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1.
新疆西天山喇嘛萨依铜矿床地质和C、O、S、Pb同位素地球化学 总被引：1，自引：0，他引：1
喇嘛萨依铜矿是新疆西天山赛里木微地块内的一处典型铜矿床,关于其成因类型尚存争议。总结了该铜矿床的地质特征,测试围岩、脉石碳酸盐的C、O同位素和硫化物的S、Pb同位素组成,探讨其成因类型。研究表明,喇嘛萨依铜矿床具有后生矿床特征,发育矽卡岩化蚀变,脉石方解石的δ13C值变化范围为-1.04‰~-0.87‰,低于围岩灰岩的δ13C值(变化范围为3.51‰~5.47‰),δ18O值变化范围为9.33‰~9.61‰,明显低于正常的海相碳酸盐岩的O同位素(δ18O=20‰~26‰),C、O同位素组成反映喇嘛萨依铜矿成矿晚阶段流体来自岩浆水和地下水的混合水;硫化物的δ34S值主要变化范围为3.75‰~8.64‰,与区域上海西期斑岩的硫同位素组成(如达巴特斑岩铜钼矿床硫化物的δ34S变化范围为4.9‰~7.9‰)接近,反映硫来源于斑岩;黄铜矿的铅同位素为206Pb/204Pb=18.264~19.544,207Pb/204Pb=15.575~15.656,208Pb/204Pb=38.103~38.705,具有富含放射成因铅、两阶段异常铅特征,与区域上海西期斑岩(达巴特流纹斑岩)的铅同位素组成特征相似,反映成矿金属物质部分来源于斑岩。通过综合分析认为,喇嘛萨依铜矿是与斑岩有关的矽卡岩型矿床。 相似文献
2.
西藏嘎拉勒铜金矿床成矿物质来源探讨——来自硫、铅、碳和氢氧同位素地球化学特征的证据 总被引：1，自引：0，他引：1
西藏嘎拉勒铜金矿床位于班公湖—怒江成矿带西段,是近年来发现的一个大型镁质矽卡岩型铜金矿床。本文在野外地质调查的基础上,通过S-Pb-C-H-O同位素分析,对嘎拉勒铜金矿床的物质来源进行了探讨。结果表明:(1)矽卡岩型矿石中黄铜矿的δ~(34)S_(V-CDT)值在硫同位素直方图上呈塔式分布,变化范围为–4.4‰~6‰,有少许样品值变化范围较大,表明嘎拉勒矿床硫同位素主要以幔源硫为主,有少量壳源的混染;(2)~(208)Pb/~(204)Pb变化范围为38.427‰~39.008‰,~(207)Pb/~(204)Pb变化范围为15.588‰~15.701‰,~(206)Pb/~(204)Pb变化范围为18.330‰~18.871‰,显示矿区铅同位素来源以造山带铅为主,少量上地壳铅相结合的特征;嘎拉勒矿床形成于碰撞的造山带环境;(3)含辉钼矿石英脉中δ~(18)O_(V-SMOW)值范围为12.2‰~12.8‰,平均值12.5‰,δD_(V-SMOW)范围为–103.3‰~–95.3‰,平均值为–99.3‰,δ~(18)O_(V-PDB)值范围为–18.1‰~–17.6‰,平均值为–17.85‰,显示受到大气降水加入明显;(4)矽卡岩中方解石C-O同位素测试结果δ~(13)C_(V-PDB)为–2‰,δ~(18)O_(V-PDB)为–15.1‰,δ~(18)O_(V-SMOW)为15.4‰,显示嘎拉勒铜金矿床碳酸盐为海相碳酸盐并经历了溶解作用。综合表明,嘎拉勒铜金矿床是由幔源成矿流体作用形成的,成矿过程中有大气降水的加入,成矿流体与碳酸盐岩发生接触交代作用形成矽卡岩型铜金矿床。 相似文献
3.
安庆铁铜矿床是安徽沿江地区具代表性的大型铁铜矿床之一,其形成机制一直存在较大争议。本文在分析成矿地质特征的基础上,研究了矿石和围岩的硫、碳、氧同位素组成特征,探讨了该矿床的成矿物质来源与成矿过程。研究结果表明,矿床具有显著的水平分带特征。矿石硫化物δ~(34)S值范围为-6.5‰～10.6‰,变化大,闪长岩浆为成矿提供了大部分硫,前三叠纪碎屑地层和三叠纪围岩提供了部分硫;从闪长岩体到围岩,δ~(34)S值呈V字型变化,是不同来源硫混合的结果。碳酸盐矿物δ~(13)C范围为-5.5‰～2.0‰,从外带到内带呈下降趋势,表明碳主要源自岩浆热液,混入了部分地层碳。近矿围岩中δ~(13)C和δ~(18)O值相对地层偏低,是流体改造作用的结果。外接触带致密块状磁铁矿体具有最低的δ~(18)O值和部分贯入成因地质特征,可能为高温流体沿接触带和断层贯入充填的产物。综合研究认为,该矿床可能存在流体贯入充填与热液交代两种成矿形式。高温富铁流体贯入接触带形成了外带块状磁铁矿体,其分异热液与闪长岩体的交代作用、地层流体混入等综合作用形成了矽卡岩型铜矿体和含铜蚀变闪长岩,二者在空间上的叠加构成了矽卡岩型铁铜矿床,不同成矿方式的叠加导致了矿床分带及元素迁移特征有别于典型矽卡岩矿床。 相似文献
4.
鄂东南铜绿山矿田矽卡岩型铜铁金矿床的辉钼矿Re-Os同位素年龄及其地质意义 总被引：25，自引：6，他引：19
鄂东南地区(斑岩-)矽卡岩型铜铁金多金属矿床是长江中下游地区金属成矿带的重要组成部分,铜绿山矿田以成矿类型齐全和矿体规模较大为特点,是鄂东南矿集区最重要的矿田.但目前对不同成矿元素的矽卡岩型铜铁金矿床的成矿时代、成岩成矿时差和构造背景的研究相对较少.本文利用Re-Os同位素定年方法对铜绿山矿田两个典型的大型铜绿山矽卡岩铜(铁金)矿床和大型鸡冠嘴矽卡岩(铜)金矿床进行了成矿时代的研究,获得了辉钼矿的Re-Os同位素年龄范围分别为(1368±19)～(1381±18) Ma和(1371±19)～(1388±19) Ma,等时线年龄分别为(1371±19) Ma和(1382±22) Ma,表明铜绿山矿田不同类型的矿床几乎同时形成;与矿田花岗闪长岩锆石SHRIMP U-Pb年龄[(1403±18) Ma]在误差范围内基本一致,存在较短的成岩成矿时差,该成矿时代与鄂东南地区其他矿田的(斑岩-)矽卡岩型铜钼矿床和矽卡岩型铁矿床,以及长江中下游地区铜陵、安庆、九瑞矿集区(斑岩-)矽卡岩铜多金属矿床的形成时代基本一致.铜绿山矿田矽卡岩铜铁金矿床可能是在太平洋板块俯冲的撕裂或开天窗时,由于玄武质岩浆底侵和岩石圈减薄导致中国东部大规模侵入岩和成矿作用产物的形成. 相似文献
5.
硫同位素地质特征及其在湖南省铜矿床成矿物质来源示踪中的应用 总被引：1，自引：0，他引：1
硫是铜矿床的重要成矿物质,硫同位素特征可用于示踪含硫矿物或流体来源,从而为矿床成因和成矿预测研究提供支持。本文简述了硫同位素特征在地质勘查中的应用进展,并将湖南省以铜为主要矿种的铜矿床分为岩浆热液型和砂页岩型两大类,对矿床的基本地质特征和硫同位素特征进行了分析,总结了硫同位素的分布特征:矽卡岩型铜矿床矿石矿物中硫化物δ34S分布较为集中,峰值通常位于3~5‰之间,热液交代型铜矿床含硫矿物中δ34S的分布范围和峰值与矽卡岩型铜矿床有明显区别;砂岩型铜矿床中δ34S分布范围一般较广,峰值通常为较大的负值。硫同位素特征在湖南省铜矿床成矿作用研究中可以发挥更大的作用。 相似文献
6.
湖北金山店矽卡岩型铁矿田硫同位素特征及其地质意义 总被引：2，自引：1，他引：1
矿集区或矿田尺度硫同位素的空间分布特征研究不仅具有重要的理论意义,而且对找矿实践具有重要的指示作用。本文对金山店矿田范围内的矽卡岩型铁矿床开展了系统的硫同位素研究工作,发现该矿田内矽卡岩型铁矿床中的黄铁矿(+15. 1‰~+25. 6‰)、硬石膏(+24. 9‰~+31. 5‰)和石膏(+27. 5‰~+30. 4‰)均具有富集重硫同位素的特征,明显不同于岩浆热液矿床中这些矿物的δ~(34)S值组成特征,且硬石膏和石膏的δ~(34)S值与三叠系嘉陵江组地层中沉积石膏的δ34S值较为接近,暗示金山店矿田内矽卡岩型铁矿中的硫可能主要来自于含膏盐地层。含膏盐地层广泛参与了金山店矿田中矽卡岩型铁矿的成矿作用,对成矿作用产生了重要的影响:大量硫酸根(SO_4~(2-))的还原过程可以将成矿体系中的Fe~(2+)氧化成Fe~(3+),导致大量磁铁矿的形成;含膏盐地层与流体作用形成大量的盐溶角砾岩,有利于加速成矿流体与围岩之间的水岩作用,并提供容矿空间。系统的对比研究发现,大冶地区的矽卡岩型铁矿和矽卡岩型铁铜矿的赋矿地层、热液硬石膏/石膏规模和硫同位素值组成均存在明显的差异,暗示这些矿床的成矿围岩存在显著的差异。鄂东矿集区尺度的硫同位素等值线所揭示的空间变化规律具有重要的找矿指示作用:在天青石矿区(如狮子立山)或附近可能具有寻找大冶式矽卡岩型铁矿床或铁铜矿床的潜力,而在硬石膏/石膏发育的矽卡岩型铁矿区(如金山店铁矿田和程潮铁矿)或附近则具有寻找狮子立山式热液天青石矿床的潜力。 相似文献
7.
鄂东南地区大型矽卡岩型铁矿床金云母40Ar-39Ar同位素年龄及其构造背景初探 总被引：13，自引：7，他引：6
鄂东南地区铜铁多金属矿床是长江中下游地区金属成矿带的重要组成部分,但其精确的成矿时代和构造背景的研究显得较少.本文选择与磁铁矿密切共生的金云母为研究对象,利用40Ar-39Ar阶段加热同位素定年方法对该地区典型大型程潮和金山店矽卡岩铁矿床中金云母进行了成矿时代的研究,获得了金云母的40Ar-39Ar同位素坪年龄分别为132.6±1.4Ma和131.6±1.2Ma,对应等时线年龄为136±4Ma和132.0±2.8Ma.结合矿物共生组合特征和流体包裹体温度的分析,认为金云母的40Ar-39Ar坪年龄分别代表程潮和金山店矽卡型铁矿床的成矿时代,结果与大冶矽卡岩型铁矿床和鄂东南地区斑岩-矽卡岩型铜多金属矿床的成矿时代可以对比.在整合已有的岩石学、地球化学和地球物理学资料基础上,笔者认为鄂东南大型矽卡岩型铁矿床形成于区域岩石圈伸展和减薄构造环境. 相似文献
8.
青海双朋西金铜矿床成矿模式研究 总被引：1，自引：0，他引：1
双朋西金铜矿床位于西秦岭同仁-泽库成矿带,矿体呈透镜状、似层状产于印支期花岗闪长岩与石炭—二叠纪甘家组碳酸盐岩的外接触带矽卡岩中,是典型的矽卡岩型金铜矿床。矿石金属矿物以磁黄铁矿、黄铁矿、黄铜矿和褐铁矿为主;脉石矿物以石英、方解石、透闪石和透辉石为主。成矿作用经历了矽卡岩期、石英-硫化物期和表生作用期。稳定同位素研究表明:δD为-56‰～-49‰,δ18O为+9.2‰～+9.4‰,成矿流体为岩浆水,δ34S为+5.1‰～+6.6‰,显示S主要来源于深部岩浆。δ13C为-8.9‰～-8.4‰,代表δ13C主要来源于深部岩浆。依据矿床地质特征,结合同位素地球化学特征,初步建立了双朋西矽卡岩型金铜矿成矿模式,对该地区找矿评价工作具有一定的借鉴意义。 相似文献
9.
福建紫金山矿田浅成低温热液型矿床成矿物质来源探讨——H、O、S、Pb同位素地球化学证据 总被引：1，自引：0，他引：1
紫金山高硫型浅成低温热液型铜金矿床和悦洋低硫型浅成低温热液型银多金属矿床为紫金山矿田内2个典型矿床。为了确定矿床成矿流体和成矿金属来源,文章系统研究了2个矿床的H、O、S、Pb同位素组成特征。结果显示,在紫金山铜金矿床深部的铜矿脉中,6件石英的δDV-SMOW值为-62.0‰~-58.5‰,δ18OV-SMOW值为12.0‰~14.6‰,δ18OH2O值介于2.4‰~6.5‰;26件金属硫化物的δ34S值介于-13‰~2.9‰,峰值介于-5‰~1‰;16件金属硫化物的206Pb/204Pb值介于17.966~18.785,207Pb/204Pb值介于15.571~15.722,208Pb/204Pb值介于38.127~38.849。在悦洋矿区的矿脉中,1件石英样品的δDV-SMOW值为66.6‰;5件石英样品δ18OV-SMOW值介于10.0‰~13.7‰,δ18OH2O值介于-1.1‰~3.4‰;13件金属硫化物的δ34S值介于-6.8‰~-1.0‰,平均值-4‰;5件金属硫化物的206Pb/204Pb值介于18.405~18.521,207Pb/204Pb值介于15.620~15.685,208Pb/204Pb值介于38.587~38.863。H、O同位素特征显示,紫金山铜金矿床的成矿流体水主要来自岩浆水,混合少量大气降水;悦洋银矿床则以大气降水为主,有少量的岩浆水加入。硫化物的S和Pb同位素特征显示,紫金山铜金矿床的成矿物质主要来源于早白垩世岩浆岩,悦洋银矿床的成矿物质主要来源于围岩及早白垩世岩浆岩。 相似文献
10.
内蒙古金厂沟梁金矿床稳定同位素组成和矿床成因讨论 总被引：7，自引：0，他引：7
稳定同位素的研究对于分析矿床成因、阐明成矿物质来源等具有重要意义。金厂沟梁金矿成矿流体的同位素组成与本区变质岩、岩浆岩的同位素组成具有非常密切的关系,成矿流体的H、O、C、S同位素特征继承了本区变质岩、岩浆岩的H、O、C、S同位素特征,它们的δ18O、δD、δ13C、δ34S值具有相似的变化范围,其同位素的变化规律表明变质岩是本区成矿物质的母岩。本区岩浆构造活动频繁,为成矿物质活化提供了动力条件。成矿模式为本区太古宙变质岩经过多次活化,使成矿物质逐步聚集,到了燕山晚期,岩浆期后热液活动将成矿物质带到构造有利部位聚集形成了金矿床,因此,该矿床属重熔岩浆热液型矿床。 相似文献
11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
12.
针对兖州煤田下组煤深部开采受奥灰高承压水威胁以及当地大型煤化工企业生产用水量大的现状,在已进行的水文地质勘探及放水试验基础上,评价奥灰富水性,并采用有限差分法进行奥灰疏水降压数值模拟研究,提出水煤共采观点。研究结果表明:兖州煤田深部奥灰水压高,合理布置水煤共采孔,可以实现奥灰水位的有效疏降,疏降中心区水位最大降深可达110 m,突水系数显著下降,提高了下组煤开采的安全性;同时可提供煤化工43200 m3/d的供水量,能达到可持续的、水资源保护性的供水效果,实现下组煤的水煤共采。 相似文献
13.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
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16.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
17.
The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements. 相似文献
18.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
19.
Todd Dunn 《Contributions to Mineralogy and Petrology》1987,96(4):476-484
The crystal/liquid partition coefficients of Lu, Hf, Ti, Mn and Ca have been measured between olivine, clinopyroxene and basaltic melt. The Ti, Mn, and Ca partition coefficients were determined at natural abundance levels. The Lu and Hf partition coefficients were determined at doping levels ranging from 0.5 to 1.5 wt% “trace element” as oxide in order to allow analysis by electron microprobe. Olivine/liquid partition coefficients for Lu, Hf, Ti, Mn, and Ca were determined at 1 bar and temperatures from 1150 to 1177° C. Clinopyroxene/liquid partition coefficients were determined for Lu, Hf, Ti, and Mn at pressures of 10, 15, and 20 kbars and temperatures from 1250 to 1290° C. The olivine/liquid partition coefficients of Hf, Lu, Ti, and Ca are small. D(Hf-ol) is zero within the analytical uncertainty. Both D(Lu-ol) and D(Mn-ol) decrease with increasing temperature, but D(Ti-ol) and D(Ca-ol) are constant over the narrow temperature range studied. The partition coefficient results are summarized below.
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20.
Stratiform quartz-sulphide lodes in Ingladhal occur in a typical Precambrian green-stone-belt environment comprising metabasalts, tuff, chert and cherty iron-sulphide formation. Unusually high cobalt contents of metavolcanics and of sulphide minerals in orebodies suggest a consanguinity between ores and rocks. 90% of total nickel, 70% of total cobalt but only 30% of total copper in rocks occur in silicate phases and thus indicate an early separation of copper from cobalt and nickel. Unusually high non-sulphide copper in barren bedded cherts implies availability of Cu-rich solution prior to their lithification. Pyrite in sediments, in volcanics, and in orebodies is characterized by a distinctive pattern of Co-Ni distribution in each case. Partitioning of Co and Ni between coexisting sulphide pairs is complex, but gross equilibrium is indicated. Very high trace metal content of orebody pyrite sharply contrasts with very low such values in pyrite from adjacent sediments and points to a higher temperature of formation of orebodies. 相似文献
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