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1.
Huang  Xiangui  Ping  Jianhua  Leng  Wei  Yu  Yan  Zhang  Min  Zhu  Yaqiang 《Hydrogeology Journal》2021,29(6):2149-2170

Studies on groundwater recharge are essential for sustainable exploitation of groundwater resources, especially in areas of extensive groundwater exploitation such as the Anyanghe River alluvial fan (ARAF) in the North China Plain (NCP). However, the recharge sources and processes and the contribution of each recharge flow component remain unclear. This study used hydrochemistry, stable isotopes, and tritium to investigate sources and underlying processes of groundwater recharge, along with the steady flow Mixing Cell Model (MCMsf) to quantify the proportion of each source flow for the shallow confined groundwater system in the medial fan. The results showed that groundwater mainly originates from precipitation occurring on the eastern Taihang Mountain area with average elevation estimated at 700–1,000 m above sea level during the East Asia summer monsoon period since 1952. Recharge mechanisms are: (1) river water seepage for the unconfined aquifers of the proximal and medial fan; (2) lateral flow for the confined aquifers of the medial and distal fan; and (3) precipitation infiltration for the phreatic water system. The MCMsf simulation showed that the shallow confined groundwater system in the central zone of the medial fan mainly recharged by the lateral flow from the proximal fan, a constant and considerable recharge flow from the southwestern and southern hills, and river water seepage in the medial fan; the lateral recharge flow from the Zhanghe alluvial aquifer was insignificant by comparison. The results of this study can act as a valuable reference for sustainable groundwater management in the ARAF.

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2.
The relationship between surface water and groundwater not only influences the water quantity, but also affects the water quality. The stable isotopes (δD, δ 18O) and hydrochemical compositions in water samples were analysed in the Second Songhua River basin. The deep groundwater is mainly recharged from shallow groundwater in the middle and upper reaches. The shallow groundwater is discharged to rivers in the downstream. The runoff from upper reaches mainly contributed the river flow in the downstream. The CCME WQI indicated that the quality of surface water and groundwater was ‘Fair’. The mixing process between surface water and groundwater was simulated by the PHREEQC code with the results from the stable isotopes. The interaction between surface water and groundwater influences the composition of ions in the mixing water, and further affects the water quality with other factors.  相似文献   

3.
潮白河冲洪积扇中上游地区作为北京市最主要地表水和地下水供给区,在城市供水中的作用举足轻重。由于多年连续超采,地下水位持续下降,1999-2013年地下水位下降最大达45 m;应急水源地地区地下水硬度年均上升2.6%,密云十里堡地区地下水硬度和硝酸盐氮超标。通过分析潮白河冲洪积扇区域地下水开发利用、地下水位和水质变化情况以及地下水位变化对地下水水质的影响,认为：超量开采导致的地下水水位下降是引起该区域地下水水质恶化的主要原因之一,控制地下水超量开采和地表水污染,并利用南水北调的水进京之机回灌和停采以涵养地下水,是恢复区域水资源和水环境的良好途径。  相似文献   

4.
为了查明曹妃甸浅层地下水水化学及咸化成因,采集研究区河水、地下淡水、微咸水、咸水、卤水、雨水和海水等不同类型水样,对其水化学组成、离子比、Piper三线图、吉布斯图、氢氧同位素组成及14C测年结果进行了分析。结果表明：(1)曹妃甸浅层地下水包括全新世沉积层潜水和晚更新世沉积层微承压水,且非原始封存在地层中而是形成于全新世中晚期。(2)地下潜水向海方向分布有淡水、微咸水、咸水水质类型,微承压水以咸水和卤水为主要水质类型;近冲洪积扇前缘水化学特征主要受岩石风化作用控制,围填海区及河口处水化学特征受海水混合作用控制,滨海平原区水化学特征主要受蒸发/结晶作用控制。(3)曹妃甸浅层地下水咸化过程主要是晚更新世以来海侵海退时期形成海洋蒸发盐经大气降水和河水多期溶滤所致,其盐分来源于海水蒸发盐,河口及围填海区地下潜水盐分主要来源于现代海水入侵。  相似文献   

5.
Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population, quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater was recharged by precipitation and was characterized by Ca–HCO3 type water with depleted δ18O and δD (mean value of −8.8‰ δ18O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex (Ca–Na–Mg–HCO3–Cl–SO4 type), and heavier δ18O and δD were observed (around −8‰ δ18O). Before the surface water with mean δ18O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ18O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal end of the fan. The groundwater underwent chemical evolution from Ca–HCO3, Na–HCO3, to Na–SO4. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical evolution, and groundwater flow paths in the complex alluvial fan aquifer system.  相似文献   

6.
An investigation was conducted in Beijing to identify the groundwater evolution and recharge in the quaternary aquifers. Water samples were collected from precipitation, rivers, wells, and springs for hydrochemical and isotopic measurements. The recharge and the origin of groundwater and its residence time were further studied. The groundwater in the upper aquifer is characterized by Ca-Mg-HCO3 type in the upstream area and Na-HCO3 type in the downstream area of the groundwater flow field. The groundwater in the lower aquifer is mainly characterized by Ca-Mg-HCO3 type in the upstream area and Ca-Na-Mg-HCO3 and Na-Ca-Mg-HCO3 type in the downstream area. The δD and δ18O in precipitation are linearly correlated, which is similar to WMWL. The δD and δ18O values of river, well and spring water are within the same ranges as those found in the alluvial fan zone, and lay slightly above or below LMWL. The δD and δ18O values have a decreasing trend generally following the precipitation → surface water → shallow groundwater → spring water → deep groundwater direction. There is evidence of enrichment of heavy isotopes in groundwater due to evaporation. Tritium values of unconfined groundwater give evidence for ongoing recharge in modern times with mean residence times <50 a. It shows a clear renewal evolution along the groundwater flow paths and represents modern recharge locally from precipitation and surface water to the shallow aquifers (<150 m). In contrast, according to 14C ages in the confined aquifers and residence time of groundwater flow lines, the deep groundwater is approximately or older than 10 ka, and was recharged during a period when the climate was wetter and colder mainly from the piedmont surrounding the plain. The groundwater exploitation is considered to be “mined unsustainably” because more water is withdrawn than it is replenished.  相似文献   

7.
地下水具有重要的生态价值,地下水生态系统中的地下水位、水质和包气带含水率与含盐量的变化驱动着表生生态格局的演变,但目前对各变量的生态阈值研究尚处于起步阶段,理论与方法体系还不完善。以保定平原区为例,采用地下水位及地下水生态环境的历史回归法、GIS法、差分网格计算法等方法,从时空角度分析了地下水位变化的驱动力以及生态效应,在此基础上确定不同水文地质单元的生态水位阈值。研究表明:（1）20世纪50—60年代,研究区依赖于地下水的生态格局基本维持着天然状态;1959—2000年,地下水位持续下降,局部地段出现降落漏斗;2000—2008年,地下水位骤降,降落漏斗迅速扩张,地下水与地表水补排关系发生变异;2008年至今,部分区域地下水位逐渐上升。（2）研究区内山前地带地下水生态水位埋深为10~15?m,拒马河冲洪积扇群与漕河—瀑河冲洪积扇群为5~10?m,唐河—大沙河冲洪积扇群为3~5?m,冲积平原中定州—望都范围为3~5?m,保定市为10~15?m,其余均为5~10?m,冲湖积平原环淀区域小于3?m。（3）以确定的地下水生态水位为标准,初步估算研究区现状地下水位恢复至生态水位的需水量为57.14×108?m3。研究成果对恢复当地地下水生态环境格局有重要意义,对华北平原地下水生态水位的确定也具有借鉴意义。  相似文献   

8.
Source, type, and quantity of various components of groundwater, as well as their spatial and temporal variations were determined by different hydrochemical methods in the alluvial aquifer of the upper Rhone River valley, Bois de Finges, Wallis Canton, Switzerland. The methods used are hydrochemical modeling, stable-isotope analysis, and chemical analysis of surface water and groundwater. Sampling during high- and low-water periods determined the spatial distribution of the water chemistry, whereas monthly sampling over three years provided a basis for understanding seasonal variability. The physico-chemical parameters of the groundwater have spatial and seasonal variations. The groundwater chemical composition of the Rhone alluvial aquifer indicates a mixing of weakly mineralized Rhone River water and SO4-rich water entering from the south side of the valley. Temporal changes in groundwater chemistry and in groundwater levels reflect the seasonal variations of the different contributors to groundwater recharge. The Rhone River recharges the alluvial aquifer only during the summer high-water period. Electronic Publication  相似文献   

9.
This paper gives an account of the implementation of hydrochemical and isotopic techniques to identify and explain the processes that govern solute exchange in two groundwater-dependent shallow lakes in the Southeastern Pampa Plain of Argentina. Water samples (lakes, streams, spring water and groundwater) for hydrochemical and stable isotopic determination were collected and the main physical–chemical parameters were measured. The combination of stable isotope data with hydrogeochemical techniques was used for the identification of sources and preferential recharge areas to these aquatic ecosystems which allowed the explanation of the lake water origin. The hydrochemical processes which explain Los Padres Lake water chemistry are evaporation from groundwater, CO2 input, calcite dissolution, Na+ release by Ca2+ and Mg2+ exchange, and sulfate reduction. The model that best aligns with La Brava Lake hydrochemical constraints includes: mixing, CO2 and calcite dissolution, cationic exchange with Na+ release and Mg2+ adsorption, and to a lesser extent, Ca/Na exchange. This model suggests that the fractured aquifer contribution to this water body is greater than 50 %. An isotopic-specific fingerprint for each lake was identified, finding a higher evaporation rate for La Brava Lake compared to Los Padres Lake. Isotopic data demonstrate the importance of these shallow lakes as recharge areas to the regional aquifer, becoming areas of high groundwater vulnerability. The Tandilia Range System, considered in many hydrogeological studies as the impermeable bedrock of the Pampean aquifer, acts as a fissured aquifer in this area, contributing to low salinity waters and with a fingerprint similar to groundwater isotopic composition.  相似文献   

10.
Hydrochemical and isotopic researches were conducted in El-Sadat City groundwater system to identify groundwater alteration, recharge, residence time and extent of pollution. The groundwater salinity gradually increases as the groundwater moves from northeastern to southwestern parts of the city. Groundwater generally shows mineralization decreasing with depth, indicating that the possibility of recent water penetration far below the surface is limited. Shallow groundwater has an elevated level of nitrate, which is attributed to anthropogenic sources due to intensive agricultural activity. The limit of high nitrate water may mark the maximum penetration of groundwater from the surface, which is found in depths <100 m. The northeastern and southwestern industrial areas are highly contaminated by some heavy metals, which may originate from some local industrial effluents. The sewage oxidation ponds seem to show no effect on groundwater; hence, these ponds are not a point source for these heavy metals. Dissolved ions depict five different hydrochemical facies, and stable isotopes define the recharge mechanisms, the origin of groundwater and the hydraulic confinement of deep groundwater. The deep groundwater is untritiated and has long residence times (in the order of thousands of years). Three different hydrochemical groups have been recognized and mapped in El-Sadat City, based on the chemical and isotopic information of the groundwater. These groups have different levels of contamination. The deep groundwater samples are significantly less impacted by surface activities and it appears that these important water resources have very low recharge rates and would, therefore, be severely impacted by overabstraction. The extensive exploitation of groundwater for drinking water supply would shortly be reflected by a gradual decline of the groundwater table in El-Sadat City. Amelioration of groundwater quality requires further management strategies and efforts in the forthcoming years.  相似文献   

11.
Rapid population growth and urbanization has placed a high demand on freshwater resources in southeast costal Tanzania. In this paper, we identify the various sources of groundwater and the major factors affecting the groundwater quality by means of multivariate statistical analyses, using chemical tracers and stable isotope signatures. The results from hierarchical cluster analyses show that the groundwater in the study area may be classified into four groups. A factor analysis indicates that groundwater composition is mainly affected by three processes, accounting for 80.6% of the total data variance: seawater intrusion, dilution of groundwater by recharge, and sewage infiltration. The hydrochemical facies of shallow groundwater was mostly of the Na–Ca–Cl type, although other water types were also observed. The deep groundwater samples were slightly to moderately mineralized and they were of the NaHCO3 type. This water type is induced mainly by dissolution of carbonate minerals and modified by ion exchange reactions. The signal from the stable isotope composition of the groundwater samples corresponded well with the major chemical characteristics. In the shallow groundwater, both high-nitrate and high-chloride concentrations were associated with localized stable isotope enrichments which offset the meteoric isotopic signature. This is inferred to be due to the contamination by influx of sewage, as well as intrusion by seawater. The depleted stable isotope values, which coincides with a chemical signature for the deep aquifer indicates that this deep groundwater is derived from infiltration in the recharge zone followed by slow lateral percolation. This study shows that a conceptual hydrogeochemical interpretation of the results from multivariate statistical analysis (using HCA and FA) on water chemistry, including isotopic data, provides a powerful tool for classifying the sources of groundwater and identifying the significant factors governing the groundwater quality. The derived knowledge generated by this study constitutes a conceptual framework for investigating groundwater characteristics. This is a prerequisite for developing a sound management plan, which is a requirement for ensuring a sustainable exploitation of the deep aquifer water resource in the coastal area of Tanzania.  相似文献   

12.
In the Kushkak Valley (Khuzestan, Southwest Iran) an anticlinal structure has partially impounded an ephemeral stream. This natural impounded area has been chosen for an artificial recharge site due to its current rate of recharge, capability to store water and favorable situation for the construction of man-made barriers to stream flow. The aquifer to be recharged is the Kushkak unconfined aquifer which consists of medium to coarse-grained alluvial deposits that overlie consolidated conglomerate rock. In this semi-arid area with infrequent relatively heavy falls of rain, alluvial aquifer recharge can be an important process that sustains shallow, over-exploited groundwater bodies. In this investigation a multidisciplinary approach including: hydrometerological studies, and a detailed hydrogeochemical survey, have been carried out. Other essential prerequisite parameters for the scheme were also taken into account to determine the suitability of this location for groundwater artificial recharge. The assessment has brought out that (1) the proposed reservoir will conserve a major part of the water being lost, (2) annual runoff of about 0.27 MCM can be injected into the aquifer through recharge from impounded water, (3) hydrochemical data from surface water and from the Kushkak aquifer water demonstrates that dilution and change in compositional trend in the groundwater proximal to the impounded alluvial bed areas would be expected based on the infiltration capacity of this site, and (4) cost–benefit ratio of the project is 1:2 and it is assumed to recover the investment within six years.  相似文献   

13.
针对黄土梁峁地区砂岩-泥岩互层覆岩突水水源难以准确判别以及不同水源所占比例无法定量化问题,在系统采集了陕北朱家峁煤矿地表水、地下水水样基础上,采用数理统计、Piper三线图、Gibbs图、常规水化学特征比值法,揭示了不同含水系统水化学演化规律和水源补给关系。通过分析水体稳定同位素组成演变特征,明确了不同环境背景下各类水源水质时空变异性。在此基础上,以常规、同位素特征比因子作为判别指标,构建了基于T-球型模糊聚集算子TOPSIS法(T-TOPSIS)、粗糙集理论(RST)、D-S证据理论(DSET)与单指标未知测度函数(SIUMF)的突水水源混合比例计算模型。结果表明,研究区地表水、地下水水化学类型虽均以Na-SO4·Cl为主,但两者受控因素有着明显差别,即地表水水化学成分受硅酸盐岩风化和蒸发结晶共同控制;地下水成分则主要受控于蒸发结晶作用。此外,经历了强烈蒸发作用的地表水对地下水存在一定程度的补给作用。T-TOPSISRST-DSET-SIUMF突水水源混合比例判别模型表明,陕北朱家峁煤矿50%以上的突水水源为顶板砂岩水和地表沙空沟水。三维高密度电法探测结果验证了该模型的准确性。  相似文献   

14.
河流与地下水相互作用研究是水文学研究的难点和热点。安阳河与地下水相互作用研究,对于安阳市水资源科学开发与管理具有重要意义。安阳河冲洪积扇地表水与地下水转化率为17%～27%。潜水位标高为80 m,向下游逐渐变成多层含水层（水位40 m）。当地降水环境同位素监测数据表明,当地大气降水线与全球大气降水线接近平行,表明该线代表本地区大气降水的氢氧同位素特征。地表水同位素值较集中,2016年8月δ18O值变化范围为-9‰~-8.7‰,δD值变化范围为-65‰~-63‰,2017年1月δ18O值变化范围为-8.5‰~-8.2‰,δD值变化范围为-63‰~-61‰,河水水化学类型为HCO3·SO4—Ca型,表明流域内地表水的同位素值受距离的影响较小。地下水稳定同位素值变化较大,2016年8月δ18O值范围为-10.4‰~-5.5‰,δD值范围为-75‰~-46‰,2017年1月δ18O值范围为-10.2‰~-5.4‰,δD值范围为-75‰~-45‰,即从接近降水值到最大值形成一条“蒸发”线。河流出山口一带地下水同位素值呈现最大蒸发值,表明地表水补给地下水,地下水化学类型为HCO3·SO4·Cl—Ca,存在明显人为污染成分。下游为大气降水补给浅层地下水,中深层地下水主要来源于中游侧向径流,水化学类型主要为HCO3—Ca·Mg型,综合分析表明,安阳河中下游（冲洪积扇）地带“三水”转换积极,并影响其水质、水量。  相似文献   

15.
A hydrochemical investigation was conducted in the Ejina Basin to identify the hydrochemical characteristics and the salinity of groundwater. The results indicate that groundwater in the area is brackish and are significantly zonation in salinity and water types from the recharge area to the discharge area. The ionic ration plot and saturation index (SI) calculation suggest that the silicate rock weathering and evaporation deposition are the dominant processes that determine the major ionic composition in the study area. Most of the stable isotope δ18O and δD compositions in the groundwater is a meteoric water feature, indicating that the groundwater mainly sources from meteoric water and most groundwater undergoes a long history of evaporation. Based on radioactive isotope tritium (3H) analysis, the groundwater ages were approximately estimated in different aquifers. The groundwater age ranges from less than 5 years, between 5 years and 50 years, and more than 50 years. Within 1 km of the river water influence zone, the groundwater recharges from recent Heihe river water and the groundwater age is about less than 5 years in shallow aquifer. From 1 km to 10 km of the river water influence zone, the groundwater sources from the mixture waters and the groundwater age is between 5 years and 50 years in shallow aquifer. The groundwater age is more than 50 years in deep confined aquifer.  相似文献   

16.
山东德州凹陷地下热水地球化学特征及成因   总被引：5，自引：1，他引：5  
典型地区地下水成因和演化机制的研究不仅对于热水资源的合理利用与开发具有重要的指导意义,而且可以为日后的地热资源勘查评价提供重要信息。笔者通过对德州凹陷的地下热水的化学成分、同位素及其水文地质特征的分析,进而对这一地区的地下热水的成岩和演化过程进行了研究。结果显示地下热水的形成受区内深大断裂和基底构造对地热形成的控制,地下热水补给是来自大气降水,为入渗变质水,水化学成分以易溶盐溶解作用为主,其气体组分主要起源于大气、地壳和地幔的混合物,反映了地下水长期径流及深循环中各种水化学作用。  相似文献   

17.
Hydrogeochemistry and environmental isotope data were utilized to understand origin, geochemical evolution, hydraulic interconnection, and renewability of groundwater in Qingshuihe Basin, northwestern China. There are four types of groundwater: (1) shallow groundwater in the mountain front pluvial fans, originating from recent recharge by precipitation, (2) deep paleo-groundwater of the lower alluvial plains, which was formed long ago, (3) shallow groundwater in the lower alluvial plains, which has undergone evaporation during the recharge process, and (4) mixed groundwater (shallow and deep groundwater in the plain). The main water types are Na–HCO3, which dominates type (1), and Na–SO4, which dominates types (2) and (3). Geochemical evolution in the upper pluvial fans is mainly the result of CO2 gas dissolution, silicates weathering and cation exchange; in the lower alluvial plains, it is related to mineral dissolution. The evaporative enrichment only produces significant salinity increases in the shallow groundwater of the lower alluvial plains. Shallow groundwater age in the upper plain is 10 years or so, showing a strong renewability. Deep groundwater ages in the lower plain are more than 200 years, showing poor renewability. In the exploitation areas, the renewability of groundwater evidently increases and the circulation period is 70–100 years.  相似文献   

18.
河套灌区西部浅层地下水咸化机制   总被引：2，自引：0，他引：2       下载免费PDF全文
浅层地下水水位埋深浅、含盐量高,是导致河套灌区土壤次生盐渍化的重要原因.以河套灌区西部地区为研究区,通过对浅层地下水的水化学和氢氧同位素特征分析以及水文地球化学模拟,探讨了灌区浅层地下水的补给来源和主控水-岩作用过程,并定量估算了蒸发作用对浅层地下水含盐量的影响.研究区内浅层地下水为弱碱性咸水,pH为7.23~8.45,总溶解性固体（total dissolved solids,TDS）变化范围为371~7 599 mg/L;随着地下水咸化程度增大,水化学类型由HCO3-Na·Mg·Ca型向Cl-Na型过渡.引黄灌溉和大气降水是浅层地下水的主要补给来源,径流过程中浅层地下水受蒸发作用和植物蒸腾作用影响,地下水化学组分主要来源于蒸发盐溶解和硅酸盐风化水解,并受强烈的蒸发作用和离子交换作用影响.水文地球化学模拟和主成分分析结果显示,蒸发作用和岩盐溶解作用对区内浅层地下水咸化贡献最大,石膏和白云石等矿物的溶解、硅酸盐的水解、Na-Ca离子交换以及局部地形起伏对地下水咸化过程也有较大贡献.   相似文献   

19.
为了探究平朔矿区所在流域不同水体同位素的时空变化规律, 揭示采煤活动下区域水循环规律, 于2020年8月和12月对流域内地表水、地下水和矿井水进行采样, 测试样品的D和18O同位素组成, 并利用贝叶斯混合模型MixSIAR计算了矿井水不同来源的贡献率。结果表明: ①地表水和矿井水δD和δ18O夏季较冬季高; 地下水δD和δ18O季节差异不明显。地表水氢氧同位素值沿程呈增加趋势, 但局部受到矿井水的补给, 出现贫化; 地下水氢氧同位素值沿径流方向呈逐渐增加趋势。②采煤区氢氧同位素值较非采煤区明显增加。受季节效应影响, 在空间分布上8月浅层地下水氢氧同位素高值区域较12月明显增多。③ δ18O与δD关系图表明, 地表水在接受大气降水的补给之后受到了蒸发分馏作用的影响; 浅层地下水的补给源较复杂, 深层地下水由于采煤形成的导水裂隙带受到了浅层地下水和地表水的补给; 矿井水受地表水、浅层地下水和深层地下水的补给。④ MixSIAR模型揭示出深层地下水是矿井水的主要补给来源, 占61.60%~67.20%, 且补给比例冬季大于夏季; 浅层地下水对矿井水的补给存在明显季节差异。  相似文献   

20.
This study aims to investigate the hydrochemical characteristics of shallow aquifer in a semi-arid region situated in northwest Algeria, and to understand the major factors governing groundwater quality. The study area is suffering from recurring droughts, groundwater resource over-exploitation and groundwater quality degradation. The approach used is a combination of traditional hydrochemical analysis methods of multivariate statistical techniques, principal component analysis (PCA), and ratios of major ions, based on the data derived from 33 groundwater samples collected in February 2014. Results show that groundwater in the study area are highly mineralized and collectively has a high concentration of chloride (as Cl?). The dominant water types are Na-Cl (27%), Mg-HCO3 (24%) and Mg-Cl (24%). According to the (PCA) approach, salinization is the main process that controls the hydrochemical variability. The PCA analysis reveal the impact of anthropogenic factor especially the agricultural activities on the groundwater quality. The PCA highlighted two types of recharge: Superficial recharge from effective rainfall and excess irrigation water distinguished by the presence of nitrate and lateral recharge or vertical leakage from carbonate formations marked by the omnipresence of HCO3?. Additionally, three categories of samples were identified: (1) samples characterized by good water quality and receiving notable recharge from carbonate formations; (2) samples impacted by the natural salinization process; and (3) samples contaminated by anthropogenic activities. The major natural processes influencing water chemistry are the weathering of carbonate and silicate rocks, dissolution of evaporite as halite, evaporation and cation exchange. The study results can provide the basis for local decision makers to ensure the sustainable management of groundwater and the safety of drinking water.  相似文献   

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