共查询到20条相似文献，搜索用时 46 毫秒
1.
为探讨新类型"盆内隆缘式"富铀地层微量元素地球化学特征和铀的富集规律,选取松辽盆地XX地区四方台组富铀砂岩地层进行野外踏勘和系统采样,对研究区东西方向4个钻孔剖面含矿砂岩和不含矿砂岩进行了岩石学、矿物学和微量元素地球化学分析。结果表明,铀主要在长石岩屑砂岩中富集,并且靠近铀富集层位的岩石类型在横向上、纵向上呈规律性变化。稀土元素北美页岩标准化配分显示,围岩、矿化砂岩和富铀砂岩均呈右倾,具有轻稀土富集特点,并且轻稀土组分内部分异弱于重稀土;富铀砂岩δEu呈正异常,可能由富含斜长石所致;δCe基本无异常或略显负异常。富铀地层砂岩中的微量元素Grant等位线法分析表明铀初级富集过程中,微量元素大多表现为迁入,尤其稀土元素整体基本上是迁入,在再次富集过程中,微量元素迁出组分增加,尤其稀土元素整体表现为迁出,这反映铀的两次富集过程中的水解作用强度不同,后者较弱。 相似文献
2.
冀中坳陷火成岩岩石学及地球化学特征 总被引：1，自引：0，他引：1
冀中坳陷发育大量隐伏玄武质岩石,尤其是坳陷北部的廊固凹陷和霸县凹陷,岩石类型以玄武岩为主,辉绿岩次之,凝灰岩分布较少,火山角砾岩极少。通过岩心、镜下薄片及铸体薄片观察,主量和微量元素测试分析,表明该区火成岩为碱性玄武岩和拉斑玄武岩系列;REE配分曲线呈轻稀土元素富集型,Eu异常不明显;火成岩微量元素原始地幔标准化曲线呈强不相容元素富集。该区玄武岩的喷发环境为水下喷发;火成岩微量元素构造环境判别图解、岩石组合、岩石系列、稀土元素和微量元素特征表明该区火成岩形成于板内大陆裂谷构造环境。通过冀中坳陷玄武岩与邻区对比发现,冀中坳陷及邻区玄武岩岩浆活动具有随时代变化往北迁移的趋势,SiO2含量显示从南往北略为增加的趋势,北部稀土元素总量变化范围相对较大,轻稀土元素富集程度较南部低。 相似文献
3.
4.
《地下水》2021,(5)
宜君地区延长组页岩发育,埋藏较浅,开发前景较好,分析该区页岩元素地球化学特征对沉积环境具有重要指示意义。应用X射线荧光光谱议(XRF)、等离子体质谱法(ICP-MS)对宜君地区长9段页岩样品的主量元素、微量元素及稀土元素进行测试,分析了主量元素、微量元素及稀土元素的地球化学参数、空间分布规律及分布模式等地球化学特征。研究表明,与上地壳相比,宜君地区长9段页岩主量元素富含P_2O_5、K_2O、TFe_2O_3和Al_2O_3;微量元素可大致分为极度富集型、富集型、微富集型和亏损型四类,U、Mo、As元素极度富集;稀土元素特征属于轻重稀土元素分异程度较高的轻稀土中度富集型。 相似文献
5.
铅锌矿床中微量元素的富集特征、富集机制及对矿床成因指示是当前矿床学研究的热点之一。对铅锌矿床微量元素富集及关键测试技术研究新进展进行了综述,指出:①富集微量元素的铅锌矿床不仅分布于古陆边缘,造山带也是有利的构造背景;②不同成因类型铅锌矿床所富集的微量元素种类和含量不同,元素组合、含量及比值可以指示矿床成因;③微量元素以类质同象、固熔体、微细矿物包裹体形式甚至是独立矿物形式存在于闪锌矿和方铅矿中,富集过程受扩散速率、结晶温度、氧化还原条件、硫逸度、成矿物质和成矿流体等物理化学条件控制;④硫化物LA-ICP-MS微区分析能精确测定硫化物中微量元素的含量,了解其赋存状态,可为铅锌矿床成因研究提供微观证据。最后指出微量元素研究过程中要加强LA-ICP-MS原位微区测试技术的应用,并与宏观矿床地质特征研究相结合。 相似文献
6.
淮北矿区固废堆积区土壤微量元素时空分布规律与环境影响研究 总被引：1，自引：0，他引：1
以淮北矿区固废堆积区周边土壤为研究对象,采集不同开采年限矿区的矸石、煤泥和土壤样品,运用ICPAES测定了Cr、Ni、Cu、Zn、Pb和As 6种微量元素的含量。研究了不同堆积区土壤中微量元素的分布规律,探讨了堆积时间和固废类型对土壤中微量元素富集的影响,并运用地积累指数法评价土壤环境质量。结果表明,矸石堆积区周边土壤中Pb和As元素含量较高,而煤泥堆积区更易富集Ni、Cu和Zn元素;矸石堆积区周边土壤中微量元素含量随距离和时间增长的变化规律表现出不同的特征;研究区土壤中只有Cu和Zn元素含量超出背景值;根据地积累指数评价结果可知,只有Zn元素属于无污染-轻度污染,研究区整体处于清洁水平。 相似文献
7.
湖润锰矿床的元素地球化学特征 总被引：2，自引：0，他引：2
湖润锰矿床锰矿石包括两种类型：原生碳酸锰矿石和次生富集的氧化锰矿石。本文主要结合该矿床的分布与地质特征,研究了微量元素和稀土元素的地球化学特征。研究结果表明,从原生带到氧化带,随着氧化程度的升高,与Ｍｎ成类质同像的Ｃｏ,Ｎｉ,Ｐｂ和Ｚｎ等微量元素的含量都随着锰含量的增加而增加,其富集系数也相应地增大;同时,稀土元素的总量也呈增加趋势而且氧化带比原生带更富轻稀土元素。 相似文献
8.
福建马坑矿区水化学微量组分的指示作用 总被引：1，自引：1，他引：0
通过对区域地质背景调查分析、现场取样和室内测试,研究了马坑矿区地下水水化学特征,确定不同类型地下水的特征鉴别离子,分析地下水中微量元素含量异常原因所在,并通过研究地下水中稀土元素的水文地球化学特征,判断矿区地下水径流交替的强弱和稀土元素富集特征,为判别矿坑主要涌水水源提供确切依据。 相似文献
9.
本文采用基础地质同统计数学相结合的方法,通过对扬砦金矿区微量元素在各岩类中的分布特征及空间上分布规律的研究,探讨成矿过程中金及伴生元素的迁移富集之规律,同时研究微量元素的指示性特征,并依此指示成矿有利地段和找矿靶区。 相似文献
10.
鄂尔多斯盆地砂岩型铀矿床地球化学特征及其地质意义 总被引：7，自引：0，他引：7
本文在系统的取样分析基础上,详细研究鄂尔多斯盆地砂岩型铀矿的稀土、微量元素地球化学特征,分析研究了鄂尔多斯盆地砂岩型铀矿富集成矿的机理及多种能源共存的内在联系,从而进一步探讨盆地型多种能源富集成藏（矿）的潜在的规律。高精度ICPMS分析表明：鄂尔多斯盆地砂岩型铀矿REE总体特征为轻稀土富集,重稀土亏损;ΣREE在36.7~701.8μg/g之间变化, 泥岩ΣREE总体高于砂岩,Y含量都比较高;Eu异常差异明显, 在0.3~2.5内变化。微量元素Rb、U、La、Ce、Pb和Pr呈特别明显正异常,其中U含量在0.6~2204μg/g之间,U的富集和一些微量元素如Ti、V、Zr、Mo、Au等相关,本研究对该区铀矿质沉淀和富集规律的认识具有理论意义。 相似文献
11.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
12.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
13.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
14.
15.
16.
17.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
19.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献