Most of these features are attributed to the origin of these dykes from the metasomatized mantle affected by subduction-related fluid. These lamprophyres are compositionally similar to Salu lamprophyres in eastern China. The Sikait lamprophyre samples have high LREE (320×10-6-419×10-6) relative to HREE (20×10-6-33×10-6) with ratios (LREE/HREE=11.6-18.7) and no negative Eu anomaly (Eu/Eu*=0.9-1.04). The relative presence of posi-tive Ce anomaly (Ce/Ce*=1.04) in lamprophyre samples suggests the oxidizing condition under which the REEs were precipitated due to the common occurrence of fluorite and apatite.  相似文献   

11.
Based on studies of the reflectance of Ordovician and Silurian zooclasts from 11 sections around the Huangling Anticline, Hubei, China, combined with determination of the conodont colour alteration indices (CAI) and of infrared spectroscopy of dispersed organic matter from the same or adjacent horizons, it is further proved that reflectances of graptolites, chitinozoans and scolecldonts, like vitrinite and natural bitumen, increase with increasing maturation, but follow different reflectance paths. They may be used, therefore, as thermal maturation indicators. Graptolites display optically strong anisotropy. The maximum reflectance measured from graptolite on polished section cut parallel to the bedding plane is the most suitable for determination of maturation of their host rocks. In polished section chitinozoan and scolecodont show reflectance, but no bireflectance owing to their isotropy. The random reflectance of chitinozoans is higher than that of scolecodonts in the case of the same maturity. By analysing the distribution trends of graptolite, chitionzoan and scolecodont reflectances, the Ordovician and Silurian strata can be subdivided into three areas of maturation in the present region. The potential of oil or gas generation is discussed for each area. The result is basically coincident with the distribution pattern of regional organic maturation presented by CAI and infrared spectroscopic determination of organic matter.  相似文献   

12.
The tectonic evolution of SE China block since late Paleozoic remains debated.Here we present a new set of zircon U-Pb geochronological,Lu-Hf isotopic data and whole-rock geochemistry for two stages of basicintermediate dykes from the southwestern Fujian.The samples were collected from the NE-trending(mainly diabases) and NW-trending(mainly diabasic diorites) dykes and yielded zircon U-Pb ages of 315 and 141 Ma,with ε_(Hf)(t) values of-8.90 to 7.49 and-23.39 to-7.15(corresponding to T_(DM2) values of 850 to 1890 Ma and 737 to 2670 Ma),respectively.Geochemically these rocks are characterized by low TiO_2(0.91-1.73 wt.%)and MgO(3.04-7.96 wt.%),and high Al_2O_3(12.5-16.60 wt.%) and K_2O(0.60-3.63 wt.%).Further they are enriched in LREEs and ULEs(Rb,Ba,Th and K).but depleted in HFSEs(Nb,Ta and Zr).The tectonic discrimination analysis revealed that the dykes were formed in an intraplate extensional environment.However,the NW trending dykes show crust-mantle mixed composition,which indicate an extensional tectonic setting with evidence for crustal contamination.The SE China block experienced two main stages of extensional tectonics from late Carboniferous to early Cretaceous.The tectonic evolution of the SE China block from late Devonian to Cretaceous is also evaluated.  相似文献   

13.
The Tengchong volcanies in western Yunnan Province, China, are located in the eastern part of the collision margin between Indian and Eurasian Plates. Alternating extention and compression controlled the eruption, from late Tertiary to Holeeno, of at least 5 groups of volcanics consisting of a Major series of hlgh-Al basalts (3 groups), a high-K andesite-dacite group and a high-Mg basalt group. The Major series has a range of GNd from 0.7 to-6.7 and Sr^87/Sr^86 from 0.70595 to 0.70881, exhibiting good linear correlations between Zr/Ni and Zr as well as between Nd. and both Sm/Nd and 1/Nd and similar chondrite-normalized incompatible element patterns. This suggests an ecologitic source metasomatized with fluids derived from parts of thesubducted Indian plate.The high-K andesite-dacite group shows a more extreme isotopic composition of GNd=-12.3, Sr^87/Sr^66=0.71124. It is chemically comparable to the calc-alkaline lavas in Xizang and could be resulted from mixing between shallow mantle zones and lower crust. The high-Mg basalt group has Sr^87/Sr^86-0.708 and slightly negative GNd (-2). They are similar, in chemical composition and possibly also in source, to the intraplate basalts in east China. A partial melting model of isotopic tmequilibrium system has been proposed to explain the isotope and trace element correlations of Tengchong volcanics.  相似文献   

14.
New data from abundant vegetative shoots and cuticular analysis are provided for the Cretaceous cheirolepidiaceous conifer Pseudofrenelopsis gansuensis Deng, Yang et Lu. The material was found from a new locality of the Lower Cretaceous strata in the Luozigou Basin, Wangqing, Jilin Province, northeastern China. Pseudofrenelopsis is a common plant in the Dalazi Formation of the Yanji Basin about 150 km from Wangqing, but there exists different species, Pseudofrenelopsis dalatzensis only. Both P. dalatzensis and P. gansuensis have been recorded from the Lower Cretaceous of Jiuquan, Gansu Province, but they are in different stratigraphic horizons. The Lower Cretaceous plant-bearing strata in Luozigou have used to correlate with the Dalazi Formation of the Yanji Basin. The discovery of P. gansuensis, which is lower in horizon than P. dalatzensis in Jiuquan, may indicate that they are also different in horizon in Jilin. Cheirolepidiaceous conifers are among the few fossils of red beds of the Early Cretaceous in China. The present discovery of Pseudofrenelopsis gansuensis provides important evidence for classification, correlation and determination of geological ages of the Early Cretaceous non-marine red deposits of the two separate basins in remote areas of North China.  相似文献   

15.
The Cretaceous-early Eocene tectonic stress field in China was reconstructed using the data of 369 largeand medium-scale flexural folds and 157 joint sets. It was found that the maximum compressive principal stress axis in eastern China dips 32° NE (nearly horizontal), and strikes SW 212°, whereas that in western China dips 15° NE (also nearly horizontal) and trends SW 195°. The estimation of the dip angles of fold limbs and the palaeotectonic stress values indicates that there was a tendency of gradual weakening of tectonism from southwestern to northeastern China in the Cretaceous-early Eocene. At the depth of 2-3 km, the differential stress value changes from 183 MPa in Tibet to 100 MPa in North and East China.The authors consider that the tectonic stress of this period was related to the north-northeastward movement and push of the Indian-Australian plate.  相似文献   

16.
The Jingbaoshan platinum-palladium deposit is China's largest independent PGM (platinum-group metals) deposit so far discovered. There are eleven kinds of useful components in the ore: Pt, Pd, Os, Ir, Ru, Rh, Au, Ag, Cu, Ni, and Co. The platinum-group elements, gold and silver occur in the form of minerals in ores. twenty-five kinds of precious metal minerals have been found, of which twenty one belong to the platinum-group minerals. The minerals are very small in grain size. Copper occurs mainly as copper sulfide with a small amount of free copper oxide, and the beneficiated copper accounts for 95.21%. Nickel occurs mainly as nickel sulfide, and some nickel silicate and nickel oxide occur in the ore. The beneficiated nickel accounts for 72.03%. Cobalt occurs mainly as cobalt sulfide, and there are some cobalt oxide and other kinds of cobalt. The beneficiated cobalt accounts for 77.58%.  相似文献   

17.
Using the secondary spinel standard, the authors have precisely measured the Fe3+/∑ Fe values of spinels in mantle xenoliths from Cenozoic basalts in eastern China, and estimated the oxygen fugacities recorded by 63 mantle xenoliths through olivine-orthopyroxene-spinel oxygen barometry. The results indicate that the oxygen fugacities of the lithospheric mantle in eastern China are higher in the south than in the north. Among them, the oxygen fugacity of the North China craton lithospheric mantle is the lowest, similar to that of the oceanic mantle, while that of Northeast and South China are the same as that of the global continental mantle. The variations of mantle redox state in eastern China are mainly controlled by the C-O-H fluids derived from the asthenospheric mantle. According to the mantle oxidation state, it can be concluded that the C-O-H fluids in the lithospheric mantle of eastern China consist mainly of CO2 and minor H2O, but CH4-rich fluids should come from the asthenosphere where the ox  相似文献   

18.
Fluorite is one of the main gangue minerals in the Maoniuping REE deposit,Sichuan Province,China.Fluorite with different colors occurs not only within various orebodies,but also in wallrocks of the orefield.Based on REE geochemistry,fluorite in the orefield can be classified as the LREE-rich,LREE-flat and LREE-depleted types.The three types of fluorite formed at different stages from the same hydrothermal fluid source,with the LREE-rich fluorite forming at the relatively early stage,the LREE-flat fluorite in the middle,and the LREE-depleted fluorite at the latest stage.Various lines of evidence demonstrate that the variation of the REE contents of fluorite shows no relation to the color.The mineralization of the Maoniuping REE deposit is associated spatially and temporally with carbonatite-syenite magmatism and the ore-forming fluids are mainly derived from carbonatite and syenite melts.  相似文献   

19.
The recently discovered macaque fossils, including isolated teeth and mandible fragments, from Tianyuan Cave and the juvenile maxilla from Wanglaopu Cave near Zhoukoudian can be identified as Macaca mulatta; they represent the first recognized occurrence of fossil M. mulatta in the far north of China. Some previously unearthed but still unpublished Macaca specimens were also studied, including a cranium and the associated mandible from CKT Loc.13A, a maxilla and a mandible from Loc.1, a mandible from Loc.4, and a maxilla from Loc.20, as well as a mandible with complete toothrow from Zhoukoudian but without locality details, all of them can be referred to M. robusta. The study shows M. robusta is more closely related to M. mulatta than to M. anderssonL Zhoukoudian is the richest area of Macacina fossils in North China, totally 2 genera and 4 species were once recognized from 9 localities, namely, Procynocephalus wimani, M. cf. anderssoni, M. robusta and M. mulatta. The fossil records of Macacina in Zhoukoudian area were almost continuous through the Quaternary Period, and it's reasonable to assume that Zhoukoudian used to be an evolutionary center for macaques in North China. Therefore, the macaque population of M. mulatta once existed decades ago around Beijing probably originated from the Pleistocene ancestors in the local area, rather than being human-introduced as previously thought.  相似文献   

20.
Cenozoic volcanic rocks widespread in eastern China constitute an important part of the circum-Pacific volcanic belt.This paper presents more than 150K-Ar dates and a great deal of petrochemical analysis data from the Cenozoic volcanic rocks distributed in Tengchong,China‘s southeast coast,Shandong,Hebei,Nei Monggol and Northeast China.An integrated study shows that ubiquitous but uneven volcanic activities prevailed from the Eogene to the Holocene,characterized as being multi-eqisodic and multicycled.For example,in the Paleocene(67-58Ma),Eocene(57-37.5Ma),Miocene(22-18,16-19Ma),Pliocene(8-3Ma),and Early Pleistocene-Middle Pleistocene(1.2-0.5Ma) there were upsurges of volcanism,while in the Oligocene there was a repose period.In space,the older Eogene volcanic rocks are distributed within the region or in the central part of the NE-NNE-striking fault depression,while the younger Neogene and Quaternary volcanic rocks are distributed in the eastern and western parts.Petrologically,they belong essentially to tholeiite-series and alkali-series basalts,with alkalinity in the rocks increasing from old to youg.The above regularities are controlled by both global plate movement and regional inherent tectonic pattern.  相似文献   

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