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1.
In the central and eastern part of the Northern Calcareous Alps, Upper Permian evaporitic rocks form a tectonic mélange whose distribution is restricted largely to the topmost thrust unit (Juvavicum). Mudrock and dolostone samples associated with the evaporites in ten major outcrops (mostly mines) were examined in order to constrain the paleothermal conditions of the mélange. Measurements of illite "crystallinity" reveal a regionally variable pattern of metamorphic grade ranging from diagenesis to the high anchizone and possibly epizone. Most samples contained very little organic matter and vitrinite particles were rare. Samples containing vitrinite show consistent minimum reflectance values of ～1.3–1.7% Ro, whereas maximum reflectance values are more variable (up to 4.9%). The former data constrain the minimum burial temperatures to ～160–180°C. The observed variability in illite "crystallinity" and organic maturity both between and within individual outcrops is consistent with the mélange architecture of this unit and is in good agreement with the regional thermal pattern recognized in Middle to Upper Triassic carbonate formations within the Juvavicum by conodont color alteration studies. Mélange formation and heating of the evaporites is suggested to be linked to the Upper Jurassic closure of the Meliata-Hallstatt Ocean and subsequent thrusting of obducted terranes (Juvavicum) into the depositional realm of the Northern Calcareous Alps.  相似文献   

2.
The Himalia Ridge Formation (Fossil Bluff Group), AlexanderIsland is a 2·2-km-thick sequence of Upper Jurassic–LowerCretaceous conglomerates, sandstones and mudstones, derivedfrom an andesitic volcanic arc and deposited in a fore-arc basin.The metamorphic and thermal history of the formation has beendetermined using authigenic mineral assemblages and vitrinitereflectance measurements. Metamorphic effects include compaction,pore-space reduction, cementation and dissolution and replacementof detrital grains by clay minerals (smectite, illite/smectite,corrensite and kaolinite), calcite, chlorite, laumontite, prehnite,pumpellyite, albite and mica, with less common quartz, haematite,pyrite and epidote. The authigenic mineral assemblages exhibita depth-dependence, and laumontite and calcite exhibit a strongantipathetic relationship. Detrital organic matter in the argillaceouslayers has vitrinite reflectance values (Ro) ranging from 2·3to 3·7%. This indicates considerable thermal maturation,with a systematic increase in reflectivity with increasing depth.There is good correlation of metamorphic mineral assemblageswith chlorite crystallinity and vitrinite reflectance values—allindicating temperatures in the range of 140 ± 20°Cat the top of the sequence to 250 ± 10°C at the baseof the sequence. The temperatures suggest a geothermal gradientof 36–64°C/km and a most likely gradient of 50°C/km.It is suggested that this higher-than-average gradient for afore-arc basin resulted either from rifting during basin formationor from a late-stage arc migration event. KEY WORDS: Antarctica; diagenesis; fore-arc basin; low-temperature metamorphism; vitrinite reflectance  相似文献   

3.
The chemical and isotopic compositions of clay minerals such as illite and chlorite are commonly used to quantify diagenetic and low-grade metamorphic conditions, an approach that is also used in the present study of the Monte Perdido thrust fault from the South Pyrenean fold-and-thrust belt. The Monte Perdido thrust fault is a shallow thrust juxtaposing upper Cretaceous–Paleocene platform carbonates and Lower Eocene marls and turbidites from the Jaca basin. The core zone of the fault, about 6 m thick, consists of intensely deformed clay-bearing rocks bounded by major shear surfaces. Illite and chlorite are the main hydrous minerals in the fault zone. Illite is oriented along cleavage planes while chlorite formed along shear veins (<50 μm in thickness). Authigenic chlorite provides essential information about the origin of fluids and their temperature. δ18O and δD values of newly formed chlorite support equilibration with sedimentary interstitial water, directly derived from the local hanging wall and footwall during deformation. Given the absence of large-scale fluid flow, the mineralization observed in the thrust faults records the P–T conditions of thrust activity. Temperatures of chlorite formation of about 240°C are obtained via two independent methods: chlorite compositional thermometers and oxygen isotope fractionation between cogenetic chlorite and quartz. Burial depth conditions of 7 km are determined for the Monte Perdido thrust reactivation, coupling calculated temperature and fluid inclusion isochores. The present study demonstrates that both isotopic and thermodynamic methods applied to clay minerals formed in thrust fault are useful to help constrain diagenetic and low-grade metamorphic conditions.  相似文献   

4.
Based on the tested data of pressure and vitrinite reflectance of some wells in sedimentary basins, abnormal high pressure is regarded as not the only factor to retard the increase of vitrinite reflectance (R o). Apart from the types of the organic matter, the physical environment (temperature and pressure) and chemical environment (fluid composition and inorganic elements) will result in the abnormal vitrinite reflectance values in the sedimentary basins. This paper tested trace elements and vitrinite reflectance data from the the abnormal high pressure and normal pressure strata profiles, respectively, and found that the acidic and lower salinity starta are favorable for the increase of R o. By discussing the corresponding relationship between the contents of some trace elements in the mudstone and the vitrinite reflectance values, the typical trace elements were found to suppress and/or catalyze the vitrinite reflectance of organic matter, while the elements of Ca, Mn, Sr, B, Ba and P may result in the retardation of R o. However, elements of Fe, Co, Zn, Ni and Rb may catalyze the organic matter maturation. This study is conductive to the organic maturation correction, oil and gas assessment and thermal history reconstruction by the paleothermometry. Translated from Acta Geologica Sinica, 2006, 80(11): 1760–1769 [译自: 地质学报]  相似文献   

5.
The Macraes orogenic gold deposit is hosted by a graphitic micaceous schist containing auriferous porphyroblastic sulphides. The host rock resembles zones of unmineralised micaceous graphitic pyritic schists, derived from argillaceous protoliths, that occur locally in background pelitic Otago Schist metasediments. This study was aimed at determining the relationship between these similar rock types, and whether the relationship had implications for ore formation. Argillites in the protolith turbidites of the Otago Schist metamorphic belt contain minor amounts of detrital organic matter (<0.1 wt.%) and diagenetic pyrite (<0.3 wt.% S). The detrital organic carbon was mobilised by metamorphic–hydrothermal fluids and redeposited as graphite in low-grade metaturbidites (pumpellyite–actinolite and greenschist facies). This carbon mobility occurred through >50 million years of evolution of the metamorphic belt, from development of sheared argillite in the Jurassic, to postmetamorphic ductile extension in the Cretaceous. Introduced graphite is structurally controlled and occurs with metamorphic muscovite and chlorite as veins and slicken-sided shears, with some veins having >50% noncarbonate carbon. Graphitic foliation seams in low-grade micaceous schist and metamorphic quartz veins contain equant graphite porphyroblasts up to 2 mm across that are composed of crystallographically homogeneous graphite crystals. Graphite reflectance is anisotropic and ranges from ~1% to ~8% (green light). Texturally similar porphyroblastic pyrite has grown in micaceous schist (up to 10 wt.% S), metamorphic quartz veins and associated muscovite-rich shears. These pyritic schists are weakly enriched in arsenic (up to 60 ppm). The low-grade metamorphic mobility and concentration of graphite in micaceous schists is interpreted to be a precursor process that structurally and geochemically prepared parts of the Otago Schist belt for later (more restricted) gold mineralisation. Economic amounts of gold, and associated arsenic, were subsequently introduced to carbonaceous sulphidic schists in the Macraes gold deposit by a separate metamorphic fluid derived from high-grade metaturbidites. Fluid flow at all stages in these processes occurred at metamorphic rates (mm/year), and fluids were broadly in equilibrium with the rocks through which they were passing.  相似文献   

6.
使用Renishaw System-1000型激光拉曼光谱仪, 研究了大兴安岭北部上古生界泥质岩石碳质物的拉曼光谱特征及其对形成温度的表征, 探讨了拉曼光谱参数与镜质体反射率(Ro)的关系。研究表明:研究区上古生界泥质岩石碳质物不具有石墨的拉曼光谱谱带吸收峰, 揭示了地层的变质程度未达到低绿片岩相。利用此次经过完善建立的拉曼光谱地质温度计, 对大兴安岭北部上古生界泥质岩石变质温度的估算结果主要为270~320℃, 表明研究区上古生界遭受了极低级变质作用, 变质程度属近变质带。依据碳质物拉曼光谱参数与镜质体反射率的相互关系, 估算研究区有机质成熟度的Ro值主要分布为3.03%~4.23%, 与实测Ro值吻合, 表明有机质演化处于过成熟阶段, 泥质岩石具有生烃的能力, 部分层位可能具有形成油气资源的潜力。  相似文献   

7.
A worldwide dataset of organic material from 553 samples belonging to coal and carbonaceous materials was used to analyze the evolution of hydrogen index (HI) and bitumen index (BI) with increasing thermal maturity. Basic statistical analyses were applied to detect the boundary lines of HImax and BImax in delineating the upper and lower limits of the HI and BI bands for the majority of samples. In addition, cross-plots of HI or BI versus maturity (Ro% and T max) also provide criteria for defining the HImax and BImax boundary lines. The constructed HI and BI bands are broad at low maturities and become narrower with increasing thermal maturities. The petroleum generation potential is completely exhausted at the vitrinite reflectance of 2.0–2.2% or T max of 510–520°C. An increase in HI implies extra petroleum generation which was related to changes in structure of organic materials. A declining BI means that the oil expulsion window starts to occur at the vitrinite reflectance range of 0.75–1.05%. The petroleum potential can be divided into four different areas based on the cross-plot of HI versus Ro%. The highest petroleum potential area is located in section II with Ro = 0.6–1.0% and HI > 100. The oil generation potential is rapidly exhausted at section III with Ro > 1.0%. This result is also in accordance with the result of curve regression of HI versus Ro% based on 80 samples with Ro = 1.02–3.43% (R 2 = 0.72). Overall, the total oil window can be extended up to Ro = ~1.25–1.95%. Finally, in the cross-plots of S1 versus S2, shale or C-shale exhibits a higher and slowly decreased slope, compared with a lower and then sharply increased slope of coal samples, which is attributable to their compositional difference in organic material.  相似文献   

8.
Paleoproterozoic carbonaceous shales in the Tim-Yastrebovskii ancient rift, which underwent zonal metamorphism at 350–550°C, contain REE mineralization of silicates (allanite, thorite, and Ce-P huttonite) fluorcarbonates (bastnaesite and synchysite), phosphates (monazite and xenotime), and REE-bearing apatite. The reason for the wide occurrence of bastnaesite and other REE minerals is relatively high REE concentrations in the sulfide-bearing carbonaceous shales, with these elements accumulated in the organic matter in the course of diagenesis. Reaction textures with REE-bearing chlorite, bastnaesite, and allanite suggest that REE-bearing chlorite and bastnaesite provided REE for the forming of higher temperature allanite and monazite. This is corroborated by the REE patterns of the monazite, allanite, and bastnaesite, which are almost identical and are characterized by the strong predominance of LREE. The replacements of REE minerals during metamorphism at 350–550°C took place via a number successive transitions: (1) Mnz → Aln, Chl REE → Bst, Chl REE → Aln, Bst → Aln and (2) Bst → Mnz and Ap LREE → Mnz. These replacements can be accounted for by prograde metamorphic reactions.  相似文献   

9.
Summary ?Corundum-bearing amphibolites are part of the metamorphic basement of the Krivaja–Konjuh ultramafic massif in the Dinaride Ophiolite Zone in Bosnia. Pinkish corundum occurs as porphyroblasts and together with edenitic–pargasitic hornblende and anorthite within the amphibolites. Based on major and trace element contents, the protoliths of the corundum-bearing amphibolites were tholeiitic gabbro cumulates. Geothermobarometric estimations on the corundum-bearing amphibolites yielded preliminary P–T conditions of 620–830 °C and 6–10 kbar for amphibole and plagioclase inclusions inside corundum and 4.5–8 kbar for the main metamorphic assemblage. These estimates are thought to reflect the metamorphic conditions achieved during the Late Jurassic obduction of the Krivaja–Konjuh ultramafic massif onto ophiolite mélange. This study documents the mineralogy, petrology and geochemistry of these unusual corundum-bearing ophiolite-related edenite–pargasitic amphibolites. Received June 20, 2002; accepted October 22, 2002  相似文献   

10.
The upper part of Madbi Formation organic-rich shale is considered an important regional source rock in the Masila Basin, Yemen. Ten cutting samples from this Upper Jurassic organic-rich shale were collected from wells drilled in the Kharir Oilfield, Masila Basin in order to geochemically assess the type of organic matter, thermal maturity and depositional environment conditions. Results reveal that Upper Jurassic organic-rich shale samples contain high organic matter more than 2.0 wt.% TOC and have very good to excellent hydrocarbon potential. Marine algae organic matter is the main source input for the Upper Jurassic shale sequence studied. This has been identified from organic petrographic characteristics and from the n-alkane distributions, which dominated by n-C14-n-C20 alkanes. This is supported by the high value of the biomarker sterane/hopane ratio that approaches unity, as well as the relatively high C27 sterane concentrations. A mainly suboxic depositional environment is inferred from pr/ph ratios (1.75–2.38). This is further supported by relatively high homohopane value, which is dominated by low carbon numbers and decrease towards the C35 homohopane. The concentrations of C35 homohopane are very low. The depositional environment conditions are confirmed by some petrographic characteristics (e.g. palynofacies). Detailed palynofacies analysis of Madbi shales shows that the Madbi shale formation is characterised by a mix of amorphous organic matter, dinoflagellates cysts and phytoclasts, representing a suboxic, open marine setting. The Upper Jurassic marine shale sequence in the Masila Basin is thermally mature for hydrocarbon generation as indicated by biomarker thermal maturity parameters. The 22 S/22 S + 22R C32 homohopane has reached equilibrium, with values range from 0.58 to 0.62 which suggest that the Upper Jurassic shales are thermally mature and that the oil window has been reached. 20 S/(20 S + 20R) and ββ/(ββ + αα) C29 sterane ratios suggest a similar interpretation, as do the moretane/hopane ratio. This is supported by vitrinite reflectance data ranging from 0.74% to 0.90%Ro and thermal alteration of pollen and spore. The thermal alteration index value is around 2.6–3.0, corresponding to a palaeotemperature range of 60–120°C. These are the optimum oil-generating strata. On the basis of this study, the Madbi source rock was deposited under suboxic conditions in an open marine environment and this source rock is still within the oil window maturity range.  相似文献   

11.
The Kenting Mélange on the Hengchun Peninsula, Taiwan, formed through tectonic shearing of subduction complex lithologies, probably within the plate boundary subduction channel between the Eurasian and Philippine Sea plates, with further deformation and exhumation in the Pliocene–Pleistocene during arc–continent collision. Field relations reveal a structural gradation from normal stratified turbidite sequence (Mutan Formation) through broken formation to highly sheared Kenting Mélange containing allochthonous polygenic blocks. This gradation is consistent with an increase of average vitrinite reflection values from ~ 0.72% in the Mutan Formation through ~ 0.93% in the broken formation to ~ 0.99% in the mélange, suggesting temperatures of at least 140 °C during formation of the Kenting Mélange. Zircons from gabbro in the Kenting Mélange are dated as 25.46 ± 0.18 Ma, which together with geochemical data constrains the source to South China Sea oceanic lithosphere. In combination with the field relationships, vitrinite reflectance values, microfossil stratigraphy, and offshore geophysical data from S and SE Taiwan, we propose that the Kenting Mélange initially formed at the subduction plate boundary from off-scraped trench deposits. Minor Plio–Pleistocene microfossils (< 5%) occur within the mélange in proximity to slope basin of equivalent age and were likely sheared into the mélange during out-of-sequence thrusting associated with active arc–continent collision, which in the Hengchun Peninsula commenced after 6.5 Ma.  相似文献   

12.
 The kinematic pattern and associated metamorphism of the predominant ductile deformation and the subsequent deformational stages of the Serbomacedonian metamorphic rocks and granitoids are presented in terms of peri-Tethyan tectonics. A systematic record of structural and metamorphic data gives evidence of a main top-to-ENE to ESE ductile flow of Cretaceous age (120–90 Ma) associated with a crustal stretching and unroofing. A subordinate WSW to WNW antithetic sense of movement of the tectonic top is observed in places. The associated metamorphic conditions are estimated at 4.5–7.5 kbar and 510–580  °C. During Eocene to Miocene times these fabrics were successively deformed by low-angle extensional De ductile shear zones with top-to-NE and SW sense of movement and brittle shear zones of similar kinematic pattern, suggesting a transition from ductile to brittle deformation. De deformation was accompanied during its later stages by NW/SE-directed shortening. We also discuss the relation of this Cretaceous–Tertiary deformation of the Serbomacedonian metamorphic rocks with the Eocene to Miocene ductile, top-to-southwestward crustal shear of the adjacent Rhodope crystalline rocks. We regard the Serbomacedonian and the Rhodope metamorphic rocks to represent related metamorphic provinces, the most recent exhumation and cooling history of which is bracketed between the Eocene and Neogene. Received: 8 December 1998 / Accepted: 19 April 1999  相似文献   

13.
Partial melting of subducted oceanic crust has been identifiedin the Sierra del Convento mélange (Cuba). This serpentinite-matrixmélange contains blocks of mid-ocean ridge basalt (MORB)-derivedplagioclase-lacking epidote ± garnet amphibolite intimatelyassociated with peraluminous trondhjemitic–tonalitic rocks.Field relations, major element bulk-rock compositions, mineralassemblages, peak metamorphic conditions (c. 750°C, 14–16kbar), experimental evidence, and theoretical phase relationssupport formation of the trondhjemitic–tonalitic rocksby wet melting of subducted amphibolites. Phase relations andmass-balance calculations indicate eutectic- and peritectic-likemelting reactions characterized by large stoichiometric coefficientsof reactant plagioclase and suggest that this phase was completelyconsumed upon melting. The magmatic assemblages of the trondhjemitic–tonaliticmelts, consisting of plagioclase, quartz, epidote, ±paragonite, ± pargasite, and ± kyanite, crystallizedat depth (14–15 kbar). The peraluminous composition ofthe melts is consistent with experimental evidence, explainsthe presence of magmatic paragonite and (relict) kyanite, andplaces important constraints on the interpretation of slab-derivedmagmatic rocks. Calculated P–T conditions indicate counterclockwiseP–T paths during exhumation, when retrograde blueschist-faciesoverprints, composed of combinations of omphacite, glaucophane,actinolite, tremolite, paragonite, lawsonite, albite, (clino)zoisite,chlorite, pumpellyite and phengite, were formed in the amphibolitesand trondhjemites. Partial melting of subducted oceanic crustin eastern Cuba is unique in the Caribbean realm and has importantconsequences for the plate-tectonic interpretation of the region,as it supports a scenario of onset of subduction of a youngoceanic lithosphere during the early Cretaceous (c. 120 Ma).The counterclockwise P–T paths were caused by ensuingexhumation during continued subduction. KEY WORDS: amphibolite; Cuba; exhumation; partial melting; trondhjemite; subduction  相似文献   

14.
Disseminated carbon has been extracted from 19 samples of arkosic rocks from the chlorite, biotite and garnet zones in the Narragansett basin, and analysed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD of these samples yields only the (002) peak which may be as much as four times wider than the silicon internal standard peak and is always skewed to low angles 2θ. All (002) peaks were digitized and the four moments calculated. The results suggest that width at half-height (W1/2) provides a poorer estimate of peak shape than coefficients of skewness and kurtosis. The positive correlation of these coefficients with grain size determined by SEM in the range of 0.1–100 μm suggest a direct relationship between peak shape and grain size. No variable measured in this study correlates with metamorphic grade. However, W1/2, skewness and kurtosis of the (002) diffraction peak of the carbonaceous material in the biotite and garnet zones correlates inversely with modal carbon. This suggests that the volatilization reaction: C+2H2=CH4 may be an important step in the mechanism of graphitization. Variable fugacities of H2 and CH4 and/or variable permeabilities may be responsible for the non-uniform development of graphite crystallinity in the greenschist facies rocks in Rhode Island.  相似文献   

15.
Brecciated mafic+ultramafic plutonic rocks of the East Taiwan Ophiolite occur as detritus and slide blocks in the Pliocene Lichi Mélange. These plutonic rocks have been subjected to two stages of post-magmatic recrystallization: (I) pre-brecciation ridge-type metamorphism attended by high-grade greenschist and rare amphibolite facies physical conditions; and (II) later off-axis metamorphism under zeolite to lowest greenschist facies conditions that postdated brecciation, submarine talus accumulation and deposition of associated pelagic sediments. The effects of the earlier ridge metamorphism are the main concern of this paper. (I) Dominant antigorite together with chlorite and talc in some ultramafics suggests that these rocks recrystallized at T>350 ° C. The primary compositions of gabbroic calcic plagioclase have been modified from An 45–70 to An 13–38, and the igneous clinopyroxenes and hornblendes partly replaced by actinolite+chlorite. Stable mineral assemblages in the metagabbros are thus ∼oligoclase+actinolite+chlorite±very rare epidote+sphene, and intermediate plagioclase +actinolite+chlorite+sphene. Amphibolites are less common and consist of more calcic plagioclase (An 25–49)+hornblende. The presence of assemblages transitional between greenschist and amphibolite facies for basaltic compositions is suggestive of very low-pressure thermal metamorphism such as would be appropriate to the crustal portions of an oceanic spreading center. (II) The occurrence of vein albite+actinolite+ chlorite near the base of the brecciated plutonic sequence and vein prehnite+laumontite in the upper part suggests that the brecciated plutonic rocks were later feebly retrograded under conditions of the greenschist and zeolite facies respectively-probably some distance removed from the thermal regime of a mid-oceanic ridge. The East Taiwan Ophiolite probably represents the western termination of the Philippine Sea lithospheric plate. Portions of this oceanic crust and underlying mantle were incorporated in the Lichi Mélange of the Coastal Range of eastern Taiwan as a consequence of antithetic faulting and erosion. This process evidently accompanied east-directed underflow of the Asiatic (South China Sea) plate.  相似文献   

16.
Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.  相似文献   

17.
Reconstruction of Mesozoic and Cenozoic sedimentary ‘cover’ on the Precambrian shield in the Lac de Gras diamond field, Northwest Territories, Canada, has been achieved using Cretaceous and early Tertiary sedimentary xenoliths and contemporaneous organic matter preserved in volcaniclastic sediments associated with late Cretaceous to early Tertiary kimberlite pipe intrusions, and in situ, Eocene crater lake, lacustrine and peat bog strata. Percent reflectance in oil (%Ro) of vitrinite within shale xenoliths for: (i) Albian to mid-Cenomanian to Turonian ranges from > 0.27 to 0.42 %Ro (mean = 0.38 %Ro), (ii) Maastrichtian to early Paleocene from 0.24 to < 0.30%; (iii) latest Paleocene to early middle Eocene 0.15 to < 0.23 %Ro (mean = 0.18 %Ro). These levels of thermal maturity are corroborated by Rock Eval pyrolysis Tmax (°C) and VIS region fluorescence of liptinites, with wavelengths of maximum emission for sporinite, prasinophyte alginite and dinoflagellates consistent with vitrinite reflectance of 0.20 to < 0.50 %Ro. Burial–thermal history modeling, constrained by measured vitrinite reflectance and porosity of shale xenoliths, predicts a maximum burial temperature for Mid to Late Albian strata (∼115 Ma) of 60 °C with ∼1.2 to 1.4 km of Cretaceous strata in the Lac de Gras kimberlite field region prior to major uplift and erosion, which began at 90 Ma. Late Paleocene to middle Eocene volcanic crater lake lacustrine to peat bog strata were only buried to a few hundreds of meters and are in a peat-brown coal stage of thermal maturation.  相似文献   

18.
Magnesian metamorphic rocks with metapelitic mineral assemblage and composition are of great interest in metamorphic petrology for their ability to constrain P–T conditions in terranes where metamorphism is not easily visible. Phase–assemblage diagrams for natural and model magnesian metapelites in the system KFMASH are presented to document how phase relationships respond to water activity, bulk composition, pressure and temperature. The phase assemblages displayed on these phase diagrams are consistent with natural mineral assemblages occurring in magnesian metapelites. It is shown that the equilibrium assemblages at high pressure conditions are very sensitive to a(H2O). Specifically, the appearance of the characteristic HP assemblage chloritoid–talc–phengite–quartz (with excess H2O) in the magnesian metapelites of the Monte Rosa nappe (Western Alps) is due to the reduction of a(H2O). Furthermore, the mineral assemblages are determined by the whole-rock FeO/(FeO+MgO) ratio and effective Al content X A as well as P and T. The predicted mineral associations for the low- and high-X A model bulk compositions of magnesian metapelites at high pressure are not dependent on the X A variations as they show a similar sequence of mineral assemblages. Above 20 kbar, the prograde sequence of assemblages associated with phengite (with excess SiO2 and H2O) for low- and high-X A bulk compositions of magnesian metapelites is: carpholite–chlorite → chlorite–chloritoid → chloritoid–talc → chloritoid–talc–kyanite → talc–garnet–kyanite → garnet–kyanite ± biotite. At low to medium P–T conditions, a low-X A stabilises the phengite-bearing assemblages associated with chlorite, chlorite + K-feldspar and chlorite + biotite while a high-X A results in the chlorite–phengite bearing assemblages associated with pyrophyllite, andalusite, kyanite and carpholite. A high-X A magnesian metapelite with nearly iron-free content stabilises the talc–kyanite–phengite assemblage at moderate to high P–T conditions. Taking into account the effective bulk composition and a(H2O) involved in the metamorphic history, the phase–assemblage diagrams presented here may be applied to all magnesian metapelites that have compositions within the system KFMASH and therefore may contribute to gaining insights into the metamorphic evolution of terranes. As an example, the magnesian metapelites of the Monte Rosa nappe have been investigated, and an exhumation path with P–T conditions for the western roof of the Monte Rosa nappe has been derived for the first time. The exhumation shows first a near-isothermal decompression from the Alpine eclogite peak conditions around 24 kbar and 505°C down to approximately 8 kbar and 475°C followed by a second decompression with concomitant cooling.M. Frey: deceased  相似文献   

19.
The andesitic early Oligocene Taveyanne metagreywacke of the Helvetic nappes of western Switzerland shows an increase of metamorphic grade from zeolite facies through lower greenschist facies. Electron microprobe analysis, fluid inclusion thermometry, stable isotope analysis, coal rank, illite and chlorite crystallinity and thermodynamic calculations were carried out to determine metamorphic conditions. Evaluation of all techniques used in this study suggest that only combinations of different parameters yield reliable information to constrain very low-grade metamorphic conditions. Electron microprobe analyses are presented for actinolite, chlorite, epidote, phengite, laumontite, prehnite, pumpellyite, and titanite. With increasing metamorphic grade, chlorite is enriched in tetrahedral Al, pumpellyite becomes poorer in Fetot and more homogeneous in chemical composition, and titanite tends to incorporate Ti at the expense of Al and Fe3+. Metamorphic P-T conditions were determined by a combination of fluid inclusion microthermobarometry, stable isotope thermometry on quartz-calcite veins, chlorite “geothermometry” and thermodynamic calculations. Peak temperatures range from 210–250 °C for zeolite facies to 270–300 °C for prehnite-pumpellyite facies to 300–360 °C for pumpellyite-actinolite facies. An evaluation of 289 chlorite analyses indicates that the tetrahedral Al content is negatively correlated with the saponite component. Temperatures derived from chlorite “geothermometry” match maximum temperature conditions mentioned above. Illite crystallinity data for shales and slates intercalated with the Taveyanne metagreywacke indicate that the diagenetic zone correlates with the zeolite facies, the upper anchizone with the prehnite-pumpellyite facies, and the lower epizone with the pumpellyite-actinolite facies. A comparison of coal rank and illite crystallinity data (n=12,r=0.91) yielded R max values of 2.9 and 5.5% for the lower and upper boundary of the anchizone, respectively. Received: 2 August 1996 / Accepted: 16 July 1997  相似文献   

20.
The Amassia–Stepanavan blueschist-ophiolite complex of the Lesser Caucasus in NW Armenia is part of an Upper Cretaceous-Cenozoic belt, which presents similar metamorphic features as other suture zones from Turkey to Iran. The blueschists include calcschists, metaconglomerates, quartzites, gneisses and metabasites, suggesting a tectonic mélange within an accretionary prism. This blueschist mélange is tectonically overlain by a low-metamorphic grade ophiolite sequence composed of serpentinites, gabbro-norite pods, plagiogranites, basalts and radiolarites. The metabasites include high-P assemblages (glaucophane–aegirine–clinozoisite–phengite), which indicate maximal burial pressure of ∼1.2 GPa at ∼550°C. Most blueschists show evidence of greenschist retrogression (chlorite—epidote, actinolite), but locally epidote-amphibolite conditions were attained (garnet—epidote, Ca/Na amphibole) at a pressure of ∼0.6 GPa and a temperature of ∼500°C. This LP–MT retrogression is coeval with exhumation and nappe-stacking of lower grade units over higher grade ones. 40Ar/39Ar phengite ages obtained on the high-P assemblages range between 95 and 90 Ma, while ages obtained for epidote-amphibolite retrogression assemblages range within 73.5–71 Ma. These two metamorphic phases are significant of (1) HP metamorphism during a phase of subduction in the Cenomanian–Turonian times followed by (2) exhumation in the greenschist to epidote-amphibolite facies conditions during the Upper Campanian/Maastrichtian due to the onset of continental subduction of the South Armenian block below Eurasia.  相似文献   

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